Surface phenomena in the structural and mechanical behaviour of solid polymers:
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| Main Authors: | , |
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| Format: | Book |
| Language: | English |
| Published: |
Boca Raton ; London ; New York
CRC Press
[2016]
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | viii, 525 Seiten Illustrationen, Diagramme |
| ISBN: | 9781498743686 1498743684 |
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Record in the Search Index
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| adam_text | Titel: Surface phenomena in the structural and mechanical behaviour of solid polymers
Autor: Volynskiĭ, Aleksandr Lʹvovich
Jahr: 2016
ix 1 9 12 19 29 33 36 41 41 45 49 56 58 63 68 79 81 81 88 Contents Abbreviations Preface Development of the interfacial surface in deformation of polymers The method for visualisation of structural rearrangements taking place during the variation of the surface area of deformed polymers Visualisation of structural rearrangements accompanying the development of the interfacial surface in deformation of rubbery polymers Visualisation of structural rearrangements taking place during annealing of amorphous polymers oriented above the glass transition temperature Rolling of glassy polycarbonate Structural rearrangement in the deformed polymer in the conditions of isometric heating Healing of the interfacial surface in polymer systems Healing of the interfacial surfaces in rubbery polymers Healing of the interfacial surface in glassy polymers Heterophase healing of polymer interfaces Heterochemical healing of the polymer-polymer interfaces Monolithization of powders Healing of the interfaces produced upon fracture of glassy polymers Healing of the interfacial surface in deformed polymers Special features of the structure and properties of surface layers and thin (nanometric) films of glassy polymers Measurement of the glass transition temperature of amorphous glassy polymers in thin films and thin surface layers Glass transition temperature of thin films of glassy polymers, deposited on solid substrates The glass transition temperature of free-standing thin films of glassy polymers Measurement of the glass transition temperature and
vi Contents molecular mobility in surface layers of bulk glassy polymers 90 3.5. Interaction of metal nanoparticles with polymer surfaces 91 3.6. Possible reasons for the decrease of the glass transition temperature in thin films and surface layers of amorphous polymers 99 4. Role of surface phenomena in shear yielding of glassy polymers 108 4.1. Thermal ageing of polymer glasses 110 4.2. The main features of the effect of thermal ageing on the properties of glassy polymers 111 4.4. Physical ageing and the structure of glassy polymers 114 4.4. Molecular mechanism of thermal ageing of glassy polymers 120 4.5. Effect of mechanical action on the process of physical ageing of polymer glasses 124 4.6. Properties of glassy polymers subjected to mechanical effects 126 4.7. The spatial inhomogeneity of deformation of polymer glasses 137 4.8. Structure of shear bands formed during deformation of glassy polymers 147 4.9. The nature of structural-mechanical anomalies in the properties of deformed glassy polymers 152 5. Role of surface phenomena in the strain softening of glassy and crystalline polymers 176 5.1. Strain softening of polymer systems, taking place without the formation of porosity 177 5.2. Strain softening of glassy polymers 180 5.3. Factors causing force softening of glassy polymers during crazing 187 5.4. Strain softening of crystalline polymers 190 5.5. Mechanism of strain softening of crystalline polymers 199 6. Role of surface phenomena in deformation of polymers in active liquid media 216 6.1. What is the adsorption-active medium? 217 6.2. Structural special features of deformation of polymers in adsorption-active media 227 6.3. Crazing in liquid media - manifestation of the Rehbinder effect in polymers 228 6.4. Mechanism of the formation of the unique structure of crazes 229 6.5. Crazing dynamics of polymers in liquid media 232 6.6. Main factors determining the dynamics of crazing of the polymer in the AAM
245 6.7. The multiplicity factor of the number of areas of localised
vii 249 251 254 259 276 276 292 308 310 320 320 339 341 343 355 364 364 365 368 370 374 389 400 407 410 415 Contents plastic deformation Relationship of the crazing dynamics of polymers in liquid media with the fine structure of crazes Crazing mechanism of polymers in liquid media Delocalized crazing of the polymers in liquid media The structure and properties of crazed polymers Structural-mechanical aspects of deformation of crazed polymers Thermomechanical properties of crazed polymers Colloidal swelling Adsorption properties of the crazed polymers Multiphase nanodispersed systems based on crazed polymers Interaction of low-molecular substances with the highly developed surface of the crazed polymer Polymer-polymer nanomixtures based on crazed polymers Crazing as a method of producing nanosized porosity in polymers Special features of production of polymer-polymer nanocomposite by polymerisation in situ in a crazed polymer matrix Direct addition of the second polymer component to the crazed polymer matrix Instability and self-organisation of polymer surfaces Special features of the development of interfacial surfaces during the flow of polymer melts and solutions Loss of stability and dispersion in flow and during phase separation in polymer systems Inhomogeneous swelling of polymers Electrodynamic and thermomechanical instability of polymer surfaces Polymers with thin rigid coatings Mechanism of the formation of the regular microrelief Regular fragmentation of the coating Surface structure formation in polymers with a chemically modified surface Polymer films with nanometric coatings - ‘rigid coating on a soft substratum’ systems Evaluation of the structural and mechanical properties of nanometric surface layers Physical fundamentals of the method for evaluating the
Contents stress-strain properties of surface layers and nanometric coatings deposited on polymer films 416 10.2. Modification of polymer surfaces 419 10.3. Evaluation of the stress-strain properties of coatings deposited on polymer surfaces 428 10.4. Evaluation of the stress-strain properties nanometric aluminium coatings 430 10.5. Evaluation of the stress-strain properties of nanometric coatings based on noble metals 438 10.6. The non-metallic coatings 451 11. Natural systems constructed on the basis of the ‘rigid coating on a soft substratum’ principle 460 11.1. Examples of ‘rigid coating on a soft substratum’ natural systems 461 11.2. The Earth - the typical ‘rigid coating on the soft substratum’ system 463 11.3. Evaluation of the thickness of the Earth’s crust 470 11.4. Evaluation of the strength and longevity of the Earth’s crust 471 12. Perspectives for the practical application of surface phenomena in solid polymers 479 12.1. A new approach to the formation of nanocomposites with a polymer matrix 480 12.2. Production of polymer films and fibres capable of influencing the environment 492 12.3. Technological aspects of polymer modification by crazing 497 12.4. Methods for increasing the efficiency of crazing 498 12.5. Producing the transverse microrelief in polymer fibres and films 508 12.6. Practical application of polymer films with a regular microrelief 509 Index 520
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| isbn | 9781498743686 1498743684 |
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| spelling | Volynskii, A. L. (DE-588)1067604561 aut Surface phenomena in the structural and mechanical behaviour of solid polymers A.L. Volynskii, N.F. Bakeev Boca Raton ; London ; New York CRC Press [2016] © 2016 viii, 525 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Polymers Mechanical properties Bakeev, Nikolaĭ Filippovich (DE-588)1067604553 aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029152135&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Volynskii, A. L. Bakeev, Nikolaĭ Filippovich Surface phenomena in the structural and mechanical behaviour of solid polymers Polymers Mechanical properties |
| title | Surface phenomena in the structural and mechanical behaviour of solid polymers |
| title_auth | Surface phenomena in the structural and mechanical behaviour of solid polymers |
| title_exact_search | Surface phenomena in the structural and mechanical behaviour of solid polymers |
| title_full | Surface phenomena in the structural and mechanical behaviour of solid polymers A.L. Volynskii, N.F. Bakeev |
| title_fullStr | Surface phenomena in the structural and mechanical behaviour of solid polymers A.L. Volynskii, N.F. Bakeev |
| title_full_unstemmed | Surface phenomena in the structural and mechanical behaviour of solid polymers A.L. Volynskii, N.F. Bakeev |
| title_short | Surface phenomena in the structural and mechanical behaviour of solid polymers |
| title_sort | surface phenomena in the structural and mechanical behaviour of solid polymers |
| topic | Polymers Mechanical properties |
| topic_facet | Polymers Mechanical properties |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029152135&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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