Macromolecular self-assembly:
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| Other Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Hoboken, New Jersey
Wiley
[2016]
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Item Description: | Includes bibliographical references and index |
| Physical Description: | xiv, 257 Seiten, 16 ungezählte Seiten Bildtafeln Illustrationen, Diagramme (teilweise farbig) |
| ISBN: | 9781118887127 |
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MARC
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Record in the Search Index
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| adam_text | CONTENTS
List of Contributors
Preface
1 A Supramolecular Approach to Macromolecular Self-Assembly:
Cyclodextrin Host/Guest Complexes
Bernhard V. K. J. Schmidt and Christopher Burner-Kowollik
1.1 Introduction, 1
1.2 Synthetic Approaches to Host/Guest Functionalized Building Blocks, 3
1.2.1 CD Functionalization, 3
1.2.2 Suitable Guest Groups, 5
1.3 Supramolecular CD Self-Assemblies, 7
L3.1 Linear Polymers, 7
1.3.2 Branched Polymers, 12
1.3.3 Cyclic Polymer Architectures, 17
1.4 Higher Order Assemblies of CD-Based Polymer Architectures Toward
Nanostructures, 17
1.4.1 Micelles/Core-Shell Particles, 17
1.4.2 Vesicles, 19
1.4.3 Nanotubes and Fibers, 20
1.4.4 Nanoparticles and Hybrid Materials, 21
1.4.5 Planar Surface Modification, 22
1.5 Applications, 23
1.6 Conclusion and Outlook, 26
References, 26
iv
CONTENTS
2 Polymerization-Induced Self-Assembly: The Contribution of Controlled
Radical Polymerization to The Formation of Self-Stabilized Polymer
Particles of Various Morphologies 33
Muriel Lansalot, Jutta Rieger, and Franck D Agosto
2.1 Introduction, 33
2.2 Preliminary Comments Underlying Controlled Radical Polymerization, 36
2.2.1 Introduction, 36
2.2.2 Major Methods Based on a Reversible Termination Mechanism, 37
2.2.3 Major Methods Based on a Reversible Transfer Mechanism, 39
2.3 Pisa Via CRP Based on Reversible Termination, 40
2.3.1 PISA Using NMP, 40
2.3.2 Using ATRP, 46
2.4 Pisa Via CRP Based on Reversible Transfer, 48
2.4.1 Using RAFT in Emulsion Polymerization, 48
2.4.2 Using RAFT in Dispersion Polymerization, 61
2.4.3 Using TERP, 70
2.5 Concluding Remarks, 71
Acknowledgments, 73
Abbreviations, 73
References, 75
3 Amphiphilic Gradient Copolymers: Synthesis and Self-Assembly in
Aqueous Solution 83
Elise Deniau-Lejeune, Olga Borisova, Petr Stepdnek, Laurent Billon,
and Oleg Borisov
3.1 Introduction, 83
3.2 Synthetic Strategies for The Preparation of Gradient Copolymers, 86
3.2.1 Preparation of Gradient Copolymers by Controlled Radical
Copolymerization, 87
3.2.2 Preparation of Block-Gradient Copolymers Using Controlled
Radical Polymerization, 106
3.3 Self-Assembly, 110
3.3.1 Gradient Copolymers, 110
3.3.2 Diblock-Gradient Copolymers, 111
3.3.3 Triblock-Gradient Copolymers, 113
3.4 Conclusion and Outlook, 114
Abbreviations, 115
References, 117
4 Electrostatically Assembled Complex Macromolecular Architectures Based
on Star-Like Polyionic Species 125
Dmitry V. Pergushov and Felix A. Plamper
4.1 Introduction, 125
CONTENTS
V
4.2 Core-Corona Co-Assemblies of Homopolyelectrolyte Stars Complexed
with Linear Polyions, 127
4.3 Core-Shell-Corona Co-Assemblies of Star-Like Micelles of Ionic
Amphiphilic Diblock Copolymers Complexed with Linear Polyions, 130
4.4 Vesicular Co-Assemblies of Bis-Hydrophilic Miktoarm Stars Complexed
with Linear Polyions, 133
4.5 Conclusions, 137
Acknowledgment, 137
References, 137
5 Solution Properties of Associating Polymers 141
Olga Philippova
5.1 Introduction, 141
5.2 Structures of Associating Polyelectrolytes, 142
5.3 Associating Polyelectrolytes in Dilute Solutions, 142
5.3.1 Intramolecular Association, 145
5.3.2 Intermolecular Association, 147
5.4 Associating Polyelectrolytes in Semidilute Solutions, 151
5.5 Conclusions, 155
References, 155
6 Macromolecular Decoration of Nanoparticles for Guiding
Self-Assembly in 2D and 3D 159
Christian Kuttner, Munish Chanana, Matthias Karg, and Andreas Fery
6.1 Introduction, 159
6.2 Guiding Assembly by Decoration with Artificial Macromolecules, 160
6.2.1 Decoration of Nanoparticles, 161
6.2.2 Distance Control in 2D and 3D, 166
6.2.3 Breaking the Symmetry, 171
6.3 Guiding Assembly by Decoration with Biomacromolecules, 173
6.3.1 DNA-Assisted Assembly, 173
6.3.2 Protein-Assisted Assembly, 177
6.4 Application of Assemblies, 181
6.5 Conclusions and Outlook, 183
References, 184
7 Self-Assembly of Biohybrid Polymers 193
Dawid Kedracki, Jancy Nixon Abraham; Enora Prado, and Corinne
Nardin
7.1 Introduction, 193
7.1.1 Amphiphiles, 194
7.1.2 Packing Parameter and Interfacial Tension, 195
7.1.3 Interaction Forces in Self-Assembly, 196
7.2 Self-Assembly of Biohybrid Polymers, 198
7.2.1 Polymer-DNA Hybrids, 198
7.2.2 Polypeptide Block Copolymers, 204
7.2.3 Block Copolypeptides, 205
7.3 Self-Assembly Driven Nucléation Polymerization, 207
7.3.1 Polymer-DNA Hybrids, 209
7.3.2 Polymer-Peptide Hybrids, 209
7.3.3 DNA-Peptide Hybrids, 212
7.4 Self-Assembly Driven by Electrostatic Interactions, 213
7.4.1 DNA/Polymer Bio-IPECs, 216
7.4.2 DNA/Copolymer Bio-IPECs, 216
7.5 Conclusion, 218
References, 219
8 Biomedical Application of Block Copolymers
Martin Hruby, Sergey K. Filippov; and Petr Stëpânek
8.1 Introduction, 231
8.2 Diblock and Triblock Copolymers, 234
8.3 Graft and Statistical Copolymers, 240
8.4 Concluding Remarks, 245
Acknowledgment, 245
References, 245
Index
Molecular self-assembly, the process by which molecules adopt a defined
arrangement without human guidance or management, is crucial to the function of
cells. It is characteristic of lipids forming membranes, the formation of double helical
DNA, and the assembly of proteins forming quaternary structures. Macromolecular
self-assembly is also considered as the most promising bottom-up approach in
nano(bio)technology.
This book describes techniques of synthesis and self-assembly of macromolecules
that may be useful for developing new materials and improving the functionality of
existing materials. Because self-assembly is how nature creates complex systems,
emulation of this process is likely to have a good chance at succeeding in real-world
biomedical applications.
A valuable and comprehensive resource for researchers and graduate students,
Macromolecular Self-Assembly offers readers benefits that include:
• Use of synthetic chemistry, physical chemistry, and materials science principles and
techniques
• Emphasis on self-assembly in solutions (particularly, aqueous solutions) and at
solid-liquid interfaces
• Description of polymer assembly driven by multitude interactions, including
solvophobic and electrostatic ones
• Illustration of the assembly of bio-hybrid macromolecules and applications in
biomedical engineering
Laurent Billon, PhD, is Professor at Pau University, France, and leader of the polymer
group at the Interdisciplinary Institute of Environmental and Material Research (IPREM)
in Pau, France. Fie is the author of over 90 scientific publications and 12 patents. Fie
received his PhD in Polymer Chemistry from Pau University.
Oleg Borisov. PhD, is research director at the Institute of Environmental and
Material Research at Pau University, France. Fie received his PhD in the physics and
mechanics of polymers at the Institute of Macromolecular Compounds of the Russian
Academy of Sciences. Fie is the author of over 150 scientific publications.
ISBN 978-1 -118-88712-7
|
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| dewey-tens | 570 - Biology |
| discipline | Chemie / Pharmazie Biologie |
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| language | English |
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| spelling | Billon, Laurent 1968- (DE-588)1117939855 edt Macromolecular self-assembly edited by Laurent Billon, Oleg Borisov Hoboken, New Jersey Wiley [2016] © 2016 xiv, 257 Seiten, 16 ungezählte Seiten Bildtafeln Illustrationen, Diagramme (teilweise farbig) txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Biopolymers Macromolecules Self-assembly (Chemistry) Borisov, Oleg (DE-588)1119261899 edt Erscheint auch als Online-Ausgabe, pdf 978-1-118-88784-4 Erscheint auch als Online-Ausgabe, epub 978-1-118-88797-4 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029067545&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029067545&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Macromolecular self-assembly Biopolymers Macromolecules Self-assembly (Chemistry) |
| title | Macromolecular self-assembly |
| title_auth | Macromolecular self-assembly |
| title_exact_search | Macromolecular self-assembly |
| title_full | Macromolecular self-assembly edited by Laurent Billon, Oleg Borisov |
| title_fullStr | Macromolecular self-assembly edited by Laurent Billon, Oleg Borisov |
| title_full_unstemmed | Macromolecular self-assembly edited by Laurent Billon, Oleg Borisov |
| title_short | Macromolecular self-assembly |
| title_sort | macromolecular self assembly |
| topic | Biopolymers Macromolecules Self-assembly (Chemistry) |
| topic_facet | Biopolymers Macromolecules Self-assembly (Chemistry) |
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