Iron oxides: from nature to applications
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Wiley-VCH Verlag GmbH & Co. KGaA
[2016]
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| Online Access: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-33882-5/ Inhaltsverzeichnis |
| Physical Description: | XXVIII, 598 Seiten Illustrationen, Diagramme (teilweise farbig) |
| ISBN: | 9783527338825 9783527691395 |
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| 100 | 1 | |a Faivre, Damien |d 1977- |0 (DE-588)1082258423 |4 edt | |
| 245 | 1 | 0 | |a Iron oxides |b from nature to applications |c edited by Damien Faivre |
| 264 | 1 | |a Weinheim |b Wiley-VCH Verlag GmbH & Co. KGaA |c [2016] | |
| 264 | 4 | |c © 2016 | |
| 300 | |a XXVIII, 598 Seiten |b Illustrationen, Diagramme (teilweise farbig) | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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| 653 | |a Anorganische Chemie | ||
| 653 | |a Chemie | ||
| 653 | |a Chemistry | ||
| 653 | |a Earth Sciences | ||
| 653 | |a Geochemie, Mineralogie | ||
| 653 | |a Geochemistry & Minerology | ||
| 653 | |a Geowissenschaften | ||
| 653 | |a Industrial Chemistry | ||
| 653 | |a Inorganic Chemistry | ||
| 653 | |a Nanomaterialien | ||
| 653 | |a Nanomaterials | ||
| 653 | |a Nanotechnologie | ||
| 653 | |a Nanotechnology | ||
| 653 | |a Technische u. Industrielle Chemie | ||
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| adam_text | CONTENTS
LIST OF CONTRIBUTORS XVII
FOREWORD XXV
PREFACE XXVII
1 INTRODUCTION I
DAMIEN FAIVRE
1.1 IRON OXIDES: FROM NATURE TO APPLICATIONS 1
1.2 A VERY BRIEF OVERVIEW OF THE IRON OXIDES AND HOW THEY FOUND
NAMES 3
REFERENCES 5
PART I FORMATION, TRANSFORMATION 7
2 GEOLOGICAL OCCURRENCES AND RELEVANCE OF IRON OXIDES 9
FRANCE LAGROIX, SUBIRK. BANERJEE, AND MIKE 1 JACKSON
2.1 INTRODUCTION 9
2.2 ELEMENTAL IRON: FROM THE UNIVERSE TO THE EARTH 9
2.3 RESIDENCY OF ELEMENTAL IRON ON EARTH 10
2.4 MINERAL FORMS OF IRON OXIDES 11
2.5 OCCURRENCE AND GEOLOGICAL RELEVANCE OF IRON OXIDES 13
2.5.1 CRYSTALLIZATION FROM MELT AND PARTIAL MELTS 13
2.5.2 PRECIPITATION FROM SOLUTION AND ALTERATION/TRANSFORMATION 15
2.6 IRON OXIDES IN CONTINENTAL DUST DEPOSITS 19
2.7 CONCLUDING REMARKS 23
ACKNOWLEDGMENTS 23
REFERENCES 23
3 REDUCTIVE DISSOLUTION AND REACTIVITY OF FERRIC (HYDR)OXIDES: NEW
INSIGHTS AND IMPLICATIONS FOR ENVIRONMENTAL REDOX PROCESSES 31
STEFAN PEIFFER AND MOLI WAN
3.1 INTRODUCTION 31
3.2 THE CLASSICAL PERSPECTIVE ON REDUCTIVE DISSOLUTION 32
3.3 ELECTRON TRANSFER AT FERRIC (HYDR)OXIDES SURFACES: THE ROLE OF
FE(II) 33
3.4 ENERGETICS AT THE FERRIC (HYDR)OXIDE INTERFACE 35
3.4.1 REDOX POTENTIAL OF FE(II) SORBED TO FERRIC HYDROXIDES 35
3.4.2 THE SEMICONDUCTING PROPERTIES OF FERRIC (HYDR)OXIDES 36
3.5 RATE CONTROL: SURFACE VERSUS STRUCTURAL PROPERTIES 39
3.5.1 ELECTRON TRANSFER VERSUS DISSOLUTION 39
3.5.2 INTER-MINERAL VERSUS INTRA-MINERAL VARIABILITY OF REACTIVITY 40
3.6 INTERACTION BETWEEN DISSOLVED SULFIDE AND FERRIC
HYDROXIDES 42
3.6.1 THE DYNAMIC NATURE OF THE REACTION 42
3.6.2 PRODUCT MASS BALANCE: THE OCCURRENCE OF EXCESS FE(II) 43
3.6.3 PYRITE FORMATION AND EXCESS FE(II) 46
3.7 IMPLICATIONS 47
REFERENCES 48
4 FORMATION AND TRANSFORMATION OF IRON-BEARING MINERALS BY
LRON(LL)-OXIDIZING AND LRON(LLL)-REDUCING BACTERIA 53
JENNY FER MIOT AND MARJORIE ETIQUE
4.1 INTRODUCTION 53
4.2 BIOMINERALIZATION OF IRON THROUGH MICROBIAL FE(II)
OXIDATION 54
4.2.1 MICROBIAL FE(II) OXIDATION UNDER ANOXIC CONDITIONS 55
4.2.1.1 ANOXYGENIC PHOTOSYNTHESIS 57
4.2.1.2 NITRATE-DEPENDENT FERROUS OXIDATION 58
4.2.2 MICROBIAL MICROAEROBIC FE(II) OXIDATION 58
4.2.3 MICROBIAL FE(II) OXIDATION UNDER OXIC CONDITIONS 60
4.3 IRON(III) MINERALS: ELECTRON ACCEPTORS FOR IRON-REDUCING
BACTERIA 60
4.3.1 TRANSFERRING ELECTRONS TO FE OXIDES: A MICROBIAL
CHALLENGE 60
4.3.2 DIVERSITY OF FE OXIDES USED AND PRODUCED BY IRB 63
4.4 SPECIFIC PROPERTIES OF IRON BIOMINERALS 64
4.4.1 MICROBIAL AND ENVIRONMENTAL PARAMETERS CONTROL FE
MINERALOGY 65
4.4.2 THE ORGANIC M ATTER-FE OXIDE INTERFACE 67
4.4.3 COULD FE BIOMINERALS CONSTITUTE BIOSIGNATURES? 68
4.5 MICROBIAL FE REDOX CYCLING: PAST, PRESENT, AND FUTURE 72
4.5.1 MICROBIAL SCENARIO FOR PAST DEPOSITION OF FE OXIDES 72
4.5.2 MODERN ENVIRONMENTS HOSTING FE CYCLING BACTERIA 73
4.5.3 IMPACT OF FE CYCLING BACTERIA ON POLLUTANT SPECIATION AND
MOBILITY 75
4.5.4 TECHNOLOGICAL APPLICATIONS BASED ON MICROBIAL INTERACTIONS WITH
IRON OXIDES 76
4.5.4.1 BIOREMEDIATION STRATEGIES 76
4.5.4.2 ENERGY PRODUCTION AND STORAGE 76
4.6 CONCLUSION 77
REFERENCES 78
5 CONTROLLED BIOMINERALIZATION OF MAGNETITE IN BACTERIA 99
ELODIE C.T. DESCAMPS, JEAN-BAPTISTE ABBE, DAVID PIGNOL, AND
CHRISTOPHER T LEFEVRE
5.1 INTRODUCTION 99
5.2 MAGNETOTACTIC BACTERIA 100
5.2.1 DISCOVERY 100
5.2.2 ECOLOGY 100
5.2.3 DIVERSITY 101
5.3 ORGANIZATION AND ROLE OF MAGNETOSOMES 102
5.3.1 ARRANGEMENT OF MAGNETOSOMES WITHIN THE CELLS 102
5.3.2 MAGNETO-AEROTAXIS 104
5.4 BIOMINERALIZATION OF MAGNETOSOMES 104
5.4.1 BIOCHEMISTRY OF THE MAGNETOSOME MEMBRANE 104
5.4.2 GENOMICS AND GENETICS OF MTB 105
5.4.3 MAGNETOSOME FORMATION 105
5.5 MINERAL PHASE OF MAGNETOSOMES 108
5.5.1 COMPOSITION 108
5.5.2 SIZE 109
5.5.3 MORPHOLOGIES 109
5.5.4 APPLICATION OF MAGNETOSOMES 110
ACKNOWLEDGMENTS 111
REFERENCES 111
6 FERRITIN IRON MINERALIZATION AND STORAGE: FROM STRUCTURE TO
FUNCTION 117
NOAM ARONOVITZ, MICHAL NEEMAN, AND RAZZARIVACH
6.1 INTRODUCTION 117
6.2 BASIC STRUCTURE OF FERRITINS 118
6.2.1 THE FERRITIN SUBUNIT 118
6.2.2 THE FERRITIN QUATERNARY ASSEMBLY 120
6.2.2.1 THE TWOFOLD AXIS 120
6.2.2.2 THE THREEFOLD AXIS 120
6.2.2.3 THE FOURFOLD AXIS 121
6.2.2.4 THE B-CHANNEL 123
6.3 IRON STORAGE AND MINERALIZATION 123
6.3.1 FERRITIN FERROXIDASE CENTERS 123
6.3.2 THE NUCLEATION SITE 125
6.3.3 IRON MINERALIZATION 125
6.4 NMR AND MRI STUDIES OF THE FERRITIN IRON CORE 126
6.5 MAGNETOFERRITIN 127
6.5.1 INTRODUCTION TO MAGNETOFERRITIN 127
6.5.2 EXPERIMENTAL PROTOCOL FOR MAGNETOFERRITIN SYNTHESIS 128
6.5.2.1 PRODUCT DESCRIPTION 129
6.5.3 METHOD DISCUSSION 129
6.5.3.1 CRYSTALLIZATION 129
6.5.3.2 PUTTING THEORY TO PRACTICE 130
6.5.4 CONCLUSION 130
6.6 FERRITIN AS A BIOTECHNOLOGICAL TOOL 131
6.6.1 BIOMEDICAL TREATMENT AND DIAGNOSIS 131
6.6.2 CHEMICAL REACTION CATALYSIS 132
6.6.3 ELECTRONICS 132
6.6.4 CONCLUSION 133
6.7 PROTOCOL ANNEXES 133
6.7.1 ANNEX 1: FERRITIN PURIFICATION 133
6.7.1.1 PURIFICATION OF CHLOROBIUM TEPIDUM FERRITIN USING BOILING AS A
HEAT
RESISTANCE SELECTION TOOL 133
6.7.1.2 PURIFICATION OF RECOMBINANT SOYBEAN SEED FERRITIN: PURIFICATION
BY
HIS TAG AFFINITY 134
6.7.2 ANNEX 2: MAGNETOFERRITIN PREPARATION 135
REFERENCES 137
7 IRON OXIDES IN THE HUMAN BRAIN 143
JOANNA F. COLLINGWOOD AND NEIL D. TELLING
7.1 INTRODUCTION 143
12 IRON OXIDES OBSERVED IN THE HUMAN BRAIN 146
7.2.1 FERRIHYDRITE 146
7 2 2 HEMATITE 146
7 2 3 MAGNETITE 147
7.2.4 MAGHEMITE 148
7 2 3 WUESTITE 148
7.2.6 GOETHITE 150
7.3 PROPERTIES OF IRON OXIDES IN THE BRAIN 150
7.3.1 CRYSTALLOGRAPHIC AND STRUCTURAL PROPERTIES 150
7.3.2 MAGNETIC PROPERTIES 153
7.4 STORED AND SEQUESTERED IRON OXIDE IN THE HUMAN BRAIN 155
7.4.1 FERRITIN 155
7.4.2 MITOCHONDRIAL IRON 156
7.4.3 HEMOSIDERIN 158
7.4.4 NEUROMELANIN 159
7.5 METHODS TO DETECT IRON OXIDES IN THE BRAIN 160
7.5.1 POSTMORTEM ANALYSIS 160
7 3 2 CLINICAL EVALUATION 162
7.6 TOOLS AND TREATMENTS: MANIPULATING IRON OXIDES IN THE BRAIN 163
7.6.1 IMAGING 164
7.62 TARGETING 164
7.6.3 THERAPEUTIC USE OF IRON OXIDE NANOPARTICLES 165
7.6.4
IN
8
8.1
8.2
8.3
8.4
8.5
8.6
8.7
8.8
8.9
8.10
8.11
8.12
8.13
9
9.1
9.2
9.3
9.4
9.4.1
9.4.2
9.4.3
9.5
10
10.1
10.2
10
.
2.1
10
.
2.2
10.3
THERAPEUTIC REMOVAL OF IRON 165
CONCLUDING REMARKS 166
ACKNOWLEDGMENTS 166
REFERENCES 166
THE CHITON RADULA: A MODEL SYSTEM FOR VERSATILE USE OF IRON
OXIDES 177
DERK JOESTER AND LESLEY R. BROOKER
FUNCTIONAL ANATOMY OF THE MOLLUSK RADULA 177
DEVELOPMENT OF THE RADULA: ORGANIC MATRIX 180
THE DISCOVERY OF BIOMINERALS IN THE RADULA 180
THE MICROARCHITECTURE OF CHITON RADULA TEETH 181
DEVELOPMENT OF THE CHITON RADULA: STAGES OF
BIOMINERALIZATION 183
DEVELOPMENT OF THE RADULA: BIOLOGICAL CONTROL 185
ROLE OF ACIDIC MACROMOLECULES IN THE INSOLUBLE ORGANIC
MATRIX 186
SOLUBLE ORGANIC MATRIX COMPOSITION 186
SELECTIVE DEPOSITION OF FERRIHYDRITE IN STAGE II 187
CONVERSION OF FERRIHYDRITE TO MAGNETITE IN STAGE III 190
PHASE TRANSFORMATIONS IN STAGE IV 192
FINAL FUNCTIONAL ARCHITECTURE 194
CONCLUDING REMARKS 197
REFERENCES 198
MINERALIZATION OF GOETHITE IN LIMPET RADULAR TEETH 207
TINA UKMAR-GODEC
INTRODUCTION 207
STRUCTURE, PROPERTIES, AND FUNCTION OF THE LIMPET RADULA 207
GOETHITE PRODUCED IN THE LABORATORY 210
GOETHITE PRODUCED IN LIMPETS 213
MORPHOLOGY OF NEWLY FORMED BIOGENIC GOETHITE 213
IRON TRANSPORT INTO THE TOOTH 216
NUCLEATION AND GROWTH OF BIOGENIC GOETHITE 219
CONCLUSION 221
REFERENCES 222
SYNTHETIC FORMATION OF IRON OXIDES 225
CORINNE CHANEAC, ANNE DUCHATEAU, AND ALI ABOU-HASSAN
INTRODUCTION 225
IRON OXIDE AND OXYHYDROXIDE FROM AQUEOUS FERRIC
SOLUTION 226
VERSATILITY OF HEMATITE MORPHOLOGY 226
GOETHITE AND AKAGANEITE OXYHYDROXIDES 230
IRON OXIDE AND OXYHYDROXIDE FROM AQUEOUS FERROUS SOLUTION 231
10.4 IRON OXIDE SYNTHESIS USING MICROFLUIDIC PROCESS 233
10.4.1 FROM BULK SYNTHESIS TO MICROREACTORS 233
10.4.2 SYNTHESIS OF Y-FE20 3 NANOPARTICLES IN MICROFLUIDIC
REACTORS 235
10.4.3 SYNTHESIS OF AR-FEOOH NANOPARTICLES IN MICROFLUIDIC
REACTORS 238
REFERENCES 240
11 ORIENTED ATTACHMENT AND NONCLASSICAL FORMATION IN IRON OXIDES 243
JENNIFER A. SOLTIS AND R. LEE PENN
11.1 INTRODUCTION 243
11.2 OA IN IRON OXIDES IN THE LITERATURE 245
11.2.1 GOETHITE 247
11.2.2 HEMATITE 248
11.2.3 OTHER IRON OXIDES 248
11.2.4 NATURAL SAMPLES 248
11.3 OA AND PHASE TRANSFORMATION 249
11.4 DETECTION AND CHARACTERIZATION OF GROWTH BY OA 249
11.4.1 IMAGING 249
11.4.2 CRYOGENIC AND FLUID CELL TEM 250
11.4.3 CORRELATIVE METHODS 252
11.5 KINETICS OF GROWTH BY OA 253
11.5.1 MOLECULAR DIMER FORMATION MODELS 253
11.5.2 POPULATION BALANCE MODEL 255
11.5.3 POLYMERIZATION MODEL 255
11.5.4 MODELING SIMULTANEOUS OA, COARSENING, AND PHASE
TRANSFORMATION 256
11.6 THERMODYNAMICS 257
11.7 MORPHOLOGY AND SURFACE CHEMISTRY 258
11.8 FORCES GOVERNING ASSEMBLY 259
11.9 FUTURE WORK 260
REFERENCES 261
12 THERMODYNAMICS OF IRON OXIDES AND OXYHYDROXIDES IN DIFFERENT
ENVIRONMENTS 269
HAIBO GUO AND AMANDA
S.
BARNARD
12.1 INTRODUCTION 269
12.2 MAGNETIC TRANSFORMATIONS 270
12.3 POLYMORPHIC TRANSFORMATIONS 274
12.3.1 AT THE MACROSCALE 274
12.3.2 AT THE NANOSCALE 278
12.3.2.1 NANOMORPHOLOGY 280
12.3.2.2 SIZE-DEPENDENT STABILITY 286
12.4 SUMMARY 288
REFERENCES 289
PART II CHARACTERIZATION TECHNIQUES
293
13 INTRODUCTION TO STANDARD SPECTROSCOPIC METHODS: XRD, IR/RAMAN, AND
MOESSBAUER 295
FERNANDO VEREDA
13.1 INTRODUCTION 295
13.2 X-RAY DIFFRACTION (XRD) 297
13.2.1 THE MAGNETITE-MAGHEMITE SYSTEM 301
13.3 VIBRATIONAL SPECTROSCOPY 302
13.3.1 THE MAGNETITE-MAGHEMITE SYSTEM 311
13.4 MOESSBAUER SPECTROSCOPY 311
13.4.1 THE MAGNETITE-MAGHEMITE SYSTEM 316
13.4.2 PARTICLE SIZE AND SUPERPARAMAGNETISM 316
ACKNOWLEDGMENTS 319
REFERENCES 319
14 TEM AND ASSOCIATED TECHNIQUES 325
TANYA PROZOROV
COMMON ABBREVIATIONS 325
14.1 INTRODUCTION 326
14.2 NANOSCALE ANALYSIS OF IRON OXIDES 327
14.2.1 SPECIMEN PREPARATION 327
14.2.2 THE
IN SITU APPROACH 329
14.2.3 PROBING THE LOCAL CHEMISTRY 330
14.3 ELECTRON HOLOGRAPHY 331
14.4 THE NEAR
IN SITU APPROACH 335
14.5 IN SITU ANALYSIS WITH A LIQUID CELL 336
ACKNOWLEDGMENT 338
REFERENCES 339
15 MAGNETIC MEASUREMENTS AND CHARACTERIZATION 347
ANN M. HIRT
15.1 INTRODUCTION 347
15.2 SUMMARY OF MAGNETIC PROPERTIES OF IRON OXIDES AND IRON
HYDROXIDES 348
15.3 INDUCED MAGNETIZATION 349
15.3.1 MAGNETIC SUSCEPTIBILITY 349
15.3.2 MAGNETIC HYSTERESIS 354
15.4 REMANENT MAGNETIZATION 355
15.4.1 ISOTHERMAL REMANENT MAGNETIZATION 356
15.5 USAGE OF MAGNETIC PROPERTIES 357
15.5.1 COMPOSITION 358
15.5.2 CONCENTRATION 361
15.5.3 PARTICLE SIZE 362
15.5.4 MAGNETIC INTERACTION 364
15.5.5 OTHER MAGNETIC PARAMETERS 366
XII I
CONTENTS
15.6 SUMMARY 366
REFERENCES 367
16 TOTAL X-RAY SCATTERING AND SMALL-ANGLE X-RAY SCATTERING FOR
DETERMINING THE STRUCTURES, SIZES, SHAPES, AND AGGREGATION EXTENTS OF
IRON (HYDR)OXIDE NANOPARTICLES 371
YOUNG-SHIN JUN AND BYEONGDU LEE
16.1 INTRODUCTION 371
16.1.1 WHY SHOULD WE CARE ABOUT IRON (HYDR)OXIDE
NANOPARTICLES? 371
16.1.2 HOW CAN WE DETERMINE IRON (HYDR)OXIDE NANOPARTICLES STRUCTURAL
INFORMATION USING LIGHT SOURCES? 372
16.2 DETERMINATION OF PARTICLE STRUCTURES: TOTAL X-RAY SCATTERING WITH
PDF ANALYSIS 373
16.2.1 WHY SHOULD WE USE SYNCHROTRON-BASED X-RAY
SOURCES? 374
16.2.2 EXPERIMENTAL SAMPLE PREPARATION AND DATA BACKGROUND
SUBTRACTION 374
16.2.3 PDF ANALYSIS 375
16.3 DETERMINATION OF PARTICLE SIZES, SHAPES, AND AGGREGATION EXTENTS:
SAXS AND GISAXS 378
16.3.1 WHY SHOULD WE CARE ABOUT SIZE, SHAPE, LOCATION, AND AGGREGATION
OF IRON (HYDR)OXIDE NANOPARTICLES, AND WHAT ARE THE CURRENT
CHALLENGES FOR THESE MEASUREMENTS?
379
16.3.2 HOW DO SAXS AND GISAXS WORK? 380
16.3.3 IN SITU TIME-RESOLVED SIMULTANEOUS SAXS/GISAXS
MEASUREMENTS 383
16.3.4 SCATTERING DATA ANALYSIS 383
16.3.5 QUANTITATIVE COMPARISON BETWEEN HOMOGENEOUSLY AND
HETEROGENEOUSLY FORMED NANOPARTICLES 385
16.4 OUTLOOK 391
ACKNOWLEDGMENTS 392
REFERENCES 392
17 X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY IN FE OXIDES AND
OXYHYDROXIDES 397
M. LUISA FDEZ-GUBIEDA, ANA GARCIA-PRIETO, JAVIER ALONSO, AND
CARLO MENEGHINI
17.1 BRIEF INTRODUCTION TO XAFS 398
17.1.1 MEASURING XAFS 399
17.1.2 ADDITIONAL SETUPS FOR XAFS MEASUREMENT: FLUORESCENCE AND TOTAL
ELECTRON YIELD 400
17.2 XANES SPECTROSCOPY 401
17.2.1 XANES SPECTROSCOPY ON FE OXIDES AND
OXYHYDROXIDES 401
17.2.2 LINEAR COMBINATION XANES DATA ANALYSIS 404
17.3 EXAFS SPECTROSCOPY 406
17.3.1 EXAFS DATA ANALYSIS 407
17.3.2 EXAFS SPECTROSCOPY ON FE OXIDES AND
OXYHYDROXIDES 410
17.4 CONCLUSION AND PERSPECTIVES 415
REFERENCES 416
PART III APPLICATIONS 423
18 MEDICAL APPLICATIONS OF IRON OXIDE NANOPARTICLES 425
AMANDA K. ANDRIOLA SILVA, ANA ESPINOSA, JELENA KOLOSNJAJ-TABI,
CIAIRE WILHELM, AND FLORENCE GAZEAU
18.1 INTRODUCTION 425
18.2 IONPS FOR IMAGING 426
18.2.1 MRI CONTRAST MECHANISMS AND QUANTIFICATION APPROACH 426
18.2.2 IMAGING OF THE MONONUCLEAR PHAGOCYTE SYSTEM 427
18.2.3 MOLECULAR IMAGING 429
18.2.4 IMAGING OF CELL THERAPY 431
18.2.5 IMAGE-GUIDED THERAPY 432
18.2.6 MAGNETIC PARTICLE IMAGING 433
18.3 MAGNETIC DRUG TARGETING 433
18.3.1 MAGNETIC DRUG CARRIERS: DRUG-LOADING STRATEGIES 435
18.3.2 MAGNETIC NANOSYSTEMS: ACTIVE AND PASSIVE TARGETING 437
18.3.3 TARGETS IN THE ORGANISM 439
18.3.4 DRUG RELEASE FROM MAGNETIC NANOSYSTEMS 441
18.4 IONPS AND TISSUE ENGINEERING 442
18.4.1 CYTOCOMPATIBILITY OF MAGNETIC LABELING AND ITS IMPACT ON MSC
DIFFERENTIATION 442
18.4.2 THE MAGNETIC CELL: A BUILDING BLOCK FOR 3D ASSEMBLIES 444
18.4.3 TOWARD A FUNCTIONAL MAGNETIC TISSUE 445
18.5 ACTIVATION OF IONPS WITH TIME-DEPENDENT MAGNETIC FIELDS 446
18.5.1 MAGNETIC HYPERTHERMIA 447
18.5.2 PHYSICAL PRINCIPLES OF IONP MAGNETIC ACTIVATION 447
18.5.3 MAGNETIC HYPERTHERMIA EFFICIENCY IN DIFFERENT ENVIRONMENTS:
CANCER THERAPEUTICS USING IRON OXIDE-BASED NANOHEATERS 449
18.5.4 PRECLINICAL AND CLINICAL MAGNETIC HYPERTHERMIA TREATMENT 450
18.5.5 LOCAL EFFECTS OF MAGNETIC ACTIVATION OF IONPS 451
18.6 LIFE CYCLE OF IONPS 456
18.6.1 NANOPARTICLE INTERACTION WITH BIOMACROMOLECULES FROM BODILY
FLUIDS 456
18.6.2 MACROPHAGE CAPTURE OF IONPS AFTER SYSTEMIC ADMINISTRATION 457
18.6.3 IONP DISTRIBUTION AFTER LOCAL APPLICATION 458
18.6.4 PROGRESSIVE DEGRADATION PROCESSES IN THE LIVER AND SPLEEN AND
IRON
BIOASSIMILATION 458
18.7
CONCLUSION
460
REFERENCES
460
19
IRON NANOPARTICLES FOR WATER TREATMENT: IS THE FUTURE FREE OR
FIXED?
473
SARAH J. TESH AND THOMAS B. SCOTT
19.1
19.2
19.2.1
19.2.2
INTRODUCTION
473
WHY IRON?
47S
THE AQUEOUS CORROSION OF IRON
475
ENVIRONMENTAL REACTIVITY: METALLIC IRON OR
IRON OXIDE?
476
19.3
19.3.1
19.3.1.1
19.3.1.2
19.3.1.3
19.3.2
19.3.3
19.4
19.4.1
19.4.2
19.4.2.1
19.4.2.2
19.4.2.3
INPS: A VERSATILE MATERIAL FOR WATER TREATMENT
477
INP SYNTHESIS
478
THE THERMAL REDUCTION OF FERROUS IRON
480
ELECTROLYSIS
480
POLYPHENOLIC PLANT EXTRACTS
480
HOW MUCH DO INPS COST?
481
ARE INPS AS GOOD AS SOME STUDIES SUGGEST?
481
OPERATIONAL DRIVERS FOR WATER TREATMENT
483
INP SIZE
483
IMPROVING MOBILITY
484
SURFACTANTS
486
POLYELECTROLYTE COATINGS
487
IMPROVING THE MOBILITY OF INPS FOR THE REMEDIATION OF NON-AQUEOUS
PHASE LIQUIDS
487
19.4.2.4
19.4.3
19.4.3.1
19.4.4
PROTECTIVE SHELLS AND SOLID SUPPORTS
488
IMPROVING REACTIVITY: BIMETALLIC NPS
488
WILL BIMETALLICS PREVAIL OVER MONOMETALLIC?
489
IMPROVING PHYSICOCHEMICAL STRUCTURE: THERMAL
TREATMENTS
489
19.4.5
19.4.6
19.4.7
19.5
19.5.1
19.5.2
19.5.3
19.6
19.7
INP INJECTION STRATEGY
490
THE ENVIRONMENTAL TOXICOLOGY OF INPS
492
CONCLUSIONS*INPS: YES OR NO?
494
STATIC NANOCOMPOSITES
495
MEMBRANES AND MATS
496
BEADS
500
POROUS 3D STRUCTURES: THE WAY FORWARD?
503
WHAT IS HOLDING BACK STATIC NANOCOMPOSITES?
507
CONCLUSION
509
REFERENCES
510
20 ACTUATION OF IRON OXIDE-BASED NANOSTRUCTURES BY EXTERNAL MAGNETIC
FIELDS
523
PETER VACH
20.1 INTRODUCTION
523
20
.
1.1
20
.
1.2
20.2
20
.
2.1
20
.
2.2
20.2.3
20.3
20.3.1
20.3.2
20.4
21
21.1
21.2
21.3
21.3.1
21.3.2
21.3.3
21.3.4
21.3.5
21.3.6
21.4
21.4.1
21.4.2
22
22.1
22
.
1.1
22
.
1.2
22.1.3
22.1.4
22.1.5
22.2
22
.
2.1
22
.
2.2
22.2.3
22.2.4
22.2.4.1
MAGNETIC FORCES
524
ACTUATION AND ASSEMBLY
525
NANOMACHINES
525
SWIMMERS
526
ROLLERS
527
PROPELLERS
529
GUIDED SELF-ASSEMBLY
530
CONSTANT EXTERNAL MAGNETIC FIELDS
530
DYNAMIC SELF-ASSEMBLY
533
CONCLUSION
536
REFERENCES
536
IRON OXIDE-BASED PIGMENTS AND THEIR USE IN HISTORY
545
MARCO NICOLA, CHIARA MASTRIPPOLITO, AND AD MIR MASIC
INTRODUCTION
545
CHEMICAL COMPOSITION AND PROPERTIES OF IRON OXIDE-BASED
PIGMENTS
545
USE OF IRON OXIDE-BASED PIGMENTS IN HISTORY
550
PREHISTORY
550
EGYPTIAN ART
551
CLASSICAL ANTIQUITY
551
THE MIDDLE AGES AND RENAISSANCE
554
NINETEENTH CENTURY
554
USE OF IRON OXIDE-BASED PIGMENTS IN NON-EUROPEAN ART OUTSIDE THE
MEDITERRANEAN AREA
554
CASE STUDIES 559
COLOR ALTERATION 559
DATING
560
REFERENCES
563
MAGNETORECEPTION AND MAGNETOTAXIS
567
MATHIEU A. BENNETAND STEPHAN H. K. EDER
MAGNETORECEPTION
567
MAGNETIC BEHAVIOR
567
THEORETICAL MAGNETORECEPTION MODELS
570
MAGNETITE EXTRACTS FROM ORGANISMS
573
ARCHITECTURE OF MAGNETORECEPTORS
574
CONCLUSIONS
576
MAGNETO TAXIS
576
MAGNETIC PROPERTIES OF MAGNETITE PARTICLES AND THEIR
ASSEMBLY 577
THE INTRACELLULAR MAGNETIC APPARATUS
578
RANDOMIZATION VERSUS ORIENTATION 579
USE AND STUDY OF MAGNETOTAXIS IN THE LABORATORY
580
SAMPLING AND OBSERVING MTB
580
22.2.4.2 MICROCAPILLARY ASSAY 581
22.2.4.3 MAGNETIC SETUP 581
22.2.5 SEMINAL EXPERIMENTS IN MAGNETOTAXIS 581
22.2.6 ONE DESTINATION AND NUMEROUS STRATEGIES 582
22.2.7 MODEL OF MAGNETOTAXIS 583
22.2.8 CHEMOTACTIC SENSORS IN MSR-1 584
22.2.9 ON THE POSSIBILITY OF MAGNETORECEPTION IN MAGNETOTACTIC
BACTERIA 585
22.2.10 CONCLUSIONS 586
REFERENCES 586
INDEX 597
|
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV043637276 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:31:11Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527338825 9783527691395 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-029051177 |
| oclc_num | 952566019 |
| open_access_boolean | |
| owner | DE-11 DE-19 DE-BY-UBM DE-634 DE-29 |
| owner_facet | DE-11 DE-19 DE-BY-UBM DE-634 DE-29 |
| physical | XXVIII, 598 Seiten Illustrationen, Diagramme (teilweise farbig) |
| publishDate | 2016 |
| publishDateSearch | 2016 |
| publishDateSort | 2016 |
| publisher | Wiley-VCH Verlag GmbH & Co. KGaA |
| record_format | marc |
| spelling | Faivre, Damien 1977- (DE-588)1082258423 edt Iron oxides from nature to applications edited by Damien Faivre Weinheim Wiley-VCH Verlag GmbH & Co. KGaA [2016] © 2016 XXVIII, 598 Seiten Illustrationen, Diagramme (teilweise farbig) txt rdacontent n rdamedia nc rdacarrier Eisenoxide (DE-588)4151589-4 gnd rswk-swf Anorganische Chemie Chemie Chemistry Earth Sciences Geochemie, Mineralogie Geochemistry & Minerology Geowissenschaften Industrial Chemistry Inorganic Chemistry Nanomaterialien Nanomaterials Nanotechnologie Nanotechnology Technische u. Industrielle Chemie (DE-588)4143413-4 Aufsatzsammlung gnd-content Eisenoxide (DE-588)4151589-4 s DE-604 Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, EPUB 978-3-527-69138-8 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-69137-1 Erscheint auch als Online-Ausgabe, PDF 978-3-527-69136-4 http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-33882-5/ Verlag DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029051177&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Iron oxides from nature to applications Eisenoxide (DE-588)4151589-4 gnd |
| subject_GND | (DE-588)4151589-4 (DE-588)4143413-4 |
| title | Iron oxides from nature to applications |
| title_auth | Iron oxides from nature to applications |
| title_exact_search | Iron oxides from nature to applications |
| title_full | Iron oxides from nature to applications edited by Damien Faivre |
| title_fullStr | Iron oxides from nature to applications edited by Damien Faivre |
| title_full_unstemmed | Iron oxides from nature to applications edited by Damien Faivre |
| title_short | Iron oxides |
| title_sort | iron oxides from nature to applications |
| title_sub | from nature to applications |
| topic | Eisenoxide (DE-588)4151589-4 gnd |
| topic_facet | Eisenoxide Aufsatzsammlung |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-33882-5/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029051177&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT faivredamien ironoxidesfromnaturetoapplications AT wileyvch ironoxidesfromnaturetoapplications |