Photocatalysis: applications
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| Other Authors: | , , , , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Cambridge
Royal Society of Chemistry
[2016]
|
| Series: | RSC energy and environment series
no. 15 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | xiii, 380 Seiten Illustrationen, Diagramme (teilweise farbig) |
| ISBN: | 9781782627098 9781782627142 |
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Record in the Search Index
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| adam_text | Contents
Chapter 1 Photocatalytic Degradation of Organic Contaminants in
Water: Process Optimization and Degradation Pathways 1
Maria G. Antoniou, Cen Zhao, Kevin E. OfSheaf Geshan
Zhang; Dionysios D. Dionysiou, Chun Zhaof Changseok Han,
Mallikarjuna N. Nadagouda, Hyeok Choi, Theodora Fotiou,
Theodoros M. Triantis, and Anastasia Hiskia
1.1 Introduction 2
1.2 Degradation Efficiency-Kinetics of Emerging
Contaminants 7
1.2.1 Photocatalytic Degradation of Cyanotoxins 7
1.2.2 Photocatalytic Degradation and Detoxification
of Oxytetracycline 7
1.3 Effects of Water Quality Parameters on the
Photocatalytic Degradation of Emerging
Contaminants 9
1.3.1 Effects of General Water Quality Parameters 9
1.3.2 Effects of Natural Organic Matter (NOM) and
Selectivity 11
1.4 Transformation Mechanistic Pathways and Reaction
Intermediates 13
1.4.1 Transformation Products of Compounds
Resulting from the Reaction of Carbon Bonds 14
1.4.2 Transformation Products of Compounds
Resulting from the Reaction of Heteroatoms 24
1.5 Conclusions 29
Acknowledgements 29
References 30
RSC Energy and Environment Series No. 15
Photocatalysis: Applications
Edited by Dionysios D Dionysiou, Gianluca Li Puma, Jinhua Ye, Jenny Schneider,
and Detlef Bahnemann
© The Royal Society of Chemistry 2016
Published by the Royal Society of Chemistry, www.rsc.org
vii
viii
Contents
Chapter 2 Photocatalytic Removal of Metallic and Other Inorganic
Pollutants 35
Marta I. Litter, Natalia Quici,J.
and Alejandro M. Senn
2.1 Introduction 35
2.2 Thermodynamical Considerations and
Mechanistic Pathways 38
2.3 Chromium 41
2.4 Mercury 46
2.5 Lead 48
2.6 Uranium 50
2.7 Arsenic 52
2.8 Nitrate 56
2.9 Conclusions 59
References 61
Chapter 3 Solar Photocatalytic Disinfection of Water 72
Pilar Femândez-Ibânez, J. Anthony Byrne, M. Inmaculada
Polo-Lôpez, Patrick S. M. Dunlop, Popi Karaolia,
and Despo Fatta-Kassinos
3.1 Solar Disinfection of Water 72
3.1.1 Solar Spectrum and SODIS Method 72
3.1.2 Oxidative Stress Caused by UV Radiation 73
3.2 Solar Photocatalytic Disinfection of Water 75
3.2.1 Mechanisms of Ti02 Photocatalytic Disinfection 75
3.2.2 Microbiological Aspects of Photocatalytic
Disinfection 77
3.2.3 Inactivation of Antibiotic-Resistant Bacteria 80
3.3 Novel Photocatalytic Materials for Visible Light
Activity 82
3.3.1 Doped Materials 83
3.3.2 Other New Materials 83
3.4 Solar Photocatalytic Reactors for Water Disinfection 85
3.5 Conclusions 87
References 88
Chapter 4 Solar Photocatalysis: Fundamentals, Reactors and
Applications 92
Javier Marugân, Maria José Lopez-Munoz,
Pilar Femândez-Ibânez, and Sixto Malato
4.1 Solar Light 92
4.1.1 Extraterrestrial Irradiance and Spectrum 93
4.1.2 Solar Vector 95
4.1.3 Irradiance at the Earth Surface 96
Contents
ix
4.2 Solar Photocatalytic Reactors 102
4.2.1 Types of Reactors 102
4.2.2 Design of Solar Photocatalytic Reactors 103
4.2.3 Solar Reactors for Water Disinfection 104
4.3 Photocatalytic Materials for Solar Applications 108
4.3.1 Titanium Dioxide 108
4.3.2 Ti02 Modification for Solar Applications 109
4.3.3 Mode of Utilisation 113
4.4 Applications of Solar Photocatalysis 116
4.4.1 Non-Concentrating Solar Reactors Applications 117
4.4.2 CPC Solar Reactors Applications 117
4.5 Integration with Other Unit Operations 120
Acknowledgements 123
References 123
Chapter 5 Combined Photocatalysis-Separation Processes
for Water Treatment Using Hybrid Photocatalytic
Membrane Reactors 130
Teik-Thye Lim and Ronn Goei
5.1 Introduction 130
5.2 TiOa and Application for Water Treatment 132
5.3 Separation Process with Ceramic Membrane 135
5.4 Fabrication of Ti02-Coated Ceramic Membrane 137
5.5 Performance of Photocatalytic Ceramic Membrane 141
5.6 Future Outlook and Challenges 150
References 151
Chapter 6 Process Integration. Concepts of Integration and
Coupling of Photocatalysis with Other Processes 157
Sixto Malato, Pilar Fernández-Ibáñez, Isabel Oiler,
Inmaculada Polo, Manuel I. Maldonado,
Sara Miralles-Cuevas, and Ricardo Sánchez
6.1 Introduction 157
6.2 Treatment of Biorecalcitrant Wastewater by
Integrating Solar Photocatalysis and Other
Processes 159
6.3 Partially Biorecalcitrant Wastewater Treatment
by Integrating Solar Photocatalysis and Other
Processes 165
6.4 Removal of Micropollutants in Water and
Wastewater by Integrating Solar Photocatalysis
and Membrane Nanofiltration 167
6.5 Conclusions and Recommendations 171
Acknowledgements 171
References 172
X
Contents
Chapter 7 Photocatalytic Purification and Disinfection of Air 174
Alexander Vorontsov
7.1 Introduction 174
7.2 Photocatalytic Reactions for Air Purification 177
7.3 Photocatalysts and Their Supports for Air
Purification 180
7.4 Kinetics of Photocatalytic Oxidation 184
7.5 Photocatalytic Destruction of Microbiological
Objects 189
7.6 Reactors for Photocatalytic Air Treatment 190
7.7 Combined Methods of Air Purification 194
7.8 Conclusions 197
List of Abbreviations and Designations 197
Acknowledgements 197
References 197
Chapter 8 Self-Cleaning Photocatalytic Activity: Materials and
Applications 204
Niall B. McGuinness, Honey John, Maheswari K. Kavitha,
Swagata Banerjee, Dionysios D. Dionysiou,
and Suresh C. Pillai
8.1 Introduction to Self-Cleaning Materials 204
8.2 Mechanism of Self-Cleaning Activity 205
8.2.1 Light-Induced Hydroxylation of the Surface 209
8.2.2 Photo-Oxidation of Adsorbed Hydrocarbons
on the Surface 210
8.3 Photocatalytic Materials 211
8.3.1 Titanium Dioxide 211
8.3.2 Rapid Testing of Self-Cleaning
Photocatalytic Activity 212
8.3.3 Photocatalytic Antibacterial Activity 213
8.4 Semiconductor Doping and Ti02/Si02 Composites 214
8.4.1 Self-Cleaning Activity 214
8.4.2 Antireflective Properties 216
8.4.3 Metal Doped Coatings 219
8.5 Semiconductor Hybrids and Future Materials 220
8.5.1 Carbon Nanotube Hybrids of Ti02 or ZnO 220
8.5.2 Graphene Hybrids of Metal Oxides 221
8.5.3 Graphene/Ti02 Nanohybrids 222
8.5.4 ZnO/Graphene Nanohybrids 224
8.5.5 Ti02/p Cyclodextrin Encapsulated Fullerene
(C60) Composites 224
8.5.6 Conducting Polyaniline/Metal Oxide or
Graphene Oxide Hybrids 225
Contents
xi
8.6 Self-Cleaning and Superhydrophilic Coating on
Polymer Substrates 226
8.7 Commercial Materials 227
Acknowledgements 228
References 228
Chapter 9 Photocatalysis and Photoelectrocatalysis for Energy
Generation Using PhotoFuelCells 236
Panagiotis Lianos, Stavroula Sfaelou, and
Lucian-Cristian Pop
9.1 Introduction 236
9.2 Basic Features of PhotoFuelCell Operation 239
9.3 PhotoFuelCell Configurations and Related
Applications 243
9.4 Selected Results and Discussion 245
9.4.1 PFC Used for Electricity Production
Employing Ethanol as Organic Fuel 245
9.4.2 PFC Used Exclusively for Hydrogen
Production Employing Ethanol as
Organic Fuel 250
9.5 Experimental Section: Construction of
Electrodes and Devices 250
9.5.1 Materials 250
9.5.2 Preparation of Ti02 Films and Deposition
of CdS by the SILAR Method 251
9.5.3 Construction of the Counter Electrode 252
9.5.4 Device (Reactor) Construction 252
9.5.5 Measurements 253
Acknowledgements 253
References 253
Chapter 10 Photocatalytic Hydrogen Generation 255
Xin Li, Jingxiang Low,andjiaguo Yu
10.1 Introduction 255
10.2 Fundamentals of Photocatalytic Hydrogen
Generation 257
10.2.1 Thermodynamics of Photocatalytic
Hydrogen Generation 257
10.2.2 Materials and Systems for Photocatalytic
Hydrogen Production 259
10.2.3 Mechanisms and Processes of Photocatalytic
Hydrogen Production 264
10.3 Promoted Charge Separation and Transport 265
10.3.1 Improvement of the Crystallinity 265
xii
Contents
10.3.2 Rational Design of Nanostructures 266
10.3.3 Application of Carbon-Based Nanomaterials 268
10.3.4 Manipulation of Internal Electric Fields 274
10.4 Accelerated H2-Evolution Kinetics 277
10.4.1 Increasing the Active Surface Areas 277
10.4.2 Loading of H2-Evolution Co-Catalysts 278
10.4.3 Elevation of Conduction Band Positions 283
10.5 Increased Stability of Photocatalyst 285
10.5.1 Addition of Sacrificial Reagents 285
10.5.2 Introduction of a Protective Layer 287
10.5.3 Utilization of Water Oxidation Co-Catalysts 288
10.6 Conclusions, Perspectives and Remarks 289
Acknowledgements 290
References 290
Chapter 11 New Synthetic Routes in Heterogeneous Photocatalysis 303
Giovanni Palmisano, Angelo Albini, Giuseppe Marci,
Leonardo Palmisano, and Davide Ravelli
11.1 Introduction 303
11.2 Reactions 304
11.2.1 Oxidations 305
11.2.2 Reductions 313
11.2.3 Alkylations 321
11.3 Influence of Catalyst Properties on Selectivity 328
11.4 Green Organic Solvents in Photocatalysis 333
11.5 Conclusion 337
References 337
Chapter 12 An Overview of the Potential Applications of Ti02
Photocatalysis for Food Packaging, Medical Implants,
and Chemical Compound Delivery 345
Pierre Pichat
12.1 Introduction 345
12.2 Potential Advantages of Ti02 Photocatalysis for
Food Packaging 346
12.2.1 Generalities 346
12.2.2 Effect of Ti02 on the Package Physical
Properties 347
12.2.3 Effect of TiOa on the Package Antibacterial
Properties 347
12.2.4 Effect of Ti02 on the Concentrations of
C2H4 and 02 in Packages 350
12.2.5 Potential Barriers to the Use of Ti02 in
Packages
353
Contents
xiii
12.3 Roles of Ti02 and Ti02 Photocatalysis in Medical
Implants 353
12.3.1 Role of Non-UV-Irradiated Ti02 353
12.3.2 Roles of UV-Irradiated Ti02 354
12.4 Potential Use of TiOz Photocatalysis for Chemical
Compound Delivery 356
12.4.1 Generalities 356
12.4.2 Use of Ti02 Nanotubes Containing the
Chemical to be Delivered 357
12.4.3 Use of Ti02 Photocatalysis to Deliver
Chemicals Contained in Microcapsules 360
12.4.4 Issues About the Use of Ti02 Photocatalysis
for Delivery of Chemicals 362
12.5 Conclusions 363
12.5.1 Food Packaging 363
12.5.2 Medical Implants 363
12.5.3 Chemical Compound Delivery 364
12.5.4 Comparisons About the Viability of
These Three Applications 364
References 365
Subject Index 368
From environmental remediation to alternative fuels, this book
explores the numerous important applications of photocatalysis.
The book covers topics such as the photocatalytic processes in the
treatment of water and air; the fundamentals of solar photocatalysis;
the challenges involved in developing self-cleaning photocatalytic
materials; photocatalytic hydrogen generation; photocatalysts in the
synthesis of chemicals; and photocatalysis in food packaging and
biomedical and medical applications. The book also critically discusses
concepts for the future of photocatalysis, providing a fascinating
insight for researchers.
Together with Photocatalysis: Fundamentals and Perspectives, these
volumes provide a complete overview of photocatalysis.
Front cover image © Shutterstock
ISBN 978-1-78262-709-8
|
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| id | DE-604.BV043554352 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:28:43Z |
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| publisher | Royal Society of Chemistry |
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| series | RSC energy and environment series |
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| spelling | Photocatalysis applications edited by Dionysios D Dionysiou, Gianluca Li Puma, Jinhua Ye, Jenny Schneider, Detlef Bahnemann Cambridge Royal Society of Chemistry [2016] © 2016 xiii, 380 Seiten Illustrationen, Diagramme (teilweise farbig) txt rdacontent n rdamedia nc rdacarrier RSC energy and environment series no. 15 Fotokatalyse (DE-588)4193873-2 gnd rswk-swf Fotokatalyse (DE-588)4193873-2 s 1\p DE-604 Dionysiou, Dionysios D. (DE-588)1100723498 edt Li Puma, Gianluca edt Ye, Jinhua edt Schneider, Jenny (DE-588)1100701605 edt Bahnemann, Detlef 1953- (DE-588)171963172 edt Erscheint auch als Online-Ausgabe, EPUB 978-1-78262-798-2 Erscheint auch als Online-Ausgabe, PDF 978-1-78262-710-4 RSC energy and environment series no. 15 (DE-604)BV036744686 15 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028969541&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028969541&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Photocatalysis applications RSC energy and environment series Fotokatalyse (DE-588)4193873-2 gnd |
| subject_GND | (DE-588)4193873-2 |
| title | Photocatalysis applications |
| title_auth | Photocatalysis applications |
| title_exact_search | Photocatalysis applications |
| title_full | Photocatalysis applications edited by Dionysios D Dionysiou, Gianluca Li Puma, Jinhua Ye, Jenny Schneider, Detlef Bahnemann |
| title_fullStr | Photocatalysis applications edited by Dionysios D Dionysiou, Gianluca Li Puma, Jinhua Ye, Jenny Schneider, Detlef Bahnemann |
| title_full_unstemmed | Photocatalysis applications edited by Dionysios D Dionysiou, Gianluca Li Puma, Jinhua Ye, Jenny Schneider, Detlef Bahnemann |
| title_short | Photocatalysis |
| title_sort | photocatalysis applications |
| title_sub | applications |
| topic | Fotokatalyse (DE-588)4193873-2 gnd |
| topic_facet | Fotokatalyse |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028969541&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028969541&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV036744686 |
| work_keys_str_mv | AT dionysioudionysiosd photocatalysisapplications AT lipumagianluca photocatalysisapplications AT yejinhua photocatalysisapplications AT schneiderjenny photocatalysisapplications AT bahnemanndetlef photocatalysisapplications |