Enantioselective titanium-catalysed transformations:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London
Imperial College Press
[2016]
|
| Series: | Catalytic science series
vol. 14 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | xi, 265 Seiten Illustrationen |
| ISBN: | 9781783268948 |
Staff View
MARC
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| 100 | 1 | |a Pellissier, Hélène |e Verfasser |0 (DE-588)1097416917 |4 aut | |
| 245 | 1 | 0 | |a Enantioselective titanium-catalysed transformations |c Hélène Pellissier, CNRS, France |
| 264 | 1 | |a London |b Imperial College Press |c [2016] | |
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| 650 | 4 | |a Enantioselective catalysis | |
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Record in the Search Index
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| adam_text | Contents
General Introduction ix
Chapter 1 Enantioselective Titanium-Promoted Alkylation,
Arylation, Alkynylation, Allylation, and Vinylation
Reactions of Carbonyl Compounds 1
1.1. Introduction 1
1.2. Titanium-Promoted Alkylation and Arylation
Reactions of Carbonyl Compounds 3
1.2.1. Additions of Dialkylzinc Reagents to
Carbonyl Compounds 4
1.2.1.1. Aldehydes as electrophiles 4
1.2.1.2. Ketones as electrophiles 21
1.2.2. Additions of Organoaluminum Reagents
to Carbonyl Compounds 25
1.2.2.1. Aldehydes as electrophiles 25
1.2.2.2. Ketones as electrophiles 29
1.2.3. Additions of Grignard Reagents
to Aldehydes 33
1.2.4. Additions of Organotitanium Reagents
to Aldehydes 42
1.2.5. Additions of Alkylboron Reagents
to Aldehydes 45
V
vi Contents
1.2.6. Additions of Organolithium Reagents
to Aldehydes 48
1.3. Titanium-Promoted Alkynylation Reactions
of Carbonyl Compounds 51
1.3.1. Aldehydes as Electrophiles 51
1.3.1.1. Addition of phenylacetylene 52
1.3.1.2. Addition of various terminal alkynes 59
1.3.1.3. Addition of 1,3-diynes and 1,3-enynes 67
1.3.2. Ketones as Electrophiles 68
1.4. Titanium-Promoted Allylation and Vinylation
Reactions of Carbonyl Compounds 71
1.4.1. Allylations 71
1.4.2. Vinylations 75
1.5. Conclusions 78
References 79
Chapter 2 Enantioselective Titanium-Catalysed
Cyanation Reactions of Carbonyl
Compounds and Derivatives 85
2.1. Introduction 85
2.2. Aldehydes as Electrophiles 87
2.2.1. Cyanations of aldehydes with
trimethylsilyl cyanide 87
2.2.1.1. Salen ligands 87
2.2.1.2. BINOL-derived ligands 99
2.2.1.3. Schiffbase ligands 102
2.2.1.4. Other ligands 105
2.2.2. Cyanations of aldehydes with other
sources of cyanide 108
2.2.2.1. Salen ligands 108
2.2.2.2. Other ligands 112
2.3. Ketones as Electrophiles 118
2.4. Strecker-Type Reactions 122
2.5. Conclusions 126
References 127
Contents vii
Chapter 3 Enantioselective Titanium-Catalysed
Thioether Oxidations 133
3.1. Introduction 133
3.2. Alkyl Hydroperoxides as Oxidants 135
3.3. Hydrogen Peroxide as Oxidant 145
3.4. Conclusions 151
References 152
Chapter 4 Enantioselective Titanium-Catalysed
Epoxidation Reactions 155
4.1. Introduction 155
4.2. Epoxidations using Hydrogen Peroxide 156
4.3. Epoxidations using Alkyl Hydroperoxides 162
4.4. Darzens Reactions 163
4.5. Conclusions 167
References 167
Chapter 5 Enantioselective Titanium-Catalysed
Cycloaddition Reactions 169
5.1. Introduction 169
5.2. (Hetero)-Diels-Alder Cycloadditions 170
5.3. 1,3-Dipolar Cycloadditions 176
5.4. Cyclopropanations 180
5.5. Conclusions 182
References 183
Chapter 6 Enantioselective Titanium-Catalysed
Aldol-Type Reactions 187
Conclusions 196
References 197
Chapter 7 Enantioselective Titanium-Catalysed
Reduction Reactions 199
7.1. Introduction 199
7.2. Hydroaminations 200
7.3. Hydrophosphonylations 202
viii Contents
7.4. Miscellaneous Reductions 205
7.5. Conclusions 208
References 208
Chapter 8 Enantioselective Titanium-Catalysed
Ring-Opening Reactions of Epoxides
and Aziridines 211
8.1. Introduction 211
8.2. Ring-Opening Reactions of Epoxides 211
8.3. Ring-Opening Reactions of Aziridines 218
8.4. Conclusions 221
References 222
Chapter 9 Enantioselective Titanium-Catalysed
Domino and Tandem Reactions 223
Conclusions 232
References 233
Chapter 10 Enantioselective Titanium-Catalysed
Miscellaneous Reactions 237
10.1. Introduction 237
10.2. Michael-Type Reactions 237
10.3. Friedel-Crafts Reactions 241
10.4. Other Reactions 243
10.5. Conclusions 249
References 249
General Conclusions 251
References 252
Index 255
Enantioselective
Titanium-Catalysed
Transformations
Chiral titanium complexes are low-cost, low-toxicity and high-efficiency
catalysts. Impressive progress on enantioselective titanium-catalysed
transformations has been achieved in the past seven years, with exciting new
discoveries ranging from basic reactions to novel methodologies. Despite this,
the field has not been substantially reviewed since 2008.
This book contains up to date research and covers all types of enantioselective
transformations using chiral titanium catalysts. It illustrates the economic,
health, and environmental benefits of chiral titanium catalysts, showing the
types of highly enantioselective reactions that they are able to induce are
unlimited.
Work presented here is aimed at researchers in organic and catalytic
chemistry, and has been carefully curated to encourage future research
possibilities.
Imperial College Press
P1065 he
ISBN 978-1-78326-894-8
9 ”78 1783
III
268948
www.icpress.co.uk
|
| any_adam_object | 1 |
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| discipline | Chemie / Pharmazie |
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| indexdate | 2024-07-10T07:23:30Z |
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| language | English |
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| physical | xi, 265 Seiten Illustrationen |
| publishDate | 2016 |
| publishDateSearch | 2016 |
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| publisher | Imperial College Press |
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| series | Catalytic science series |
| series2 | Catalytic science series |
| spelling | Pellissier, Hélène Verfasser (DE-588)1097416917 aut Enantioselective titanium-catalysed transformations Hélène Pellissier, CNRS, France London Imperial College Press [2016] © 2016 xi, 265 Seiten Illustrationen txt rdacontent n rdamedia nc rdacarrier Catalytic science series vol. 14 Enantioselective catalysis Catalysts Titanium Catalytic science series vol. 14 (DE-604)BV013477807 14 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028761476&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028761476&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Pellissier, Hélène Enantioselective titanium-catalysed transformations Catalytic science series Enantioselective catalysis Catalysts Titanium |
| title | Enantioselective titanium-catalysed transformations |
| title_auth | Enantioselective titanium-catalysed transformations |
| title_exact_search | Enantioselective titanium-catalysed transformations |
| title_full | Enantioselective titanium-catalysed transformations Hélène Pellissier, CNRS, France |
| title_fullStr | Enantioselective titanium-catalysed transformations Hélène Pellissier, CNRS, France |
| title_full_unstemmed | Enantioselective titanium-catalysed transformations Hélène Pellissier, CNRS, France |
| title_short | Enantioselective titanium-catalysed transformations |
| title_sort | enantioselective titanium catalysed transformations |
| topic | Enantioselective catalysis Catalysts Titanium |
| topic_facet | Enantioselective catalysis Catalysts Titanium |
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