Modern enolate chemistry: from preparation to applications in asymmetric synthesis
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2016
|
| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | VIII, 443 S. Ill. |
| ISBN: | 9783527334520 9783527671069 |
Staff View
MARC
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| 653 | |a Chemie | ||
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| 653 | |a Enol | ||
| 653 | |a Methods - Synthesis & Techniques | ||
| 653 | |a Organische Chemie | ||
| 653 | |a Organische Chemie / Methoden, Synthesen, Verfahren | ||
| 653 | |a Organometallchemie | ||
| 653 | |a Organometallic Chemistry | ||
| 653 | |a Pharmaceutical & Medicinal Chemistry | ||
| 653 | |a Pharmazeutische u. Medizinische Chemie | ||
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Record in the Search Index
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| adam_text |
CONTENTS
PREFACE VII
1 INTRODUCTORY REMARKS 1
REFERENCES 7
2 GENERAL METHODS FOR THE PREPARATION OF ENOLATES 11
2.1 ENOLATE FORMATION BY DEPROTONATION 11
2.2 ENOLATE FORMATION BY CONJUGATE ADDITION TO YY,YY-YYNSATURATED
CARBONYL COMPOUNDS 51
2.3 ALKALI METAL ENOLATES BY CLEAVAGE OF ENOL ACETATES OR SILYL ENOL
ETHERS 60
2.4 ENOLATES FROM KETENES AND ORGANOLITHIUM COMPOUNDS 62
2.5 ENOLATES FROM A-HALOGEN-SUBSTITUTED CARBONYL COMPOUNDS BY
HALOGEN-METAL EXCHANGE 63
2.6 FORMATION OF ENOLATES BY TRANSMETALLATION 65
2.7 ENOLATES BY MISCELLANEOUS METHODS 70
REFERENCES 72
3 STRUCTURES OF ENOLA^ES 83
3.1 ENOLATES OF ALKALI AND ALKALINE EARTH METALS 83
3.2 ENOLATES OF OTHER MAIN GROUP METALS 98
3.3 TRANSITION METAL ENOLATES 100
REFERENCES 109
4 ENOLATES WITH CHIRAL AUXILIARIES IN ASYMMETRIC SYNTHESES 115
4.1 AUXILIARY-BASED ALKYLATION OF E
116
4.2 AUXILIARY-BASED ARYLATION OF ENOLATES 144
4.3 AUXILIARY-BASED ALDOL, VINYLOGOUS ALDOL, AND REFORMATSKY
REACTIONS 147
4.4 AUXILIARY-BASED MANNICH REACTIONS AND ESTER ENOLATELMINE
CONDENSATIONS 202
4.5 AUXILIARY-BASED CONJUGATE ADDITIONS 214
CONTENTS
4.6
5
5.1
5.2
5.3
5.4
5.5
5.6
5.7
AUXILIARY-BASED OXIDATION OF ENOLATES 227
REFERENCES 242
ENOLATES IN ASYMMETRIC CATALYSIS 257
ENANTIOSELECTIVE CATALYSIS IN ALKYLATIONS AND ALLYLATIONS OF
ENOLATES 257
ENANTIOSELECTIVE CATALYSIS FOR ENOLATE ARYLATION 300
CATALYTIC
YY
ENANTIOSELECTIVE ALDOL, VINYLOGOUS ALDOL
YY
AND REFORMATSKY
REACTIONS 309
CATALYTIC ENANTIOSELECTIVE MANNICH REACTIONS
YY
ESTER ENOLATE-IMINE
CONDENSATIONS, AND IMINE REFORMATSKY REACTIONS 352
CATALYTIC ENANTIOSELECTIVE CONJUGATE ADDITIONS 369
ENANTIOSELECTIVE PROTONATION OF ENOLATES 385
ENANTIOSELECTIVE OXIDATION OF ENOLATES 394
REFERENCES 408
LIST OF PROCEDURES 423
INDEX 437 |
| any_adam_object | 1 |
| author | Braun, Manfred 1948- |
| author_GND | (DE-588)1085658589 |
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| classification_rvk | VK 5500 |
| ctrlnum | (OCoLC)909796981 (DE-599)DNB1070857076 |
| dewey-full | 540 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 540 - Chemistry and allied sciences |
| dewey-raw | 540 |
| dewey-search | 540 |
| dewey-sort | 3540 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| indexdate | 2025-03-10T15:04:46Z |
| institution | BVB |
| isbn | 9783527334520 9783527671069 |
| language | English |
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| physical | VIII, 443 S. Ill. |
| publishDate | 2016 |
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| publisher | Wiley-VCH |
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| spelling | Braun, Manfred 1948- Verfasser (DE-588)1085658589 aut Modern enolate chemistry from preparation to applications in asymmetric synthesis Manfred Braun Weinheim Wiley-VCH 2016 VIII, 443 S. Ill. txt rdacontent n rdamedia nc rdacarrier Enolate (DE-588)4345140-8 gnd rswk-swf Asymmetrische Synthese (DE-588)4135603-2 gnd rswk-swf Chemie Chemistry Enol Methods - Synthesis & Techniques Organische Chemie Organische Chemie / Methoden, Synthesen, Verfahren Organometallchemie Organometallic Chemistry Pharmaceutical & Medicinal Chemistry Pharmazeutische u. Medizinische Chemie Enolate (DE-588)4345140-8 s Asymmetrische Synthese (DE-588)4135603-2 s DE-604 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-67108-3 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-67107-6 Erscheint auch als Online-Ausgabe, PDF 978-3-527-67109-0 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=5249460&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028747094&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Braun, Manfred 1948- Modern enolate chemistry from preparation to applications in asymmetric synthesis Enolate (DE-588)4345140-8 gnd Asymmetrische Synthese (DE-588)4135603-2 gnd |
| subject_GND | (DE-588)4345140-8 (DE-588)4135603-2 |
| title | Modern enolate chemistry from preparation to applications in asymmetric synthesis |
| title_auth | Modern enolate chemistry from preparation to applications in asymmetric synthesis |
| title_exact_search | Modern enolate chemistry from preparation to applications in asymmetric synthesis |
| title_full | Modern enolate chemistry from preparation to applications in asymmetric synthesis Manfred Braun |
| title_fullStr | Modern enolate chemistry from preparation to applications in asymmetric synthesis Manfred Braun |
| title_full_unstemmed | Modern enolate chemistry from preparation to applications in asymmetric synthesis Manfred Braun |
| title_short | Modern enolate chemistry |
| title_sort | modern enolate chemistry from preparation to applications in asymmetric synthesis |
| title_sub | from preparation to applications in asymmetric synthesis |
| topic | Enolate (DE-588)4345140-8 gnd Asymmetrische Synthese (DE-588)4135603-2 gnd |
| topic_facet | Enolate Asymmetrische Synthese |
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