Introduction to heterogeneous catalysis:
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| Main Authors: | , , |
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| Format: | Book |
| Language: | English |
| Published: |
London ; Singapore ; Hackensack, NJ
World Scientific, Imperial College Press
[2016]
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| Series: | Advanced textbooks in chemistry
vol. 1 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | xii, 333 Seiten Illustrationen, Diagramme |
| ISBN: | 9781786340801 9781786340818 9781783267873 9781783267866 |
| ISSN: | 2059-7673 |
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Record in the Search Index
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| adam_text | Titel: Introduction to heterogeneous catalysis
Autor: Prins, Roel
Jahr: 2016
Advanced Textbooks in Chemistry __Introduction to Heterogeneous Catalysis Roel Prins Institute for Chemical and Bioengineering, ETH Zurich, Switzerland Anjie Wang Dalian University of Technology, China Xiang Li Dalian University of Technology, China World Scientific ? Imperial College Press
Contents Preface v 1. Introduction 1 1.1 Catalysis and Catalysts..................... 1 1.2 Heterogeneous and Homogeneous Catalysis.......... 3 1.3 Production of Ammonia.................... 7 1.3.1 Kinetics and Thermodynamics............. 8 1.3.2 Activity, Selectivity and Stability ........... 11 1.3.3 H 2 Synthesis....................... 14 1.3.4 Ammonia Synthesis................... 18 1.4 Relevance of Catalysis..................... 22 References............................... 22 Questions............................... 23 2. Adsorption 25 2.1 Physisorption.......................... 25 2.1.1 Adsorption on Surfaces................. 28 2.1.2 Adsorption Isotherms.................. 30 2.1.3 Multilayer Adsorption, BET.............. 33 2.2 Surface Diffusion........................ 39 2.3 Chemisorption.......................... 42 2.3.1 Chemical Bonding.................... 42 2.3.2 Dissociative Chemisorption............... 50 References............................... 53 Questions............................... 54 ix.
x Contents 3. Catalyst Characterisation 55 3.1 Crystal Structures ........................ 55 3.2 X-Ray Diffraction........................ 62 3.3 Electron Microscopy ...................... 66 3.4 Scanning Tunnelling Microscopy and Atomic Force Microscopy........................ 71 3.5 Infrared and Raman Spectroscopy............... 73 3.6 Nuclear Magnetic Resonance.................. 81 3.7 Thermal Techniques ...................... 85 References............................... 88 Questions............................... 90 4. Catalyst Preparation 91 4.1 Heterogeneous Catalysts.................... 91 4.2 Aluminas............................. 94 4.2.1 Aluminium Hydroxides, Oxyhydroxides and Oxides........................ 95 4.2.2 Q-AI2O3 ......................... 100 4.2.3 7-AI2O3, 7-AI9O3 and y-Al20,3 101 4.2.4 Ö-AI2O3 and k,-A1 2 0 3 .................. 105 4.3 Surface of 7-AI2O3....................... 106 4.4 Silica............................... Ill 4.5 Zeolites.............................. 113 4.6 Preparation of Supported Catalysts.............. 122 References............................... 127 Questions............................... 129 5. Kinetics 131 5.1 Langmuir-Hinshelwood Model................. 131 5.2 Monomolecular Reaction.................... 133 5.2.1 Surface Reaction is Rate-Determining......... 134 5.2.2 Adsorption of the Reactant or Product is Rate-Determining................... 137 5.3 Bimolecular Reaction...................... 137 5.4 Influence of Diffusion...................... 139 Questions............................... 148
Contents xi 6. Metal Surfaces 149 6.1 Surface Structures........................ 149 6.2 Surface Analysis......................... 152 6.2.1 X-ray Photoelectron Spectroscopy........... 153 6.2.2 Auger Electron Spectroscopy.............. 156 6.2.3 Surface Sensitivity.................... 157 6.3 Surface Enrichment....................... 159 6.4 Metal Binding.......................... 164 References............................... 169 Questions............................... 171 7. Metal Catalysis 173 7.1 Dissociation of H 2 ........................ 174 7.2 Hydrogenation of Ethene.................... 177 7.3 Synthesis of CO and H 2 .................... 181 7.3.1 Bergius, Fischer-Tropsch and Methanation Reactions......................... 181 7.3.2 Production of CO and H 2 ................ 183 7.4 Hydrogenation of CO...................... 185 7.4.1 Fischer-Tropsch and Methanation........... 185 7.4. 1.1 CO dissociation................. 185 7.4. 1.2 Methanation.................. 190 7.4.1.3 Fischer-Tropsch reaction ........... 193 7.4.2 Methanol Synthesis................... 197 7.5 Hydrogenation of N 2 to Ammonia............... 201 7.5.1 Fe Catalyst........................ 201 7.5.2 Ru Catalyst....................... 203 7.6 Volcano Curves......................... 207 References............................... 211 Questions............................... 214 8. Catalysis by Acids 215 8.1 Reactions Catalysed by Solid Acids.............. 215 8.2 Reactions of Carbenium Ions.................. 217 8.3 Isomerisation of C 5 , C 6 and CJ ................ 224 8.4 Alcohols from Alkenes ..................... 231
Contents xii 8.5 Alkylation of Aromatics .................... 233 8.5.1 Ethylation and Propylation of Benzene ........ 233 8.5.2 Méthylation of Toluene................. 238 8.5.3 Isomerisation, Disproportionation, Transalkylation . . 242 8.6 Methanol to Hydrocarbons................... 247 8.7 Bifunctional Catalysis ..................... 253 8.7.1 Principles......................... 253 8.7.2 Industrially Relevant Bifunctional Catalysis ..... 262 References............................... 264 Questions............................... 267 9. Oxidation Catalysis 269 9.1 CO Oxidation.......................... 269 9.1.1 Mechanism........................ 269 9.1.2 Three-Way Catalysis.................. 276 9.2 Production of Sulphuric and Nitric Acid........... 279 9.2.1 Sulphuric Acid...................... 279 9.2.2 Nitric Acid........................ 281 9.3 Oxidation of Hydrocarbons .................. 284 9.3.1 Oxidation by Oxygen.................. 287 9.3.2 Oxidation by Hydroperoxide.............. 291 9.3.3 Selective Partial Oxidation of Hydrocarbons..... 295 9.3.3.1 Oxidation of propene to acrylic acid and acrylonitrile................ 295 9.3.3.2 Oxidation of C4 and C6 molecules...... 299 References............................... 300 Questions............................... 303 Answers 305 Index 321
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| spelling | Prins, Roel 1941- Verfasser (DE-588)1089120761 aut Introduction to heterogeneous catalysis Roel Prins (Institute for Chemical and Bioengineering, ETH Zurich, Switzerland), Anjie Wang (Dailan University of Technology, China), Xiang Li (Dailan University of Technology, China) London ; Singapore ; Hackensack, NJ World Scientific, Imperial College Press [2016] © 2016 xii, 333 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Advanced textbooks in chemistry vol. 1 2059-7673 Heterogene Katalyse (DE-588)4123377-3 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Heterogene Katalyse (DE-588)4123377-3 s DE-604 Wang, Anjie 1965- Verfasser (DE-588)1101842733 aut Li, Xiang Verfasser aut Advanced textbooks in chemistry vol. 1 (DE-604)BV043588784 1 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028713966&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
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| subject_GND | (DE-588)4123377-3 (DE-588)4123623-3 |
| title | Introduction to heterogeneous catalysis |
| title_auth | Introduction to heterogeneous catalysis |
| title_exact_search | Introduction to heterogeneous catalysis |
| title_full | Introduction to heterogeneous catalysis Roel Prins (Institute for Chemical and Bioengineering, ETH Zurich, Switzerland), Anjie Wang (Dailan University of Technology, China), Xiang Li (Dailan University of Technology, China) |
| title_fullStr | Introduction to heterogeneous catalysis Roel Prins (Institute for Chemical and Bioengineering, ETH Zurich, Switzerland), Anjie Wang (Dailan University of Technology, China), Xiang Li (Dailan University of Technology, China) |
| title_full_unstemmed | Introduction to heterogeneous catalysis Roel Prins (Institute for Chemical and Bioengineering, ETH Zurich, Switzerland), Anjie Wang (Dailan University of Technology, China), Xiang Li (Dailan University of Technology, China) |
| title_short | Introduction to heterogeneous catalysis |
| title_sort | introduction to heterogeneous catalysis |
| topic | Heterogene Katalyse (DE-588)4123377-3 gnd |
| topic_facet | Heterogene Katalyse Lehrbuch |
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