Photochemistry: past, present and future
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Heidelberg ; New York ; Dordrecht ; London
Springer
[2016]
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | x, 302 Seiten Diagramme, Illustrationen (teilweise farbig) |
| ISBN: | 3662479761 9783662479766 |
Internformat
MARC
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| 100 | 1 | |a Albini, Angelo |d 1946- |e Verfasser |0 (DE-588)140159193 |4 aut | |
| 245 | 1 | 0 | |a Photochemistry |b past, present and future |c Angelo Albini |
| 264 | 1 | |a Heidelberg ; New York ; Dordrecht ; London |b Springer |c [2016] | |
| 264 | 4 | |c © 2016 | |
| 300 | |a x, 302 Seiten |b Diagramme, Illustrationen (teilweise farbig) | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Fotochemie |0 (DE-588)4045873-8 |2 gnd |9 rswk-swf |
| 653 | |a Research | ||
| 653 | |a Photochemistry history | ||
| 653 | |a Discovery photochemical reactions | ||
| 653 | |a Excited states evolution | ||
| 653 | |a Photochemistry applications | ||
| 653 | |a Photochemistry in medicine | ||
| 653 | |a Photochemistry in nanotechnology | ||
| 653 | |a Photochemistry and the environment | ||
| 653 | |a Deep into time resolution | ||
| 653 | |a Deep into space resolution | ||
| 689 | 0 | 0 | |a Fotochemie |0 (DE-588)4045873-8 |D s |
| 689 | 0 | |5 DE-604 | |
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Datensatz im Suchindex
| _version_ | 1804175685363695616 |
|---|---|
| adam_text | CONTENTS
1 EARLY TIMES OF PHOTOCHEMISTRY 1
1.1 INTRODUCTION 1
1.2 LIGHT AND CHEMISTRY 3
1.3 HISTORIC NOTES 4
REFERENCES 7
2 THE FRAMEWORK OF PHOTOCHEMISTRY: THE LAWS 9
2.1 THE RELATION WITH LIGHT WAVELENGTH 10
2.2 RELATION WITH LIGHT INTENSITY 16
2.3 EARLY ATTEMPTS TO RATIONALIZE PHOTOCHEMICAL REACTIONS 18
2.4 RELATION WITH LIGHT QUANTA 22
2.5 MEASURED QUANTUM YIELD 25
2.6 MECHANISM 33
2.7 KINETICS 34
2.8 THE LAWS OF PHOTOCHEMISTRY 35
REFERENCES 37
3 THE FRAMEWORK OF PHOTOCHEMISTRY: STATE DIAGRAM 41
3.1 ABSORPTION/EMISSION 41
3.2 THE TRIPLET STATE: EMISSION 42
3.3 THE TRIPLET STATE: REACTIONS 52
3.4 PARADIGMS OF PHOTOCHEMISTRY 56
3.5 GENERALIZED USE OF THE STATE DIAGRAM 57
3.6 MOVING ALONG THE STATES 58
REFERENCES 60
4 SOME PARADIGMATIC TOPICS 63
4.1 PHOTOCHEMISTRY FOR SYNTHESIS 63
4.1.1 SOME EXEMPLARY CASES OF EARLY REPORTED
PHOTOREACTIONS: SANTONIN, ANTHRACENE, 2+2
CYCLOADDITION 65
4.1.2 THE SYNTHETIC POTENTIAL OF PHOTOCHEMISTRY 74
VII
HTTP://D-NB.INFO/1072559072
VIII CONTENTS
4.1.3 A GREEN SYNTHETIC METHOD 78
4.2 BORN TO MEASURE 79
4.2.1 O-NITROBENZALDEHYDE AND THE EQUIVALENCE LAW 79
4.2.2 MECHANISM: EARLY STUDIES 81
4.2.3 MECHANISM: MODERN STUDIES 83
4.2.4 O-NITROBENZALDEHYDE AS AN ACTINOMETER 85
4.3 OXYGENATION REACTIONS AND SINGLET OXYGEN 87
4.3.1 PHOTOSENSITIZED OXYGENATIONS IN BIOLOGIC SYSTEMS . . . 87
4.3.2 OXYGENATION REACTIONS 88
4.3.3 MECHANISM 90
4.4 INORGANIC PHOTOCHEMISTRY 95
4.4.1 EARLY WORK 95
4.4.2 PHOTOCHEMISTRY AND PHOTOPHYSICS OF TRANSITION METAL
COMPLEXES 97
4.4.3 TRANSITION METAL COMPLEXES AS SENSITIZERS 99
4.5 ENERGY FROM THE SUN 101
4.5.1 CIAMICIAN IN 1912 101
4.5.2 BODENSTEIN IN 1915 103
4.5.3 THE BEGINNING OF PHOTOCATALYSIS 105
4.6 CURSORY ELEMENTS OF PHOTOBIOLOGY 106
4.6.1 PHOTOSYNTHESIS 107
4.6.2 VISION 114
4.6.3 VITAMIN D 116
4.6.4 MEDICINAL APPLICATIONS OF PHOTOCHEMISTRY 117
REFERENCES 121
5 THE ROLE OF PHOTOCHEMISTRY IN CHEMISTRY 131
5.1 PHOTOCHEMISTRY IN CHEMISTRY MEETINGS 131
5.2 THE ROLE OF PHOTOCHEMISTRY, 1912-2013 133
5.3 PUBLICATIONS IN PHOTOCHEMISTRY 134
REFERENCES 136
6 PHOTOCHEMISTRY, A POWERFUL SCIENCE 139
6.1 HARRY POTTER MEETS PHOTOCHEMISTRY 139
6.2 THIS IS HOW IT HAPPENS: TIME-RESOLVED SPECTROSCOPY IN
PHOTOCHEMISTRY 142
6.2.1 FLASH PHOTOLYSIS WITH LAMPS 143
6.2.2 LASER FLASH PHOTOLYSIS AND PUMP-PROBE
SPECTROSCOPY 148
6.2.3 TWO-COLOR FLASH PHOTOLYSIS 153
6.2.4 LOCAL INTERACTIONS 154
6.2.5 FLASH PHOTOLYSIS WITH DIFFERENT DETECTION 157
6.3 THIS IS HOW IT HAPPENS: BLOCKING THE INTERMEDIATES 158
6.4 ANYTHING YOU CAN DO, PHOTOCHEMISTRY CAN DO BETTER:
GENERATING INTERMEDIATES 164
6.4.1 CARBOCATIONS 165
6.4.2 CARBENES 168
CONTENTS IX
6.4.3 NITRENES 169
6.4.4 AROMATIC BIRADICALS: DIDEHYDROBENZENES AND
DIDEHYDROTOLUENES 172
6.5 ANYTHING YOU CAN DO PHOTOCHEMISTRY CAN DO BETTER: MAKING
(STRAINED) MOLECULES 175
REFERENCES 179
7 OF EXCITED STATES AGAIN 183
7.1 EXPANDING THE STATE DIAGRAM 183
7.2 UPCONVERSION 187
7.3 MULTIPHOTONIC PROCESSES 190
7.4 QUANTUM YIELD OF EXCITED STATES LARGER THAN ONE 191
7.5 ULTRAFAST PROCESSES 193
7.6 REACTIONS VIA UPPER STATES 194
7.7 THE FUTURE OF PHOTOCHEMISTRY 199
REFERENCES 201
8 PHOTOCHEMICAL AND PHOTOCATALYZED SYNTHESIS 205
8.1 APPLICATION IN SYNTHESIS: SYNTHETIC SEQUENCES 205
8.1.1 PHOTOCHEMICAL STEPS IN SYNTHETIC PLANNING 206
8.1.2 OLD AND NEW STRATEGIES IN SYNTHESIS 209
8.1.3 SYNTHESIS VIA CHIRAL AUXILIARY 211
8.2 ASYMMETRIC (PHOTOCHEMICAL) SYNTHESIS 212
8.2.1 ABSOLUTE ASYMMETRIC SYNTHESIS 212
8.2.2 CHIRALITY TRANSFER 213
8.3 CATALYSIS 214
8.3.1 ORGANOCATALYSIS 214
8.3.2 CATALYSIS: ONLY THE COMPLEXED REAGENT IS ACTIVATED ... 215
8.3.3 CATALYSIS: ATROPISOMENSM 216
8.3.4 CATALYSIS: ONLY THE COMPLEXED FORM IS REACTIVE 217
8.3.5 BY USING A STRONG CHIRAL COMPLEX IN A WAY TO LIMIT
REVERSIBILITY, EVEN WHEN HINDERED 218
8.3.6 POLYFUNCTIONAL CATALYSIS 219
8.3.7 BY RESORTING TO AN INTRINSICALLY FAST REACTION, SUCH AS
PROTON TRANSFER 220
8.3.8 CATALYSIS: CHIRAL MEMORY 221
8.3.9 ONE-POT CATALYTIC PROCEDURE 222
REFERENCES 222
9 MEDICINAL AND DIAGNOSTIC APPLICATIONS 227
9.1 WHERE AND WHEN 227
9.1.1 PHOTOCHEMICAL DRUG RELEASE 227
9.1.2 APPLICATIONS WITH UV LIGHT 228
9.1.3 APPLICATION WITH NEAR IR 229
9.1.4 NANOPARTICLES 230
9.1.5 TRANSITION METAL COMPLEXES 232
X CONTENTS
9.2 PHOTOCHEMICAL INTERNALIZATION 233
9.3 UPCONVERSION FOR THE PHOTOACTIVATION OF DRUGS 233
9.4 DIAGNOSTIC APPLICATIONS: TWO-PHOTON FLUORESCENCE 235
9.5 DIAGNOSTIC APPLICATIONS. AGGREGATION-ENHANCED
FLUORESCENCE 239
9.6 ANTIMICROBICS 241
REFERENCES 242
10 SOLAR ENERGY CONVERSION 245
10.1 NON-PHOTOSYNTHETIC STRATEGIES 246
10.2 ARTIFICIAL PHOTOSYNTHESIS 247
10.3 DYE-SENSITIZED SOLAR CELLS 253
10.4 COMPARING DIFFERENT APPROACHES 254
10.5 SINGLET FISSION 256
10.6 HYDROGEN AS AN ENERGY CARRIER 257
10.7 SOCIOECONOMIC ISSUES 258
REFERENCES 259
11 ACTUATORS 263
11.1 PHOTOCHROMISM 263
11.1.1 FLUORESCENT SWITCHES 263
11.1.2 ELECTRICAL FUNCTIONS OF PHOTOCHROMIC MOLECULES 268
11.2 TWO COLOR/ONE COLOR 269
11.3 PHOTOMECHANICAL ACTUATORS 272
11.3.1 MOLECULAR MOTORS FROM MOLECULAR MOVEMENTS 272
11.3.2 MACROSCOPIC EFFECTS 273
11.3.3 MECHANICAL WORK FROM CRYSTAL DEFORMATIONS CAUSED
BY MOLECULAR TRANSFORMATIONS 277
11.4 SELF-ASSEMBLING 279
REFERENCES 281
12 PHOTOCHEMISTRY AND GREEN SYNTHESIS 285
12.1 PHOTOCHEMISTRY FOR BIORESOURCES 285
12.2 PREPARATIVE PHOTOCHEMISTRY 286
12.2.1 ASSESSING THE GREEN POTENTIAL 286
12.3 WHAT TO BE AFRAID OF AND WHAT NOT TO BE AFRAID OF IN
PHOTOCHEMICAL REACTIONS 288
12.4 METHOD OF IRRADIATION 291
12.5 SCALING UP A PHOTOCHEMICAL REACTION 292
12.6 DESTRUCTIVE GREEN PHOTOCHEMISTRY 295
REFERENCES 296
INDEX 299
|
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| dewey-ones | 541 - Physical chemistry 540 - Chemistry and allied sciences |
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| id | DE-604.BV043194520 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:20:13Z |
| institution | BVB |
| isbn | 3662479761 9783662479766 |
| language | English |
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| spelling | Albini, Angelo 1946- Verfasser (DE-588)140159193 aut Photochemistry past, present and future Angelo Albini Heidelberg ; New York ; Dordrecht ; London Springer [2016] © 2016 x, 302 Seiten Diagramme, Illustrationen (teilweise farbig) txt rdacontent n rdamedia nc rdacarrier Fotochemie (DE-588)4045873-8 gnd rswk-swf Research Photochemistry history Discovery photochemical reactions Excited states evolution Photochemistry applications Photochemistry in medicine Photochemistry in nanotechnology Photochemistry and the environment Deep into time resolution Deep into space resolution Fotochemie (DE-588)4045873-8 s DE-604 Erscheint auch als Online-Ausgabe 978-3-662-47977-3 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028618066&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Albini, Angelo 1946- Photochemistry past, present and future Fotochemie (DE-588)4045873-8 gnd |
| subject_GND | (DE-588)4045873-8 |
| title | Photochemistry past, present and future |
| title_auth | Photochemistry past, present and future |
| title_exact_search | Photochemistry past, present and future |
| title_full | Photochemistry past, present and future Angelo Albini |
| title_fullStr | Photochemistry past, present and future Angelo Albini |
| title_full_unstemmed | Photochemistry past, present and future Angelo Albini |
| title_short | Photochemistry |
| title_sort | photochemistry past present and future |
| title_sub | past, present and future |
| topic | Fotochemie (DE-588)4045873-8 gnd |
| topic_facet | Fotochemie |
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