Chirality from dynamic kinetic resolution:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
London
Royal Society of Chemistry
2011
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| Schlagworte: | |
| Online-Zugang: | FAW01 FAW02 Volltext |
| Beschreibung: | The last 15 years have witnessed significant developments in the efficiency and scope of the application of DKR. These now offer a serious alternative to conventional methods for asymmetric synthesis. Indeed, impressive examples using new enzymes and major progress in the DKR of racemates have taken place over the past few years. The powerful combination of enzymes and metals has also been the subject of spectacular development. In addition, a new type of DKR, involving organocatalysts, has recently appeared. Although asymmetric catalysis has undergone development during the last two decades, the most common industrial process used to obtain enantiomerically pure compounds is still via resolution of racemic mixtures. This is despite the major disadvantage that only a maximum of 50% product yield can be obtained. It is not surprising that DKR, which solves the problem of the limitation in yield, has attracted an increasing amount of interest from both the industrial and the academic perspective.This book provides an up-date on the principle methods employed to obtain dynamic kinetic resolution (DKR) by either enzymatic or non-enzymatic methods. It also illustrates the diversity of useful chiral products that can be obtained through this powerful concept. Divided into three sections, the book deals successively with non-enzymatic methods, enzymatic methods, and the use of transition metals and enzymes in tandem |
| Beschreibung: | 1 Online-Ressource (xviii, 299 p.) |
| ISBN: | 1849732671 9781849732673 |
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| 500 | |a The last 15 years have witnessed significant developments in the efficiency and scope of the application of DKR. These now offer a serious alternative to conventional methods for asymmetric synthesis. Indeed, impressive examples using new enzymes and major progress in the DKR of racemates have taken place over the past few years. The powerful combination of enzymes and metals has also been the subject of spectacular development. In addition, a new type of DKR, involving organocatalysts, has recently appeared. Although asymmetric catalysis has undergone development during the last two decades, the most common industrial process used to obtain enantiomerically pure compounds is still via resolution of racemic mixtures. This is despite the major disadvantage that only a maximum of 50% product yield can be obtained. It is not surprising that DKR, which solves the problem of the limitation in yield, has attracted an increasing amount of interest from both the industrial and the academic perspective.This book provides an up-date on the principle methods employed to obtain dynamic kinetic resolution (DKR) by either enzymatic or non-enzymatic methods. It also illustrates the diversity of useful chiral products that can be obtained through this powerful concept. Divided into three sections, the book deals successively with non-enzymatic methods, enzymatic methods, and the use of transition metals and enzymes in tandem | ||
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Datensatz im Suchindex
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| author | Pellissier, Hélène |
| author_facet | Pellissier, Hélène |
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| dewey-ones | 547 - Organic chemistry |
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| dewey-search | 547/.1223 |
| dewey-sort | 3547 41223 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| id | DE-604.BV043147804 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T07:18:55Z |
| institution | BVB |
| isbn | 1849732671 9781849732673 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-028571995 |
| oclc_num | 725827818 |
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| physical | 1 Online-Ressource (xviii, 299 p.) |
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| publishDate | 2011 |
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| spelling | Pellissier, Hélène Verfasser aut Chirality from dynamic kinetic resolution Hélène Pellissier London Royal Society of Chemistry 2011 1 Online-Ressource (xviii, 299 p.) txt rdacontent c rdamedia cr rdacarrier The last 15 years have witnessed significant developments in the efficiency and scope of the application of DKR. These now offer a serious alternative to conventional methods for asymmetric synthesis. Indeed, impressive examples using new enzymes and major progress in the DKR of racemates have taken place over the past few years. The powerful combination of enzymes and metals has also been the subject of spectacular development. In addition, a new type of DKR, involving organocatalysts, has recently appeared. Although asymmetric catalysis has undergone development during the last two decades, the most common industrial process used to obtain enantiomerically pure compounds is still via resolution of racemic mixtures. This is despite the major disadvantage that only a maximum of 50% product yield can be obtained. It is not surprising that DKR, which solves the problem of the limitation in yield, has attracted an increasing amount of interest from both the industrial and the academic perspective.This book provides an up-date on the principle methods employed to obtain dynamic kinetic resolution (DKR) by either enzymatic or non-enzymatic methods. It also illustrates the diversity of useful chiral products that can be obtained through this powerful concept. Divided into three sections, the book deals successively with non-enzymatic methods, enzymatic methods, and the use of transition metals and enzymes in tandem SCIENCE / Chemistry / Organic bisacsh Chemical kinetics fast Chirality fast Chemie Chirality Chemical kinetics Reaktionskinetik (DE-588)4048655-2 gnd rswk-swf Enantiomerentrennung (DE-588)4135272-5 gnd rswk-swf Enantiomerentrennung (DE-588)4135272-5 s Reaktionskinetik (DE-588)4048655-2 s 1\p DE-604 http://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=519333 Aggregator Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Pellissier, Hélène Chirality from dynamic kinetic resolution SCIENCE / Chemistry / Organic bisacsh Chemical kinetics fast Chirality fast Chemie Chirality Chemical kinetics Reaktionskinetik (DE-588)4048655-2 gnd Enantiomerentrennung (DE-588)4135272-5 gnd |
| subject_GND | (DE-588)4048655-2 (DE-588)4135272-5 |
| title | Chirality from dynamic kinetic resolution |
| title_auth | Chirality from dynamic kinetic resolution |
| title_exact_search | Chirality from dynamic kinetic resolution |
| title_full | Chirality from dynamic kinetic resolution Hélène Pellissier |
| title_fullStr | Chirality from dynamic kinetic resolution Hélène Pellissier |
| title_full_unstemmed | Chirality from dynamic kinetic resolution Hélène Pellissier |
| title_short | Chirality from dynamic kinetic resolution |
| title_sort | chirality from dynamic kinetic resolution |
| topic | SCIENCE / Chemistry / Organic bisacsh Chemical kinetics fast Chirality fast Chemie Chirality Chemical kinetics Reaktionskinetik (DE-588)4048655-2 gnd Enantiomerentrennung (DE-588)4135272-5 gnd |
| topic_facet | SCIENCE / Chemistry / Organic Chemical kinetics Chirality Chemie Reaktionskinetik Enantiomerentrennung |
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| work_keys_str_mv | AT pellissierhelene chiralityfromdynamickineticresolution |