Reactive absorption of carbon dioxide: experimental studies, physico-chemical modeling, and simulation
Saved in:
| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
Kaiserslautern
Techn. Univ., Laboratory of Engineering Thermodynamics
2014
|
| Series: | Scientific report series / Technische Universität Kaiserslautern, Laboratory of Engineering Thermodynamics
14 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XX, 104 S. graph. Darst. |
| ISBN: | 9783944433134 |
Staff View
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Record in the Search Index
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|---|---|
| adam_text | CONTENTS
XIII
CONTENTS
ABSTRACT IX
KURZFASSUNG XI
LIST OF SYMBOLS XVII
1 INTRODUCTION 1
2 PHYSICO-CHEMICAL MODEL 5
2.1 VAPOR-LIQUID EQUILIBRIUM 5
2.2 PITZER S MOLALITY SCALE BASED EQUATION FOR THE EXCESS GIBBS ENERGY
... 6
2.2.1 PROPERTIES OF PURE WATER 8
2.2.2 HENRY S CONSTANT FOR THE SOLUBILITY OF CO2 IN WATER AND PARTIAL
MOLAR VOLUMES AT INFINITE DILUTION OF CO2 IN WATER 9
2.3 CHEMICAL REACTION EQUILIBRIUM IN THE LIQUID PHASE 9
3 SOLUBILITY OF CARBON DIOXIDE IN AQUEOUS SOLUTIONS OF MONOETHANOL-
AMINE 11
3.1 INTRODUCTION 11
3.2 MATERIALS AND METHODS 11
3.2.1 SYNTHETIC GAS SOLUBILITY APPARATUS . 12
3.2.2 MATERIALS 14
3.3 EXPERIMENTAL RESULTS AND COMPARISON WITH LITERATURE DATA 14
3.4 THERMODYNAMIC MODEL 19
3.4.1 CHEMICAL REACTION EQUILIBRIA IN AQUEOUS SOLUTION OF C0
2
AND MEA 19
3.4.2 CHEMICAL EQUILIBRIUM CONSTANTS 20
3.4.3 HENRY S CONSTANT FOR THE SOLUBILITY OF CO2 AND MEA IN WATER . . 22
3.4.4 INTERACTION PARAMETERS IN PITZER S EQUATION FOR THE EXCESS GIBBS
ENERGY 23
3.5 SPECIATION STUDY - COMPARISON WITH NMR DATA 24
3.6 ENTHALPY OF ABSORPTION 27
HTTP://D-NB.INFO/1072398745
XIV CONTENTS
4 SOLUBILITY OF CARBON DIOXIDE IN AQUEOUS SOLUTIONS OF ACTIVATED HOT
POTASH 29
4.1 INTRODUCTION 29
4.2 CHEMICAL REACTIONS 30
4.3 EXPERIMENTAL DATA 32
4.4 THERMODYNAMIC MODEL 32
4.4.1 CHEMICAL REACTION EQUILIBRIUM CONSTANTS 33
4.4.2 HENRY S CONSTANT FOR THE SOLUBILITY OF CO2 IN WATER * . . 36
4.4.3 INTERACTION PARAMETERS IN PITZER S EQUATION FOR THE EXCESS GIBBS
ENERGY 36
4.5 COMPARISON WITH LITERATURE DATA AND MODEL RESULTS 38
5 PREDICTING SUPERSATURATION BY RATE-BASED SIMULATIONS OF REACTIVE
ABSORPTION 47
5.1 INTRODUCTION 47
5.2 SATURATION AND NUCLEATION 48
5.3 RATE-BASED MODEL AND SIMULATION 50
5.3.1 CHEMICAL SYSTEM AND THERMODYNAMIC MODEL 51
5.3.2 SIMULATIONS 51
5.4 RESULTS AND DISCUSSION 53
5.4.1 BASE CASE 53
5.4.2 PARAMETER VARIATIONS . 56
5.4.2.1 TEMPERATURE OF THE RICH GAS 56
5.4.2.2 TEMPERATURE OF THE LEAN SOLVENT 56
5.4.2.3 MASS AND COMPOSITION OF CONDENSATE 58
5.4.2.4 CONCENTRATION OF CO2 IN THE RICH GAS 58
5.4.2.5 CASE WITHOUT
CO2 61
5.4.3 INFLUENCE OF A WASHING SECTION 61
5.4.4 CO2 REMOVAL RATE 64
6 CONCLUSION 65
LITERATURE 67
APPENDIX 82
A SUPPLEMENTARY MATERIAL: SOLUBILITY OF C0
2
IN AQUEOUS MEA SOLUTION 82
A.L ENTHALPY OF ABSORPTION 82
A.2 EXPERIMENTAL RESULTS FOR THE SOLUBILITY OF CARBON DIOXIDE 84
A.3 EXPERIMENTAL RESULTS FOR THE DENSITY 86
CONTENTS XV
B SUPPLEMENTARY MATERIAL: SOLUBILITY OF CO2 IN AQUEOUS POTASH SOLU
TION 87
B.L ENTHALPY MODEL 87
B.L.L VAPOR PHASE 87
B.L.2 LIQUID PHASE 87
B.1.3 MODEL PARAMETERS 89
B.2 EXPERIMENTAL RESULTS FOR THE SOLUBILITY OF CARBON DIOXIDE 92
B.3 EXPERIMENTAL RESULTS FOR THE DENSITY 96
C DOUBLE-STIRRED CELL 97
C.L EXPERIMENTAL SETUP 97
C.2 EXPERIMENTAL PROCEDURE 101
DECLARATION 102
STUDENT THESES 104
CURRICULUM VITAE 105
|
| any_adam_object | 1 |
| author | Imle, Michael 1984- |
| author_GND | (DE-588)1072398605 |
| author_facet | Imle, Michael 1984- |
| author_role | aut |
| author_sort | Imle, Michael 1984- |
| author_variant | m i mi |
| building | Verbundindex |
| bvnumber | BV042660134 |
| ctrlnum | (OCoLC)912511577 (DE-599)DNB1072398745 |
| dewey-full | 660.2969 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering |
| dewey-raw | 660.2969 |
| dewey-search | 660.2969 |
| dewey-sort | 3660.2969 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| id | DE-604.BV042660134 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:06:52Z |
| institution | BVB |
| isbn | 9783944433134 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-028092386 |
| oclc_num | 912511577 |
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| physical | XX, 104 S. graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Techn. Univ., Laboratory of Engineering Thermodynamics |
| record_format | marc |
| series2 | Scientific report series / Technische Universität Kaiserslautern, Laboratory of Engineering Thermodynamics |
| spelling | Imle, Michael 1984- Verfasser (DE-588)1072398605 aut Reactive absorption of carbon dioxide experimental studies, physico-chemical modeling, and simulation Michael Imle Kaiserslautern Techn. Univ., Laboratory of Engineering Thermodynamics 2014 XX, 104 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Scientific report series / Technische Universität Kaiserslautern, Laboratory of Engineering Thermodynamics 14 Zugl. Kaiserslautern, Techn. Univ., Diss., 2014 Kohlendioxid (DE-588)4031648-8 gnd rswk-swf Reaktivdestillation (DE-588)4491776-4 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Kohlendioxid (DE-588)4031648-8 s Reaktivdestillation (DE-588)4491776-4 s DE-604 Technische Universität Kaiserslautern, Laboratory of Engineering Thermodynamics Scientific report series 14 (DE-604)BV040983565 14 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028092386&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Imle, Michael 1984- Reactive absorption of carbon dioxide experimental studies, physico-chemical modeling, and simulation Kohlendioxid (DE-588)4031648-8 gnd Reaktivdestillation (DE-588)4491776-4 gnd |
| subject_GND | (DE-588)4031648-8 (DE-588)4491776-4 (DE-588)4113937-9 |
| title | Reactive absorption of carbon dioxide experimental studies, physico-chemical modeling, and simulation |
| title_auth | Reactive absorption of carbon dioxide experimental studies, physico-chemical modeling, and simulation |
| title_exact_search | Reactive absorption of carbon dioxide experimental studies, physico-chemical modeling, and simulation |
| title_full | Reactive absorption of carbon dioxide experimental studies, physico-chemical modeling, and simulation Michael Imle |
| title_fullStr | Reactive absorption of carbon dioxide experimental studies, physico-chemical modeling, and simulation Michael Imle |
| title_full_unstemmed | Reactive absorption of carbon dioxide experimental studies, physico-chemical modeling, and simulation Michael Imle |
| title_short | Reactive absorption of carbon dioxide |
| title_sort | reactive absorption of carbon dioxide experimental studies physico chemical modeling and simulation |
| title_sub | experimental studies, physico-chemical modeling, and simulation |
| topic | Kohlendioxid (DE-588)4031648-8 gnd Reaktivdestillation (DE-588)4491776-4 gnd |
| topic_facet | Kohlendioxid Reaktivdestillation Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028092386&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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