Optimization based methods for the conceptual design of separation processes for azeotropic mixtures:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
Düsseldorf
VDI-Verl.
2015
|
| Ausgabe: | Als Ms. gedr. |
| Schriftenreihe: | Fortschritt-Berichte VDI
Reihe 3, Verfahrenstechnik ; 946 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVII, 254 S. graph. Darst. |
| ISBN: | 9783183946037 |
Internformat
MARC
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| 245 | 1 | 0 | |a Optimization based methods for the conceptual design of separation processes for azeotropic mixtures |c Mirko Skiborowski |
| 246 | 1 | |a Optimization-based methods for the conceptual design of separation processes for azeotropic mixtures | |
| 250 | |a Als Ms. gedr. | ||
| 264 | 1 | |a Düsseldorf |b VDI-Verl. |c 2015 | |
| 300 | |a XVII, 254 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Fortschritt-Berichte VDI : Reihe 3, Verfahrenstechnik |v 946 | |
| 490 | 0 | |a Berichte aus der Aachener Verfahrenstechnik - Prozesstechnik | |
| 502 | |a Zugl.: Aachen, Techn. Hochsch., Diss., 2015 | ||
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Datensatz im Suchindex
| _version_ | 1804174803730432000 |
|---|---|
| adam_text | CONTENTS
1 INTRODUCTION 1
1.1 CONCEPTUAL DESIGN OF CHEMICAL PROCESSES 1
1.2 PROCESS SYNTHESIS FRAMEWORK 3
1.3 STRUCTURE OF THIS THESIS 5
1.4 PREVIOUS PUBLICATION OF RESULTS 7
2 CONCEPTUAL DESIGN METHODS FOR THE SEPARATION OF AZEOTROPIC MIXTURES 8
2.1 DISTILLATION-BASED SEPARATION PROCESSES 8
2.1.1 GENERATION OF VARIANTS 8
2.1.2 RAPID SCREENING WITH SHORTCUT DESIGN MODELS 9
2.1.3 OPTIMIZATION-BASED DESIGN WITH CONCEPTUAL MODELS 11
2.1.4 OPTIMIZATION-BASED DESIGN WITH RATE-BASED ENGINEERING MODELS ...
12
2.1.5 OPEN ISSUES 13
2.2 HYBRID PROCESSES 13
2.2.1 SEPARATION BY DISTILLATION AND CRYSTALLIZATION 14
2.2.2 HETEROAZEOTROPIC DISTILLATION 17
2.2.3 SEPARATION BY DISTILLATION AND LIQUID-LIQUID EXTRACTION 22
2.2.4 MEMBRANE-ASSISTED DISTILLATION PROCESSES 26
2.3 CONCLUDING REMARKS 32
3 ANALYSIS AND EVALUATION OF SHORTCUT-BASED DESIGN OF DISTILLATION
PROCESSES FOR
THE SEPARATION OF AZEOTROPIC MIXTURES 34
3.1 DETERMINATION OF FEASIBLE PRODUCT COMPOSITIONS 35
3.1.1 DISTILLATION COLUMNS OPERATED AT TOTAL REFLUX 35
3.1.2 REVERSIBLE DISTILLATION 40
3.1.3 DISTILLATION COLUMNS OPERATED AT FINITE REFLUX RATIO 45
3.2 ACCURACY OF PINCH-BASED SHORTCUT CALCULATIONS 59
3.3 SHORTCUT-BASED PROCESS DESIGN 63
3.3.1 RBM APPROACH 64
3.3.2 FAM APPROACH 66
V
HTTP://D-NB.INFO/1072569418
CONTENTS
3.3.3 SHORTCUT METHODS RELYING ON COMPOSITION PROFILE CALCULATIONS ....
68
3.4 CONCLUSIONS 68
4 OPTIMIZATION-BASED DESIGN FOR THE SEPARATION OF HETEROGENEOUS
AZEOTROPIC
MIXTURES 70
4.1 ANALYSIS OF THE PROCESS DESIGN PROBLEM 71
4.2 OPTIMIZATION MODEL 72
4.2.1 SIMPLE DISTILLATION COLUMN 73
4.2.2 DECANTER AND HETEROAZEOTROPIC DISTILLATION COLUMN 81
4.2.3 PROCESS OPTIMIZATION MODEL 84
4.3 SOLUTION STRATEGY 85
4.4 CASE STUDIES 89
4.4.1 PARTIAL DEHYDRATION OF 2-BUTANONE 90
4.4.2 PURIFICATION OF 1-HEXANOL 93
4.4.3 DEHYDRATION OF A QUATERNARY MIXTURE 96
4.4.4 IPA/WATER SEPARATION USING CYCLOHEXANE AS ENTRAINER 97
4.5 CONCLUSIONS 101
5 OPTIMIZATION-BASED CONCEPTUAL DESIGN OF MEMBRANE-ASSISTED DISTILLATION
PRO
CESSES 102
5.1 ANALYSIS OF THE PROCESS DESIGN PROBLEM 103
5.2 OPTIMIZATION MODEL 104
5.2.1 DISTILLATION COLUMN MODEL 104
5.2.2 MEMBRANE NETWORK MODEL 106
5.2.3 PROCESS OPTIMIZATION MODEL 112
5.3 SOLUTION STRATEGY 113
5.4 CASE STUDIES 115
5.4.1 ETHANOL DEHYDRATION PROCESS 116
5.4.2 SEPARATION PROCESSES FOR MTBE PRODUCTION 122
5.4.3 SEPARATION PROCESS FOR ACETONE PRODUCTION 125
5.5 CONCLUSIONS 131
6 A HYBRID EVOLUTIONARY-DETERMINISTIC OPTIMIZATION APPROACH FOR
CONCEPTUAL DE
SIGN 133
6.1 METAHEURISTICS AND HYBRID OPTIMIZATION ALGORITHMS 134
6.2 NOVEL HYBRID OPTIMIZATION APPROACH 137
6.2.1 INITIALIZATION 140
6.2.2 EVALUATION 141
VI
CONTENTS
6.2.3 SELECTION 142
6.2.4 RECOMBINATION AND MUTATION 142
6.2.5 PARAMETER ADAPTION 143
6.2.6 TERMINATION 144
6.2.7 PARALLELIZATION 144
6.3 CASE STUDIES 145
6.3.1 SINGLE DISTILLATION COLUMN 145
6.3.2 ENTRAINER-ENHANCED PRESSURE-SWING DISTILLATION 148
6.3.3 EXTRACTIVE DISTILLATION 155
6.4 CONCLUSIONS 159
7 CONCLUSIONS AND FINAL THOUGHTS 161
7.1 SUMMARY 161
7.2 OPEN RESEARCH TOPICS 163
A UNIFYING APPROACH TO AZEOTROPE AND PINCH POINT CALCULATION 166
A.L INTRODUCTION 166
A.2 CONTINUATION-BASED CALCULATION OF PINCH LINES 167
A.3 CALCULATION OF AZEOTROPES 169
A.4 CONCLUSIONS 174
B IMPROVED REFORMULATION OF THE FEED ANGLE METHOD 175
B.L ORIGINAL FAM FORMULATION 175
B.2 IMPROVED REFORMULATION 177
B.3 APPLICATION TO MULTI-COLUMN PROCESSES 180
C EXTERNAL FUNCTIONS 181
C.L EXTERNAL EQUATIONS FOR (QUASI-)VLE CALCULATION IN GAMS 181
C.2 EXTERNAL FUNCTION FOR (QUASI-)VLE CALCULATION 182
C.2.1 CALCULATION OF EXTERNAL EQUATIONS (/) 184
C.2.2 CALCULATION OF SENSITIVITIES
(D)
184
C.3 EXTERNAL FUNCTIONS FOR FURTHER CALCULATIONS 187
C.3.1 DECANTATION AND HETEROAZEOTROPIC DISTILLATION 187
C.3.2 MEMBRANE ASSISTED DISTILLATION 188
D THERMODYNAMICAL PROPERTY CALCULATIONS 190
D.L PROPERTY MODELS 190
D.L.L ACTIVITY COEFFICIENTS 190
D.L.2 VAPOR PRESSURE 192
VII
CONTENTS
D.1.3 FUGACITY COEFFICIENTS 192
D.1.4 MOLAR ENTHALPIES 193
D.1.5 VAPOR HEAT CAPACITY 194
D.1.6 HEAT OF VAPORIZATION 195
D.2 PROPERTY MODEL PARAMETERS 195
D.2.1 SHORTCUT-BASED DESIGN CASE STUDIES (CHAPTER 3) 195
D.2.2 HETEROAZEOTROPIC DISTILLATION CASE-STUDIES (CHAPTER 4) 198
D.2.3 MEMBRANE-ASSISTED DISTILLATION CASE-STUDIES (CHAPTER 5) 204
D.2.4 HYBRID OPTIMIZATION APPROACH CASE-STUDIES (CHAPTER 6) 209
D.2.5 CASE STUDIES FOR AZEOTROPE CALCULATION (APPENDIX A) 209
D.2.6 CASE STUDY FOR THE IMPROVED FAM FORMULATION (APPENDIX B) . . . .
210
E ECONOMIC MODEL 211
E.L DISTILLATION COLUMNS 211
E.2 MEMBRANE NETWORK 214
F MEMBRANE MASS-TRANSFER MODELS AND VALIDATION OF COLLOCATION METHOD 216
F.L ETHANOL DEHYDRATION 216
F.2 MEOH/MTBE/BUTENE SEPARATION 217
F.3 ACETONE/IPA/WATER SEPARATION 218
F.4 VALIDATION OF COLLOCATION METHOD 218
BIBLIOGRAPHY 220
VIII
|
| any_adam_object | 1 |
| author | Skiborowski, Mirko 1982- |
| author_GND | (DE-588)1071772430 |
| author_facet | Skiborowski, Mirko 1982- |
| author_role | aut |
| author_sort | Skiborowski, Mirko 1982- |
| author_variant | m s ms |
| building | Verbundindex |
| bvnumber | BV042626090 |
| classification_rvk | VN 7127 |
| classification_tum | CIT 215d |
| ctrlnum | (OCoLC)912317656 (DE-599)BSZ433500360 |
| dewey-full | 660.28425 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering |
| dewey-raw | 660.28425 |
| dewey-search | 660.28425 |
| dewey-sort | 3660.28425 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Chemie-Ingenieurwesen |
| edition | Als Ms. gedr. |
| format | Thesis Book |
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| genre_facet | Hochschulschrift |
| id | DE-604.BV042626090 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:06:12Z |
| institution | BVB |
| isbn | 9783183946037 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-028058741 |
| oclc_num | 912317656 |
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| owner_facet | DE-91G DE-BY-TUM DE-83 DE-634 DE-210 DE-29T |
| physical | XVII, 254 S. graph. Darst. |
| publishDate | 2015 |
| publishDateSearch | 2015 |
| publishDateSort | 2015 |
| publisher | VDI-Verl. |
| record_format | marc |
| series | Fortschritt-Berichte VDI |
| series2 | Fortschritt-Berichte VDI : Reihe 3, Verfahrenstechnik Berichte aus der Aachener Verfahrenstechnik - Prozesstechnik |
| spelling | Skiborowski, Mirko 1982- Verfasser (DE-588)1071772430 aut Optimization based methods for the conceptual design of separation processes for azeotropic mixtures Mirko Skiborowski Optimization-based methods for the conceptual design of separation processes for azeotropic mixtures Als Ms. gedr. Düsseldorf VDI-Verl. 2015 XVII, 254 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Fortschritt-Berichte VDI : Reihe 3, Verfahrenstechnik 946 Berichte aus der Aachener Verfahrenstechnik - Prozesstechnik Zugl.: Aachen, Techn. Hochsch., Diss., 2015 Extraktive Destillation (DE-588)4153419-0 gnd rswk-swf Konzeptionelle Modellierung (DE-588)4123555-1 gnd rswk-swf Membrandestillation (DE-588)4529411-2 gnd rswk-swf Kombinationsverfahren (DE-588)4533702-0 gnd rswk-swf Prozessentwicklung Technik (DE-588)4278925-4 gnd rswk-swf Azeotropes Gemisch (DE-588)4122061-4 gnd rswk-swf Prozessmodell (DE-588)4237203-3 gnd rswk-swf Kristallisation (DE-588)4033215-9 gnd rswk-swf Trennverfahren (DE-588)4078395-9 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Azeotropes Gemisch (DE-588)4122061-4 s Trennverfahren (DE-588)4078395-9 s Kombinationsverfahren (DE-588)4533702-0 s Extraktive Destillation (DE-588)4153419-0 s Membrandestillation (DE-588)4529411-2 s Kristallisation (DE-588)4033215-9 s Prozessentwicklung Technik (DE-588)4278925-4 s Prozessmodell (DE-588)4237203-3 s Konzeptionelle Modellierung (DE-588)4123555-1 s DE-604 Fortschritt-Berichte VDI Reihe 3, Verfahrenstechnik ; 946 (DE-604)BV001897067 946 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028058741&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Skiborowski, Mirko 1982- Optimization based methods for the conceptual design of separation processes for azeotropic mixtures Fortschritt-Berichte VDI Extraktive Destillation (DE-588)4153419-0 gnd Konzeptionelle Modellierung (DE-588)4123555-1 gnd Membrandestillation (DE-588)4529411-2 gnd Kombinationsverfahren (DE-588)4533702-0 gnd Prozessentwicklung Technik (DE-588)4278925-4 gnd Azeotropes Gemisch (DE-588)4122061-4 gnd Prozessmodell (DE-588)4237203-3 gnd Kristallisation (DE-588)4033215-9 gnd Trennverfahren (DE-588)4078395-9 gnd |
| subject_GND | (DE-588)4153419-0 (DE-588)4123555-1 (DE-588)4529411-2 (DE-588)4533702-0 (DE-588)4278925-4 (DE-588)4122061-4 (DE-588)4237203-3 (DE-588)4033215-9 (DE-588)4078395-9 (DE-588)4113937-9 |
| title | Optimization based methods for the conceptual design of separation processes for azeotropic mixtures |
| title_alt | Optimization-based methods for the conceptual design of separation processes for azeotropic mixtures |
| title_auth | Optimization based methods for the conceptual design of separation processes for azeotropic mixtures |
| title_exact_search | Optimization based methods for the conceptual design of separation processes for azeotropic mixtures |
| title_full | Optimization based methods for the conceptual design of separation processes for azeotropic mixtures Mirko Skiborowski |
| title_fullStr | Optimization based methods for the conceptual design of separation processes for azeotropic mixtures Mirko Skiborowski |
| title_full_unstemmed | Optimization based methods for the conceptual design of separation processes for azeotropic mixtures Mirko Skiborowski |
| title_short | Optimization based methods for the conceptual design of separation processes for azeotropic mixtures |
| title_sort | optimization based methods for the conceptual design of separation processes for azeotropic mixtures |
| topic | Extraktive Destillation (DE-588)4153419-0 gnd Konzeptionelle Modellierung (DE-588)4123555-1 gnd Membrandestillation (DE-588)4529411-2 gnd Kombinationsverfahren (DE-588)4533702-0 gnd Prozessentwicklung Technik (DE-588)4278925-4 gnd Azeotropes Gemisch (DE-588)4122061-4 gnd Prozessmodell (DE-588)4237203-3 gnd Kristallisation (DE-588)4033215-9 gnd Trennverfahren (DE-588)4078395-9 gnd |
| topic_facet | Extraktive Destillation Konzeptionelle Modellierung Membrandestillation Kombinationsverfahren Prozessentwicklung Technik Azeotropes Gemisch Prozessmodell Kristallisation Trennverfahren Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028058741&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV001897067 |
| work_keys_str_mv | AT skiborowskimirko optimizationbasedmethodsfortheconceptualdesignofseparationprocessesforazeotropicmixtures |