The art of problem solving in organic chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, NJ
Wiley
2014
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| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | XIX, 450 S. graph. Darst. |
| ISBN: | 9781118530214 |
Internformat
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Datensatz im Suchindex
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| adam_text | Titel: The art of problem solving in organic chemistry
Autor: Alonso-Amelot, Miguel E
Jahr: 2014
CONTENTS Preface xi Preface to the First Edition xvii Acknowledgments xix 1 Problem Analysis in Organic Reaction Mechanism 1 1.1 Overview, 1 1.2 Introduction, 1 1.2.1 “Pushing Forward” a Solution in Formal and Exhaustive Terms, 2 1.2.2 Lessons from this Example, 7 1.3 Avoiding the Quagmire, 7 1.4 The Basic Steps of Problem Analysis, 8 1.4.1 Recognizing the Problem, 8 1.4.2 Analyzing Problems by Asking the Right Questions, Discarding the Irrelevant, 11 1.4.3 Drawing a First Outline for Guidance, 12 1.4.4 Asking the Right Questions and Proposing the Right Answers... is enough?, 13 1.5 Intuition and Problem Solving, 14 1.6 Summing Up, 17 References and Notes, 17 Vll
viii CONTENTS 2 Electron Flow in Organic Reactions 19 2.1 Overview, 19 2.2 Introduction, 19 2.3 Practical Rules Governing Electron Redeployment, 22 2.3.1 Issue 1: Electrons within Orbitals, 22 2.3.2 Issue 2: Electron Transfer and Stereochemistry, 23 2.3.3 Issue 3: Electron Energy Level and Accessibility, 24 2.3.4 Issue 4: Electron Flow and Molecular Active Sectors, 26 2.3.4.1 Case A: tt-ic Interactions, 26 2.3.4.2 Case B: jc - a Interactions, 27 2.3.4.3 Case C: When Reactivity Patterns Seem to Break Down, 27 2.3.5 Issue 5: Electron Traffic and Electronic Density Differences, 31 2.3.5.1 M° Metals as Electron Source, 31 23.5.2 Metal Hydrides and Organic Hydrides as Electron Source, 32 2.3.6 Issue 6: Creating Zones of High Electron Density, 34 2.3.6.1 The Natural Polarization, 35 2.3.6.2 Reversing the Natural Polarization: Umpolung, 35 2.3.7 Issue 7: Electron Flow and Low Electron Density Zones, 36 2.3.7.1 Identifying LEDZs, 36 23.1.2 Creating a New LEDZ in the Substrate, 37 2.3.7.3 Finding Unsuspected LEDZs among the Other Reagents in the Mixture, 41 2.3.7.4 When Compounds Show Double Personality, 42 2.4 Summing Up, 42 2.5 A Flowchart of Organized Problem Analysis, 44 References and Notes, 45 3 Additional Techniques to Postulate Organic Reaction Mechanisms 49 3.1 Overview, 49 3.2 Take Your Time, 50 3.3 Clear and Informative Molecular Renderings, 50 3.3.1 The Value of Molecular Sketches, 50 3.3.2 Two- Versus Three-Dimensional Renderings and the “Flat” Organic Compounds, 52 3.4 Element and Bond Budgets, 53 3.5 Looking at Molecules from Various Perspectives, 55 3.6 Separate the Grain from the Chaff, 58 3.7 Dissecting Products in Terms of Reactants: Fragmentation Analysis, 59 3.7.1 The Fundamental Proposition, 59 3.7.2 Adding Potentially Nucleophilic or Electrophilic Character to Fragments, 61
CONTENTS ix 3.7.3 When Fragmentation Analysis Fails, Getting Help from Atom Labels, 63 3.8 Oxidation Levels and Mechanism, 65 3.8.1 Methods to Estimate Oxidation Status, 65 3.9 The Functionality Number, 66 3.9.1 What Exactly Is FN?, 66 3.9.2 Properties of FN, 67 3.10 Combining Fragmentation Analysis and Functionality Numbers, 72 3.11 Summing Up, 74 References, 75 4 Solved Problem Collection Problem 1 to 60. See Graphical Problem Index, 79 77 Glossary 405 Subject/Reaction Index 409 Reagent Index 425 Author Index 433 Graphical Problem Index 445
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| language | English |
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| spelling | Alonso-Amelot, Miguel E. Verfasser aut The art of problem solving in organic chemistry Miguel E. Alonso-Amelot 2. ed. Hoboken, NJ Wiley 2014 XIX, 450 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Chemistry, Organic Problem solving Methode (DE-588)4038971-6 gnd rswk-swf Problemlösen (DE-588)4076358-4 gnd rswk-swf Organische Chemie (DE-588)4043793-0 gnd rswk-swf Organische Chemie (DE-588)4043793-0 s Methode (DE-588)4038971-6 s DE-604 Problemlösen (DE-588)4076358-4 s HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027985454&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Alonso-Amelot, Miguel E. The art of problem solving in organic chemistry Chemistry, Organic Problem solving Methode (DE-588)4038971-6 gnd Problemlösen (DE-588)4076358-4 gnd Organische Chemie (DE-588)4043793-0 gnd |
| subject_GND | (DE-588)4038971-6 (DE-588)4076358-4 (DE-588)4043793-0 |
| title | The art of problem solving in organic chemistry |
| title_auth | The art of problem solving in organic chemistry |
| title_exact_search | The art of problem solving in organic chemistry |
| title_full | The art of problem solving in organic chemistry Miguel E. Alonso-Amelot |
| title_fullStr | The art of problem solving in organic chemistry Miguel E. Alonso-Amelot |
| title_full_unstemmed | The art of problem solving in organic chemistry Miguel E. Alonso-Amelot |
| title_short | The art of problem solving in organic chemistry |
| title_sort | the art of problem solving in organic chemistry |
| topic | Chemistry, Organic Problem solving Methode (DE-588)4038971-6 gnd Problemlösen (DE-588)4076358-4 gnd Organische Chemie (DE-588)4043793-0 gnd |
| topic_facet | Chemistry, Organic Problem solving Methode Problemlösen Organische Chemie |
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