Biodegradable polyesters:
Gespeichert in:
Weitere Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Weinheim
Wiley-VCH
2015
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Schlagworte: | |
Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
Beschreibung: | XX, 347 S. Ill., graph. Darst. |
ISBN: | 9783527330867 9783527656950 |
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CONTENTS
LIST OF CONTRIBUTORS XIII
LIST OF ABBREVIATIONS AND SYMBOLS XVII
PREFACE XIX
1 BIODEGRADABLE POLYESTERS: SYNTHESIS, PROPERTIES, APPLICATIONS 1
CHI ZHANG
1.1 HISTORICAL OVERVIEW ON THE ORIGIN OF POLYMER SCIENCE AND SYNTHESIS
OF POLYAMIDES AND POLYESTERS 1
1.1.1 SYNTHESIS OF POLYAMIDES 3
1.1.2 INITIAL KNOWLEDGE ABOUT POLYESTERS 5
1.2 PUBLICATION TREND OF REPRESENTATIVE BIODEGRADABLE AND
NONBIODEGRADABLE POLYESTERS IN THE PAST CENTURY
6
1.3 BIODEGRADABLE POLYESTERS
6
1.3.1 BIODEGRADABLE ALIPHATIC POLYESTERS AND THEIR COPOLYMERS 7
1.3.1.1 POLY(LACTIC ACID) 7
1.3.1.2 POLYGLYCOLIDE OR POLY(GLYCOLIC ACID) 12
1.3.1.3 POLY(CAPROLACTONE) 15
1.4 CONCLUDING REMARKS 18
ACKNOWLEDGMENT 18
REFERENCES 19
2 FUNCTIONAL (BIO)DEGRADABLE POLYESTERS BY RADICAL RING-OPENING
POLYMERIZATION 25
SEEMA AGARWAL
2.1 INTRODUCTION 25
2.2 RADICAL RING-OPENING POLYMERIZATION (RROP) OF CYCLIC KETENE
ACETALS 26
2.2.1 STARTING MONOMERS: CYCLIC KETENE ACETALS 26
2.2.2 RADICAL RING-OPENING POLYMERIZATION MECHANISM 28
2.2.3 FUNCTIONAL POLYESTERS BY CONVENTIONAL AND CONTROLLED RADICAL
HOMOPOLYMERIZATION OF CKAS 30
2.2.4 FUNCTIONAL POLYESTERS BY COPOLYMERIZATION OF CKAS AND VINYL
MONOMERS 31
HTTP://D-NB.INFO/1059940167
VII
CONTENTS
2.3 CONCLUSIONS 41
REFERENCES 41
3 MICROBIAL SYNTHESIS OF BIODEGRADABLE POLYESTERS: PROCESSES, PRODUCTS,
APPLICATIONS 47
BERND H.A. REHM
3.1 INTRODUCTION 47
3.2 BIOGENESIS OF MICROBIAL POLYHYDROXYALKANOATE GRANULES 48
3.3 THE DIVERSITY OF BIOPOLYESTERS 49
3.4 POLYESTER (PHA) SYNTHASES ARE THE KEY ENZYMES SI
3.5 CATALYTIC REACTION MECHANISM 52
3.6 PHA INCLUSIONS: SELF-ASSEMBLY AND STRUCTURE 53
3.7 INDUSTRIAL PRODUCTION OF BACTERIAL POLYHYDROXYALKANOATES:
PHAS VIA FERMENTATION 56
3.8 APPLICATION OPPORTUNITIES OF BACTERIAL
POLYHYDROXYALKANOATES 58
3.8.1 IN ENERGY INDUSTRY: BIOFUELS BASED ON PHAS 58
3.8.2 IN MATERIAL INDUSTRY: PHAS AS POLYMERIC MATERIALS 59
3.8.2.1 PHAS AS BIODEGRADABLE PLASTICS AND FIBER MATERIALS 59
3.8.2.2 PHAS AS MEDICAL IMPLANT MATERIALS 59
3.8.2.3 PHAS AS DRUG DELIVERY CARRIER 60
3.8.3 FINE CHEMICAL INDUSTRY: PHA CHIRAL MONOMERS 60
3.8.4 APPLICATION OF PHA GRANULE SURFACE PROTEINS 61
3.8.5 PRODUCTION OF TAILOR-MADE BIOPOLYESTER NANOPARTICLES AND
POTENTIAL APPLICATIONS 61
3.8.6 FUTURE DEVELOPMENT OF PHA-BASED INDUSTRY 62
3.8.6.1 THE DEVELOPMENT OF LOW-COST PHA PRODUCTION
TECHNOLOGY 62
3.8.6.2 UNUSUAL PHAS WITH SPECIAL PROPERTIES 63
3.8.6.3 HIGH VALUE ADDED APPLICATIONS 64
3.8.6.4 OTHER FUTURE APPLICATIONS 64
3.8.6.5 MICROBIAL SYNTHESIS OF POLY(LACTIC ACID) (PLA) 64
3.8.7 APPLICATIONS OF PHA INCLUSIONS AS FUNCTIONALIZED
BIOBEADS 65
3.8.7.1 BIOSEPARATIONS 65
3.8.7.2 DRUG DELIVERY 65
3.8.7.3 PROTEIN PURIFICATION 65
3.8.7.4 ENZYME IMMOBILIZATION
66
3.8.7.5 DIAGNOSTICS AND IMAGING 66
3.8.7.6 VACCINE DELIVERY 66
3.9 CONCLUSIONS AND OUTLOOK 67
ACKNOWLEDGMENTS 67
REFERENCES 67
CONTENTS
VII
4 SYNTHESIS, PROPERTIES, AND MATHEMATICAL MODELING OF BIODEGRADABLE
ALIPHATIC POLYESTERS BASED ON 1,3-PROPANEDIOL AND DICARBOXYLIC
ACIDS 73
DIMITRIS S. ACHILLAS AND DIMITRIOS N. BIKIARIS
4.1 INTRODUCTION 73
4.1.1 ALIPHATIC POLYESTERS 73
4.1.2 PRODUCTION OF 1,3-PROPANEDIOL 75
4.2 SYNTHESIS OF ALIPHATIC POLYESTERS FROM 1,3-PROPANEDIOL AND ALIPHATIC
ACIDS 78
4.3 PROPERTIES OF POLY(PROPYLENE ALKYLENEDICARBOXYLATES) 80
4.4 MATHEMATICAL MODELING OF THE SYNTHESIS OF ALIPHATIC POLYESTERS 85
4.4.1 BRIEF HISTORY OF STEP REACTION KINETIC MODELING 85
4.4.2 MATHEMATICAL MODELING OF THE ESTERIFICATION REACTION FOR THE
SYNTHESIS OF ALIPHATIC POLYESTERS 87
4.4.2.1 LITERATURE SURVEY 87
4.4.2.2 MODELING APPROACHES 88
4.4.2.3 MODELING USING THE FUNCTIONAL GROUP APPROACH 88
4.4.2.4 MODELING USING AN OVERALL REACTION MODEL 97
4.4.2.5 MODELING THE EFFECT OF SILICA NANOPARTICLES ON THE
ESTERIFICATION
REACTION 98
4.4.3 MODELING THE POLYCONDENSATION REACTION KINETICS FOR THE SYNTHESIS
OF ALIPHATIC POLYESTERS 100
4.4.3.1 REACTION SCHEME 100
4.4.3.2 DEVELOPMENT OF THE MATHEMATICAL MODEL 101
4.4.3.3 SIMULATION MODEL RESULTS 102
4.5 CONCLUSIONS 105
REFERENCES 106
5 CRYSTALLIZATION OF POLY(LACTIC ACID) 109
MARIA LAURA DI LORENZO AND
RENE ANDROSCH
5.1 INTRODUCTION 109
5.2 CRYSTAL POLYMORPHISM IN POLY
(L
-LACTIC ACID) 111
5.3 KINETICS OF CRYSTAL NUCLEATION 114
5.4 CRYSTAL GROWTH RATE 119
5.5 INFLUENCE OF COMONOMER CONTENT 122
5.6 STEREOCOMPLEX CRYSTALS OF POLY
(L
-LACTIDE)/POLY
(D
-LACTIDE) 123
5.7 CONCLUSIONS 125
REFERENCES 125
6 SHAPE MEMORY SYSTEMS WITH BIODEGRADABLE POLYESTERS 131
JOZSEFKARGER KOCSIS AND
SUCHART SIENGCHIN
6.1 INTRODUCTION 131
6.2 SHAPE MEMORY POLYMER SYSTEMS 133
6.2.1 HOMOPOLYMERS AND COMPOSITES 134
6.2.1.1 LINEAR 134
VIIII CONTENTS
6.2.1.2 CROSS-LINKED 134
6.2.2 COPOLYMERS AND COMPOSITES 138
6.2.2.1 LINEAR 138
6.2.2.2 CROSS-LINKED 140
6.2.3 POLYESTER-CONTAINING POLYURETHANES AND RELATED COMPOSITES 142
6.2.4 BLENDS AND COMPOSITES J 42
6.2.4.1 LINEAR 144
6.2.4.2 CROSS-LINKED 145
6.2.5 POLYMERS WITH THERMOSETS 145
6.2.5.1 CONETWORKS 145
6.2.5.2 SEMI-INTERPENETRATING NETWORK 146
6.2.5.3 INTERPENETRATING NETWORK 148
6.3 APPLICATIONS 148
6.4 OUTLOOK AND FUTURE TRENDS 149
ACKNOWLEDGMENTS 149
REFERENCES 149
7 ELECTROSPUN SCAFFOLDS OF BIODEGRADABLE POLYESTERS: MANUFACTURING AND
BIOMEDICAL APPLICATION 155
PATRICIA PRANKE, DANIEL E.
WEIBEL,
AND DAIKELLYI. BRAGHIROLII
7.1 INTRODUCTION 155
7.2 PREPARATION OF POLYESTERS FOR THE ELECTROSPINNING METHOD 157
7.3 IMPROVING THE BIOACTIVITY OF ELECTROSPUN POLYESTERS 160
7.3.1 SURFACE MODIFICATION TECHNIQUES 160
7.3.1.1 WET CHEMICAL SURFACE MODIFICATION 160
7.3.1.2 PLASMA 162
7.3.1.3 OZONE 165
7.3.1.4 ULTRAVIOLET RADIATION 167
7.3.1.5 FUNCTIONALIZATION OF POLYESTER ELECTROSPUN SCAFFOLDS WITH
BIOACTIVE
MOLECULES 170
7.3.2 PRETREATMENTS: ASSOCIATION OF POLYESTERS WITH BIOMOLECULES BEFORE
ELECTROSPINNING 172
7.3.2.1 BLENDS OF POLYESTERS WITH OTHER POLYMERS AND/OR BIOMOLECULES 172
73.2.2 CO-ELECTROSPINNING AND ELECTROSPRAYING 174
7.4 APPLICATIONS 175
7.5 CONCLUSIONS 180
REFERENCES 180
8 SYSTEMATIC DEVELOPMENT OF ELECTROSPUN PLA/PCL FIBER HYBRID MATS:
PREPARATION, MATERIAL CHARACTERIZATION, AND APPLICATION IN DRUG
DELIVERY 191
HAZIM J. HAROOSH AND
YU DONG
8.1 INTRODUCTION 191
8.2 MATERIAL PREPARATION AND CHARACTERIZATION 193
8.3 MORPHOLOGICAL OBSERVATIONS 197
CONTENTS
I IX
8.3.1 EFFECT OF SOLUTION VISCOSITY 197
8.3.2 EFFECT OF BLEND RATIO 198
8.3.3 EFFECT OF SOLVENTS 200
8.4 CRYSTALLINE STRUCTURES 202
8.5 THERMAL PROPERTIES 204
8.6 FTIR ANALYSIS 205
8.7 TCH DRUG RELEASE 206
8.8 FIBER BIODEGRADABILITY 207
8.9 CONCLUSIONS 208
REFERENCES 209
9 ENVIRONMENT-FRIENDLY METHODS FOR CONVERTING BIODEGRADABLE
POLYESTERS INTO NANO-SIZED MATERIALS 215
STOYKO FAKIROV
9.1 TISSUE ENGINEERING IN MEDICINE AND THE POLYMERIC MATERIALS
NEEDED 215
9.2 MFC CONCEPT AND ITS POTENTIAL FOR BIOMEDICAL APPLICATIONS 219
9.3 EFFECT OF HYDROGEN BONDING IN POLYMER BLENDS ON
NANO-MORPHOLOGY 223
9.4 MECHANISM OF NANO-MORPHOLOGY FORMATION IN POLYMER BLENDS
WITHOUT AND WITH HYDROGEN BONDING 227
9.5 BIOMEDICAL APPLICATION OPPORTUNITIES OF NANO-SIZED
POLYMERS 229
9.6 CONCLUSIONS 231
ACKNOWLEDGMENTS 232
REFERENCES 232
10 HIGHLY TOUGHENED POLYLACTIDE-BASED MATERIALS THROUGH MELT-BLENDING
TECHNIQUES 235
JEREMY
ODENT,
JEAN-MARIE RAQUEZ,
AND PHILIPPE DUBOIS
10.1 INTRODUCTION 235
10.1.1 POLYLACTIDE AS A BIO-BASED ALTERNATIVE 235
10.1.2 POLYLACTIDE AND ITS INDUSTRIAL PRODUCTION 237
10.1.3 MAIN PROPERTIES OF PL A 240
10.2 POLYLACTIDE STRENGTHENING AND STRATEGIES 242
10.2.1 IMPACT AND TOUGHENING MECHANISMS: GENERAL CONSIDERATIONS 243
10.2.2 RUBBER-TOUGHENED POLYLACTIDE 248
10.2.3 NANOPARTICLE-MEDIATED COMPATIBILIZATION PROCESS 257
10.2.4 INTERPENETRATING NETWORKS AND SELF-ASSEMBLING OF PLA-BASED
MATERIALS 261
10.3 CRYSTALLIZATION-INDUCED TOUGHNESS AND MORPHOLOGICAL
CONTROL 263
10.4 CONCLUSIONS 268
REFERENCES 268
X |
CONTENTS
11 ELECTROSPUN BIOPOLYMER NANOFIBERS AND THEIR COMPOSITES FOR DRUG
DELIVERY APPLICATIONS 275
YUE-EMIAO AND
TIANXI LIU
11.1 INTRODUCTION 275
11.2 SIMPLY BLENDED DRUG/BIOPOLYMER NANOFIBERS BY CONVENTIONAL
ELECTROSPINNING FOR DRUG DELIVERY 276
11.2.1 DRUG-LOADED SINGLE-COMPONENT BIOPOLYMER NANOFIBERS 277
11.2.2 DRUG-LOADED MULTICOMPONENT BIOPOLYMER NANOFIBERS 279
11.2.3 DRUG-LOADED NANOPARTICLE/BIOPOLYMER COMPOSITES 280
11.3 UNIQUELY ENCAPSULATED DRUG/BIOPOLYMER NANOFIBER SYSTEMS FOR
DRUG DELIVERY 283
11.3.1 COAXIAL ELECTROSPUN DRUG/BIOPOLYMER NANOFIBERS 283
11.3.2 EMULSION ELECTROSPUN DRUG/BIOPOLYMER NANOFIBERS 286
11.3.3 ELECTROSPRAYED DRUG/BIOPOLYMER NANOFIBERS 289
11.4 CONCLUSIONS AND OUTLOOK 292
ACKNOWLEDGMENT 293
REFERENCES 293
12 BIODEGRADABLE POLYESTERS POLYMER-POLYMER COMPOSITES WITH
IMPROVED PROPERTIES FOR POTENTIAL STENT APPLICATIONS 299
LLOYD D. KIMBLE AND DEBES
BHATTACHARYYA
12.1 INTRODUCTION 299
12.2 STENTING DEVELOPMENT 300
12.2.1 BARE METAL STENTS 300
12.2.2 COATED METAL STENTS 301
12.2.3 DRUG-ELUTING STENTS 301
12.2.4 RECAP AND THE NEXT PHASE OF STENT EVOLUTION: BIODEGRADABLE
STENTS 301
12.3 STENTS - AN ENGINEERING POINT OF VIEW 302
12.3.1 STENT DEPLOYMENT: THE NEED FOR DUCTILITY 302
12.3.2 IMPORTANCE OF CREEP AFTER IMPLANTATION 303
12.3.3 A VESSEL IS NOT STATIC: MATERIAL FATIGUE CONSIDERATIONS 304
12.3.4 MATERIAL DEGRADATION: A CRITICAL VARIABLE 304
12.3.5 ENGINEERING SOLUTIONS VERSUS CLINICAL IMPLICATIONS 305
12.4 BIODEGRADABLE STENTS 305
12.4.1 SELECTION CRITERIA FOR BIODEGRADABLE STENT MATERIALS 305
12.5 THE MFC CONCEPT FOR PREPARATION OF POLYMER - POLYMER COMPOSITES
WITH SUPERIOR MECHANICAL PROPERTIES 309
12.5.1 PREPARATION OF POLYMER-POLYMER COMPOSITES FROM PLLA/PGA
BLENDS 310
12.5.2 MFC FILM MOLDING 310
12.6 PROPERTIES OF PL A/PGA POLYMER - POLYMER NANOFIBRILLAR
COMPOSITES 311
12.6.1 MORPHOLOGY OF PLA/PGA NANO-/MICROFIBRILLAR POLYMER- POLYMER
COMPOSITES 311
CONTENTS
| XI
12.6.2 MECHANICAL PROPERTIES OF PLA/PGA NANO-/MICROFIBRILLAR
POLYMER - POLYMER NANOFIBRILLAR COMPOSITES 314
12.6.3 VISCOELASTIC BEHAVIOR OF PLLA/PGA NANO-/MICROFIBRILLAR
POLYMER-POLYMER COMPOSITES 314
12.6.4 ANALYSIS OF PROPERTIES OF PLLA/PGA NANO-/MICROFIBRILLAR
POLYMER-POLYMER COMPOSITES WITH RESPECT TO THEIR POTENTIAL STENT
APPLICATIONS 316
12.7 CONCLUSIONS AND OUTLOOK 317
REFERENCES 318
13 BIODEGRADABLE POLYESTER-BASED BLENDS AND COMPOSITES:
MANUFACTURING, PROPERTIES, AND APPLICATIONS 321
RAJ DAS AND KARIAPPA M. KARUMBAIAH
13.1 INTRODUCTION 321
13.2 REINFORCEMENTS IN POLYMER COMPOSITES 322
13.2.1 GLASS AND CARBON FIBER REINFORCEMENTS 323
13.2.2 NATURAL FIBER REINFORCEMENTS 323
13.2.3 SYNTHETIC FIBER REINFORCEMENTS 324
13.3 BLENDS OF BIODEGRADABLE POLYESTERS 325
13.4 COMPOSITES OF BIODEGRADABLE POLYESTERS 326
13.4.1 COMPOSITES REINFORCED WITH CARBON AND GLASS FIBERS 326
13.4.2 COMPOSITES REINFORCED WITH NATURAL FIBERS 327
13.4.3 POLYMER-POLYMER COMPOSITES BASED ON BIODEGRADABLE
POLYESTERS 330
13.5 APPLICATION OF BIODEGRADABLE POLYESTER-BASED BLENDS AND
COMPOSITES 331
13.5.1 BIOMEDICAL APPLICATIONS 331
13.5.2 COMMODITY APPLICATIONS 333
13.6 SUMMARY 334
REFERENCES 335
INDEX 341 |
any_adam_object | 1 |
author2 | Fakirov, Stoyko 1936- |
author2_role | edt |
author2_variant | s f sf |
author_GND | (DE-588)115146210 |
author_facet | Fakirov, Stoyko 1936- |
building | Verbundindex |
bvnumber | BV042487263 |
classification_rvk | UV 9250 UV 9450 VK 8000 VN 5900 ZM 5300 |
ctrlnum | (OCoLC)894691662 (DE-599)DNB1059940167 |
dewey-full | 668.4225 |
dewey-hundreds | 600 - Technology (Applied sciences) |
dewey-ones | 668 - Technology of other organic products |
dewey-raw | 668.4225 |
dewey-search | 668.4225 |
dewey-sort | 3668.4225 |
dewey-tens | 660 - Chemical engineering |
discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften / Fertigungstechnik |
format | Book |
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genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
genre_facet | Aufsatzsammlung |
id | DE-604.BV042487263 |
illustrated | Illustrated |
indexdate | 2024-09-10T01:40:49Z |
institution | BVB |
isbn | 9783527330867 9783527656950 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027922115 |
oclc_num | 894691662 |
open_access_boolean | |
owner | DE-29T DE-703 DE-11 DE-83 DE-19 DE-BY-UBM |
owner_facet | DE-29T DE-703 DE-11 DE-83 DE-19 DE-BY-UBM |
physical | XX, 347 S. Ill., graph. Darst. |
publishDate | 2015 |
publishDateSearch | 2015 |
publishDateSort | 2015 |
publisher | Wiley-VCH |
record_format | marc |
spelling | Biodegradable polyesters ed. by Stoyko Fakirov Weinheim Wiley-VCH 2015 XX, 347 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Abbaubarer Kunststoff (DE-588)4305214-9 gnd rswk-swf Biologischer Abbau (DE-588)4145625-7 gnd rswk-swf Kunststoff (DE-588)4033676-1 gnd rswk-swf Polyester (DE-588)4175168-1 gnd rswk-swf Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd rswk-swf Biopolymere (DE-588)4006893-6 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Polyester (DE-588)4175168-1 s Biologisch abbaubarer Kunststoff (DE-588)4634464-0 s DE-604 Kunststoff (DE-588)4033676-1 s Abbaubarer Kunststoff (DE-588)4305214-9 s Biopolymere (DE-588)4006893-6 s Biologischer Abbau (DE-588)4145625-7 s Fakirov, Stoyko 1936- (DE-588)115146210 edt Erscheint auch als Online-Ausgabe, EPUB 978-3-527-65697-4 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-65696-7 Erscheint auch als Online-Ausgabe, PDF 978-3-527-65698-1 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4809096&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027922115&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Biodegradable polyesters Abbaubarer Kunststoff (DE-588)4305214-9 gnd Biologischer Abbau (DE-588)4145625-7 gnd Kunststoff (DE-588)4033676-1 gnd Polyester (DE-588)4175168-1 gnd Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd Biopolymere (DE-588)4006893-6 gnd |
subject_GND | (DE-588)4305214-9 (DE-588)4145625-7 (DE-588)4033676-1 (DE-588)4175168-1 (DE-588)4634464-0 (DE-588)4006893-6 (DE-588)4143413-4 |
title | Biodegradable polyesters |
title_auth | Biodegradable polyesters |
title_exact_search | Biodegradable polyesters |
title_full | Biodegradable polyesters ed. by Stoyko Fakirov |
title_fullStr | Biodegradable polyesters ed. by Stoyko Fakirov |
title_full_unstemmed | Biodegradable polyesters ed. by Stoyko Fakirov |
title_short | Biodegradable polyesters |
title_sort | biodegradable polyesters |
topic | Abbaubarer Kunststoff (DE-588)4305214-9 gnd Biologischer Abbau (DE-588)4145625-7 gnd Kunststoff (DE-588)4033676-1 gnd Polyester (DE-588)4175168-1 gnd Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd Biopolymere (DE-588)4006893-6 gnd |
topic_facet | Abbaubarer Kunststoff Biologischer Abbau Kunststoff Polyester Biologisch abbaubarer Kunststoff Biopolymere Aufsatzsammlung |
url | http://deposit.dnb.de/cgi-bin/dokserv?id=4809096&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027922115&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT fakirovstoyko biodegradablepolyesters |