Theoretical and experimental study of capillary effect on melting:
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| Main Author: | |
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| Format: | Thesis Book |
| Language: | English |
| Published: |
2015
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | X, 98 S. Ill., graph. Darst. |
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Record in the Search Index
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| adam_text | CONTENTS
1 THEORETICAL BACKGROUND 3
1.1 INTERFACIAL THERMODYNAMICS 3
1.1.1 INTERFACIAL & SURFACE ENERGY 3
1.1.2 YOUNG-DUPRE EQUATION 4
1.1.3 YOUNG-LAPLACE EQUATION 6
1.1.4 GIBBS FREE ENERGY IN FIRST-ORDER PHASE TRANSITION 8
1.1.5 KELVIN EQUATION 8
1.2 THEORETICAL STUDY OF MELTING 9
1.2.1 BULK MELTING MODELS 9
1.2.2 SURFACE PREMELTING 12
1.2.3 SURFACE FREEZING 14
1.3 THEORY OF NUCLEATION 17
1.3.1 NUCLEATION BARRIER 17
1.3.2 CONCENTRATION OF NUCLEI 19
1.3.3 RATE OF NUCLEATION 20
1.3.4 NUCLEATION OF MELT 20
INTRODUCTION 3
2 EXPERIMENTAL METHODS AND EQUIPMENT 23
2.1 MATERIAL AND SAMPLE PREPARATION 23
2.1.1 ALKANE AND SUBSTRATE 23
2.1.2 CLEANING PROCEDURE 23
2.1.3 ALKANE MONO- AND MULTI-LAYER PREPARATION 24
2.2 EXPERIMENT METHODS AND EQUIPMENT 24
2.2.1 TYPICAL EXPERIMENT METHODS 24
2.2.2 OPTICAL MICROSCOPY 25
2.2.3 ATOMIC FORCE MICROSCOPY 27
2.3 NUMERICAL METHOD 29
IX
HTTP://D-NB.INFO/106828045X
3 MELTING OF THIN TERRACES 31
4 MELTING OF SMALL CYLINDRICAL AGGREGATES 37
4.1 MELTING OF SMALL CYLINDRICAL AGGREGATES 37
4.2 SUPPLEMENTAL SECTION 43
4.2.1 DEDUCTION OF GIBBS-THOMSON EQUATION 43
4.2.2 EXPERIMENTAL METHODS 46
4.2.3 NORMALIZATIONS 48
4.2.4 THE SURFACE OF DELAUNAY 51
4.2.5 LIQUID COEXISTS WITH SOLID BELOW
T
M
54
4.2.6 EFFECT OF CAPILLARY INSTABILITY ON MELTING SCENARIO 54
4.2.7 EFFECT OF SOLID SHAPE ON MELTING SCENARIO 56
5 MELTING OF FILM FROM HOLES 59
6 EFFECT OF MICROSCALE MASS TRANSFER ON MELTING 67
6.1 LIQUID DISTRIBUTION AROUND SOLID ISLAND 67
6.1.1 PREFERENTIAL POSITION FOR A BULGE ON A NON-CIRCULAR ISLAND 67
6.1.2 FLOW RATE AROUND SOLID ISLAND 69
6.2 ANNEALING OF SOLID ISLAND 72
6.2.1 EQUILIBRIUM SOLID SHAPE 72
6.2.2 ANNEALING RATE 75
6.2.3 MODEL AND CALCULATION 75
6.3 CONCLUSION & CONJECTURE 77
7 LIQUID DROP TRAPPED IN THIN SOLID IILM 79
7.1 OBSERVATION OF TEMPERATURE RESPONSIVE DROPS 79
7.2 ANALYSIS 81
7.2.1 MODEL 81
7.2.2 ENERGY PROFILE 82
7.2.3 ANALYSIS OF THE APPARENT CONTACT ANGLE 83
7.3 CONCLUSION 85
CONCLUSION 89
BIBLIOGRAPHY 89
DECLARATION OF AUTHORSHIP 97
ACKNOWLEDGEMENT 96
X
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| author | Jin, Chenyu |
| author_GND | (DE-588)1066502234 |
| author_facet | Jin, Chenyu |
| author_role | aut |
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| bvnumber | BV042418440 |
| ctrlnum | (OCoLC)905371946 (DE-599)GBV817656995 |
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| dewey-ones | 530 - Physics |
| dewey-raw | 530.414 |
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| dewey-sort | 3530.414 |
| dewey-tens | 530 - Physics |
| discipline | Physik |
| format | Thesis Book |
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| physical | X, 98 S. Ill., graph. Darst. |
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| spelling | Jin, Chenyu Verfasser (DE-588)1066502234 aut Theoretical and experimental study of capillary effect on melting von Jin, Chenyu 2015 X, 98 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Potsdam, Univ., Diss., 2015 Mit einer Zssfassung in dt. Sprache Schmelzen (DE-588)4179780-2 gnd rswk-swf Kapillarchemie (DE-588)4163248-5 gnd rswk-swf Phasengesetz (DE-588)4174155-9 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Schmelzen (DE-588)4179780-2 s Kapillarchemie (DE-588)4163248-5 s Phasengesetz (DE-588)4174155-9 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027853869&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Jin, Chenyu Theoretical and experimental study of capillary effect on melting Schmelzen (DE-588)4179780-2 gnd Kapillarchemie (DE-588)4163248-5 gnd Phasengesetz (DE-588)4174155-9 gnd |
| subject_GND | (DE-588)4179780-2 (DE-588)4163248-5 (DE-588)4174155-9 (DE-588)4113937-9 |
| title | Theoretical and experimental study of capillary effect on melting |
| title_auth | Theoretical and experimental study of capillary effect on melting |
| title_exact_search | Theoretical and experimental study of capillary effect on melting |
| title_full | Theoretical and experimental study of capillary effect on melting von Jin, Chenyu |
| title_fullStr | Theoretical and experimental study of capillary effect on melting von Jin, Chenyu |
| title_full_unstemmed | Theoretical and experimental study of capillary effect on melting von Jin, Chenyu |
| title_short | Theoretical and experimental study of capillary effect on melting |
| title_sort | theoretical and experimental study of capillary effect on melting |
| topic | Schmelzen (DE-588)4179780-2 gnd Kapillarchemie (DE-588)4163248-5 gnd Phasengesetz (DE-588)4174155-9 gnd |
| topic_facet | Schmelzen Kapillarchemie Phasengesetz Hochschulschrift |
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| work_keys_str_mv | AT jinchenyu theoreticalandexperimentalstudyofcapillaryeffectonmelting |