Carbyne and Carbynoid Structures:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Dordrecht
Springer Netherlands
1999
|
| Schriftenreihe: | Physics and Chemistry of Materials with Low-Dimensional Structures
21 |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | 1.1. THE DISCOVERY OF CARBYNE Yu.P. KUDRYA VTSEV A.N. Nesmeyanov Institute ofOrganoelement Compounds, Russian Academy of Sciences, 117813 Moscow, Russia Abstract - The history of the discovery of carbyne is briefly recalled. The existence of carbyne was first disclosed by Russian researchers in 1960. It was obtained for the first time via oxidative dehydropolycondensation of acetylene based on the Glaser coupling of ethynyl compounds. 1. Introduction The polymeric nature of carbon was first pointed out by Mendeleev. He wrote: "The molecules of coal, graphite, and diamond are very complicated, and carbon atoms exhibit the capability of binding one to another to form complex molecules in all compounds of carbon. None of the elements possesses an ability of complicating in such an extent as does carbon. There is still no basis to define the polymerization degree of the coal, graphite, or diamond molecules. One should believe, however that they contain en species, where 'n' is a large value" [IJ. Until the 1960s only two allotropic forms of carbon were known, viz., graphite and diamond, including their polymorphous modifications. For a long time 'amorphous carbon' was also included among the simple forms. Presently, however, the structure of amorphous and quasi-amorphous carbons (such as carbon blacks, soot, cokes, glassy carbon, etc.) is known to approach that of graphite to various degrees [2J. |
| Beschreibung: | 1 Online-Ressource (XVII, 446 p) |
| ISBN: | 9789401147422 9789401059930 |
| ISSN: | 0924-6339 |
| DOI: | 10.1007/978-94-011-4742-2 |
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| 490 | 0 | |a Physics and Chemistry of Materials with Low-Dimensional Structures |v 21 |x 0924-6339 | |
| 500 | |a 1.1. THE DISCOVERY OF CARBYNE Yu.P. KUDRYA VTSEV A.N. Nesmeyanov Institute ofOrganoelement Compounds, Russian Academy of Sciences, 117813 Moscow, Russia Abstract - The history of the discovery of carbyne is briefly recalled. The existence of carbyne was first disclosed by Russian researchers in 1960. It was obtained for the first time via oxidative dehydropolycondensation of acetylene based on the Glaser coupling of ethynyl compounds. 1. Introduction The polymeric nature of carbon was first pointed out by Mendeleev. He wrote: "The molecules of coal, graphite, and diamond are very complicated, and carbon atoms exhibit the capability of binding one to another to form complex molecules in all compounds of carbon. None of the elements possesses an ability of complicating in such an extent as does carbon. There is still no basis to define the polymerization degree of the coal, graphite, or diamond molecules. One should believe, however that they contain en species, where 'n' is a large value" [IJ. Until the 1960s only two allotropic forms of carbon were known, viz., graphite and diamond, including their polymorphous modifications. For a long time 'amorphous carbon' was also included among the simple forms. Presently, however, the structure of amorphous and quasi-amorphous carbons (such as carbon blacks, soot, cokes, glassy carbon, etc.) is known to approach that of graphite to various degrees [2J. | ||
| 650 | 4 | |a Analytical biochemistry | |
| 650 | 4 | |a Chemistry, inorganic | |
| 650 | 4 | |a Chemistry, Physical organic | |
| 650 | 4 | |a Surfaces (Physics) | |
| 650 | 4 | |a Materials Science | |
| 650 | 4 | |a Characterization and Evaluation of Materials | |
| 650 | 4 | |a Inorganic Chemistry | |
| 650 | 4 | |a Physical Chemistry | |
| 650 | 4 | |a Analytical Chemistry | |
| 700 | 1 | |a Evsyukov, Sergey E. |e Sonstige |4 oth | |
| 700 | 1 | |a Kavan, Ladislav |e Sonstige |4 oth | |
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Datensatz im Suchindex
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| author | Heimann, Robert B. 1938- |
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| author_sort | Heimann, Robert B. 1938- |
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| bvnumber | BV042416024 |
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| dewey-full | 620.11 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 620 - Engineering and allied operations |
| dewey-raw | 620.11 |
| dewey-search | 620.11 |
| dewey-sort | 3620.11 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Physik |
| doi_str_mv | 10.1007/978-94-011-4742-2 |
| format | Electronic eBook |
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| id | DE-604.BV042416024 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T01:20:58Z |
| institution | BVB |
| isbn | 9789401147422 9789401059930 |
| issn | 0924-6339 |
| language | English |
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| physical | 1 Online-Ressource (XVII, 446 p) |
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| series2 | Physics and Chemistry of Materials with Low-Dimensional Structures |
| spelling | Heimann, Robert B. 1938- Verfasser (DE-588)10837601X aut Carbyne and Carbynoid Structures edited by Robert B. Heimann, Sergey E. Evsyukov, Ladislav Kavan Dordrecht Springer Netherlands 1999 1 Online-Ressource (XVII, 446 p) txt rdacontent c rdamedia cr rdacarrier Physics and Chemistry of Materials with Low-Dimensional Structures 21 0924-6339 1.1. THE DISCOVERY OF CARBYNE Yu.P. KUDRYA VTSEV A.N. Nesmeyanov Institute ofOrganoelement Compounds, Russian Academy of Sciences, 117813 Moscow, Russia Abstract - The history of the discovery of carbyne is briefly recalled. The existence of carbyne was first disclosed by Russian researchers in 1960. It was obtained for the first time via oxidative dehydropolycondensation of acetylene based on the Glaser coupling of ethynyl compounds. 1. Introduction The polymeric nature of carbon was first pointed out by Mendeleev. He wrote: "The molecules of coal, graphite, and diamond are very complicated, and carbon atoms exhibit the capability of binding one to another to form complex molecules in all compounds of carbon. None of the elements possesses an ability of complicating in such an extent as does carbon. There is still no basis to define the polymerization degree of the coal, graphite, or diamond molecules. One should believe, however that they contain en species, where 'n' is a large value" [IJ. Until the 1960s only two allotropic forms of carbon were known, viz., graphite and diamond, including their polymorphous modifications. For a long time 'amorphous carbon' was also included among the simple forms. Presently, however, the structure of amorphous and quasi-amorphous carbons (such as carbon blacks, soot, cokes, glassy carbon, etc.) is known to approach that of graphite to various degrees [2J. Analytical biochemistry Chemistry, inorganic Chemistry, Physical organic Surfaces (Physics) Materials Science Characterization and Evaluation of Materials Inorganic Chemistry Physical Chemistry Analytical Chemistry Evsyukov, Sergey E. Sonstige oth Kavan, Ladislav Sonstige oth https://doi.org/10.1007/978-94-011-4742-2 Verlag Volltext |
| spellingShingle | Heimann, Robert B. 1938- Carbyne and Carbynoid Structures Analytical biochemistry Chemistry, inorganic Chemistry, Physical organic Surfaces (Physics) Materials Science Characterization and Evaluation of Materials Inorganic Chemistry Physical Chemistry Analytical Chemistry |
| title | Carbyne and Carbynoid Structures |
| title_auth | Carbyne and Carbynoid Structures |
| title_exact_search | Carbyne and Carbynoid Structures |
| title_full | Carbyne and Carbynoid Structures edited by Robert B. Heimann, Sergey E. Evsyukov, Ladislav Kavan |
| title_fullStr | Carbyne and Carbynoid Structures edited by Robert B. Heimann, Sergey E. Evsyukov, Ladislav Kavan |
| title_full_unstemmed | Carbyne and Carbynoid Structures edited by Robert B. Heimann, Sergey E. Evsyukov, Ladislav Kavan |
| title_short | Carbyne and Carbynoid Structures |
| title_sort | carbyne and carbynoid structures |
| topic | Analytical biochemistry Chemistry, inorganic Chemistry, Physical organic Surfaces (Physics) Materials Science Characterization and Evaluation of Materials Inorganic Chemistry Physical Chemistry Analytical Chemistry |
| topic_facet | Analytical biochemistry Chemistry, inorganic Chemistry, Physical organic Surfaces (Physics) Materials Science Characterization and Evaluation of Materials Inorganic Chemistry Physical Chemistry Analytical Chemistry |
| url | https://doi.org/10.1007/978-94-011-4742-2 |
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