Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory:
Saved in:
| Main Author: | |
|---|---|
| Format: | Electronic eBook |
| Language: | English |
| Published: |
Dordrecht
Springer Netherlands
1992
|
| Series: | NATO ASI Series, Series C: Mathematical and Physical Sciences
376 |
| Subjects: | |
| Online Access: | Volltext |
| Item Description: | The scope of this paper is to recall fundamental notions of the molecular spectroscopy and dynamics, necessary for discussion of photophysical and photochemical processes in condensed phases. We will thus treat in a more detailed way the specific features which are important for molecular systems strongly interacting with their environment. Other aspects such as the time evolution of isolated molecules, single-level excitation and state-to-state chemistry, important for the gas-phase photophysics are omitted. We start (Sec.2) with a brief description of radiative processes (light absorption and emission) in molecules. In the quantum-mechanical treatment of this problem, the appropriate basis is that of so-called zero-order states, corresponding to the traditional scheme of electronic states (singlets, doublets, triplets etc.) and vibrational levels belonging to each state. The important point will be deduction of selection rules for most radiative transitions. At this stage all molecular states are considered as stationary states. In order to treat the breakdown of simple selection rules and non-radiative transitions between individual molecular states, it is necessary to take into account the mechanisms coupling the zero-order states (Sec.3). We will first focus on intramolecular coupling effects and then discuss the solvent effects on intramolecular relaxation processes. The problem of the non-radiative transfer of the electronic energy between different molecules - closely related to that of the energy dissipation within a single molecule will be treated in Sec.4 |
| Physical Description: | 1 Online-Ressource (X, 449 p) |
| ISBN: | 9789401126984 9789401051958 |
| ISSN: | 1389-2185 |
| DOI: | 10.1007/978-94-011-2698-4 |
Staff View
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Record in the Search Index
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| id | DE-604.BV042415891 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T01:20:58Z |
| institution | BVB |
| isbn | 9789401126984 9789401051958 |
| issn | 1389-2185 |
| language | English |
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| series2 | NATO ASI Series, Series C: Mathematical and Physical Sciences |
| spelling | Kochanski, Elise Verfasser aut Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory edited by Elise Kochanski Proceedings of the NATO Advanced Study Institute, Aussois, France, September 1-13, 1991 Dordrecht Springer Netherlands 1992 1 Online-Ressource (X, 449 p) txt rdacontent c rdamedia cr rdacarrier NATO ASI Series, Series C: Mathematical and Physical Sciences 376 1389-2185 The scope of this paper is to recall fundamental notions of the molecular spectroscopy and dynamics, necessary for discussion of photophysical and photochemical processes in condensed phases. We will thus treat in a more detailed way the specific features which are important for molecular systems strongly interacting with their environment. Other aspects such as the time evolution of isolated molecules, single-level excitation and state-to-state chemistry, important for the gas-phase photophysics are omitted. We start (Sec.2) with a brief description of radiative processes (light absorption and emission) in molecules. In the quantum-mechanical treatment of this problem, the appropriate basis is that of so-called zero-order states, corresponding to the traditional scheme of electronic states (singlets, doublets, triplets etc.) and vibrational levels belonging to each state. The important point will be deduction of selection rules for most radiative transitions. At this stage all molecular states are considered as stationary states. In order to treat the breakdown of simple selection rules and non-radiative transitions between individual molecular states, it is necessary to take into account the mechanisms coupling the zero-order states (Sec.3). We will first focus on intramolecular coupling effects and then discuss the solvent effects on intramolecular relaxation processes. The problem of the non-radiative transfer of the electronic energy between different molecules - closely related to that of the energy dissipation within a single molecule will be treated in Sec.4 Chemistry Chemistry, inorganic Chemistry, Organic Life sciences Organometallic Chemistry Organic Chemistry Inorganic Chemistry Life Sciences, general Biowissenschaften Chemie https://doi.org/10.1007/978-94-011-2698-4 Verlag Volltext |
| spellingShingle | Kochanski, Elise Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory Chemistry Chemistry, inorganic Chemistry, Organic Life sciences Organometallic Chemistry Organic Chemistry Inorganic Chemistry Life Sciences, general Biowissenschaften Chemie |
| title | Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory |
| title_alt | Proceedings of the NATO Advanced Study Institute, Aussois, France, September 1-13, 1991 |
| title_auth | Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory |
| title_exact_search | Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory |
| title_full | Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory edited by Elise Kochanski |
| title_fullStr | Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory edited by Elise Kochanski |
| title_full_unstemmed | Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory edited by Elise Kochanski |
| title_short | Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory |
| title_sort | photoprocesses in transition metal complexes biosystems and other molecules experiment and theory |
| topic | Chemistry Chemistry, inorganic Chemistry, Organic Life sciences Organometallic Chemistry Organic Chemistry Inorganic Chemistry Life Sciences, general Biowissenschaften Chemie |
| topic_facet | Chemistry Chemistry, inorganic Chemistry, Organic Life sciences Organometallic Chemistry Organic Chemistry Inorganic Chemistry Life Sciences, general Biowissenschaften Chemie |
| url | https://doi.org/10.1007/978-94-011-2698-4 |
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