Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization:
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| Main Author: | |
|---|---|
| Format: | Electronic eBook |
| Language: | English |
| Published: |
Dordrecht
Springer Netherlands
1990
|
| Series: | NATO ASI Series, Series C: Mathematical and Physical Sciences
314 |
| Subjects: | |
| Online Access: | Volltext |
| Item Description: | The activation of carbon dioxide by transition metal complexes has been extensively studied. both experimentally and theoretically. 1 Central reactions in this chemistry are the insertion of C02 into M-X bonds. where X = H. C. 0. and N. (eq. 1-4). We are presently investigating the mechanistic aspects of these reaction processes and will herein deSCribe our current level of understanding. Comparisons of the pathway of the carbon-carbon bond fonning process in transition metal chemistry with the well known analogous chemistry involving organolithium reagents will be presented. Furthermore. the role of these reaction types in both homogeneous and heterogenous catalytic processes leading to useful chemicals will be elaborated. _OM> (1) lMt-H + ~ lMlopi _OM> (2) [Mt-R + C0. 2 [M]0. 2CR _OM> (3) [Mt-OR+ ~ [M]0. 2COR _OM> (4) [Mt-NR2 + C0. 2 [M]~CNR2 Insertion of C02 into the Metal-Hydride Bond. The reaction of anionic group 6 (Cr. Mo. W) transition metal hydrides with carbon dioxide to afford metalloformates occurs readlly at ambient temperature and 2 reduced pressures of carbon dioxide. This insertion process is referred to the normal pathway (Scheme 1). There are no documented cases of C02 insertion into the metal hydride bond to provide the alternative. metallocarboxylic acid. isomer (referred in Scheme 1 as abnormal). 3 Recent theoretical studies ascribe this preference to an unfavorable electrostatic interaction and poorer orbital overlap in the latter pro 4 cess. Nevertheless |
| Physical Description: | 1 Online-Ressource (452p) |
| ISBN: | 9789400906631 9789401067836 |
| ISSN: | 1389-2185 |
| DOI: | 10.1007/978-94-009-0663-1 |
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| 245 | 1 | 0 | |a Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization |c edited by M. Aresta, J. V. Schloss |
| 246 | 1 | 3 | |a Proceedings of the NATO Advanced Study Institute, Riva dei Tessali, Italy, June 17-28, 1989 |
| 264 | 1 | |a Dordrecht |b Springer Netherlands |c 1990 | |
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| 500 | |a The activation of carbon dioxide by transition metal complexes has been extensively studied. both experimentally and theoretically. 1 Central reactions in this chemistry are the insertion of C02 into M-X bonds. where X = H. C. 0. and N. (eq. 1-4). We are presently investigating the mechanistic aspects of these reaction processes and will herein deSCribe our current level of understanding. Comparisons of the pathway of the carbon-carbon bond fonning process in transition metal chemistry with the well known analogous chemistry involving organolithium reagents will be presented. Furthermore. the role of these reaction types in both homogeneous and heterogenous catalytic processes leading to useful chemicals will be elaborated. _OM> (1) lMt-H + ~ lMlopi _OM> (2) [Mt-R + C0. 2 [M]0. 2CR _OM> (3) [Mt-OR+ ~ [M]0. 2COR _OM> (4) [Mt-NR2 + C0. 2 [M]~CNR2 Insertion of C02 into the Metal-Hydride Bond. The reaction of anionic group 6 (Cr. Mo. W) transition metal hydrides with carbon dioxide to afford metalloformates occurs readlly at ambient temperature and 2 reduced pressures of carbon dioxide. This insertion process is referred to the normal pathway (Scheme 1). There are no documented cases of C02 insertion into the metal hydride bond to provide the alternative. metallocarboxylic acid. isomer (referred in Scheme 1 as abnormal). 3 Recent theoretical studies ascribe this preference to an unfavorable electrostatic interaction and poorer orbital overlap in the latter pro 4 cess. Nevertheless | ||
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| dewey-full | 546 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546 |
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| dewey-sort | 3546 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| doi_str_mv | 10.1007/978-94-009-0663-1 |
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| institution | BVB |
| isbn | 9789400906631 9789401067836 |
| issn | 1389-2185 |
| language | English |
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| series2 | NATO ASI Series, Series C: Mathematical and Physical Sciences |
| spelling | Aresta, M. Verfasser aut Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization edited by M. Aresta, J. V. Schloss Proceedings of the NATO Advanced Study Institute, Riva dei Tessali, Italy, June 17-28, 1989 Dordrecht Springer Netherlands 1990 1 Online-Ressource (452p) txt rdacontent c rdamedia cr rdacarrier NATO ASI Series, Series C: Mathematical and Physical Sciences 314 1389-2185 The activation of carbon dioxide by transition metal complexes has been extensively studied. both experimentally and theoretically. 1 Central reactions in this chemistry are the insertion of C02 into M-X bonds. where X = H. C. 0. and N. (eq. 1-4). We are presently investigating the mechanistic aspects of these reaction processes and will herein deSCribe our current level of understanding. Comparisons of the pathway of the carbon-carbon bond fonning process in transition metal chemistry with the well known analogous chemistry involving organolithium reagents will be presented. Furthermore. the role of these reaction types in both homogeneous and heterogenous catalytic processes leading to useful chemicals will be elaborated. _OM> (1) lMt-H + ~ lMlopi _OM> (2) [Mt-R + C0. 2 [M]0. 2CR _OM> (3) [Mt-OR+ ~ [M]0. 2COR _OM> (4) [Mt-NR2 + C0. 2 [M]~CNR2 Insertion of C02 into the Metal-Hydride Bond. The reaction of anionic group 6 (Cr. Mo. W) transition metal hydrides with carbon dioxide to afford metalloformates occurs readlly at ambient temperature and 2 reduced pressures of carbon dioxide. This insertion process is referred to the normal pathway (Scheme 1). There are no documented cases of C02 insertion into the metal hydride bond to provide the alternative. metallocarboxylic acid. isomer (referred in Scheme 1 as abnormal). 3 Recent theoretical studies ascribe this preference to an unfavorable electrostatic interaction and poorer orbital overlap in the latter pro 4 cess. Nevertheless Chemistry Chemistry, inorganic Chemistry, Organic Biochemistry Plant physiology Inorganic Chemistry Biochemistry, general Plant Physiology Organic Chemistry Chemie Schloss, J. V. Sonstige oth https://doi.org/10.1007/978-94-009-0663-1 Verlag Volltext |
| spellingShingle | Aresta, M. Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization Chemistry Chemistry, inorganic Chemistry, Organic Biochemistry Plant physiology Inorganic Chemistry Biochemistry, general Plant Physiology Organic Chemistry Chemie |
| title | Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization |
| title_alt | Proceedings of the NATO Advanced Study Institute, Riva dei Tessali, Italy, June 17-28, 1989 |
| title_auth | Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization |
| title_exact_search | Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization |
| title_full | Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization edited by M. Aresta, J. V. Schloss |
| title_fullStr | Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization edited by M. Aresta, J. V. Schloss |
| title_full_unstemmed | Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization edited by M. Aresta, J. V. Schloss |
| title_short | Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization |
| title_sort | enzymatic and model carboxylation and reduction reactions for carbon dioxide utilization |
| topic | Chemistry Chemistry, inorganic Chemistry, Organic Biochemistry Plant physiology Inorganic Chemistry Biochemistry, general Plant Physiology Organic Chemistry Chemie |
| topic_facet | Chemistry Chemistry, inorganic Chemistry, Organic Biochemistry Plant physiology Inorganic Chemistry Biochemistry, general Plant Physiology Organic Chemistry Chemie |
| url | https://doi.org/10.1007/978-94-009-0663-1 |
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