Physics and Chemistry of Small Clusters:
Gespeichert in:
1. Verfasser: | |
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Format: | Elektronisch E-Book |
Sprache: | English |
Veröffentlicht: |
Boston, MA
Springer US
1987
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Schlagworte: | |
Online-Zugang: | Volltext |
Beschreibung: | Recent advances in experimental techniques now enable researchers to produce in a laboratory clusters of atoms of desired composition from any of the elements of the periodic table. This has created a new area of research into novel materials since clusters cannot be regarded either as a "large" molecule or as a fragment of the bulk. Both experimental and theoretical studies are revealing unusual properties that are not ob served in solid state environments. The structures of micro-clusters are found to be significantly distorted from the most symmetric arrangement, some even exhibiting pentagonal symmetry commonly found in icosahedric structures. The unusual stability of certain clusters, now described as "magic number species", shows striking similarities with the nuclear shell structure. The relative stabilities of clusters depend not only on the composition of the clusters but also on their charged states. The studies on spontaneous fragmentation of mUltiply charged clusters, commonly referred to as Coulomb explosion, illustrate the role of electronic bonding mechanisms on stability of clusters. The effect of foreign atoms on geometry and stability of clusters and the interaction of gas atoms with clusters are showing promise for an indepth understanding of chemisorption and catalysis. The magnetic and optical properties are dependent not only on cluster size but also on its geometry. These findings have the potential for aiding industry in the area of micro-electronics and catalysis |
Beschreibung: | 1 Online-Ressource (XV, 957 p) |
ISBN: | 9781475703573 9781475703597 |
DOI: | 10.1007/978-1-4757-0357-3 |
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Datensatz im Suchindex
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---|---|
any_adam_object | |
author | Jena, P. |
author_facet | Jena, P. |
author_role | aut |
author_sort | Jena, P. |
author_variant | p j pj |
building | Verbundindex |
bvnumber | BV042412252 |
classification_tum | PHY 000 |
collection | ZDB-2-PHA ZDB-2-BAE |
ctrlnum | (OCoLC)905466959 (DE-599)BVBBV042412252 |
dewey-full | 539 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 539 - Modern physics |
dewey-raw | 539 |
dewey-search | 539 |
dewey-sort | 3539 |
dewey-tens | 530 - Physics |
discipline | Physik |
doi_str_mv | 10.1007/978-1-4757-0357-3 |
format | Electronic eBook |
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indexdate | 2024-07-10T01:20:50Z |
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isbn | 9781475703573 9781475703597 |
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spelling | Jena, P. Verfasser aut Physics and Chemistry of Small Clusters edited by P. Jena, B. K. Rao, S. N. Khanna Boston, MA Springer US 1987 1 Online-Ressource (XV, 957 p) txt rdacontent c rdamedia cr rdacarrier Recent advances in experimental techniques now enable researchers to produce in a laboratory clusters of atoms of desired composition from any of the elements of the periodic table. This has created a new area of research into novel materials since clusters cannot be regarded either as a "large" molecule or as a fragment of the bulk. Both experimental and theoretical studies are revealing unusual properties that are not ob served in solid state environments. The structures of micro-clusters are found to be significantly distorted from the most symmetric arrangement, some even exhibiting pentagonal symmetry commonly found in icosahedric structures. The unusual stability of certain clusters, now described as "magic number species", shows striking similarities with the nuclear shell structure. The relative stabilities of clusters depend not only on the composition of the clusters but also on their charged states. The studies on spontaneous fragmentation of mUltiply charged clusters, commonly referred to as Coulomb explosion, illustrate the role of electronic bonding mechanisms on stability of clusters. The effect of foreign atoms on geometry and stability of clusters and the interaction of gas atoms with clusters are showing promise for an indepth understanding of chemisorption and catalysis. The magnetic and optical properties are dependent not only on cluster size but also on its geometry. These findings have the potential for aiding industry in the area of micro-electronics and catalysis Physics Atomic, Molecular, Optical and Plasma Physics Cluster-Theorie (DE-588)4148108-2 gnd rswk-swf Cluster (DE-588)4010318-3 gnd rswk-swf Elektronenstruktur (DE-588)4129531-6 gnd rswk-swf Clusterverbindungen (DE-588)4127102-6 gnd rswk-swf 1\p (DE-588)1071861417 Konferenzschrift 1986 Richmond, Va. gnd-content Cluster (DE-588)4010318-3 s Elektronenstruktur (DE-588)4129531-6 s 2\p DE-604 Cluster-Theorie (DE-588)4148108-2 s 3\p DE-604 Clusterverbindungen (DE-588)4127102-6 s 4\p DE-604 Rao, B. K. Sonstige oth Khanna, S. N. Sonstige oth https://doi.org/10.1007/978-1-4757-0357-3 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
spellingShingle | Jena, P. Physics and Chemistry of Small Clusters Physics Atomic, Molecular, Optical and Plasma Physics Cluster-Theorie (DE-588)4148108-2 gnd Cluster (DE-588)4010318-3 gnd Elektronenstruktur (DE-588)4129531-6 gnd Clusterverbindungen (DE-588)4127102-6 gnd |
subject_GND | (DE-588)4148108-2 (DE-588)4010318-3 (DE-588)4129531-6 (DE-588)4127102-6 (DE-588)1071861417 |
title | Physics and Chemistry of Small Clusters |
title_auth | Physics and Chemistry of Small Clusters |
title_exact_search | Physics and Chemistry of Small Clusters |
title_full | Physics and Chemistry of Small Clusters edited by P. Jena, B. K. Rao, S. N. Khanna |
title_fullStr | Physics and Chemistry of Small Clusters edited by P. Jena, B. K. Rao, S. N. Khanna |
title_full_unstemmed | Physics and Chemistry of Small Clusters edited by P. Jena, B. K. Rao, S. N. Khanna |
title_short | Physics and Chemistry of Small Clusters |
title_sort | physics and chemistry of small clusters |
topic | Physics Atomic, Molecular, Optical and Plasma Physics Cluster-Theorie (DE-588)4148108-2 gnd Cluster (DE-588)4010318-3 gnd Elektronenstruktur (DE-588)4129531-6 gnd Clusterverbindungen (DE-588)4127102-6 gnd |
topic_facet | Physics Atomic, Molecular, Optical and Plasma Physics Cluster-Theorie Cluster Elektronenstruktur Clusterverbindungen Konferenzschrift 1986 Richmond, Va. |
url | https://doi.org/10.1007/978-1-4757-0357-3 |
work_keys_str_mv | AT jenap physicsandchemistryofsmallclusters AT raobk physicsandchemistryofsmallclusters AT khannasn physicsandchemistryofsmallclusters |