Solid Hydrogen: Theory of the Properties of Solid H2, HD, and D2
Saved in:
| Main Author: | |
|---|---|
| Format: | Electronic eBook |
| Language: | English |
| Published: |
Boston, MA
Springer US
1983
|
| Subjects: | |
| Online Access: | Volltext |
| Item Description: | The solid molecular hydrogens are the simplest and most fundamental molecular solids. Except at ultrahigh pressures on the order of a few mega bars, where a transition to a metallic, atomic phase is expected, these solids are true molecular crystals in which the molecules retain their identity with properties not too different from those of the free molecules. At energies below the electronic excitation energy, the thermal and spectroscopic pro perties of these solids are determined by the translational, rotational, and intramolecular vibrational motions of the interacting molecules. The theo retical analysis of the solid-state properties in terms of the free molecules and the intermolecular interactions forms the main topic of this book. The available detailed knowledge of the properties of the free molecules makes it feasible to carry out this program to a large extent on the basis of first principles, and this is one of the attractive features of these systems. The solid hydrogens are dominated by quantum effects, the most out standing property being that the rotation of the molecules is free down to the lowest temperatures, in the sense that the rotational quantum number J characterizing the rotational motion of the free molecules remains a good quantum number in all of the solid-state phases except at ultrahigh pressures |
| Physical Description: | 1 Online-Ressource (XV, 306 p) |
| ISBN: | 9781468443011 9781468443035 |
| DOI: | 10.1007/978-1-4684-4301-1 |
Staff View
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| 500 | |a The solid molecular hydrogens are the simplest and most fundamental molecular solids. Except at ultrahigh pressures on the order of a few mega bars, where a transition to a metallic, atomic phase is expected, these solids are true molecular crystals in which the molecules retain their identity with properties not too different from those of the free molecules. At energies below the electronic excitation energy, the thermal and spectroscopic pro perties of these solids are determined by the translational, rotational, and intramolecular vibrational motions of the interacting molecules. The theo retical analysis of the solid-state properties in terms of the free molecules and the intermolecular interactions forms the main topic of this book. The available detailed knowledge of the properties of the free molecules makes it feasible to carry out this program to a large extent on the basis of first principles, and this is one of the attractive features of these systems. The solid hydrogens are dominated by quantum effects, the most out standing property being that the rotation of the molecules is free down to the lowest temperatures, in the sense that the rotational quantum number J characterizing the rotational motion of the free molecules remains a good quantum number in all of the solid-state phases except at ultrahigh pressures | ||
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| isbn | 9781468443011 9781468443035 |
| language | English |
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| spelling | Kranendonk, Jan Verfasser aut Solid Hydrogen Theory of the Properties of Solid H2, HD, and D2 by Jan Kranendonk Boston, MA Springer US 1983 1 Online-Ressource (XV, 306 p) txt rdacontent c rdamedia cr rdacarrier The solid molecular hydrogens are the simplest and most fundamental molecular solids. Except at ultrahigh pressures on the order of a few mega bars, where a transition to a metallic, atomic phase is expected, these solids are true molecular crystals in which the molecules retain their identity with properties not too different from those of the free molecules. At energies below the electronic excitation energy, the thermal and spectroscopic pro perties of these solids are determined by the translational, rotational, and intramolecular vibrational motions of the interacting molecules. The theo retical analysis of the solid-state properties in terms of the free molecules and the intermolecular interactions forms the main topic of this book. The available detailed knowledge of the properties of the free molecules makes it feasible to carry out this program to a large extent on the basis of first principles, and this is one of the attractive features of these systems. The solid hydrogens are dominated by quantum effects, the most out standing property being that the rotation of the molecules is free down to the lowest temperatures, in the sense that the rotational quantum number J characterizing the rotational motion of the free molecules remains a good quantum number in all of the solid-state phases except at ultrahigh pressures Physics Solid State Physics Spectroscopy and Microscopy Fester Zustand (DE-588)4334485-9 gnd rswk-swf Deuterium (DE-588)4149226-2 gnd rswk-swf Wasserstoff (DE-588)4064784-5 gnd rswk-swf Deuterium (DE-588)4149226-2 s Fester Zustand (DE-588)4334485-9 s 1\p DE-604 Wasserstoff (DE-588)4064784-5 s 2\p DE-604 https://doi.org/10.1007/978-1-4684-4301-1 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Kranendonk, Jan Solid Hydrogen Theory of the Properties of Solid H2, HD, and D2 Physics Solid State Physics Spectroscopy and Microscopy Fester Zustand (DE-588)4334485-9 gnd Deuterium (DE-588)4149226-2 gnd Wasserstoff (DE-588)4064784-5 gnd |
| subject_GND | (DE-588)4334485-9 (DE-588)4149226-2 (DE-588)4064784-5 |
| title | Solid Hydrogen Theory of the Properties of Solid H2, HD, and D2 |
| title_auth | Solid Hydrogen Theory of the Properties of Solid H2, HD, and D2 |
| title_exact_search | Solid Hydrogen Theory of the Properties of Solid H2, HD, and D2 |
| title_full | Solid Hydrogen Theory of the Properties of Solid H2, HD, and D2 by Jan Kranendonk |
| title_fullStr | Solid Hydrogen Theory of the Properties of Solid H2, HD, and D2 by Jan Kranendonk |
| title_full_unstemmed | Solid Hydrogen Theory of the Properties of Solid H2, HD, and D2 by Jan Kranendonk |
| title_short | Solid Hydrogen |
| title_sort | solid hydrogen theory of the properties of solid h2 hd and d2 |
| title_sub | Theory of the Properties of Solid H2, HD, and D2 |
| topic | Physics Solid State Physics Spectroscopy and Microscopy Fester Zustand (DE-588)4334485-9 gnd Deuterium (DE-588)4149226-2 gnd Wasserstoff (DE-588)4064784-5 gnd |
| topic_facet | Physics Solid State Physics Spectroscopy and Microscopy Fester Zustand Deuterium Wasserstoff |
| url | https://doi.org/10.1007/978-1-4684-4301-1 |
| work_keys_str_mv | AT kranendonkjan solidhydrogentheoryofthepropertiesofsolidh2hdandd2 |