Modern optical spectroscopy: with exercises and examples from biophysics and biochemistry
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Heidelberg, New York, Dordrecht, London
Springer
2015
|
| Edition: | Second edition |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVI, 572 S. Illustrationen |
| ISBN: | 9783662500217 9783662467763 |
Staff View
MARC
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| 245 | 1 | 0 | |a Modern optical spectroscopy |b with exercises and examples from biophysics and biochemistry |c William W. Parson |
| 250 | |a Second edition | ||
| 264 | 1 | |a Heidelberg, New York, Dordrecht, London |b Springer |c 2015 | |
| 300 | |a XVI, 572 S. |b Illustrationen | ||
| 336 | |b txt |2 rdacontent | ||
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Record in the Search Index
| _version_ | 1804153053891264512 |
|---|---|
| adam_text | CONTENTS
1 INTRODUCTION 1
1.1 OVERVIEW 1
1.2 THE BEER-LAMBERT LAW 3
1.3 REGIONS OF THE ELECTROMAGNETIC SPECTRUM 4
1.4 ABSORPTION SPECTRA OF PROTEINS AND NUCLEIC ACIDS 6
1.5 ABSORPTION SPECTRA OF MIXTURES 8
1.6 THE PHOTOELECTRIC EFFECT 9
1.7 TECHNIQUES FOR MEASURING ABSORBANCE 10
1.8 PUMP-PROBE AND PHOTON-ECHO EXPERIMENTS 14
1.9 LINEAR AND CIRCULAR DICHROISM 15
1.10 DISTORTIONS OF ABSORPTION SPECTRA BY LIGHT SCATTERING OR
NONUNIFORM DISTRIBUTIONS OF THE ABSORBING MOLECULES 17
1.11 FLUORESCENCE 19
1.12 IR AND RAMAN SPECTROSCOPY 24
1.13 LASERS 25
1.14 NOMENCLATURE 26
EXERCISES 27
REFERENCES 28
2 BASIC CONCEPTS OF QUANTUM MECHANICS 31
2.1 WAVEFUNCTIONS, OPERATORS AND EXPECTATION VALUES 31
2.1.1 WAVEFUNCTIONS 31
2.1.2 OPERATORS AND EXPECTATION VALUES 32
2.2 THE TIME-DEPENDENT AND TIME-INDEPENDENT SCHRODINGER
EQUATIONS 38
2.2.1 SUPERPOSITION STATES 44
2.3 SPATIAL WAVEFUNCTIONS 45
2.3.1 A FREE PARTICLE 45
2.3.2 A PARTICLE IN A BOX 46
2.3.3 THE HARMONIC OSCILLATOR 49
2.3.4 ATOMIC ORBITALS 52
2.3.5 MOLECULAR ORBITALS 56
2.3.6 WAVEFUNCTIONS FOR LARGE SYSTEMS 60
2.4 SPIN WAVEFUNCTIONS AND SINGLET AND TRIPLET STATES 62
IX
HTTP://D-NB.INFO/1067668608
X CONTENTS
2.5 TRANSITIONS BETWEEN STATES: TIME-DEPENDENT PERTURBATION
THEORY 70
2.6 LIFETIMES OF STATES AND THE UNCERTAINTY PRINCIPLE 73
EXERCISES 76
REFERENCES 77
3 LIGHT 81
3.1 ELECTROMAGNETIC FIELDS 81
3.1.1 ELECTROSTATIC FORCES AND FIELDS 81
3.1.2 ELECTROSTATIC POTENTIALS 82
3.1.3 ELECTROMAGNETIC RADIATION 85
3.1.4 ENERGY DENSITY AND IRRADIANCE 92
3.1.5 THE COMPLEX ELECTRIC SUSCEPTIBILITY AND REFRACTIVE
INDEX 99
3.1.6 LOCAL-FIELD CORRECTION FACTORS 104
3.2 THE BLACK-BODY RADIATION LAW 106
3.3 LINEAR AND CIRCULAR POLARIZATION 108
3.4 QUANTUM THEORY OF ELECTROMAGNETIC RADIATION 110
3.5 SUPERPOSITION STATES AND INTERFERENCE EFFECTS IN QUANTUM
OPTICS 114
3.6 DISTRIBUTION OF FREQUENCIES IN SHORT PULSES OF LIGHT 118
EXERCISES 120
REFERENCES 121
4 ELECTRONIC ABSORPTION 123
4.1 INTERACTIONS OF ELECTRONS WITH OSCILLATING ELECTRIC FIELDS 123
4.2 THE RATES OF ABSORPTION AND STIMULATED EMISSION 128
4.3 TRANSITION DIPOLES AND DIPOLE STRENGTHS 132
4.4 CALCULATING TRANSITION DIPOLES FOR
N
MOLECULAR ORBITALS 141
4.5 MOLECULAR SYMMETRY AND FORBIDDEN AND ALLOWED
TRANSITIONS 143
4.6 LINEAR DICHROISM 160
4.7 CONFIGURATION INTERACTIONS 164
4.8 CALCULATING ELECTRIC TRANSITION DIPOLES WITH THE GRADIENT
OPERATOR 168
4.9 TRANSITION DIPOLES FOR EXCITATIONS TO SINGLET AND TRIPLET
STATES 177
4.10 THE BORN-OPPENHEIMER APPROXIMATION, FRANCK-CONDON
FACTORS, AND THE SHAPES OF ELECTRONIC ABSORPTION BANDS 179
4.11 SPECTROSCOPIC HOLE BURNING 188
4.12 EFFECTS OF THE SURROUNDINGS ON MOLECULAR TRANSITION
ENERGIES 191
4.13 THE ELECTRONIC STARK EFFECT 199
4.14 METAL-LIGAND AND LIGAND-METAL CHARGE-TRANSFER
TRANSITIONS AND RYDBERG TRANSITIONS 205
4.15 THERMODYNAMICS OF PHOTOEXCITATION 208
EXERCISES 214
REFERENCES 216
CONTENTS XI
5 FLUORESCENCE 225
5.1 THE EINSTEIN COEFFICIENTS 225
5.2 THE STOKES SHIFT 228
5.3 THE MIRROR-IMAGE LAW 230
5.4 THE STRICKLER-BERG EQUATION AND OTHER RELATIONSHIPS
BETWEEN ABSORPTION AND FLUORESCENCE 233
5.5 QUANTUM THEORY OF ABSORPTION AND EMISSION 239
5.6 FLUORESCENCE YIELDS AND LIFETIMES 245
5.7 FLUORESCENT PROBES AND TAGS 256
5.8 PHOTOBLEACHING 260
5.9 FLUORESCENCE ANISOTROPY 261
5.10 SINGLE-MOLECULE FLUORESCENCE AND HIGH-RESOLUTION
FLUORESCENCE MICROSCOPY 267
5.11 FLUORESCENCE CORRELATION SPECTROSCOPY 272
5.12 INTERSYSTEM CROSSING, PHOSPHORESCENCE, AND DELAYED
FLUORESCENCE 279
EXERCISES 282
REFERENCES 283
6 VIBRATIONAL ABSORPTION 297
6.1 VIBRATIONAL NORMAL MODES AND WAVEFUNCTIONS 297
6.2 VIBRATIONAL EXCITATION 305
6.3 INFRARED SPECTROSCOPY OF PROTEINS 312
6.4 VIBRATIONAL STARK EFFECTS 315
EXERCISES 317
REFERENCES 318
7 RESONANCE ENERGY TRANSFER 325
7.1 INTRODUCTION 325
7.2 THE FORSTER THEORY 327
7.3 USING ENERGY TRANSFER TO STUDY FAST PROCESSES IN SINGLE PROTEIN
MOLECULES 342
7.4 EXCHANGE COUPLING 344
7.5 ENERGY TRANSFER TO AND FROM CAROTENOIDS IN PHOTOSYNTHESIS . . . 346
EXERCISES 348
REFERENCES 350
8 EXCITON INTERACTIONS 353
8.1 STATIONARY STATES OF SYSTEMS WITH INTERACTING MOLECULES 353
8.2 EFFECTS OF EXCITON INTERACTIONS ON THE ABSORPTION SPECTRA OF
OLIGOMERS 361
8.3 TRANSITION-MONOPOLE TREATMENTS OF INTERACTION MATRIX ELEMENTS
AND MIXING WITH CHARGE-TRANSFER TRANSITIONS 367
8.4 EXCITON ABSORPTION BAND SHAPES AND DYNAMIC LOCALIZATION OF
EXCITATIONS 370
8.5 EXCITON STATES IN PHOTOSYNTHETIC ANTENNA COMPLEXES 373
XII
CONTENTS
8.6 EXCIMERS AND EXCIPLEXES 376
EXERCISES 377
REFERENCES 379
9 CIRCULAR DICHROISM 383
9.1 MAGNETIC TRANSITION DIPOLES AND N-JT* TRANSITIONS 383
9.2 THE ORIGIN OF CIRCULAR DICHROISM 394
9.3 CIRCULAR DICHROISM OF DIMERS AND HIGHER OLIGOMERS 400
9.4 CIRCULAR DICHROISM OF PROTEINS AND NUCLEIC ACIDS 405
9.5 MAGNETIC CIRCULAR DICHROISM 409
EXERCISES 412
REFERENCES 414
10 COHERENCE AND DEPHASING 417
10.1 OSCILLATIONS BETWEEN QUANTUM STATES OF AN ISOLATED SYSTEM . . . 417
10.2 THE DENSITY MATRIX 421
10.3 THE STOCHASTIC LIOUVILLE EQUATION 427
10.4 EFFECTS OF STOCHASTIC RELAXATIONS ON THE DYNAMICS
OF QUANTUM TRANSITIONS 429
10.5 A DENSITY-MATRIX TREATMENT OF ABSORPTION OF WEAK,
CONTINUOUS LIGHT 435
10.6 THE RELAXATION MATRIX 438
10.7 MORE GENERAL RELAXATION FUNCTIONS AND SPECTRAL
LINESHAPES 448
10.8 ANOMALOUS FLUORESCENCE ANISOTROPY 454
EXERCISES 460
REFERENCES 461
11 PUMP-PROBE SPECTROSCOPY, PHOTON ECHOES AND VIBRATIONAL
WAVEPACKETS 463
11.1 FIRST-ORDER OPTICAL POLARIZATION 463
11.2 THIRD-ORDER OPTICAL POLARIZATION AND NON-LINEAR RESPONSE
FUNCTIONS 472
11.3 PUMP-PROBE SPECTROSCOPY 477
11.4 PHOTON ECHOES 480
11.5 TWO-DIMENSIONAL ELECTRONIC AND VIBRATIONAL SPECTROSCOPY . . . 487
11.6 TRANSIENT GRATINGS 490
11.7 VIBRATIONAL WAVEPACKETS 493
11.8 WAVEPACKET PICTURES OF SPECTROSCOPIC TRANSITIONS 502
EXERCISES 504
REFERENCES 506
12 RAMAN SCATTERING AND OTHER MULTI-PHOTON PROCESSES 513
12.1 TYPES OF LIGHT SCATTERING 513
12.2 THE KRAMERS-HEISENBERG-DIRAC THEORY 517
12.3 THE WAVEPACKET PICTURE OF RESONANCE RAMAN SCATTERING 526
12.4 SELECTION RULES FOR RAMAN SCATTERING 528
CONTENTS XIII
12.5 SURFACE-ENHANCED RAMAN SCATTERING 531
12.6 BIOPHYSICAL APPLICATIONS OF RAMAN SPECTROSCOPY 531
12.7 COHERENT (STIMULATED) RAMAN SCATTERING 532
12.8 MULTI-PHOTON ABSORPTION 534
12.9 QUASIELASTIC (DYNAMIC) LIGHT SCATTERING
(PHOTON CORRELATION SPECTROSCOPY) 537
EXERCISES 541
REFERENCES 542
APPENDIX A 549
A.L VECTORS 549
A.2 MATRICES 551
A.3 FOURIER TRANSFORMS 553
A.4 PHASE SHIFT AND MODULATION AMPLITUDE IN FREQUENCY-DOMAIN
SPECTROSCOPY 557
A.5 CGS AND SI UNITS AND ABBREVIATIONS 560
REFERENCES 561
INDEX 563
|
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| author | Parson, William W. |
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| dewey-full | 535.84 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 535 - Light and related radiation |
| dewey-raw | 535.84 |
| dewey-search | 535.84 |
| dewey-sort | 3535.84 |
| dewey-tens | 530 - Physics |
| discipline | Chemie / Pharmazie Physik Biologie Chemie |
| edition | Second edition |
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| id | DE-604.BV042399698 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:20:30Z |
| institution | BVB |
| isbn | 9783662500217 9783662467763 |
| language | English |
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| physical | XVI, 572 S. Illustrationen |
| publishDate | 2015 |
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| publisher | Springer |
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| spelling | Parson, William W. Verfasser (DE-588)1141916215 aut Modern optical spectroscopy with exercises and examples from biophysics and biochemistry William W. Parson Second edition Heidelberg, New York, Dordrecht, London Springer 2015 XVI, 572 S. Illustrationen txt rdacontent n rdamedia nc rdacarrier Optical spectroscopy Optische Spektroskopie (DE-588)4043680-9 gnd rswk-swf Optische Spektroskopie (DE-588)4043680-9 s DE-604 Erscheint auch als Online-Ausgabe, PDF Parson, William W. Modern optical spectroscopy 2015 978-3-662-46777-0 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027835412&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Parson, William W. Modern optical spectroscopy with exercises and examples from biophysics and biochemistry Optical spectroscopy Optische Spektroskopie (DE-588)4043680-9 gnd |
| subject_GND | (DE-588)4043680-9 |
| title | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry |
| title_auth | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry |
| title_exact_search | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry |
| title_full | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry William W. Parson |
| title_fullStr | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry William W. Parson |
| title_full_unstemmed | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry William W. Parson |
| title_short | Modern optical spectroscopy |
| title_sort | modern optical spectroscopy with exercises and examples from biophysics and biochemistry |
| title_sub | with exercises and examples from biophysics and biochemistry |
| topic | Optical spectroscopy Optische Spektroskopie (DE-588)4043680-9 gnd |
| topic_facet | Optical spectroscopy Optische Spektroskopie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027835412&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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