Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil:
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| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
Jülich
Forschungszentrum Jülich, Zentralbibliothek
2014
|
| Series: | Schriften des Forschungszentrums Jülich
Reihe Energie & Umwelt ; 225 |
| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Item Description: | Literaturverz. S. 109 - 121 |
| Physical Description: | V, 121 S. graph. Darst. |
| ISBN: | 9783893369829 |
Staff View
MARC
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| 245 | 1 | 0 | |a Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil |c Stephan Sittig |
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| 500 | |a Literaturverz. S. 109 - 121 | ||
| 502 | |a Zugl.: Bonn, Univ., Diss., 2014 | ||
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Record in the Search Index
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CONTENTS
CONTENTS I
LIST OF TABLES V
1 INTRODUCTION 1
1.1 RATIONALE 1
1.2 GENERAL OBJECTIVES AND OUTLINE OF THE THESIS . 5
2 LONG-TERM SORPTION AND SEQUESTRATION DYNAMICS OF
THE ANTIBIOTIC SULFADIAZINE - A BATCH STUDY 7
2.1 INTRODUCTION 7
2.2 MATERIALS AND METHODS 10
2.2.1 LABORATORY EXPERIMENTS 10
2.2.2 MODELING 14
2.3 RESULTS AND DISCUSSION 19
2.3.1 MULTIPLE EXTRACTIONS 19
2.3.2 LONG-TERM BATCH EXPERIMENTS: STERILIZED SOIL 21
2.3.3 LONG-TERM BATCH EXPERIMENTS: UNTREATED SOILS.
26
2.3.4 EFFECTS OF STERILIZATION 27
2.3.5 2SIS DESCRIPTION FOR THE MULTIPLE EXTRACTIONS 28
2.4 CONCLUSIONS 29
I
HTTP://D-NB.INFO/1054404488
3 DYNAMICS OF TRANSFORMATION OF THE VETERINARY ANTI
BIOTIC SULFADIAZINE IN TWO SOILS 33
3.1 INTRODUCTION 33
3.2 MATERIALS AND METHODS 36
3.2.1 CHEMICALS 36
3.2.2 LONG-TERM BATCH EXPERIMENTS 36
3.2.3 INSTRUMENTATION AND MEASUREMENTS 38
3.2.4 MATHEMATICAL DESCRIPTION OF DISSIPATION AND
TRANSFORMATION IN THE LIQUID PHASE 39
3.3 RESULTS AND DISCUSSION 42
3.3.1 TRANSFORMATION PRODUCTS OF SDZ 42
3.3.2 TRANSFORMATION IN THE TWO SOILS 44
3.4 CONCLUSIONS 50
3.5 SUPPLEMENTARY MATERIAL 51
3.5.1 SCHEDULE OF THE LABORATORY EXPERIMENTS . . 51
3.5.2 MODELING THE BI-PHASIC BEHAVIOR OF SDZ AND
DERIVING ADDITIONAL ENDPOINTS 53
3.5.3 SCHEDULE OF THE SIMULATIONS 53
3.5.4 MEASUREMENTS AT THE END OF THE 60-DAY EX
PERIMENTAL PERIOD 53
3.5.5 CORRELATIONS BETWEEN SOIL PROPERTIES AND SORP
TION
AND
TRANSFORMATION
PARAMETERS
. 54
4 TRANSPORT OF SULFADIAZINE - LABORATORY ESTIMATED SOIL
PARAMETERS STRONGLY DETERMINED BY THE CHOICE OF
THE LIKELIHOOD FUNCTION 61
4.1 INTRODUCTION 61
4.2 MATERIALS AND METHODS 65
4.2.1 UNSATURATED COLUMN EXPERIMENTS 65
4.2.2 TRANSPORT MODEL 66
4.2.3 PARAMETER ESTIMATION 67
4.2.4 APPLICATION TO A FIELD SCENARIO 70
4.3 RESULTS AND DISCUSSION 73
4.3.1 SIMULATION OF THE SOLUTE BREAKTHROUGHS WITH
TWO DIFFERENT FORMULATIONS OF THE LIKELIHOOD
FUNCTION 73
4.3.2 FIELD SCENARIO 79
4.4 CONCLUSIONS 80
5 COLUMN TRANSPORT EXPERIMENTS WITH MULTIPLE APPLI
CATIONS OF SDZ IN MANURE AND IN LIQUID SOLUTION 81
5.1 INTRODUCTION 81
5.2 MATERIALS AND METHODS 84
5.2.1 LABORATORY EXPERIMENTS 84
5.2.2 NUMERICAL EVALUATIONS 85
5.3 RESULTS AND DISCUSSION 86
5.3.1 BREAKTHROUGH CURVE'S OF THE CL~ TRACER . 86
5.3.2 BREAKTHROUGH CURVES OF THE
14
C-SDZ EQUIV
ALENT CONCENTRATIONS 88
5.3.3 CONCENTRATION PROFILES 92
5.3.4 MODELLING RESULTS 93
5.3.5 BREAKTHROUGH CURVES OF THE TRANSFORMATION
PRODUCTS 96
5.4 CONCLUSIONS 100
6 FINAL REMARKS 101
6.1 SYNTHESIS 101
6.2 OUTLOOK 103
A EXPERIMENTAL SETUP OF THE COLUMN EXPERIMENTS 105
BIBLIOGRAPHY
109 |
| any_adam_object | 1 |
| author | Sittig, Stephan |
| author_GND | (DE-588)1053647409 |
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| bvnumber | BV042238715 |
| ctrlnum | (OCoLC)894694096 (DE-599)DNB1060217104 |
| dewey-full | 631.417 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 631 - Techniques, equipment & materials |
| dewey-raw | 631.417 |
| dewey-search | 631.417 |
| dewey-sort | 3631.417 |
| dewey-tens | 630 - Agriculture and related technologies |
| discipline | Allgemeine Naturwissenschaft Agrar-/Forst-/Ernährungs-/Haushaltswissenschaft / Gartenbau |
| format | Thesis Book |
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| spelling | Sittig, Stephan Verfasser (DE-588)1053647409 aut Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil Stephan Sittig Jülich Forschungszentrum Jülich, Zentralbibliothek 2014 V, 121 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Schriften des Forschungszentrums Jülich : Reihe Energie & Umwelt 225 Literaturverz. S. 109 - 121 Zugl.: Bonn, Univ., Diss., 2014 Zsfassung in dt. Sprache Abbauprodukt (DE-588)4426159-7 gnd rswk-swf Sulfadiazin (DE-588)7553225-6 gnd rswk-swf Löss (DE-588)4168029-7 gnd rswk-swf Einlagerung (DE-588)4263440-4 gnd rswk-swf Gülle (DE-588)4017625-3 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Löss (DE-588)4168029-7 s Gülle (DE-588)4017625-3 s Sulfadiazin (DE-588)7553225-6 s Einlagerung (DE-588)4263440-4 s Abbauprodukt (DE-588)4426159-7 s DE-604 Schriften des Forschungszentrums Jülich Reihe Energie & Umwelt ; 225 (DE-604)BV023393979 225 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4812560&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027676893&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Sittig, Stephan Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil Schriften des Forschungszentrums Jülich Abbauprodukt (DE-588)4426159-7 gnd Sulfadiazin (DE-588)7553225-6 gnd Löss (DE-588)4168029-7 gnd Einlagerung (DE-588)4263440-4 gnd Gülle (DE-588)4017625-3 gnd |
| subject_GND | (DE-588)4426159-7 (DE-588)7553225-6 (DE-588)4168029-7 (DE-588)4263440-4 (DE-588)4017625-3 (DE-588)4113937-9 |
| title | Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil |
| title_auth | Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil |
| title_exact_search | Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil |
| title_full | Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil Stephan Sittig |
| title_fullStr | Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil Stephan Sittig |
| title_full_unstemmed | Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil Stephan Sittig |
| title_short | Sorption, transformation and transport of sulfadiazine in a loess and a sandy soil |
| title_sort | sorption transformation and transport of sulfadiazine in a loess and a sandy soil |
| topic | Abbauprodukt (DE-588)4426159-7 gnd Sulfadiazin (DE-588)7553225-6 gnd Löss (DE-588)4168029-7 gnd Einlagerung (DE-588)4263440-4 gnd Gülle (DE-588)4017625-3 gnd |
| topic_facet | Abbauprodukt Sulfadiazin Löss Einlagerung Gülle Hochschulschrift |
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