Synthesis of iron N-heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons:
Saved in:
| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
München
Verl. Dr. Hut
2014
|
| Edition: | 1. Aufl. |
| Series: | Anorganische Chemie
|
| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | 223 S. graph. Darst. 210 mm x 148 mm, 367 g |
| ISBN: | 9783843917889 3843917884 |
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MARC
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Record in the Search Index
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| adam_text |
TABLE OF CONTENTS
TABLE OF CONTENTS
| A. INTRODUCTION.
. 1
1. METALS
IN CATALYSIS
- IRON AS AN ALTERNATIVE? 2
2. IRON AND CATALYSIS
- AN AUSPICIOUS COMBINATION
FOR THE
FUTURE? 4
2.1. IRON
- GENERAL, PHYSICAL, CHEMICAL
PROPERTIES 4
2.2. IRON
- RELATIVE PRICE
AND COMPARISON TO PLATINUM GROUP METALS 5
2.3. IRON
- TOXICITY ASPECTS 6
2.4. IRON
- AN ENVIRONMENTAL FRIENDLY
ELEMENT? 7
2.5. EXCURSION: IRON
IN BIOLOGICAL SYSTEMS
- PRINCIPLE SELECTION RULES 7
3. IRON IN CATALYSIS 9
3.1. IRON IN INDUSTRIAL CATALYSIS 9
3.2. IRON IN ORGANIC SYNTHESIS 14
3.3 BIOLOGICAL
IRON CATALYSIS 20
4. THE
OXIDATION CHEMISTRY OF IRON
IN HOMOGENEOUS PHASE 32
4.1. THE FENTON
REACTION
- THE FREE RADICAL APPROACH 32
4.2. THE
GIF CHEMISTRY
- IN BETWEEN RADICAL AND NON-RADICAL 36
4.3. ISOLATED HEME
- FIRST MODELS FOR
BIOMIMETIC REACTIONS 37
4.4. NON-HEME COMPLEXES
IN OXIDATION CATALYSIS 41
5. ^-HETEROCYCLIC CARBENES AND IRON 60
6. SCOPE OF THE WORK 65
| B. RESULTS AND DISCUSSION. . .
. 67
1. PRECURSOR
SYNTHESIS 68
1.1. SYNTHESIS
OF DONOR SUBSTITUTED IMIDAZOLES 68
1.2. SYNTHESIS
OF A^-FUNCTIONALIZED BIS-IMIDAZOLIUM SALTS
(NCCN LIGANDS) 75
1.3. SYNTHESIS
OF FURTHER AT-FUNCTIONALIZED IMIDAZOLIUM
SALTS 77
1.4. SYNTHESIS
OF AN IRON AMIDO PRECURSOR 79
HTTP://D-NB.INFO/1060413191
TABLE OF CONTENTS
2. SYNTHESIS AND CHARACTERIZATION
OF IRON COMPLEXES 80
2.1. SYNTHESIS
AND CHARACTERIZATION OF METHYLENE
BRIDGED COMPLEX 9 80
2.2. SYNTHESIS
AND CHARACTERIZATION OF ALKYLENE BRIDGED
COMPLEXES 87
2.3. SYNTHESIS OF METHYLENE BRIDGED IRON NHC COMPLEXES WITH VARIATIONS
IN THE LIGAND
SPHERE 94
2.4. SYNTHESIS
OF AN IRON DI-NHC
COMPLEX 101
2.5. SYNTHESIS
OF AN IRON NHC COMPLEX
BEARING A CYCLIC LIGAND 101
3. REACTIVITY
STUDIES OF COMPLEXES
9-13 WITH CARBON MONOXIDE 106
3.1. SYNTHESIS
OF CARBON MONOXIDE
COMPLEXES 106
3.2. KINETIC STUDIES
ON THE FORMATION OF CO
COMPLEXES 14A^L-F. 113
4. CATALYTIC
OXIDATION OF ALKANES BY IRON NHC-COMPLEXES 116
4.1. ALKANE OXIDATION 116
4.2. OXIDATION OF OLEFINS 123
4.3. ARENE OXIDATION 124
5. MECHANISTIC
CONSIDERATIONS ON THE
CATALYTIC REACTIONS MEDIATED BY COMPLEX 9 131
5.1. UV/VIS STUDIES 131
5.2. PARAMAGNETIC 'H NMR SPECTROSCOPY 133
5.3. VIBRATIONAL SPECTROSCOPY 139
5.4. EPR SPECTROSCOPY 150
5.5. KINETIC INVESTIGATIONS
ON THE
FORMATION OF 15B 150
5.6. PROPOSED
CATALYTIC CYCLE 152
| C. EXPERIMENTAL . . .
155
1. GENERAL 156
1.1. SCHLENK TECHNIQUE 156
1.2. NMR SPECTROSCOPY 156
1.3. UV/VIS SPECTROSCOPY 156
1.4. MASS SPECTROSCOPY 156
TABLE OF CONTENTS
1.5. GAS
CHROMATOGRAPHY 157
1.6. EPR SPECTROSCOPY 157
1.7. CYCLIC
VOLTAMMETRY 157
1.8. VIBRATIONAL SPECTROSCOPY 157
1.9. ELEMENTAL
ANALYSES 158
1.10. SINGLE
CRYSTAL XRD 158
1.11. DFT
CALCULATIONS 158
2. SYNTHETIC
PROCEDURES 159
2.1. SYNTHESIS
OF 1-SUBSTITUTED IMIDAZOLES 159
2.2. SYNTHESIS
OF IMIDAZOLIUM SALTS AS LIGAND PRECURSORS 165
2.3. SYNTHESIS
OF [FE(BTSA
)2
(THF)] 173
2.4. SYNTHESIS
OF IRON NHC COMPLEXES 173
2.5. SYNTHESIS
OF IRON NHC MONOCAIBONYL COMPLEXES 181
2.6. ISOLATION OF REACTION
INTERMEDIATES 187
3. CATALYSIS
PROCEDURES 189
| D. SUMMARY . . . . 193
| . ZUSAMMENFASSUNG. . . 201
| F. REFERENCES
.
209 |
| any_adam_object | 1 |
| author | Raba, Andreas Daniel |
| author_facet | Raba, Andreas Daniel |
| author_role | aut |
| author_sort | Raba, Andreas Daniel |
| author_variant | a d r ad adr |
| building | Verbundindex |
| bvnumber | BV042191762 |
| classification_tum | CHE 376d CHE 612d CHE 334d |
| ctrlnum | (OCoLC)897057065 (DE-599)DNB1060413191 |
| dewey-full | 546.62125 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546.62125 |
| dewey-search | 546.62125 |
| dewey-sort | 3546.62125 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| edition | 1. Aufl. |
| format | Thesis Book |
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| genre_facet | Hochschulschrift |
| id | DE-604.BV042191762 |
| illustrated | Illustrated |
| indexdate | 2024-08-03T01:57:28Z |
| institution | BVB |
| isbn | 9783843917889 3843917884 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027630828 |
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| physical | 223 S. graph. Darst. 210 mm x 148 mm, 367 g |
| publishDate | 2014 |
| publishDateSearch | 2014 |
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| publisher | Verl. Dr. Hut |
| record_format | marc |
| series2 | Anorganische Chemie |
| spelling | Raba, Andreas Daniel Verfasser aut Synthesis of iron N-heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons Andreas Daniel Raba 1. Aufl. 201410 München Verl. Dr. Hut 2014 223 S. graph. Darst. 210 mm x 148 mm, 367 g txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Technische Universität, Diss., 2014 Katalyse (DE-588)4029921-1 gnd rswk-swf Eisenkomplexe (DE-588)4222910-8 gnd rswk-swf Chemische Synthese (DE-588)4133806-6 gnd rswk-swf Stickstoffheterocyclen (DE-588)4183269-3 gnd rswk-swf Carbenkomplexe (DE-588)4147284-6 gnd rswk-swf Kohlenwasserstoffe (DE-588)4125165-9 gnd rswk-swf Oxidation (DE-588)4137187-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Eisenkomplexe (DE-588)4222910-8 s Carbenkomplexe (DE-588)4147284-6 s Stickstoffheterocyclen (DE-588)4183269-3 s Chemische Synthese (DE-588)4133806-6 s DE-604 Kohlenwasserstoffe (DE-588)4125165-9 s Oxidation (DE-588)4137187-2 s Katalyse (DE-588)4029921-1 s Erscheint auch als Online-Ausgabe Raba, Andreas Daniel Synthesis of Iron N-Heterocyclic Carbene Complexes and Their Application in the Oxidation Catalysis of Hydrocarbons X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4815604&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027630828&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Raba, Andreas Daniel Synthesis of iron N-heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons Katalyse (DE-588)4029921-1 gnd Eisenkomplexe (DE-588)4222910-8 gnd Chemische Synthese (DE-588)4133806-6 gnd Stickstoffheterocyclen (DE-588)4183269-3 gnd Carbenkomplexe (DE-588)4147284-6 gnd Kohlenwasserstoffe (DE-588)4125165-9 gnd Oxidation (DE-588)4137187-2 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4222910-8 (DE-588)4133806-6 (DE-588)4183269-3 (DE-588)4147284-6 (DE-588)4125165-9 (DE-588)4137187-2 (DE-588)4113937-9 |
| title | Synthesis of iron N-heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons |
| title_auth | Synthesis of iron N-heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons |
| title_exact_search | Synthesis of iron N-heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons |
| title_full | Synthesis of iron N-heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons Andreas Daniel Raba |
| title_fullStr | Synthesis of iron N-heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons Andreas Daniel Raba |
| title_full_unstemmed | Synthesis of iron N-heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons Andreas Daniel Raba |
| title_short | Synthesis of iron N-heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons |
| title_sort | synthesis of iron n heterocyclic carbene complexes and their application in the oxidation catalysis of hydrocarbons |
| topic | Katalyse (DE-588)4029921-1 gnd Eisenkomplexe (DE-588)4222910-8 gnd Chemische Synthese (DE-588)4133806-6 gnd Stickstoffheterocyclen (DE-588)4183269-3 gnd Carbenkomplexe (DE-588)4147284-6 gnd Kohlenwasserstoffe (DE-588)4125165-9 gnd Oxidation (DE-588)4137187-2 gnd |
| topic_facet | Katalyse Eisenkomplexe Chemische Synthese Stickstoffheterocyclen Carbenkomplexe Kohlenwasserstoffe Oxidation Hochschulschrift |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4815604&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027630828&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT rabaandreasdaniel synthesisofironnheterocycliccarbenecomplexesandtheirapplicationintheoxidationcatalysisofhydrocarbons |