Functional materials: for energy, sustainable development and biomedical sciences
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| Format: | Book |
| Language: | English |
| Published: |
Berlin [u.a.]
De Gruyter
2014
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| Series: | De Gruyter graduate
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| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | XXI, 469 S. Ill., graph. Darst. |
| ISBN: | 3110307812 9783110307818 |
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| 245 | 1 | 0 | |a Functional materials |b for energy, sustainable development and biomedical sciences |c ed. by Mario Leclerc ... |
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CONTENTS
FOREWORD V
PREFACE VII
CONTRIBUTING AUTHORS XVII
ABOUT THE EDITORS XXIII
R. GAUVIN
1 INTRODUCTION 1
PART I: FUNCTIONAL MATERIALS: SYNTHESIS AND APPLICATIONS
A. AL SHBOUL, F. PIERRE, AND J. P. CLAVERIE
2 A PRIMER ON POLYMER COLLOIDS: STRUCTURE, SYNTHESIS AND
COLLOIDAL STABILITY 9
2.1 INTRODUCTION 9
2.2 POLYMER COLLOIDS INSIDE OUT 10
2.2.1 HOW MANY POLYMER CHAINS PER PARTICLE? 10
2.2.2 HOW MANY PARTICLES? 10
2.2.3 ARE THE CHAINS IMMOBILE WITHIN THE NANOPARTICLE? 12
2.2.4 MORPHOLOGY OF POLYMERIC NANOPARTICLES 13
2.3 PREPARATION OF POLYMER NANOPARTICLES 17
2.3.1 EMULSION POLYMERIZATION 18
2.3.2 MINIEMULSION POLYMERIZATION 22
2.3.3 MICROEMULSION POLYMERIZATION 24
2.3 A
SELF-ASSEMBLY IN SELECTIVE SOLVENTS 25
2.4 COLLOIDAL STABILIZATION 26
2.4.1 ELECTROSTATIC STABILIZATION 26
2.4.2 STERIC STABILIZATION 30
2.4.3 DEPLETION STABILIZATION 31
2.4.4 FUTURE DIRECTIONS 33
S. RONDEAU-GAGNE AND J.-F. MORIN
3 SYNTHESIS, FUNCTIONALIZATION AND PROPERTIES OF FULLERENES AND
GRAPHENE MATERIALS 37
3.1 INTRODUCTION 37
3.2 FULLERENES 37
HTTP://D-NB.INFO/1032207655
X
CONTENTS
3.2.1 GENERAL CONSIDERATIONS 38
3.2.2 SYNTHESIS AND PURIFICATION OFFULLERENES 39
3.2.3 CHEMICAL AND PHYSICAL PROPERTIES OF C
60
40
3.2.4 CHEMICAL FUNCTIONALIZATION OF C
60
42
3.2.5 APPLICATIONS 45
3.3 GRAPHENE 47
3.3.1 PRODUCTION OF GRAPHENE 49
3.3.2 GRAPHENE IN ENERGY CONVERSION DEVICES 52
). FLOREK, R. GUILLET-NICOLAS, AND F. KLEITZ
4 ORDERED MESOPOROUS SILICA: SYNTHESIS AND APPLICATIONS 61
4.1 INTRODUCTION 61
4.2 ORDERED MESOPOROUS SILICA (OMS) 62
4.2.1 PRINCIPLE OF SYNTHESIS 63
4.2.2 MESOSTRUCTURE DIVERSITY AND TAILORING 69
4.3 FUNCTIONALIZATION OF ORDERED MESOPOROUS SILICA 78
4.4 MORPHOLOGY CONTROL 80
4.5 SELECTED APPLICATIONS OF FUNCTIONALIZED ORDERED
MESOPOROUS SILICA 82
4.5.1 FUNCTIONALIZED MSNS AS CONTROLLED DRUG DELIVERY PLATFORMS 83
4.5.2 FUNCTIONALIZED MESOPOROUS MATERIALS FOR EXTRACTION
CHROMATOGRAPHY (EXC) APPLICATIONS 88
4.5.3 MESOPOROUS ORGANIC-INORGANIC HYBRID MEMBRANES FOR
WATER DESALINATION 91
A. RITCEY
5 NANOPARTICLES: PROPERTIES AND APPLICATIONS 101
5.1 INTRODUCTION 101
5.2 SYNTHETIC METHODS 101
5.2.1 PARTICLE NUCLEATION AND GROWTH 102
5.2.2 SYNTHESIS IN INVERSE MICELLES 104
5.3 PARTICLE AGGREGATION AND STABILIZATION OF COLLOIDAL SUSPENSIONS 105
5.4 COLLOIDAL QUANTUM DOTS 107
5.5 METAL NANOPARTICLES 110
5.6 METAL OXIDE NANOPARTICLES 112
5.6.1 TITANIUM DIOXIDE 112
5.6.2 IRON OXIDE 113
5.6.3 SILICA 115
5.7 POLYMERIC NANOPARTICLES 115
5.8 ADVANCED ARCHITECTURES AND HYBRID SYSTEMS 117
CONTENTS *
XI
N. ALLARD AND M. LEDERC
6 CONJUGATED POLYMERS FOR ORGANIC ELECTRONICS 121
6.1 INTRODUCTION 121
6.2 PROCESSABLE CONJUGATED POLYMERS 122
6.3 APPLICATIONS IN RENEWABLE ENERGY 126
6.3.1 ORGANIC SOLAR CELLS 126
6.3.2 CONJUGATED POLYMERS FOR ORGANIC SOLAR CELLS 128
6.4 APPLICATIONS IN MICRO-ELECTRONICS 130
6.4.1 FIELD-EFFECT TRANSISTORS 130
6.4.2 CONJUGATED POLYMERS FOR FIELD-EFFECT TRANSISTORS 132
6.5 APPLICATIONS IN LIGHTING 133
6.5.1 LIGHT-EMITTING DIODES 133
6.5.2 CONJUGATED POLYMERS FOR LIGHT-EMITTING DIODES 135
6.6 SUMMARY 136
A. SOLDERA
7 THEORETICAL TOOLS FOR DESIGNING MICROSCOPIC TO MACROSCOPIC PROPERTIES
OF FUNCTIONAL MATERIALS 139
7.1 METHODS 140
7.1.1 THE LINK BETWEEN MICROSCOPIC AND MACROSCOPIC SCALES 140
7.1.2 AB INITIO METHODS 142
7.1.3 BRIDGING THE GAP BETWEEN AB INITIO AND ATOMISTIC LEVELS 146
7.1.4 ATOMISTIC SIMULATION 147
7.1.5 BRIDGING THE GAP BETWEEN ATOMISTIC AND MESOSCALE LEVELS 151
7.2 EXAMPLES 151
7.2.1 QUANTUM STUDIES 152
7.2.2 ATOMISTIC SIMULATION 156
7.3 SUMMARY 164
PART II: DEVELOPMENT OF NEW MATERIALS FOR ENERGY APPLICATIONS
S. B. SCHOUGAARD AND D. BELANGER
8 ELECTROCHEMICAL ENERGY STORAGE SYSTEMS 171
8.1 INTRODUCTION 171
8.2 METRICS AND PERFORMANCE EVALUATION 171
8.3 MODELS AND THEORY OF ELECTROCHEMICAL CHARGE STORAGE 173
8.3.1 BATTERY OPERATION - A FARADAIC PROCESS 174
8.3.2 ELECTROCHEMICAL CAPACITOR OPERATION - A NON-FARADAIC PROCESS 175
8.4 ELECTROLYTES 178
8.5 ELECTRODE MATERIALS 180
8.5.1 ELECTROCHEMICAL CAPACITORS 180
XII
* CONTENTS
8.5.2 HYBRID ELECTROCHEMICAL CAPACITORS 181
8.5.3 LITHIUM BATTERY ELECTRODE MATERIALS 183
8.5.4 NEGATIVE (ANODE) ELECTRODE MATERIALS 184
8.5.5 THE POSITIVE (CATHODE) ELECTRODE 185
8.5.6 ELECTRODE PRODUCTION 186
8.6 SUMMARY 186
D. ROCHEFORT
9 FUNCTIONAL IONIC LIQUIDS ELECTROLYTES IN LITHIUM-ION BATTERIES 189
9.1 INTRODUCTION 189
9.1.1 HISTORICAL OVERVIEW 190
9.1.2 WHAT ARE IONIC LIQUIDS? 191
9.1.3 KEY PROPERTIES AS ELECTROLYTES 192
9.2 IONIC LIQUIDS AS LI AND LITHIUM-ION BATTERY ELECTROLYTES 193
9.3 FUNCTIONAL IONIC LIQUID ELECTROLYTES 194
9.3.1 OVERVIEW OF FUNCTIONAL IONIC LIQUIDS 195
9.3.2 SOLID ELECTROLYTE INTERPHASE 196
9.3.3 TRANSPORT OF LITHIUM IONS 197
9.3.4 ELECTROACTIVE IONIC LIQUIDS AS REDOX SHUTTLES 198
9.3.5 PERSPECTIVES 202
C. DE BONIS, A. D'EPIFANIO, B. MECHERI, S. LICOCCIA, AND A. C. TAVARES
10 SOLID POLYMER PROTON CONDUCTING ELECTROLYTES FOR FUEL CELLS 207
10.1 INTRODUCTION 207
10.2 PROTON EXCHANGE MEMBRANES 209
10.2.1 NAFION 210
10.2.2 ALTERNATIVE SULFONATED IONOMERS AND MEMBRANES 213
10.3 CHARACTERIZATION OF SOLID POLYMER ELECTROLYTES 218
10.3.1 PROTON CONDUCTIVITY 218
10.3.2 STATES OF WATER AND WATER MOBILITY 222
10.4 SUMMARY 233
P. BENARD, A.-M. BEAULIEU, D. DURETTE, AND R. CHAHINE
11 SUPERCRITICAL ADSORPTION OF HYDROGEN ON MICROPOROUS ADSORBENTS 241
11.1 INTRODUCTION 241
11.2 FUNDAMENTALS OF SUPERCRITICAL ADSORPTION 242
11.3 SUPERCRITICAL ADSORPTION ISOTHERMS 246
11.3.1 VIRIAL EXPANSION OF THE EXCESS DENSITY IN TERMS OF PRESSURE 246
11.3.2 BASIC ANALYTIC MODELS OF THE ADSORPTION ISOTHERM 252
11.3.3 SELF-CONSISTENT APPROACHES 256
11.4 THE THERMODYNAMICS OF ADSORPTION 257
11.4.1 PROPERTIES OF SURFACE POTENTIAL 259
CONTENTS
XIII
11.5 MICROPOROUS ADSORBENTS FOR HYDROGEN STORAGE 261
11.5.1 ACTIVATED CARBONS 261
11.5.2 SINGLE WALL NANOTUBES 262
11.5.3 METAL ORGANIC FRAMEWORKS 263
PART III: NEW TRENDS IN SUSTAINABLE DEVELOPMENT AND BIOMEDICAL
APPLICATIONS
D. MANTOVANI, L. LEVESQUE, G. SABBATIER, M. LEROY, D. G. SEIFU, R.
TOLOUEI,
V. MONTANO, M. CLOUTIER, I. BILEM, C. LOY, M. BYAD, C. PATERNOSTER, C.A.
HOESLI,
B. DROUIN, G. LAROCHE
12 ADVANCED MATERIALS FOR BIOMEDICAL APPLICATIONS 277
12.1 INTRODUCTION 277
12.2 HISTORY OF BIOMATERIALS 278
12.3 BASICS IN MATERIAL SCIENCE FOR BIOMATERIAL APPLICATIONS 280
12.3.1 BIOMATERIAL PROPERTIES 280
12.3.2 ' BIOMETALS 280
12.3.3 BIOCERAMICS 281
12.3.4 BIOSYNTHETIC POLYMERS 282
12.3.5 NATURAL POLYMERS 284
12.4 BIOMEDICAL APPLICATIONS 286
12.4.1 CARDIOVASCULAR SYSTEM 286
12.4.2 MUSCULOSKELETAL SYSTEM 291
12.4.3 VISCERAL ORGANS 300
12.4.4 NERVOUS SYSTEM AND SENSORY ORGANS 304
12.4.5 ESTHETIC APPLICATIONS 310
12.4.6 SKIN 312
12.5 FUTURE TRENDS 319
12.5.1 TISSUE ENGINEERING BASIC CONCEPTS 319
12.5.2 SCAFFOLDS 319
12.5.3 SURFACE MODIFICATION 323
12.5.4 STEM CELLS 323
12.5.5 BIOREACTORS 324
12.5.6 COMPUTATIONAL MODELS 324
12.6 SUMMARY 326
M.-A. FORTIN
13 NANOPARTICLES FOR MAGNETIC RESONANCE IMAGING (MRI) APPLICATIONS
IN MEDICINE 333
13.1 THE BASICS OF MRI IN MEDICINE 337
13.2 RELAXIVITY: THE PERFORMANCE OF MRI CONTRAST AGENTS 339
XIV
CONTENTS
13.3 SYNTHESIS AND CHARACTERIZATION OF MAGNETIC NANOPARTICLES 340
13.3.1 SYNTHESIS OF MAGNETIC NANOCRYSTALS 340
13.3.2 NANOPARTICLE COATINGS FOR MRI APPLICATIONS 344
13.3.3 PHYSICOCHEMICAL CHARACTERIZATION 346
13.4 PHYSICAL PROPERTIES OF MAGNETIC NANOPARTICLES 347
13.5 MR RELAXATION PROPERTIES OF MAGNETIC NANOPARTICLES 352
13.5.1 RELAXIVITY OF PARAMAGNETIC CAS 353
13.5.2 RELAXIVITY OF SUPERPARAMAGNETIC CAS 356
13.5.3 RELAXOMETRIC PERFORMANCE OF MRI CAS AT CLINICAL MAGNETIC FIELD
STRENGTHS 358
13.6 BIOLOGICAL PERFORMANCE OF MAGNETIC NANOPARTICLES FOR MRI 358
13.6.1 IN VIVO BARRIERS 360
13.6.2 IMPACT OF NANOPARTICLE SIZE AND SURFACE ON COLLOIDAL STABILITY
AND
BLOOD RETENTION 361
13.6.3 DIRECTING NANOPARTICLES IN VIVO 362
13.6.4 TOXICITY 363
13.7 SUMMARY 364
J. GREENER
14 MICROFLUIDICS FOR SYNTHESIS AND BIOLOGICAL FUNCTIONAL MATERIALS:
FROM DEVICE FABRICATION TO APPLICATIONS 375
14.1 INTRODUCTION 375
14.2 A PRACTICAL INTRODUCTION TO MICROFLUIDIC REACTORS FOR
MATERIAL SYNTHESIS 376
14.2.1 MICROFLUIDIC REACTOR GEOMETRIES 376
14.2.2 DEVICE FABRICATION MATERIALS 377
14.2.3 FABRICATION OF POLYMER-BASED PLANAR MICROREACTORS
AND COMPONENTS 380
14.3 MANIPULATING AND MEASURING PRECURSOR REAGENT STREAMS
IN MICROCHANNELS 383
14.3.1 HIGH SURFACE AREA TO VOLUME RATIOS IN MICROCHANNELS 383
14.3.2 RAPID HEAT TRANSFER 384
14.3.3 CONTROL OF CONCENTRATIONS 384
14.3.4 CONTROLLING "TIME ON CHIP" 386
14.3.5 CONTROL OF HYDRODYNAMICS AND MASS TRANSFER 386
14.3.6 CHARACTERIZATION IN MICROCHANNELS 389
14.4 MICROFLUIDICS FOR POLYMER MICROPARTICLES 391
14.4.1 MANIPULATING THE SHAPING OF LIQUID PRECURSORS 392
14.4.2 EFFECT OF THE CHANNEL WALL 392
14.4.3 EMULSIFICATION OF PRECURSOR DROPLETS 393
14.4.4 CHANNEL GEOMETRIES TO ACHIEVE EMULSIFIED DROPLETS 393
14.4.5 MULTIPLE EMULSIONS 395
CONTENTS
XV
14.4.6 FORMING LINEAR THREADS AND TWO-DIMENSIONAL INTERFACES 395
14.4.7 CONVERTING LIQUID PRECURSORS INTO SOLID MICRO-MATERIALS 397
14.4.8 SCALE UP: A CIRCUIT ANALYSIS OF MICROFLUIDIC FLOW IN A HIGHLY
PARALLELIZED MICROREACTOR 397
14.5 MICROFLUIDICS FOR SYNTHESIS OF FUNCTIONAL NANOPARTICLES 400
14.5.1 MICROFLUIDICS FOR HIGHLY CONTROLLED NANOPARTICLE SYNTHESIS 401
14.6 BIOMATERIALS 402
14.6.1 TISSUE ENGINEERING AND MEMBRANES 403
14.6.2 MICROENVIRONMENTS FOR ENCAPSULATED CELLS 404
14.6.3 BIOFILMS 406
14.6.4 MICRODEVICES UTILIZING FUNCTIONAL BIOMATERIALS 407
14.7 SUMMARY 410
T. LEFEVRE, F. BYETTE, I. MARCOTTE, AND M. AUGER
15 PROTEIN- AND PEPTIDE-BASED MATERIALS: A SOURCE OF INSPIRATION
FOR INNOVATION 415
15.1 INTRODUCTION 415
15.2 BASICS OF PROTEINS, PEPTIDES AND POLYPEPTIDES 417
15.2.1 POLYPEPTIDES ARE SEQUENCES OF AMINO ACIDS 417
15.2.2 POLYPEPTIDES CAN ADOPT VARIOUS CONFORMATIONS 418
15.2.3 POLYPEPTIDES POSSESS VARIOUS LEVELS OF STRUCTURAL ORGANIZATION
419
15.3 FUNCTIONAL MATERIALS FROM FIBROUS PROTEINS 420
15.3.1 RESILIN & ABDUCTIN 421
15.3.2 BYSSUS (MUSSEL ANCHORING THREADS) 422
15.3.3 SILK 425
15.4 FUNCTIONAL MATERIALS FROM GLOBULAR PROTEINS 429
15.4.1 NATURAL PROTEINS 429
15.4.2 ARTIFICIAL PROTEINS 430
15.5 FUNCTIONAL MATERIALS FROM SYNTHETIC PEPTIDES 432
15.6 SUMMARY 435
B. RIEDL, V. VARDANYAN, W. N. NKEUWA, A. KABOORANI, V. LANDRY, B. POATY,
M. VLAD,
AND C. SOW
16 NANOCOMPOSITE COATINGS 443
16.1 INTRODUCTION 443
16.2 COATING FORMULATIONS 446
16.2.1 CHEMICAL COMPONENTS 446
16.2.2 MIXING TECHNIQUES 447
16.2.3 APPLICATION AND CURING 449
16.3 NANOPARTICLE ADDITIVES 449
16.4 COATING CHARACTERIZATION 454
16.4.1 MECHANICAL PROPERTIES 454
XVI
CONTENTS
16.4.2 OPTICAL PROPERTIES 456
16.4.3 X-RAY IMAGING AND PARTICLE AGGREGATION 459
16.4.4 WEATHERING AND ARTIFICIAL AGING 459
16.5 BIO-BASED COATINGS 460
16.6 FUTURE DEVELOPMENTS 462
16.7 SUMMARY 463
INDEX 465 |
| any_adam_object | 1 |
| author2 | Leclerc, Mario |
| author2_role | edt |
| author2_variant | m l ml |
| author_facet | Leclerc, Mario |
| building | Verbundindex |
| bvnumber | BV042110200 |
| classification_rvk | UQ 8200 ZM 3000 |
| ctrlnum | (OCoLC)864645174 (DE-599)DNB1032207655 |
| dewey-full | 620.11 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 620 - Engineering and allied operations |
| dewey-raw | 620.11 |
| dewey-search | 620.11 |
| dewey-sort | 3620.11 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften / Fertigungstechnik |
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| genre | (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Lehrbuch |
| id | DE-604.BV042110200 |
| illustrated | Illustrated |
| indexdate | 2025-02-20T07:11:53Z |
| institution | BVB |
| isbn | 3110307812 9783110307818 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027550647 |
| oclc_num | 864645174 |
| open_access_boolean | |
| owner | DE-1043 DE-11 DE-703 DE-29T DE-20 DE-573 DE-83 DE-862 DE-BY-FWS |
| owner_facet | DE-1043 DE-11 DE-703 DE-29T DE-20 DE-573 DE-83 DE-862 DE-BY-FWS |
| physical | XXI, 469 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | De Gruyter |
| record_format | marc |
| series2 | De Gruyter graduate |
| spellingShingle | Functional materials for energy, sustainable development and biomedical sciences Werkstoffkunde (DE-588)4079184-1 gnd Funktionswerkstoff (DE-588)4841224-7 gnd Intelligenter Werkstoff (DE-588)4274825-2 gnd |
| subject_GND | (DE-588)4079184-1 (DE-588)4841224-7 (DE-588)4274825-2 (DE-588)4123623-3 |
| title | Functional materials for energy, sustainable development and biomedical sciences |
| title_auth | Functional materials for energy, sustainable development and biomedical sciences |
| title_exact_search | Functional materials for energy, sustainable development and biomedical sciences |
| title_full | Functional materials for energy, sustainable development and biomedical sciences ed. by Mario Leclerc ... |
| title_fullStr | Functional materials for energy, sustainable development and biomedical sciences ed. by Mario Leclerc ... |
| title_full_unstemmed | Functional materials for energy, sustainable development and biomedical sciences ed. by Mario Leclerc ... |
| title_short | Functional materials |
| title_sort | functional materials for energy sustainable development and biomedical sciences |
| title_sub | for energy, sustainable development and biomedical sciences |
| topic | Werkstoffkunde (DE-588)4079184-1 gnd Funktionswerkstoff (DE-588)4841224-7 gnd Intelligenter Werkstoff (DE-588)4274825-2 gnd |
| topic_facet | Werkstoffkunde Funktionswerkstoff Intelligenter Werkstoff Lehrbuch |
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| work_keys_str_mv | AT leclercmario functionalmaterialsforenergysustainabledevelopmentandbiomedicalsciences |
Description
THWS Schweinfurt Zentralbibliothek Lesesaal
| Call Number: |
2000 ZM 3000 L462 |
|---|---|
| Copy 1 | ausleihbar Available Place a Hold |