Thermodynamics and energy conversion:
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| Main Author: | |
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| Format: | Book |
| Language: | English |
| Published: |
Berlin [u.a.]
Springer
2014
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| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | XVII, 597 S. Ill., graph. Darst. |
| ISBN: | 3662437147 9783662437148 9783662518755 |
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1 INTRODUCTION: WHY THERMODYNAMICS? 1
1.1 ENERGY AND WORK IN OUR WORLD 1
1.2 MECHANICAL AND THERMODYNAMICAL FORCES 2
1.3 SYSTEMS, BALANCE LAWS, PROPERTY RELATIONS 4
1.4 THERMODYNAMICS AS ENGINEERING SCIENCE 6
1.5 THERMODYNAMIC ANALYSIS 7
1.6 APPLICATIONS 8
2 SYSTEMS, STATES, AND PROCESSES 11
2.1 THE CLOSED SYSTEM 11
2.2 MICRO AND MACRO 12
2.3 MECHANICAL STATE PROPERTIES 13
2.4 EXTENSIVE AND INTENSIVE PROPERTIES 14
2.5 SPECIFIC PROPERTIES 14
2.6 MOLAR PROPERTIES 15
2.7 INHOINOGENEOUS STATES 16
2.8 PROCESSES AND EQUILIBRIUM STATES 17
2.9 QUASI-STATIC AND FAST PROCESSES 17
2.10 REVERSIBLE AND IRREVERSIBLE PROCESSES 18
2.11 TEMPERATURE AND THE ZEROTH LAW 19
2.12 THERMOMETERS AND TEMPERATURE SCALE 20
2.13 GAS TEMPERATURE SCALE 21
2.14 THERMAL EQUATION OF STATE 22
2.15 IDEAL GAS LAW 23
2.16 A NOTE ON PROBLEM SOLVING 24
2.17 EXAMPLE: AIR IN A ROOM 25
2.18 EXAMPLE: AIR IN A REFRIGERATOR 26
2.19 MORE ON PRESSURE 27
PROBLEMS 30
HTTP://D-NB.INFO/1050898079
X CONTENTS
3 THE FIRST LAW OF THERMODYNAMICS 33
3.1 CONSERVATION OF ENERGY 33
3.2 TOTAL ENERGY 35
3.3 KINETIC ENERGY 35
3.4 POTENTIAL ENERGY 35
3.5 INTERNAL ENERGY AND THE CALORIC EQUATION OF STATE 36
3.0 WORK AND POWER 30
3.7 EXACT AND INEXACT DIFFERENTIALS 39
3.8 HEAT TRANSFER 39
3.9 THE FIRST LAW FOR REVERSIBLE PROCESSES 41
3.10 THE SPECIFIC HEAT AT CONSTANT VOLUME 41
3.11 ENTHALPY 43
3.12 EXAMPLE: EQUILIBRATION OF TEMPERATURE 44
3.13 EXAMPLE: UNCONTROLLED EXPANSION OF A GAS 40
3.14 EXAMPLE: FRICTION LOSS 47
3.15 EXAMPLE: HEATING PROBLEMS 47
PROBLEMS 50
4 THE SECOND LAW OF THERMODYNAMICS 55
4.1 THE SECOND LAW 55
4.2 ENTROPY AND THE TREND TO EQUILIBRIUM 55
4.3 ENTROPY FLUX 57
4.4 ENTROPY IN EQUILIBRIUM 57
4.5 ENTROPY AS PROPERTY: THE GIBBS EQUATION 59
4.6 T-S-DIAGRAM 60
4.7 THE ENTROPY BALANCE 61
4.8 THE DIRECTION OF HEAT TRANSFER 63
4.9 INTERNAL FRICTION 65
4.10 NEWTON'S LAW OF COOLING 67
4.11 ZEROTH LAW AND SECOND LAW 08
4.12 EXAMPLE: EQUILIBRATION OF TEMPERATURE 69
4.13 EXAMPLE: UNCONTROLLED EXPANSION OF A GAS 69
4.14 WHAT IS ENTROPY? 70
4.15 ENTROPY AND DISORDER 73
4.16 ENTROPY AND LIFE 74
4.17 THE ENTROPY FLUX REVISITED 75
PROBLEMS 78
5 ENERGY CONVERSION AND THE SECOND LAW 83
5.1 ENERGY CONVERSION 83
5.2 HEAT ENGINES 84
5.3 THE KELVIN-PLANCK STATEMENT 80
5.4 REFRIGERATORS AND HEAT PUMPS 87
5.5 KELVIN-PLANCK AND CLAUSIUS STATEMENTS 89
5.0 THERMODYNAMIC TEMPERATURE 90
CONTENTS
X
'
5.7 PERPETUAL MOTION ENGINES 91
5.8 REVERSIBLE AND IRREVERSIBLE PROCESSES 91
5.9 INTERNALLY AND EXTERNALLY REVERSIBLE PROCESSES 93
5.10 IRREVERSIBILITY AND WORK LOSS 93
5.11 EXAMPLES 94
PROBLEMS 100
6 PROPERTIES AND PROPERTY RELATIONS 103
6.1 STATE PROPERTIES AND THEIR RELATIONS 103
6.2 PHASES 104
6.3 PHASE CHANGES 105
6.4 P-V- AND T-S-DIAGRAMS 110
6.5 SATURATED LIQUID-VAPOR MIXTURES ILL
6.6 IDENTIFYING STATES 113
6.7 EXAMPLE: CONDENSATION OF SATURATED STEAM 115
6.8 SUPERHEATED VAPOR 117
6.9 COMPRESSED LIQUID 120
6.10 THE IDEAL GAS 123
6.11 MONATOMIC GASES (NOBLE GASES) 125
6.12 SPECIFIC HEATS AND COLD GAS APPROXIMATION 126
6.13 REAL GASES 127
6.14 FULLY INCOMPRESSIBLE SOLIDS AND LIQUIDS 128
PROBLEMS 128
7 REVERSIBLE PROCESSES IN CLOSED SYSTEMS 131
7.1 STANDARD PROCESSES 131
7.2 BASIC EQUATIONS 131
7.3 ISOCHORIC PROCESS: V = CONST., DV = 0 133
7.4 ISOBARIC PROCESS: P = CONST., DP = 0 134
7.5 ISENTROPIC PROCESS: 712
= SQ = DS = 0 135
7.6 ISOTHERMAL PROCESS: T = CONST, DT = 0 137
7.7 POLYTROPIC PROCESS (IDEAL GAS): PV
N
* CONST 138
7.8 SUMMARY 139
7.9 EXAMPLES 139
PROBLEMS 147
8 CLOSED SYSTEM CYCLES 153
8.1 THERMODYNAMIC CYCLES 153
8.2 CARNOT CYCLE 155
8.3 CARNOT, REFRIGERATION CYCLE 158
8.4 INTERNAL COMBUSTION ENGINES 159
8.5 OTTO CYCLE 162
8.6 EXAMPLE: OTTO CYCLE 164
8.7 DIESEL CYCLE 165
8.8 EXAMPLE: DIESEL CYCLE 167
XIJ CONTENTS
8.9 DUAL CYCLE 168
8.10 ATKINSON CYCLE 169
PROBLEMS 172
9 OPEN SYSTEMS 177
9.1 FLOWS IN OPEN SYSTEMS 177
9.2 CONSERVATION OF MASS 178
9.3 FLOW WORK AND ENERGY TRANSFER 179
9.4 ENTROPY TRANSFER 181
9.5 OPEN SYSTEMS IN STEADY STATE PROCESSES 181
9.6 ONE INLET, ONE EXIT SYSTEMS 182
9.7 ENTROPY GENERATION IN MASS TRANSFER 184
9.8 ADIABATIC COMPRESSORS, TURBINES AND PUMPS 186
9.9 HEATING AND COOLING OF A PIPE FLOW 187
9.10 THROTTLING DEVICES 188
9.11 ADIABATIC NOZZLES AND DIFFUSERS 188
9.12 ISENTROPIC EFFICIENCIES 190
9.13 SUMMARY: OPEN SYSTEM DEVICES 192
9.14 EXAMPLES: OPEN SYSTEM DEVICES 192
9.15 CLOSED HEAT EXCHANGERS 200
9.16 OPEN HEAT EXCHANGERS: ADIABATIC MIXING 201
9.17 EXAMPLES: HEAT EXCHANGERS 202
PROBLEMS 203
10 BASIC OPEN SYSTEM CYCLES 209
10.1 STEAM TURBINE: RANKINE CYCLE 209
10.2 EXAMPLE: RANKINE CYCLE 212
10.3 VAPOR REFRIGERATION/HEAT PUMP CYCLE 216
10.4 EXAMPLE: VAPOR COMPRESSION REFRIGERATOR 218
10.5 GAS TURBINE: BRAYTON CYCLE 221
10.6 EXAMPLE: BRAYTON CYCLE 225
10.7 GAS REFRIGERATION SYSTEM: INVERSE BRAYTON CYCLE 226
PROBLEMS 228
11 EFFICIENCIES AND IRREVERSIBLE LOSSES 235
11.1 IRREVERSIBILITY AND WORK LOSS 235
11.2 REVERSIBLE WORK AND SECOND LAW EFFICIENCY 237
11.3 EXAMPLE: CARNOT ENGINE WITH EXTERNAL IRREVERSIBILITY . 239
11.4 EXAMPLE: SPACE HEATING 241
11.5 EXAMPLE: ENTROPY GENERATION IN HEAT TRANSFER 244
11.6 WORK POTENTIAL OF A FLOW (EXHAUST LOSSES) 245
11.7 HEAT ENGINE DRIVEN BY HOT COMBUSTION GAS 246
11.8 EXERGY 251
PROBLEMS 252
CONTENTS XIII
12 VAPOR ENGINES 257
12.1 BOILER EXHAUST REGENERATION 257
12.2 REGENERATIVE RANKINE CYCLE 259
12.3 EXAMPLE: STEAM CYCLES WITH FEEDWATER HEATERS 266
12.4 COGENERATION PLANTS 273
12.5 REFRIGERATION SYSTEMS 275
12.6 LINDE METHOD FOR GCIS LIQUEFACTION 278
PROBLEMS 279
13 GAS ENGINES 289
13.1 STIRLING CYCLE 289
13.2 ERICSSON CYCLE 296
13.3 COMPRESSION WITH INTERCOOLING 297
13.4 GAS TURBINE CYCLES WITH REGENERATION AND REHEAT 300
13.5 BRAYTON CYCLE WITH INTERCOOLING AND REHEAT 303
13.6 COMBINED CYCLE 305
13.7 THE SOLAR TOWER 306
13.8 SIMPLE CHIMNEY 309
13.9 AIRCRAFT ENGINES 310
PROBLEMS 322
14 COMPRESSIBLE FLOW: NOZZLES AND DIFFUSERS 327
14.1 SUB- AND SUPERSONIC FLOWS 327
14.2 SPEED OF SOUND 327
14.3 SPEED OF SOUND IN AN IDEAL GAS 329
14.4 AREA-VELOCITY RELATION 330
14.5 NOZZLE FLOWS 333
14.6 CONVERGING NOZZLE 334
14.7 EXAMPLE: SAFETY VALVE 336
14.8 LAVAL NOZZLE 337
14.9 ROCKETS, RAMJET AND SCRAMJET 338
14.10 EXAMPLE: RANI JET 340
PROBLEMS 342
15 TRANSIENT AND INHOMOGENEOUS PROCESSES
IN OPEN SYSTEMS 345
15.1 INTRODUCTION 345
15.2 HEAT EXCHANGERS 345
15.3 HEATING OF A HOUSE 352
15.4 REVERSIBLE FILLING OF AN ADIABATIC CONTAINER 355
15.5 REVERSIBLE DISCHARGE FROM AN ADIABATIC CONTAINER 357
15.6 REVERSIBLE DISCHARGE AFTER COOLING 357
15.7 REVERSIBLE FILLING OF A GAS CONTAINER WITH HEAT
EXCHANGE 360
15.8 CAES: COMPRESSED AIR ENERGY STORAGE 362
PROBLEMS 368
XIV
CONTENTS
16 MORE ON PROPERTY RELATIONS 371
1G.1 MEASURABILITY OF PROPERTIES 371
16.2 THERMODYNAMIC POTENTIALS AND MAXWELL RELATIONS 371
16.3 TWO USEFUL RELATIONS 374
16.4 RELATION BETWEEN SPECIFIC HEATS 376
16.5 MEASUREMENT OF PROPERTIES 377
16.6 EXAMPLE: GIBBS FREE ENERGY AS POTENTIAL 380
16.7 COMPRESSIBILITY, THERMAL EXPANSION 381
16.8 EXAMPLE: VAN DER WAALS GAS 383
16.9 JOULE-THOMSON COEFFICIENT 387
16.10 EXAMPLE: INVERSION CURVE FOR THE VAN DER WAALS GAS . 388
PROBLEMS 389
17 THERMODYNAMIC EQUILIBRIUM 393
17.1 EQUILIBRIUM CONDITIONS 393
17.2 EQUILIBRIUM IN ISOLATED SYSTEMS 394
17.3 BAROMETRIC AND HYDROSTATIC FORMULAS 397
17.4 THERMODYNAMIC STABILITY 397
17.5 EQUILIBRIUM IN NON-ISOLATED SYSTEMS 398
17.6 INTERPRETATION OF THE BAROMETRIC FORMULA 401
17.7 EQUILIBRIUM IN HETEROGENEOUS SYSTEMS 402
17.8 PHASE EQUILIBRIUM 404
17.9 EXAMPLE: PHASE EQUILIBRIUM FOR THE VAN DER WAALS
GAS 406
17.10 CLAPEYRON EQUATION 407
17.11 EXAMPLE: ESTIMATE OF HEAT OF EVAPORATION 408
17.12 EXAMPLE: ICE SKATING 409
PROBLEMS 410
18 MIXTURES 415
18.1 INTRODUCTION 415
18.2 MIXTURE COMPOSITION 415
18.3 EXAMPLE: COMPOSITION AND MOLAR MASS OF AIR 416
18.4 MIXTURE PROPERTIES 417
18.5 MIXING VOLUME, HEAT OF MIXING AND ENTROPY OF MIXING. 418
18.6 IDEAL GAS MIXTURES 420
18.7 ENERGY, ENTHALPY AND SPECIFIC HEATS FOR IDEAL GASES 421
18.8 ENTROPY OF MIXING FOR IDEAL GAS 421
18.9 GIBBS PARADOX 422
18.10 EXAMPLE: ISENTROPIC EXPANSION THROUGH A NOZZLE 423
18.11 EXAMPLE: ISOCLIORIC MIXING OF TWO GASES AT
DIFFERENT P, T 424
18.12 IDEAL MIXTURES 425
18.13 ENTROPY OF MIXING AND SEPARATION WORK 428
18.14 NON-IDEAL MIXTURES 429
PROBLEMS 430
CONTENTS
19 PSYCHROMETRICS 433
19.1 CHARACTERIZATION OF MOIST,
AIR 433
19.2 DEWPOINT 435
19.3 ADIABATIC SATURATION AND WET-BULB TEMPERATURE 436
19.4 PSYCHROMETRIC CHART 437
19.5 DEHUNIIDIFICATION 440
19.6 HUNIIDIFICATION WITH STEAM 442
19.7 EVAPORATIVE COOLING 443
19.8 ADIABATIC MIXING 445
19.9 COOLING TOWERS 446
19.10 EXAMPLE: COOLING TOWER 447
PROBLEMS 449
20 THE CHEMICAL POTENTIAL 455
20.1 DEFINITION AND INTERPRETATION 455
20.2 PROPERTIES OF THE CHEMICAL POTENTIAL 456
20.3 GIBBS AND GIBBS-DULICM EQUATIONS 458
20.4 MASS BASED CHEMICAL POTENTIAL 459
20.5 THE CHEMICAL POTENTIAL FOR AN IDEAL MIXTURE 460
20.6 THE CHEMICAL POTENTIAL FOR AN IDEAL GAS MIXTURE 460
20.7 THE CHEMICAL POTENTIAL AS DRIVING FORCE FOR MASS
TRANSFER 461
PROBLEMS 463
21 MIXING AND SEPARATION 467
21.1 OSMOSIS AND OSMOTIC PRESSURE 467
21.2 OSMOTIC PRESSURE FOR DILUTE SOLUTIONS 468
21.3 EXAMPLE: PFEFFER TUBE 469
21.4 DESALINATION IN A CONTINUOUS PROCESS 471
21.5 REVERSIBLE MIXING: OSMOTIC POWER GENERATION 474
21.6 EXAMPLE: DESALINATION IN PISTON-CYLINDER DEVICE 477
21.7 EXAMPLE: REMOVAL OF CO2 479
PROBLEMS 484
22 PHASE EQUILIBRIUM IN MIXTURES 493
22.1 PHASE MIXTURES 493
22.2 GIBBS' PHASE R.ULE 493
22.3 LIQUID-VAPOR-MIXTURES: IDEALIZED RAOULT'S LAW 494
22.4 PHASE DIAGRAMS FOR BINARY MIXTURES 495
22.5 DISTILLATION 498
22.6 SATURATION PRESSURE AND TEMPERATURE OF A SOLVENT 498
22.7 FREEZING OF A LIQUID SOLUTION 501
22.8 NON-IDEAL MIXTURES: ACTIVITY AND FUGACITY 502
22.9 A SIMPLE MODEL FOR HEAT OF MIXING AND ACTIVITY 504
22.10 GAS SOLUBILITY: HENRY'S LAW 505
XVI CONTENTS
22.11 PHASE DIAGRAMS WITH AZEOTROPES 506
PROBLEMS 509
23 REACTING MIXTURES 517
23.1 STOICLIIOMETRIC COEFFICIENTS 517
23.2 MASS AND MOLE BALANCES 518
23.3 HEAT OF REACTION 519
23.4 HEATING VALUE 520
23.5 ENTHALPY OF FORMATION 520
23.6 THE THIRD LAW OF THERMODYNAMICS 522
23.7 THE THIRD LAW AND ABSOLUTE ZERO 523
23.8 LAW OF MASS ACTION 524
23.9 LAW OF MASS ACTION FOR IDEAL MIXTURES AND IDEAL GASES. 524
23.10 EXAMPLE: NH3 PRODUCTION (HABER-BOSCH PROCESS) 526
23.11 LE CLIATELIER PRINCIPLE 528
23.12 MULTIPLE REACTIONS 529
PROBLEMS 530
24 ACTIVATION OF REACTIONS 535
24.1 APPROACHING CHEMICAL EQUILIBRIUM 535
24.2 REACTION RATES AND THE CHEMICAL CONSTANT 536
24.3 GIBBS FREE ENERGY OF ACTIVATION 537
24.4 ENTROPY GENERATION 539
PROBLEMS 540
25 COMBUSTION 541
25.1 FUELS 541
25.2 COMBUSTION AIR 542
25.3 EXAMPLE: MOLE AND MASS FLOW BALANCES 542
25.4 EXAMPLE: EXHAUST WATER 544
25.5 FIRST AND SECOND LAW FOR COMBUSTION SYSTEMS 545
25.6 ADIABATIC FLAME TEMPERATURE 546
25.7 EXAMPLE: ADIABATIC FLAME TEMPERATURE 546
25.8 CLOSED SYSTEM COMBUSTION 547
25.9 EXAMPLE: CLOSED ^SYSTEM COMBUSTION 548
25.10 ENTROPY GENERATION IN CLOSED SYSTEM COMBUSTION 548
25.11 WORK POTENTIAL OF A FUEL 549
25.12 EXAMPLE: WORK LOSSES IN A CH4 FIRED STEAM
POWER PLANT 552
PROBLEMS 558
26 THERMODYNAMICS OF FUEL CELLS 563
26.1 FUEL CELLS 563
26.2 FUEL CELL POTENTIAL 564
26.3 FUEL CELL EFFICIENCY 567
26.4 NERNST EQUATION 571
CONTENTS
XVII
26.5 MASS TRANSFER LOSSES 572
26.6 RESISTANCE LOSSES 574
26.7 ACTIVATION OVERPOTENTIAL 575
26.8 VOLTAGE/CURRENT AND POWER/CURRENT, DIAGRAMS 580
26.9 CROSSOVER LOSSES 582
26.10 ELECTROLYZERS 584
26.11 HYDROGEN 585
PROBLEMS 586
INDEX 591 |
| any_adam_object | 1 |
| author | Struchtrup, Henning |
| author_facet | Struchtrup, Henning |
| author_role | aut |
| author_sort | Struchtrup, Henning |
| author_variant | h s hs |
| building | Verbundindex |
| bvnumber | BV042034389 |
| classification_rvk | UG 1200 |
| ctrlnum | (OCoLC)890014853 (DE-599)DNB1050898079 |
| dewey-full | 621.4021 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 621 - Applied physics |
| dewey-raw | 621.4021 |
| dewey-search | 621.4021 |
| dewey-sort | 3621.4021 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Physik Mathematik Energietechnik |
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| id | DE-604.BV042034389 |
| illustrated | Illustrated |
| indexdate | 2024-08-03T01:43:45Z |
| institution | BVB |
| isbn | 3662437147 9783662437148 9783662518755 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027475799 |
| oclc_num | 890014853 |
| open_access_boolean | |
| owner | DE-19 DE-BY-UBM DE-29T DE-703 DE-1050 |
| owner_facet | DE-19 DE-BY-UBM DE-29T DE-703 DE-1050 |
| physical | XVII, 597 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Springer |
| record_format | marc |
| spelling | Struchtrup, Henning Verfasser aut Thermodynamics and energy conversion Henning Struchtrup Berlin [u.a.] Springer 2014 XVII, 597 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Ingenieurwissenschaften Chemical engineering Thermodynamics Hydraulic engineering Electric engineering Engineering Thermodynamik (DE-588)4059827-5 gnd rswk-swf Energieumwandlung (DE-588)4014730-7 gnd rswk-swf Energieumwandlung (DE-588)4014730-7 s Thermodynamik (DE-588)4059827-5 s DE-604 Erscheint auch als Online-Ausgabe 978-3-662-43715-5 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4663434&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027475799&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Struchtrup, Henning Thermodynamics and energy conversion Ingenieurwissenschaften Chemical engineering Thermodynamics Hydraulic engineering Electric engineering Engineering Thermodynamik (DE-588)4059827-5 gnd Energieumwandlung (DE-588)4014730-7 gnd |
| subject_GND | (DE-588)4059827-5 (DE-588)4014730-7 |
| title | Thermodynamics and energy conversion |
| title_auth | Thermodynamics and energy conversion |
| title_exact_search | Thermodynamics and energy conversion |
| title_full | Thermodynamics and energy conversion Henning Struchtrup |
| title_fullStr | Thermodynamics and energy conversion Henning Struchtrup |
| title_full_unstemmed | Thermodynamics and energy conversion Henning Struchtrup |
| title_short | Thermodynamics and energy conversion |
| title_sort | thermodynamics and energy conversion |
| topic | Ingenieurwissenschaften Chemical engineering Thermodynamics Hydraulic engineering Electric engineering Engineering Thermodynamik (DE-588)4059827-5 gnd Energieumwandlung (DE-588)4014730-7 gnd |
| topic_facet | Ingenieurwissenschaften Chemical engineering Thermodynamics Hydraulic engineering Electric engineering Engineering Thermodynamik Energieumwandlung |
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