Emulsions, foams, suspensions, and aerosols: microscience and applications
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| Main Author: | |
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| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2014
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| Edition: | 2. ed. |
| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | XIX, 492 S. Ill., graph. Darst. |
| ISBN: | 3527337067 9783527337064 9783527679478 |
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MARC
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| 245 | 1 | 0 | |a Emulsions, foams, suspensions, and aerosols |b microscience and applications |c Laurier L. Schramm |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2014 | |
| 300 | |a XIX, 492 S. |b Ill., graph. Darst. | ||
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Record in the Search Index
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|---|---|
| adam_text |
VII
CONTENTS
PREFACE
XV
ABOUT THE AUTHOR
XVII
ACKNOWLEDGEMENTS
XIX
1 INTRODUCTION 1
1.1 FROM THE COLLOIDAL STATE TO NANOTECHNOLOGY 1
1.1.1 MICROSCIENCE, COLLOIDS, NANOSCIENCE AND NANOTECHNOLOGY 4
1.2 CLASSIFICATION OF EMULSIONS, FOAMS, SUSPENSIONS AND AEROSOLS 6
1.2.1 EMULSIONS
6
1.2.2 FOAMS 9
1.2.3 SUSPENSIONS 11
1.2.4 AEROSOLS 14
1.2.5 HYBRIDS 17
1.3 CHARACTERIZATION AND STABILITY 17
REFERENCES 18
2 DISPERSION AND DISPERSED SPECIES CHARACTERIZATION
2.1 INTRODUCTION 23
2.2 SURFACE AREA, SURFACES, POROSITY AND PERMEABILITY
2.2.1 SURFACE AREA 23
2.2.2 SURFACES 27
2.2.3 POROSITY 28
2.2.4 PERMEABILITY 29
2.3 SIZE AND SIZE DISTRIBUTION 30
2.3.1 MICROSCOPY 31
2.3.2 FILTRATION AND SIEVING 36
2.3.3 RADIATION SCATTERING 38
2.3.4 ULTRAMICROSCOPY 42
2.3.5 OTHER TECHNIQUES 42
2.4 CONDUCTIVITY 43
2.4.1 DISPERSED PHASE IDENTIFICATION 43
2.4.2 SENSING ZONE TECHNIQUES 44
2.4.3 CONDUCTIVITY OF DISPERSIONS 45
23
23
HTTP://D-NB.INFO/1049503449
VIII
I
CONTENTS
2.5 SEDIMENTATION, CREAMING AND CENTRIFUGATION 46
2.5.1 SEDIMENTATION AND CREAMING 46
2.5.2 CENTRIFUGATION AND ULTRACENTRIFUGATION 53
2.6 CHARACTERIZATION OF EMULSIONS 56
2.6.1 APPEARANCE AND EMULSION TYPE 56
2.6.2 EXPERIMENTAL ASSESSMENT OF EMULSION STABILITY 58
2.6.3 COMPOSITION 59
2.7 CHARACTERIZATION OF FOAMS 60
2.7.1 APPEARANCE AND FOAM TYPE 60
2.7.2 EXPERIMENTAL ASSESSMENT OF FOAM STABILITY 62
2.8 CHARACTERIZATION OF SUSPENSIONS
66
2.8.1 CHEMICAL AND SURFACE ANALYSIS
66
2.8.2 EXPERIMENTAL ASSESSMENT OF SUSPENSION STABILITY 66
2.9 CHARACTERIZATION OF AEROSOLS 67
2.9.1 AEROSOL COMPOSITION, CONCENTRATION, SIZE AND CHARGE 67
2.9.2 AEROSOL PROCESSES AND STABILITY 74
REFERENCES 78
3 INTERFACIAL ENERGETICS
85
3.1 SURFACE AREA 85
3.2 SURFACE AND INTERFACIAL TENSIONS 86
3.2.1 PRINCIPLES
86
3.2.2 EQUATION OF YOUNG-LAPLACE 94
3.2.3 MEASUREMENT 94
3.2.3.1 CAPILLARY RISE 95
3.2.3.2 WILHELMY PLATE 96
3.2.3.3 DU NOIIY RING 97
3.2.3.4 DROP WEIGHT AND VOLUME METHODS 98
3.2.3.5 DROP SHAPE METHODS 98
3.2.3.6 OSCILLATING JET METHOD 98
3.2.3.7 SPINNING DROP METHOD 101
3.2.3.8 MAXIMUM BUBBLE OR DROPLET PRESSURE METHOD 102
3.2.3.9 MICROFLUIDIC METHODS 103
3.2.4 EXPERIMENTAL RESULTS FOR DISPERSIONS 103
3.3 PRESSURE AND CURVED SURFACES 106
3.4 CONTACT ANGLE AND WETTABILITY 107
3.5 SURFACTANTS AND MICELLES 114
3.5.1 SURFACE ACTIVITY 114
3.5.1.1 RETARDATION OF EVAPORATION BY MONOLAYERS 117
3.5.2 CLASSIFICATION AND ANALYSIS OF SURFACTANTS 118
3.5.3 MICELLES 120
3.5.4 SURFACE ELASTICITY 126
3.5.5 POLYMERIC SURFACTANTS 129
3.6 APPLICATIONS OF SURFACE ACTIVITY 129
3.6.1 SURFACTANTS AND EMULSIFICATION 129
CONTENTS
IIX
3.6.2 SURFACTANTS AND FOAMING 132
3.6.3 SURFACTANTS AND FLOTATION 133
3.6.4 SURFACTANTS AND SUSPENSIONS 134
3.6.5 SURFACTANTS AND WETTING 134
3.6.6 SURFACTANTS AND DETERGENCY 135
3.7 OTHER LYOPHILIC COLLOIDS: MICROEMULSIONS 138
REFERENCES 142
4 ELECTROKINETICS
147
4.1 CHARGED INTERFACES 147
4.2 ELECTRIC DOUBLE LAYER 149
4.3 ELECTROKINETIC PHENOMENA 151
4.3.1 ELECTROPHORESIS 154
4.3.2 POINT OF ZERO CHARGE AND ISOELECTRIC POINT 158
4.3.3 ELECTRODIALYSIS 159
4.4 ELECTROSTATIC PROPERTIES IN NON-AQUEOUS MEDIA 160
REFERENCES 161
5 COLLOID STABILITY
163
5.1 INTRODUCTION 163
5.2 ELECTROSTATIC AND DISPERSION FORCES 165
5.2.1 REPULSIVE FORCES 165
5.2.2 DISPERSION FORCES 167
5.3 DLVO "THEORY
AND PRACTICE 168
5.3.1 THEORY 168
5.3.2 PRACTICAL GUIDELINES 174
5.3.3 SCHULZE-HARDY RULE 176
5.3.4 PEPTIZATION 178
5.4 HYDRATION AND STERIC EFFECTS 178
5.4.1 STERIC STABILIZATION 180
5.5 ADDITIONAL STABILIZING INFLUENCES 183
5.5.1 OTHER STABILIZING INFLUENCES FOR SUSPENSION STABILITY 183
5.5.2 OTHER INFLUENCES ON EMULSION STABILITY 184
5.5.3 OTHER INFLUENCES ON FOAM STABILITY 187
5.6 KINETICS 189
5.7 DESTABILIZATION OF COLLOIDS 195
5.7.1 AGGREGATION AND FLOCCULATION 195
5.7.2 STRUCTURES IN FLOCCULATION 196
5.7.3 BRIDGING FLOCCULATION 198
5.7.4 AGGLOMERATION FLOCCULATION 200
5.7.5 DEPLETION FLOCCULATION 200
5.7.6 FILTRATION 200
5.7.7 FOAM STABILITY IN THE PRESENCE OF OIL 201
5.7.7.1 ADSORPTION OF STABILIZING AND DESTABILIZING COMPONENTS 202
5.7.7.2 SPREADING AND ENTERING COEFFICIENTS 202
X I CONTENTS
5.7.7.3 EMULSIFICATION AND IMBIBITION MODELS 202
5.7.7.4 PSEUDOEMULSION FILM MODEL 203
REFERENCES 204
6 COLLOID RHEOLOGY
209
6.1 INTRODUCTION 209
6.2 PRINCIPLES 210
6.3 MEASUREMENT 213
6.3.1 TUBE METHODS 215
6.3.2 ROTATIONAL METHODS 219
6.3.3 OTHER METHODS 222
6.4 NON-NEWTONIAN FLOW PROPERTIES 224
6.4.1 PSEUDOPLASTICITY 225
6.4.2 DILATANCY 229
6.4.3 PLASTICITY/PSEUDOPLASTICITY WITH YIELD STRESS 229
6.4.4 THIXOTROPY 230
6.4.5 RHEOPEXY 232
6.4.6 VISCOELASTICITY 233
6.4.7 RHEOMALAXIS 233
6.4.8 SUMMARY 234
6.5 OTHER VISCOSITY NOMENCLATURE AND PARAMETERS 234
6.5.1 VISCOSITY NOMENCLATURE 234
6.5.2 OTHER VISCOSITY PARAMETERS 234
6.5.3 EXPERIMENTAL CONSIDERATIONS 237
6.6 DISPERSION RHEOLOGY 238
6.6.1 EINSTEIN'S EQUATION 238
6.6.2 VIRIAL EXPANSIONS 241
6.6.3 OTHER EMPIRICAL EQUATIONS 243
6.6.4 DISPERSED PHASE SIZE AND POLYDISPERSITY 243
6.6.5 ADDITIONAL CONSIDERATIONS FOR EMULSIONS AND FOAMS 244
6.6.6 OTHER EQUATIONS 247
6.7 SURFACE RHEOLOGY 248
6.8 FLOW IN PIPELINES AND CONSTRAINING MEDIA 250
6.8.1 APPLICATIONS IN PIPELINE FLOW 250
6.8.2 APPLICATIONS IN POROUS MEDIA 252
REFERENCES 254
7 PREPARATION, INHIBITION AND DESTRUCTION OF DISPERSIONS 259
7.1 INTRODUCTION 259
7.2 PREPARATION 260
7.2.1 PREPARATION OF EMULSIONS 260
7.2.2 PREPARATION OF FOAMS 269
7.2.3 PREPARATION OF SUSPENSIONS 271
7.2.4 PREPARATION OF AEROSOLS 275
7.2.5 OSTWALD RIPENING 277
CONTENTS I XI
7.2.6 SIZE FRACTIONATION 278
7.3 DESTRUCTION AND/OR INHIBITION 279
7.3.1 DEMULSIFICATION 279
7.3.2 ANTIFOAMING AND DEFOAMING 283
REFERENCES 285
8 INTRODUCTION TO PRACTICAL AND INDUSTRIAL APPLICATIONS
291
8.1 GENERAL USES 291
8.2 EMULSIONS 292
8.3 FOAMS 295
8.4 SUSPENSIONS 297
8.5 AEROSOLS 297
8.6 HAZARDS 300
REFERENCES 303
9 APPLICATIONS IN THE ENVIRONMENT
307
9.1 INTRODUCTION 307
9.2 ROCKS, SEDIMENTS AND SOILS 307
9.2.1 MAGMAS 307
9.2.2 AQUATIC SUSPENSIONS 307
9.2.3 SOILS 310
9.3 ENVIRONMENTAL SOIL REMEDIATION 311
9.4 WATER AND WASTEWATER TREATMENT 313
9.5 SPILLS AND OTHER HAZARDS 315
9.6 ENVIRONMENTAL FOAM BLANKETS 318
9.7 ENVIRONMENTAL AEROSOLS 319
9.7.1 CLOUDS 321
9.7.2 ATMOSPHERIC AEROSOLS AND CLIMATE 323
9.7.3 AEROSOL TREATMENT 324
REFERENCES 324
10 MINING AND MINERAL PROCESSING APPLICATIONS
329
10.1 INTRODUCTION 329
10.2 HYDRAULIC MINING AND HYDROTRANSPORT 329
10.3 MINERAL FLOTATION 331
10.3.1 CARRIER, EMULSION AND FLOE FLOTATION 343
10.4 TAILINGS AND TAILINGS PONDS 344
10.5 DUST-SUPPRESSING FOAM BLANKETS 348
REFERENCES 348
11 PETROLEUM INDUSTRY APPLICATIONS
351
11.1 INTRODUCTION 351
11.2 OILWELLS, GAS WELLS AND NEAR WELLS 353
11.2.1 DRILLING AND COMPLETION FLUIDS 353
11.2.2 WELL STIMULATION: FRACTURING AND ACIDIZING 355
XII
| CONTENTS
11.2.3 GAS WELL UNLOADING 357
11.3 RESERVOIRS 358
11.3.1 PRIMARY AND SECONDARY OIL RECOVERY 358
11.3.2 ENHANCED (TERTIARY) OIL RECOVERY 360
11.3.2.1 CHEMICAL, MICROEMULSION AND MACROEMULSION FLOODING 361
11.3.2.2 FOAM INJECTION PROCESSES 365
11.4 SURFACE OPERATIONS 368
11.4.1 SURFACE TREATMENT 368
11.4.2 OIL SANDS PROCESSING 370
11.4.3 PIPELINE TRANSPORTATION 372
11.4.4 UPGRADERS AND REFINERIES 374
REFERENCES 374
12 MANUFACTURING AND MATERIALS SCIENCE APPLICATIONS
383
12.1 INTRODUCTION 383
12.2 WOOD PROCESSING AND PAPERMAKING 383
12.3 INKS AND PRINTING 386
12.4 EMULSIONS FOR ROAD PAVING 387
12.5 METALWORKING 388
12.6 CLEANING PROCESSES 389
12.6.1 DETERGENCY 389
12.6.2 DE-INKING 392
12.7 SURFACE COATINGS INCLUDING PAINTS 394
12.8 POLYMER SYNTHESIS 397
12.9 CERAMICS MANUFACTURE 398
12.9.1 AEROGELS AND XEROGELS 398
12.10 FIREFIGHTING FOAMS 399
12.11 OTHER APPLICATIONS 401
REFERENCES 401
13 FOOD PRODUCT AND AGRICULTURAL APPLICATIONS
405
13.1 INTRODUCTION TO FOOD COLLOIDS 405
13.2 STABILIZING AGENTS 406
13.3 PREPARATION 408
13.4 STABILITY 409
13.5 PROTEIN-STABILIZED EMULSIONS 410
13.5.1 ICE CREAM 414
13.5.2 CREAM LIQUEURS 416
13.6 NON-PROTEIN-STABILIZED EMULSIONS 416
13.6.1 CARBONATED SOFT DRINKS 418
13.7 FOAM FOOD PRODUCTS 419
13.7.1 BAKED PRODUCTS 420
13.7.2 FOAM TOPPINGS 421
13.7.3 CHAMPAGNE AND BEER FOAMS 422
13.7.4 COFFEE BEVERAGE FOAM 423
CONTENTS
XIII
13.7.5 UNDESIRABLE FOOD FOAMS 424
13.8 OTHER FOOD COLLOIDS 425
13.8.1 FOOD SUSPENSIONS 425
13.8.2 FOOD AEROSOLS 425
13.8.3 MIXED FOOD COLLOIDS 426
13.9 INTRODUCTION TO AGRICULTURAL COLLOIDS 427
REFERENCES 429
14 BIOLOGICAL AND MEDICAL APPLICATIONS
433
14.1 INTRODUCTION 433
14.2 VESICLE CARRIERS 438
14.3 POLYMER COATINGS 439
14.4 EMULSION CARRIERS 441
14.5 COLLOIDS IN DIAGNOSTICS 444
14.6 SMART MATERIALS IN MEDICINE 445
REFERENCES 446
15 PERSONAL CARE PRODUCT APPLICATIONS
449
15.1 INTRODUCTION 449
15.2 DETERGENTS, SHAMPOOS AND CONDITIONERS 449
15.3 COSMETIC SKIN CARE PRODUCTS 452
15.4 OTHER PERSONAL CARE PRODUCTS 458
15.4.1 AEROSOL SPRAYS AND FOAMS 459
REFERENCES 461
16 EMERGING AREAS IN EMULSIONS, FOAMS, SUSPENSIONS AND AEROSOLS
463
16.1 INTRODUCTION 463
16.2 MICROSCOPY, SUPERMICROSCOPY AND NANOSCOPY 463
16.3 COMBATTING TERROR AGENTS 465
16.4 SMART COLLOIDS AND SMART MATERIALS 467
16.5 NANOMATERIALS AND NANODISPERSIONS 471
16.5.1 NANOSHEETS, NANOTUBES AND NANOWIRES 472
16.5.2 OTHER "NANO" APPLICATIONS 474
16.6 NANOSCIENCE PHENOMENOLOGY AND BIOMIMETICS 477
16.6.1 REFLECTIVE AND ANTIREFLECTIVE SURFACES 477
16.6.2 ADHESIVE SURFACES 477
16.6.3 WETTING AND SLIP ON SURFACES 478
16.6.4 NANOMECHANICS 478
REFERENCES 479
INDEX 483 |
| any_adam_object | 1 |
| author | Schramm, Laurier L. 1954- |
| author_GND | (DE-588)1055767576 |
| author_facet | Schramm, Laurier L. 1954- |
| author_role | aut |
| author_sort | Schramm, Laurier L. 1954- |
| author_variant | l l s ll lls |
| building | Verbundindex |
| bvnumber | BV041958689 |
| classification_rvk | VE 7000 VE 7080 VE 8000 |
| ctrlnum | (OCoLC)876382509 (DE-599)DNB1049503449 |
| dewey-full | 660.294514 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering |
| dewey-raw | 660.294514 |
| dewey-search | 660.294514 |
| dewey-sort | 3660.294514 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV041958689 |
| illustrated | Illustrated |
| indexdate | 2024-09-10T01:19:03Z |
| institution | BVB |
| isbn | 3527337067 9783527337064 9783527679478 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027401558 |
| oclc_num | 876382509 |
| open_access_boolean | |
| owner | DE-29 DE-11 DE-703 DE-355 DE-BY-UBR DE-1029 DE-83 DE-19 DE-BY-UBM DE-29T |
| owner_facet | DE-29 DE-11 DE-703 DE-355 DE-BY-UBR DE-1029 DE-83 DE-19 DE-BY-UBM DE-29T |
| physical | XIX, 492 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Schramm, Laurier L. 1954- Verfasser (DE-588)1055767576 aut Emulsions, foams, suspensions, and aerosols microscience and applications Laurier L. Schramm 2. ed. Weinheim Wiley-VCH 2014 XIX, 492 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Emulsion (DE-588)4014626-1 gnd rswk-swf Aerosol (DE-588)4000595-1 gnd rswk-swf Suspension (DE-588)4058671-6 gnd rswk-swf Kolloidchemie (DE-588)4134420-0 gnd rswk-swf Dispersion (DE-588)4012484-8 gnd rswk-swf Schaum (DE-588)4116372-2 gnd rswk-swf Kolloidchemie (DE-588)4134420-0 s Emulsion (DE-588)4014626-1 s Schaum (DE-588)4116372-2 s Dispersion (DE-588)4012484-8 s DE-604 Suspension (DE-588)4058671-6 s Aerosol (DE-588)4000595-1 s 1\p DE-604 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-67948-5 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-67950-8 Erscheint auch als Online-Ausgabe, PDF 978-3-527-67949-2 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4624839&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027401558&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Schramm, Laurier L. 1954- Emulsions, foams, suspensions, and aerosols microscience and applications Emulsion (DE-588)4014626-1 gnd Aerosol (DE-588)4000595-1 gnd Suspension (DE-588)4058671-6 gnd Kolloidchemie (DE-588)4134420-0 gnd Dispersion (DE-588)4012484-8 gnd Schaum (DE-588)4116372-2 gnd |
| subject_GND | (DE-588)4014626-1 (DE-588)4000595-1 (DE-588)4058671-6 (DE-588)4134420-0 (DE-588)4012484-8 (DE-588)4116372-2 |
| title | Emulsions, foams, suspensions, and aerosols microscience and applications |
| title_auth | Emulsions, foams, suspensions, and aerosols microscience and applications |
| title_exact_search | Emulsions, foams, suspensions, and aerosols microscience and applications |
| title_full | Emulsions, foams, suspensions, and aerosols microscience and applications Laurier L. Schramm |
| title_fullStr | Emulsions, foams, suspensions, and aerosols microscience and applications Laurier L. Schramm |
| title_full_unstemmed | Emulsions, foams, suspensions, and aerosols microscience and applications Laurier L. Schramm |
| title_short | Emulsions, foams, suspensions, and aerosols |
| title_sort | emulsions foams suspensions and aerosols microscience and applications |
| title_sub | microscience and applications |
| topic | Emulsion (DE-588)4014626-1 gnd Aerosol (DE-588)4000595-1 gnd Suspension (DE-588)4058671-6 gnd Kolloidchemie (DE-588)4134420-0 gnd Dispersion (DE-588)4012484-8 gnd Schaum (DE-588)4116372-2 gnd |
| topic_facet | Emulsion Aerosol Suspension Kolloidchemie Dispersion Schaum |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4624839&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027401558&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT schrammlaurierl emulsionsfoamssuspensionsandaerosolsmicroscienceandapplications |