Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system:
Saved in:
| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English German |
| Published: |
2014
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 225 S. Ill., graph. Darst. |
Staff View
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV041954284 | ||
| 003 | DE-604 | ||
| 005 | 20150408 | ||
| 007 | t | ||
| 008 | 140704s2014 ad|| m||| 00||| eng d | ||
| 035 | |a (OCoLC)887723784 | ||
| 035 | |a (DE-599)BVBBV041954284 | ||
| 040 | |a DE-604 |b ger |e rakwb | ||
| 041 | 0 | |a eng |a ger | |
| 049 | |a DE-29 |a DE-29T |a DE-355 |a DE-12 |a DE-188 | ||
| 082 | 0 | |a 546.63653 |2 22//ger | |
| 100 | 1 | |a Höfert, Oliver |e Verfasser |0 (DE-588)1053190395 |4 aut | |
| 245 | 1 | 0 | |a Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system |c vorgelegt von Oliver Höfert |
| 264 | 1 | |c 2014 | |
| 300 | |a 225 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Erlangen-Nürnberg, Univ., Diss., 2014 | ||
| 650 | 0 | 7 | |a Nickeloxide |0 (DE-588)4171818-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Röntgen-Photoelektronenspektroskopie |0 (DE-588)4076787-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Dünne Schicht |0 (DE-588)4136925-7 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Nickeloxide |0 (DE-588)4171818-5 |D s |
| 689 | 0 | 1 | |a Dünne Schicht |0 (DE-588)4136925-7 |D s |
| 689 | 0 | 2 | |a Röntgen-Photoelektronenspektroskopie |0 (DE-588)4076787-5 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027397191&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-027397191 | ||
Record in the Search Index
| _version_ | 1804152337382506496 |
|---|---|
| adam_text | INVESTIGATION OF THE ADSORPTION AND
REACTION OF SMALL MOLECULES ON THE
NIO/PD(100) SYSTEM
DER NATURWISSENSCHAFTLICHEN FAKULTAT
DER FRIEDRICH-ALEXANDER-UNIVERSITAT
ERLANGEN-NIIRNBERG
ZUR
ERLANGUNG DES DOKTORGRADES DR. RER. NAT
VORGELEGT
VON OLIVER HOFERT
AUS LINGEN (EMS)
HTTP://D-NB.INFO/105849340X
CONTENTS
1 INTRODUCTION 7
2 THEORETICAL BACKGROUND 11
2.1 PHOTOCLECTRON SPECTROSCOPY 11
2.1.1 CHEMICAL SHIFTS 12
2.1.2 FINAL STATE EFFECTS 13
2.1.3 SIGNAL DAMPING 14
3 EXPERIMENTAL SETUP 17
3.1 SETUP 17
3.2 TRANSFER SYSTEM 18
3.2.1 INSERTING A NEW SAMPLE 10
3.3 TIME RESOLUTION IN THE MICROSECOND REGIME 21
3.3.1 EXPERIMENTAL SETUP 21
3.3.2 OPEN MID CLOSING TIME OF THE MOLECULAR LICAIU 25
4 CO 27
4.1 SURFACE CORE LEVEL SHIFT AT DIFFERENT, EXCITATION ENERGIES .... 27
4.2 OXYGEN 28
4.3 CO 2 J
4.4 NIO/PD(L()0) 31
4.5 STRUCTURE OF NIO ON PD(100) 31
4.5.1 DATA ANALYSIS OF THE NI 2P SPECTRUM 31
4.5.2 GROWTH 33
4.5.3 THERMAL STABILITY 34
4.C CO OXIDATION ON NICKEL OXIDE 3G
4.G.1 REDUCTION OF THIN NIO FILMS 3G
4.G.1.1 COMPARISON OF FILM THICKNESS REACTION 3G
4
CONTENTS
4.6.1.2 WETTING LAYER: 1 MONOLAYER 38
4.0.1.3 TWO MONOLAYERS 40
4.0.1.4 RCOXIDATIOU AND 2ND REDUCTION CYELE 45
4.7 CO OIL PT(LLL) AT HIGHER TEMPERATURES 4 J
4.7.1 MEASUREMENTS AMI DATA ANALYSIS 50
4.7.2 SIMULATION 58
4.8 CONCLUSION 00
4.8.1 CO OXIDATION ON NICKEL OXIDE 00
4.8.2 CO ADSORPTION AND DCSORPTION AT HIGHER TEMPERATURES 00
5 H
2
0 61
5.1 H
2
0 ON PD(100) 01
5.1.1 ADSORPTION 01
5.1.2 REACTION 04
5.2 H
2
0 OIL O/PD(L()0) 05
5.2.1 ADSORPTION 05
5.2.2 REACTION 07
5.3 H
2
0 OIL NIO/PD(100) 00
5.3.1 1 ML 09
5.3.1.1 ADSORPTION 09
5.3.1.2 REACTION 71
5.3.2 2 ML 73
5.3.2.1 ADSORPTION 73
5.3.2.2 REACTION 75
5.3.3 0 ML 77
5.3.3.1 ADSORPTION 77
5.3.3.2 REACTION 79
5.4 CONCLUSION 81
6 C
2
H
2
83
0.1 C
2
H
2
OIL
PD(100) 83
0.1.1 ADSORPTION 84
0.1.2 SIMULATION 89
0.1.3 REACTION 92
0.2 C
2
H
2
ON O/PD(100) 97
0.2.1 ADSORPTION 97
0.2.2 REACTION 99
CONTENTS 5
G.3 C
2
H
2
ON NIO/PD(100) 101
6.3.1 NIO FILM: 1 ML 102
G. 3.1.1 ADSORPTION 102
6.3.1.2 REACTION 104
6.3.2 NIO FILM: 2 ML 107
6.3.2.1 ADSORPTION 107
6.3.2.2 REACTION 108
6.3.3 NIO FILM: 6 ML 100
6.3.3.1 ADSORPTION 100
6.3.3.2 REACTION ILL
6.4 CONCLUSION 113
7 C
2
H
4
115
7.1 C
2
H
4
ON PD(100) 115
7.1.1 ADSORPTION 115
7.1.2 REACTION 110
7.2 COAD.SORPT.ION WITH CO 121
7.3 COADSORPTION WITH 0 124
7.3.1 ADSORPTION 124
7.3.2 REACTION 126
7.4 CONCLUSION 127
8 C
6
H
6
129
8.1 C
6
H
6
ON PD(100) 120
8.1.1 ADSORPTION 130
8.1.2 REACTION 133
8.2 C
6
H
6
ON O/PD(100) 134
8.2.1 ADSORPTION 134
8.2.2 REACTION 135
8.3 CONCLUSION 137
9 TEB 139
0.1 TEB OIL PD(100) 130
0.1.1 ADSORPTION AND RELICTION FROM 180 K 130
0.1.1.1 ADSORPTION 130
0.1.1.2 REACTION 144
0.1.2 ADSORPTION AT 120 K 150
6 CONTENTS
9.1.3 ADSORPTION AND REACTION FROM 300 K 153
9.1.3.1 ADSORPTION 153
9. 1.3.2 REACTION 150
9.2 CONCLUSION 159
10 SUMMARY 161
11 ZUSAMMENFASSUNG 165
12 ATTACHMENT 169
12.1 C
6
H
6
ON NIO/PD(100) 109
12.1.1 NIO FILM: 1 ML 109
12.1.1.1 ADSORPTION 109
12.1.1.2 REACTION 172
12.1.2 NIO FILM: 2 ML 174
12.1.2.1 ADSORPTION 174
12.1.2.2 REACTION 170
12.1.3 NIO FILM: 0 ML 178
12.1.3.1 ADSORPTION 178
12.1.3.2 REACTION 180
12.1.4 CONCLUSION 182
12.2 COVERAGE SIMULATION 184
12.3 TRANSFER SYSTEM BLUEPRINTS 180
|
| any_adam_object | 1 |
| author | Höfert, Oliver |
| author_GND | (DE-588)1053190395 |
| author_facet | Höfert, Oliver |
| author_role | aut |
| author_sort | Höfert, Oliver |
| author_variant | o h oh |
| building | Verbundindex |
| bvnumber | BV041954284 |
| ctrlnum | (OCoLC)887723784 (DE-599)BVBBV041954284 |
| dewey-full | 546.63653 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546.63653 |
| dewey-search | 546.63653 |
| dewey-sort | 3546.63653 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01580nam a2200373 c 4500</leader><controlfield tag="001">BV041954284</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20150408 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">140704s2014 ad|| m||| 00||| eng d</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)887723784</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV041954284</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield><subfield code="a">ger</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-29</subfield><subfield code="a">DE-29T</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-12</subfield><subfield code="a">DE-188</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">546.63653</subfield><subfield code="2">22//ger</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Höfert, Oliver</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)1053190395</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system</subfield><subfield code="c">vorgelegt von Oliver Höfert</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2014</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">225 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="502" ind1=" " ind2=" "><subfield code="a">Erlangen-Nürnberg, Univ., Diss., 2014</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Nickeloxide</subfield><subfield code="0">(DE-588)4171818-5</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Röntgen-Photoelektronenspektroskopie</subfield><subfield code="0">(DE-588)4076787-5</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Dünne Schicht</subfield><subfield code="0">(DE-588)4136925-7</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="0">(DE-588)4113937-9</subfield><subfield code="a">Hochschulschrift</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Nickeloxide</subfield><subfield code="0">(DE-588)4171818-5</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Dünne Schicht</subfield><subfield code="0">(DE-588)4136925-7</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="2"><subfield code="a">Röntgen-Photoelektronenspektroskopie</subfield><subfield code="0">(DE-588)4076787-5</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">DNB Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027397191&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-027397191</subfield></datafield></record></collection> |
| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV041954284 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:09:07Z |
| institution | BVB |
| language | English German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027397191 |
| oclc_num | 887723784 |
| open_access_boolean | |
| owner | DE-29 DE-29T DE-355 DE-BY-UBR DE-12 DE-188 |
| owner_facet | DE-29 DE-29T DE-355 DE-BY-UBR DE-12 DE-188 |
| physical | 225 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| record_format | marc |
| spelling | Höfert, Oliver Verfasser (DE-588)1053190395 aut Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system vorgelegt von Oliver Höfert 2014 225 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Erlangen-Nürnberg, Univ., Diss., 2014 Nickeloxide (DE-588)4171818-5 gnd rswk-swf Röntgen-Photoelektronenspektroskopie (DE-588)4076787-5 gnd rswk-swf Dünne Schicht (DE-588)4136925-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Nickeloxide (DE-588)4171818-5 s Dünne Schicht (DE-588)4136925-7 s Röntgen-Photoelektronenspektroskopie (DE-588)4076787-5 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027397191&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Höfert, Oliver Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system Nickeloxide (DE-588)4171818-5 gnd Röntgen-Photoelektronenspektroskopie (DE-588)4076787-5 gnd Dünne Schicht (DE-588)4136925-7 gnd |
| subject_GND | (DE-588)4171818-5 (DE-588)4076787-5 (DE-588)4136925-7 (DE-588)4113937-9 |
| title | Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system |
| title_auth | Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system |
| title_exact_search | Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system |
| title_full | Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system vorgelegt von Oliver Höfert |
| title_fullStr | Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system vorgelegt von Oliver Höfert |
| title_full_unstemmed | Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system vorgelegt von Oliver Höfert |
| title_short | Investigation of the adsorption and reaction of small molecules on the NiO/Pd(100) system |
| title_sort | investigation of the adsorption and reaction of small molecules on the nio pd 100 system |
| topic | Nickeloxide (DE-588)4171818-5 gnd Röntgen-Photoelektronenspektroskopie (DE-588)4076787-5 gnd Dünne Schicht (DE-588)4136925-7 gnd |
| topic_facet | Nickeloxide Röntgen-Photoelektronenspektroskopie Dünne Schicht Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027397191&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT hofertoliver investigationoftheadsorptionandreactionofsmallmoleculesontheniopd100system |