Contaminant geochemistry: interactions and transport in the subsurface environment
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| Main Authors: | , , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Heidelberg [u.a.]
Springer
2014
|
| Edition: | 2. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVI, 577 S. graph. Darst. |
| ISBN: | 9783642547768 |
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Record in the Search Index
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| adam_text | CONTENTS
PART I GEOCHEMISTRY REVISITED: SELECTED ASPECTS
1 CHARACTERIZATION OF THE SUBSURFACE ENVIRONMENT 3
1.1 SUBSURFACE SOLID PHASE 4
1.1.1 SILICA MINERALS 4
1.1.2 CLAY MINERALS 6
1.1.3 MINERALS OTHER THAN SILICA AND CLAY 13
1.1.4 ORGANIC MATTER 13
1.1.5 ELECTRICALLY CHARGED SURFACES 17
1.2 SUBSURFACE LIQUID PHASE 18
1.2.1 NEAR SOLID PHASE WATER 19
1.2.2 SUBSURFACE AQUEOUS SOLUTIONS 21
1.3 SUBSURFACE GASEOUS PHASE 22
1.4 AQUIFERS 23
1.4.1 AQUIFER STRUCTURE 23
1.4.2 GROUNDWATER COMPOSITION 25
REFERENCES 26
2 SELECTED GEOCHEMICAL PROCESSES 29
2.1 THERMODYNAMICS AND EQUILIBRIUM 29
2.1.1 ENTHALPY, ENTROPY, AND THE LAWS
OF THERMODYNAMICS 29
2.1.2 EQUILIBRIUM 31
2.1.3 SOLUBILITY, CHEMICAL POTENTIAL, AND ION ACTIVITIES 32
2.1.4 KINETIC CONSIDERATIONS AND REACTION RATE LAWS 34
2.2 WEATHERING 39
2.2.1 DISSOLUTION AND PRECIPITATION 39
2.2.2 REDOX PROCESSES 42
2.3 ADSORPTION 45
2.3.1 ADSORPTION OF CHARGED IONIC COMPOUNDS 46
2.3.2 ADSORPTION OF NONIONIC COMPOUNDS 48
2.3.3 KINETIC CONSIDERATIONS 49
REFERENCES 50
XI
HTTP://D-NB.INFO/1047725371
XII CONTENTS
PART II PROPERTIES OF POTENTIAL CONTAMINANTS: ENVIRONMENTAL
AND HEALTH HAZARDS
3 INORGANIC AND ORGANOMETALLIC COMPOUNDS 53
3.1 NITROGEN 53
3.2 PHOSPHORUS 56
3.3 SALTS 57
3.3.1 AGRICULTURAL IMPACTS 58
3.3.2 IMPACTS ON WATER USAGE 59
3.3.3 IMPACTS ON INFRASTRUCTURE 60
3.3.4 IMPACTS ON BIODIVERSITY AND THE ENVIRONMENT 60
3.4 RADIONUCLIDES 61
3.5 HEAVY METALS AND METALLOIDS 63
3.5.1 ARSENIC 63
3.5.2 CADMIUM 65
3.5.3 CHROMIUM 66
3.5.4 LEAD 67
3.5.5 NICKEL 68
3.6 NANOMATERIALS 70
REFERENCES 72
4 ORGANIC COMPOUNDS 79
4.1 PESTICIDES 79
4.1.1 ORGANOCHLORINE INSECTICIDES 81
4.1.2 ORGANOPHOSPHATES 83
4.1.3 N-METHYL CARBAMATE 83
4.1.4 TRIAZINES 84
4.1.5 PARAQUAT AND DIQUAT 84
4.2 SYNTHETIC HALOGENATED ORGANIC SUBSTANCES 86
4.2.1 CHLORINATED HYDROCARBONS 86
4.2.2 BROMINATED FLAME RETARDANTS 89
4.3 PETROLEUM HYDROCARBONS AND FUEL ADDITIVES 91
4.4 PHARMACEUTICALS AND PERSONAL CARE PRODUCTS 94
4.4.1 ANALGESICS AND ANTI-INFLAMMATORY DRUGS 96
4.4.2 HORMONES 96
4.4.3 ANTIBACTERIAL DRUGS 97
4.4.4 ANTIEPILEPTIC DRUGS 98
4.4.5 BETA-BLOCKERS 98
REFERENCES 98
CONTENTS XIII
PART III CONTAMINANT PARTITIONING IN THE SUBSURFACE
5 SORPTION, RETENTION, AND RELEASE OF CONTAMINANTS 107
5.1 SURFACE PROPERTIES OF ADSORBENTS 107
5.2 QUANTIFYING ADSORPTION 109
5.2.1 ADSORPTION-DESORPTION COEFFICIENTS 109
5.2.2 ADSORPTION ISOTHERMS 109
5.3 KINETICS OF ADSORPTION 116
5.4 ADSORPTION OF IONIC CONTAMINANTS 118
5.5 ADSORPTION OF NONIONIC CONTAMINANTS 123
5.6 OTHER FACTORS AFFECTING ADSORPTION 126
5.7 NONADSORPTIVE RETENTION OF CONTAMINANTS 129
5.7.1 CONTAMINANT PRECIPITATION 129
5.7.2 LIQUID TRAPPING 131
5.7.3 PARTICLE DEPOSITION AND TRAPPING 132
5.8 REVERSIBLE AND IRREVERSIBLE RETENTION 135
5.8.1 GENUINE HYSTERESIS 135
5.8.2 APPARENT HYSTERESIS 137
5.8.3 BOUND RESIDUES 138
REFERENCES 141
6 CONTAMINANT PARTITIONING IN THE AQUEOUS PHASE 147
6.1 SOLUBILITY EQUILIBRIUM 148
6.2 AQUEOUS SOLUBILITY OF ORGANIC CONTAMINANTS 150
6.3 LIGAND EFFECTS 151
6.4 COSOLVENTS AND SURFACTANT EFFECTS 153
6.5 SALTING-OUT EFFECT 156
6.6 APPARENT SOLUBILITY 159
REFERENCES 161
7 PARTITIONING OF VOLATILE COMPOUNDS 163
7.1 GAS-LIQUID RELATIONSHIPS 164
7.2 VOLATILIZATION FROM SUBSURFACE AQUEOUS SOLUTIONS 165
7.3 VAPOR PRESSURE-VOLATILIZATION RELATIONSHIP 166
7.4 VOLATILIZATION OF MULTICOMPONENT CONTAMINANTS 169
REFERENCES 170
8 SELECTED RESEARCH FINDINGS: CONTAMINANT PARTITIONING 171
8.1 PARTITIONING AMONG PHASES 171
8.2 CONTAMINANT VOLATILIZATION 173
8.2.1 INORGANIC CONTAMINANTS 175
8.2.2 ORGANIC CONTAMINANTS 177
8.2.3 MIXTURES OF ORGANIC CONTAMINANTS 180
XIV CONTENTS
8.3 SOLUBILITY AND DISSOLUTION 184
8.3.1 ACIDITY AND ALKALINITY EFFECTS 185
8.3.2 REDOX PROCESSES 187
8.3.3 DISSOLUTION FROM MIXTURES OF ORGANIC CONTAMINANTS.... 189
8.3.4 APPARENT SOLUBILITY 189
8.4 CONTAMINANT RETENTION IN THE SUBSURFACE 198
8.4.1 CONTAMINANT ADSORPTION 198
8.4.2 NONADSORPTIVE RETENTION 220
8.5 CONTAMINANT RELEASE 223
8.6 BOUND RESIDUES 230
8.7 CONTAMINANTS IN URBAN GEOSYSTEMS 233
REFERENCES 238
PART IV CONTAMINANT TRANSPORT FROM LAND SURFACE
TO GROUNDWATER
9 WATER FLOW IN THE SUBSURFACE ENVIRONMENT 247
9.1 WATER FLOW IN SOILS AND THE VADOSE ZONE 247
9.2 FLOW THROUGH THE CAPILLARY FRINGE 250
REFERENCES 252
10 TRANSPORT OF PASSIVE CONTAMINANTS 255
10.1 ADVECTION, DISPERSION, AND MOLECULAR DIFFUSION 256
10.2 PREFERENTIAL TRANSPORT 259
10.3 NON-FICKIAN TRANSPORT 261
REFERENCES 265
11 TRANSPORT OF REACTIVE CONTAMINANTS 267
11.1 CONTAMINANT SORPTION 267
11.2 COLLOIDS AND SORPTION ON COLLOIDS 269
11.3 DISSOLVING AND PRECIPITATING CONTAMINANTS 270
11.4 TRANSPORT OF IMMISCIBLE LIQUIDS 273
11.5 TRANSPORT OF CONTAMINANTS BY RUNOFF 279
11.5.1 OVERLAND RUNOFF 279
11.5.2 URBAN RUNOFF 281
REFERENCES 281
12 SELECTED RESEARCH FINDINGS: CONTAMINANT TRANSPORT 285
12.1 HEAVY METALS AND METALLOIDS 285
12.1.1 HEAVY METALS 286
12.1.2 METALLOIDS 296
12.2 ENGINEERED NANOPARTICLES (ENPS) 302
12.2.1 FATE OF ENPS IN AQUEOUS SOLUTIONS 302
CONTENTS XV
12.2.2 TRANSPORT OF ENPS IN SAND AND GLASS BEAD COLUMNS . . . 304
12.2.3 MODELING ENP TRANSPORT IN POROUS MEDIA 312
12.2.4 FATE OF ENPS IN SOIL COLUMN EXPERIMENTS 312
12.2.5 ENP TRANSPORT IN THE FIELD 316
12.3 PESTICIDES 320
12.4 COLLOID-MEDIATED TRANSPORT OF ORGANIC CONTAMINANTS 333
12.4.1 SURFACE RUNOFF 334
12.4.2 TRANSPORT IN THE SUBSURFACE 335
12.5 TRANSPORT OF NONAQUEOUS-PHASE LIQUIDS 337
12.5.1 INFILTRATION INTO THE SUBSURFACE 338
12.5.2 TRANSPORT OF SOLUBLE NAPL FRACTIONS IN AQUIFERS 341
REFERENCES 343
PART V TRANSFORMATIONS AND REACTIONS OF CONTAMINANTS
IN THE SUBSURFACE
13 ABIOTIC CONTAMINANT TRANSFORMATIONS IN SUBSURFACE WATER 349
13.1 ABIOTIC CONTAMINANT TRANSFORMATIONS IN NATURAL
SUBSURFACE WATER 349
13.1.1 FACTORS AFFECTING CONTAMINANT TRANSFORMATIONS 349
13.1.2 REACTIONS IN NATURAL WATERS 351
13.2 SELECTED CONTAMINANT TRANSFORMATIONS IN SEDIMENTS
AND GROUNDWATER 362
13.2.1 PH AND HYDROLYSIS REACTIONS 362
13.2.2 REDOX STATE AND REACTIONS 363
REFERENCES 369
14 ABIOTIC TRANSFORMATION AT THE SOLID-LIQUID INTERFACE 373
14.1 CATALYSIS 373
14.2 SURFACE-INDUCED TRANSFORMATION OF ORGANIC CONTAMINANTS 374
14.3 SURFACE-INDUCED INTERACTIONS OF INORGANIC CONTAMINANTS 379
REFERENCES 379
15 BIOLOGICALLY MEDIATED TRANSFORMATIONS 381
15.1 SUBSURFACE MICROBIAL POPULATIONS 381
15.2 PROCESSES GOVERNING CONTAMINANT ATTENUATION 381
15.3 BIOTRANSFORMATION OF ORGANIC CONTAMINANTS 383
15.4 BIOTRANSFORMATION OF INORGANIC CONTAMINANTS 389
REFERENCES 394
16 SELECTED RESEARCH FINDINGS: TRANSFORMATIONS AND REACTIONS 397
16.1 ABIOTIC ALTERATION OF CONTAMINANTS 397
16.1.1 TRANSFORMATION IN SUBSURFACE WATER 397
XVI CONTENTS
16.1.2 SURFACE-INDUCED TRANSFORMATION ON CLAYS 412
16.1.3 PHOTOCHEMICAL REACTIONS 416
16.1.4 LIGAND EFFECTS 422
16.1.5 MULTIPLE-COMPONENT CONTAMINANT TRANSFORMATION 425
16.2 BIOMEDIATED TRANSFORMATION OF CONTAMINANTS 437
16.2.1 PETROLEUM PRODUCTS 437
16.2.2 PESTICIDES 442
REFERENCES 452
PART VI CONTAMINANT INDUCED IRREVERSIBLE CHANGES
IN THE SOIL-SUBSURFACE REGIME
17 CONTAMINANT-INDUCED IRREVERSIBLE CHANGES IN GROUNDWATER
CHEMISTRY 457
17.1 GROUNDWATER SALINIZATION 458
17.1.1 SALINIZATION UNDER DOWNWARD FLOW CONDITIONS 458
17.1.2 SALINIZATION UNDER LATERAL FLOW CONDITIONS 461
17.2 GROUNDWATER ACIDIFICATION 465
17.3 GROUNDWATER CONTAMINATION BY INORGANIC TRACE ELEMENTS 469
17.3.1 RADIONUCLIDES 470
17.3.2 HEAVY METALS 471
17.3.3 METALLOIDS 476
17.4 GROUNDWATER CONTAMINATION BY TRACE ORGANIC COMPOUNDS .... 480
REFERENCES 497
18 CONTAMINANT IMPACTS ON THE SOIL-SUBSURFACE SOLID PHASE 501
18.1 IMPACT OF CONTAMINANTS ORIGINATING FROM AGRICULTURE 501
18.1.1 FERTILIZERS 502
18.1.2 MICRONUTRIENTS 505
18.1.3 SOIL-SUBSURFACE AMENDMENTS 507
18.1.4 PESTICIDES 517
18.2 IMPACT OF SODIC WATER 528
18.2.1 SWELLING 528
18.2.2 DISPERSION AND FLOCCULATION 531
18.2.3 WATER TRANSMISSION PROPERTIES 533
18.3 IMPACT OF MUNICIPAL AND INDUSTRIAL CONTAMINANTS 537
18.3.1 ACID RAIN INPUT 538
18.3.2 IMPACT OF EFFLUENTS 542
18.3.3 IMPACT OF SLUDGE AND COMPOST 546
18.3.4 PETROLEUM PRODUCTS 557
REFERENCES 562
INDEX
571
|
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| id | DE-604.BV041952631 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:09:04Z |
| institution | BVB |
| isbn | 9783642547768 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027395567 |
| oclc_num | 871183817 |
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| owner | DE-29 DE-12 DE-83 |
| owner_facet | DE-29 DE-12 DE-83 |
| physical | XVI, 577 S. graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Springer |
| record_format | marc |
| spelling | Berkowitz, Brian Verfasser (DE-588)1067881743 aut Contaminant geochemistry interactions and transport in the subsurface environment Brian Berkowitz ; Ishai Dror ; Bruno Yaron 2. ed. Heidelberg [u.a.] Springer 2014 XVI, 577 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Umweltgeochemie (DE-588)4404136-6 gnd rswk-swf Umweltgift (DE-588)4186801-8 gnd rswk-swf Umweltgift (DE-588)4186801-8 s Umweltgeochemie (DE-588)4404136-6 s DE-604 Dror, Ishai Verfasser aut Yaron, Bruno 1929- Verfasser (DE-588)107957523 aut Erscheint auch als Online-Ausgabe 978-3-642-54777-5 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027395567&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Berkowitz, Brian Dror, Ishai Yaron, Bruno 1929- Contaminant geochemistry interactions and transport in the subsurface environment Umweltgeochemie (DE-588)4404136-6 gnd Umweltgift (DE-588)4186801-8 gnd |
| subject_GND | (DE-588)4404136-6 (DE-588)4186801-8 |
| title | Contaminant geochemistry interactions and transport in the subsurface environment |
| title_auth | Contaminant geochemistry interactions and transport in the subsurface environment |
| title_exact_search | Contaminant geochemistry interactions and transport in the subsurface environment |
| title_full | Contaminant geochemistry interactions and transport in the subsurface environment Brian Berkowitz ; Ishai Dror ; Bruno Yaron |
| title_fullStr | Contaminant geochemistry interactions and transport in the subsurface environment Brian Berkowitz ; Ishai Dror ; Bruno Yaron |
| title_full_unstemmed | Contaminant geochemistry interactions and transport in the subsurface environment Brian Berkowitz ; Ishai Dror ; Bruno Yaron |
| title_short | Contaminant geochemistry |
| title_sort | contaminant geochemistry interactions and transport in the subsurface environment |
| title_sub | interactions and transport in the subsurface environment |
| topic | Umweltgeochemie (DE-588)4404136-6 gnd Umweltgift (DE-588)4186801-8 gnd |
| topic_facet | Umweltgeochemie Umweltgift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027395567&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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