Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2014
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| Schlagworte: | |
| Online-Zugang: | kostenfrei Inhaltsverzeichnis |
| Beschreibung: | VI, 149 S. Ill., graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy |c von Philipp Benjamin Rudolf |
| 246 | 1 | 3 | |a Untersuchungen von photoinduzierten chemischen Reaktionspfaden in flüssiger Phase mittels ultraschneller Schwingungsspektroskopie |
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Datensatz im Suchindex
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| adam_text | UNCOVERING PHOTOINDUCED CHEMICAL REACTION PATHWAYS
IN THE LIQUID PHASE
WITH ULTRAFAST VIBRATIONAL SPECTROSCOPY
TIME
DISSERTATION ZUR ERLANGUNG DES
NATURWISSENSCHAFTLICHEN DOKTORGRADES
DER JULIUS-MAXIMILIANS-UNIVERSITAT
WIIRZBURG
VORGELEGT. VON
PHILIPP BENJAMIN RUDOLF
AUS REGENSBURG
WIIRZBURG 2014
HTTP://D-NB.INFO/1052910688
CONTENTS
LIST OF PUBLICATIONS III
1 INTRODUCTION 1
2 BASIC THEORETICAL CONCEPTS 5
2.1 MATHEMATICAL FORMALISM OF FEMTOSECOND LASER PULSES 5
2.1.1 TEMPORAL AND SPECTRAL STRUCTURE OF E(. R) 6
2.1.2 SPATIAL STRUCTURE OF E(, R) 9
2.2 NONLINEAR OPTICAL PROCESSES 11
2.2.1 NONLINEAR POLARIZATION AND PHASE MATCHING 11
2.2.2 FREQUENCY CONVERSION PROCESSES 13
2.2.3 SHAPING AND CHARACTERIZING LASER PULSES IN THE UV 16
2.3 ELECTRONIC AND VIBRATIONAL STRUCTURE OF MOLECULES 22
2.4 CALCULATING MOLECULAR GROUND STATES WITH DFT 27
2.4.1 THE HARTREE-FOCK APPROXIMATION 28
2.4.2 THE FRAMEWORK OF DENSITY FUNCTIONAL THEORY 30
2.5 PUMP-PROBE SPECTROSCOPY IN THE MIR 37
2.-5.1 GENERAL DETECTION SCHEME 37
2.5.2 COHERENT EFFECTS 39
3 EXPERIMENTAL CONFIGURATIONS 45
3.1 SETUP TO INVESTIGATE THE PHOTOCHEMISTRY OF DMA 46
. 3.1.1 HOMEBUILT FEMTOSECOND LASER SYSTEM 47
3.1.2 UV AND MIR PULSE GENERATION 48
3.1.3 PUMP-PROBE SETUP 54
3.2 SETUP TO INVESTIGATE THE PHOTOCHEMISTRY OF A CORM 58
3.2.1 COMMERCIAL CPA LASER SYSTEM 58
3.2.2 NOPA: UV PULSE GENERATION 59
3.2.3 MODIFIED PUMP-PROBE SETUP 61
3.3 FURTHER INSTRUMENTATION FOR PROSPECTIVE EXPERIMENTS 62
3.3.1 UV DAZZLER AND DFG-XFROG SETUP 63
3.3.2 CPU: CONVERTING MIR PULSES TO THE VISIBLE SPECTRAL RANGE .... 64
3.3.3 DETECTING TWO-PHOTON ABSORPTION 66
4 ULTRAFAST MULTISEQUENTIAL PHOTOCHEMISTRY OF 5-DIAZO MELDRUM S ACID 69
4.1 INTRODUCTION 69
4.2 MATERIALS AND METHODS 71
V
VI CONTENTS
4.3 RESULTS 72
4.3.1 DFT CALCULATIONS AND FTIR SPECTROSCOPY 72
4.3.2 FEMTOSECOND MIDINFRARED SPECTROSCOPY 75
4.3.3 INFLUENCE OF THE MOLECULAR ENVIRONMENT 80
4.4 DISCUSSION 82
4.5 CONCLUSIONS 86
5 ULTRAFAST PHOTOCHEMISTRY OF A MANGANESE-TRICARBONYL CORM 89
5.1 INTRODUCTION 89
5.2 MATERIALS AND METHODS 90
5.3 RESULTS 91
5.3.1 STEADY-STATE SPECTRA AND DFT CALCULATIONS 91
5.3.2 TRANSIENT MIR SPECTROSCOPY WITH TWO PUMP WAVELENGTHS 95
5.3.3 TRANSIENT MIR SPECTROSCOPY WITH TWO CONSECUTIVE PUMP PULSES . . 98
5.4 CONCLUSIONS 99
6 TECHNIQUES FOR PROSPECTIVE TRANSIENT ABSORPTION EXPERIMENTS 101
6.1 PULSE SHAPING AND CHARACTERIZATION IN THE UV 101
6.2 OBTAINING TWO-PHOTON EXCITATION SPECTRA 104
6.3 RECORDING TRANSIENT MIR ABSORPTION DATA WITH THE CPU TECHNIQUE ....
107
7 SUMMARY AND OUTLOOK 117
8 ZUSAMMENFASSUNG UND AUSBLICK 121
BIBLIOGRAPHY 125
ACKNOWLEDGEMENTS 147
VI
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| spelling | Rudolf, Philipp Benjamin Verfasser (DE-588)1052832911 aut Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy von Philipp Benjamin Rudolf Untersuchungen von photoinduzierten chemischen Reaktionspfaden in flüssiger Phase mittels ultraschneller Schwingungsspektroskopie 2014 VI, 149 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Würzburg, Univ., Diss., 2014 Nichtlineare Spektroskopie (DE-588)4427818-4 gnd rswk-swf Ultrakurzzeitspektroskopie (DE-588)4209051-9 gnd rswk-swf Zeitauflösung (DE-588)4245662-9 gnd rswk-swf Schwingungsspektroskopie (DE-588)4128960-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Ultrakurzzeitspektroskopie (DE-588)4209051-9 s Nichtlineare Spektroskopie (DE-588)4427818-4 s Schwingungsspektroskopie (DE-588)4128960-2 s Zeitauflösung (DE-588)4245662-9 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:20-opus-96200 https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-96200 Resolving-System kostenfrei Volltext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027389559&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Rudolf, Philipp Benjamin Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy Nichtlineare Spektroskopie (DE-588)4427818-4 gnd Ultrakurzzeitspektroskopie (DE-588)4209051-9 gnd Zeitauflösung (DE-588)4245662-9 gnd Schwingungsspektroskopie (DE-588)4128960-2 gnd |
| subject_GND | (DE-588)4427818-4 (DE-588)4209051-9 (DE-588)4245662-9 (DE-588)4128960-2 (DE-588)4113937-9 |
| title | Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy |
| title_alt | Untersuchungen von photoinduzierten chemischen Reaktionspfaden in flüssiger Phase mittels ultraschneller Schwingungsspektroskopie |
| title_auth | Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy |
| title_exact_search | Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy |
| title_full | Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy von Philipp Benjamin Rudolf |
| title_fullStr | Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy von Philipp Benjamin Rudolf |
| title_full_unstemmed | Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy von Philipp Benjamin Rudolf |
| title_short | Uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy |
| title_sort | uncovering photoinduced chemical reaction pathways in the liquid phase with ultrafast vibrational spectroscopy |
| topic | Nichtlineare Spektroskopie (DE-588)4427818-4 gnd Ultrakurzzeitspektroskopie (DE-588)4209051-9 gnd Zeitauflösung (DE-588)4245662-9 gnd Schwingungsspektroskopie (DE-588)4128960-2 gnd |
| topic_facet | Nichtlineare Spektroskopie Ultrakurzzeitspektroskopie Zeitauflösung Schwingungsspektroskopie Hochschulschrift |
| url | https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-96200 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027389559&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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