Applications and mechanism of organorhenium(VII) oxides in the epoxidation of olefins:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2014
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | VI, 165 S. graph. Darst. 210 mm x 148 mm, 276 g |
| ISBN: | 9783843915700 3843915709 |
Internformat
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Datensatz im Suchindex
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1 PREFACE V
1.1 REFERENCES VI
2 INTRODUCTION 1
2.1 INTRODUCTION 2
2.2 MOLYBDENUM-CATALYZED EPOXIDATIONS 4
2.3 VANADIUM CATALYSTS 10
2.4 RHENIUM CATALYSTS - METHYLTRIOXOI+IENIUM(VII) AND
LITTLE MORE 12
2.5 ASYMMETRIC EPOXIDATION WITH MN AND TI CATALYSTS 14
2.6 NEW EMERGING CATALYSTS 18
2.7 OUTLOOK 20
2.8 REFERENCES 21
3 OBJECTIVES 27
3.1 REFERENCES 30
4 SYNTHESIS AND PURIFICATION OF RHENIUM(VII)OXIDE 31
4.1 INTRODUCTION 32
4.2 EXPERIMENTAL SECTION 33
4.3 RESULTS AND DISCUSSION 34
4.4 CONCLUSION 35
4.5 REFERENCES 36
5 SYNTHESIS AND CHARACTERIZATION OF DIOXODIPHENYLRHENIUM(VII) PROPIONATE
37
5.1 INTRODUCTION 38
5.2 RESULTS AND DISCUSSION 39
5.2.1 SYNTHESIS AND CHARACTERIZATION OF
DIOXODIPHENYLRHENIUM(VII)-PROPIONATE39
5.2.2 X-RAY SINGLE CRYSTAL STRUCTURE 40
5.2.3 SPECTROSCOPIC EXAMINATION 42
5.3 CONCLUSIONS 44
5.4 EXPERIMENTAL SECTION 44
5.4.1 GENERAL DETAILS 44
5.4.2 SYNTHESIS OF PHENYLZINCACETATE 44
5.4.3 SYNTHESIS OF (P-PROPIONATO)DIOXODIPHENYLRHENIUM 45
5.4.4 X-RAY SINGLE CRYSTAL STRUCTURE 45
5.4.5 COMPUTATIONAL DETAILS 46
5.5 REFERENCES 47
6 XYLYLTRIOXORHENIUM - THE FIRST ARYLRENIUM(VII) OXIDE APPLICABLE AS
OLEFIN
EPOXIDATION CATALYST 49
6.1 INTRODUCTION 50
6.2 EXPERIMENTAL SECTION 51
I
HTTP://D-NB.INFO/1051877458
6.2.1 GENERAL 51
6.2.2 IMPROVED PREPARATION 51
6.2.3 CATALYTIC REACTIONS 52
6.2.4 "O NMR-EXPERIMENTS 52
6.2.5 RAMAN EXPERIMENTS 52
6.2.6 COMPUTATIONAL DETAILS 52
6.3 RESULTS AND DISCUSSION 53
6.3.1 SYNTHESIS AND CATALYTIC PROPERTIES OF XTO 53
6.3.2 NMR SPECTROSCOPIC STUDIES 56
6.3.3 RAMAN SPECTROSCOPIC STUDIES 58
6.3.4 DECOMPOSITION OF THE CATALYST 60
6.4 CONCLUSIONS 61
6.5 REFERENCES 62
7 EVALUATION OF THEORETICAL FUNCTIONALS FOR STRUCTURAL AND VIBRATIONAL
ENERGY
PREDICTIONS ON ORGANO-RHENIUM(VII) OXIDES 65
7.1 INTRODUCTION 66
7.2 COMPUTATIONAL DETAILS 68
7.3 EXPERIMENTAL SECTION 68
7.4 SINGLE CRYSTAL
X-RAY STRUCTURE 68
7.5 RESULTS AND
DISCUSSION 69
7.5.1 SINGLE-CRYSTAL X-RAY STRUCTURE OF XYLYLTRIOXORHENIUM 69
7.5.2 COMPARISON OF DFT
FUNCTIONALS 70
7.6 CONCLUSION 74
7.7 ACKNOWLEDGEMENT 75
7.8 REFERENCES 76
8 ETHYLTRIOXORHENIUM REVISITED - CATALYTIC ACTIVITY AND DECOMPOSITION
PATHWAYS 79
8.1 INTRODUCTION 80
8.2 COMPUTATIONAL DETAILS 81
8.3 EXPERIMENTAL SECTION 81
8.4 RESULTS AND
DISCUSSION 82
8.4.1 SYNTHESIS 82
8.4.2 EPOXIDATION CATALYSIS 83
8.4.3 INFLUENCE OF ADDITIVES ON CATALYSIS 85
8.4.4
17
0 NMR STUDY
ON ACTIVATION AND DECOMPOSITION OF ETO WITH
TBHP 85
8.4.5 DECOMPOSITION OF ETHYLTRIOXORHENIUM 87
8.5 CONCLUSION 91
II
8.6 REFERENCES 92
9 ACTIVATION AND DECOMPOSITION OF ALKYL- AND ARYLTRIOXORHENIUM COMPOUNDS
IN THE PRESENCE OF TBHP 95
9.1 INTRODUCTION 96
9.2 COMPUTATIONAL DETAILS 98
9.3 RESULTS AND DISCUSSION 98
9.4 CONCLUSION 102
9.5 REFERENCES 104
10 SUMMARY 107
10.1 CATALYTIC ACTIVITY 108
10.2 MECHANISTIC INVESTIGATIONS 109
10.3 CONCLUSION & OUTLOOK 110
11 ABBREVIATIONS 111
12 APPENDIX A 113
13 APPENDIX B 117
14 APPENDIX C 121
14.1 FULL LIST OF COMPARED DATA FOR THE STATISTICS 122
14.2 GEOMETRIES AND ENERGIES OF ALL CALCULATED STRUCTURES 125
14.3 DETAILED CRYSTALLOGRAPHIC INFORMATION FOR COMPOUND 3
(CCDC-963811). 155
15 APPENDIX D 159
16 CURRICULUM VITAE 163
III |
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | 1. Aufl. |
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| spelling | Huber, Stefan Verfasser aut Applications and mechanism of organorhenium(VII) oxides in the epoxidation of olefins Stefan Huber 1. Aufl. 201406 München Verl. Dr. Hut 2014 VI, 165 S. graph. Darst. 210 mm x 148 mm, 276 g txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2014 Rheniumorganische Verbindungen (DE-588)4178006-1 gnd rswk-swf Epoxidation (DE-588)4152560-7 gnd rswk-swf Katalysator (DE-588)4029919-3 gnd rswk-swf Alkene (DE-588)4001207-4 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Rheniumorganische Verbindungen (DE-588)4178006-1 s Katalysator (DE-588)4029919-3 s Alkene (DE-588)4001207-4 s Epoxidation (DE-588)4152560-7 s DE-604 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4684213&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027389144&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Huber, Stefan Applications and mechanism of organorhenium(VII) oxides in the epoxidation of olefins Rheniumorganische Verbindungen (DE-588)4178006-1 gnd Epoxidation (DE-588)4152560-7 gnd Katalysator (DE-588)4029919-3 gnd Alkene (DE-588)4001207-4 gnd |
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| title | Applications and mechanism of organorhenium(VII) oxides in the epoxidation of olefins |
| title_auth | Applications and mechanism of organorhenium(VII) oxides in the epoxidation of olefins |
| title_exact_search | Applications and mechanism of organorhenium(VII) oxides in the epoxidation of olefins |
| title_full | Applications and mechanism of organorhenium(VII) oxides in the epoxidation of olefins Stefan Huber |
| title_fullStr | Applications and mechanism of organorhenium(VII) oxides in the epoxidation of olefins Stefan Huber |
| title_full_unstemmed | Applications and mechanism of organorhenium(VII) oxides in the epoxidation of olefins Stefan Huber |
| title_short | Applications and mechanism of organorhenium(VII) oxides in the epoxidation of olefins |
| title_sort | applications and mechanism of organorhenium vii oxides in the epoxidation of olefins |
| topic | Rheniumorganische Verbindungen (DE-588)4178006-1 gnd Epoxidation (DE-588)4152560-7 gnd Katalysator (DE-588)4029919-3 gnd Alkene (DE-588)4001207-4 gnd |
| topic_facet | Rheniumorganische Verbindungen Epoxidation Katalysator Alkene Hochschulschrift |
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