Proton exchange membrane fuel cells:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Boca Raton, FL [u.a.]
CRC Press
2014
|
| Series: | Electrochemical energy storage and conversion
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Includes bibliographical references (p. 329-331) and index |
| Physical Description: | XXIX, 343 S. Ill., graph. Darst. |
| ISBN: | 9781466513709 |
Staff View
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| 010 | |a 013027624 | ||
| 020 | |a 9781466513709 |9 978-1-4665-1370-9 | ||
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| 100 | 1 | |a Qi, Zhigang |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Proton exchange membrane fuel cells |c Zhigang Qi |
| 264 | 1 | |a Boca Raton, FL [u.a.] |b CRC Press |c 2014 | |
| 300 | |a XXIX, 343 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Electrochemical energy storage and conversion | |
| 500 | |a Includes bibliographical references (p. 329-331) and index | ||
| 650 | 0 | 7 | |a Polymer-Elektrolytmembran-Brennstoffzelle |0 (DE-588)4450903-0 |2 gnd |9 rswk-swf |
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-027297569 | ||
Record in the Search Index
| _version_ | 1804152200763539456 |
|---|---|
| adam_text | Contents
Ώ
Series
Preface
..........................................................................................................xi
Jiujun Zhang, PhD
Preface
...................................................................................................................xiii
Acknowledgments
................................................................................................xv
About the Author
...............................................................................................xvii
List of Acronyms
.................................................................................................xix
List of Units
.........................................................................................................xxv
List of Chemicals
..............................................................................................xxvii
1.
Proton Exchange Membrane Fuel Cells
.....................................................1
1.1
Fuel Cells:
...............................................................................................1
1.2
Types of Fuel Cells
................................................................................6
1.3
Advantages of Fuel Cells
......................................................................9
1.4
Proton Exchange Membrane Fuel Cells
...........................................11
1.4.1
Membrane
...............................................................................11
1.4.2
Catalysts
..................................................................................18
1.4.3
Catalyst Layer
.........................................................................21
1.4.4
Gas Diffusion Medium
.........................................................24
1.4.5
Microporous Layer
................................................................25
1.4.6
Membrane Electrode Assembly
...........................................26
1.4.7
Plate
..........................................................................................28
1.4.8
Single Cell
...............................................................................30
1.4.9
Stack
.........................................................................................32
1.4.10
System
......................................................................................37
1.4.10.1
Cell Voltage Monitoring Module (CVM)
...........38
1.4.10.2
Fuel Supply Module (FSM)
..................................39
1.4.10.3
Air Supply Module (ASM)
...................................43
1.4.10.4
Exhaust Management Module (EMM)
..............45
1.4.10.5
Heat Management Module
(HMM)
...................47
1.4.10.6
Water Management Module (WMM)
................50
1.4.10.7
Internal Power Supply Module (IPM)
................51
1.4.10.8
Power Conditioning Module (PCM)
..................53
1.4.10.9
Communications Module (COM)
.......................54
1.4.10.10
Control Module (CM)
...........................................55
1.5
Summary
..............................................................................................56
2.
Thermodynamics and Kinetics
..................................................................57
2.1
Theoretical Efficiency
.........................................................................57
2.2
Voltage
..................................................................................................60
2.3
Polarization
..........................................................................................62
ν
vi
Contents
2.4 Tafel
Equation
......................................................................................68
2.5
Voltage
Loss due to
Н2
Crossover at an Open Circuit
...................73
2.6
Example
................................................................................................75
2.7
Limiting Current Density
..................................................................77
2.7..1
Diffusion
.................................................................................77
2.7.2
Porous Electrode
....................................................................80
2.7.3
Flooded Electrode
..................................................................82
2.7.4
Achievable Current Density and Power Density
..............87
2.8
Impact of the Ionomer on the Three-Phase Boundary
..................89
2.9
System Efficiency
.................................................................................92
2.10
Water Balance
......................................................................................96
2.11
Thoughts on Ultra Thin Catalyst Layers
.........................................99
2.12
Startup and Shutdown Strategies
...................................................105
2.12.1
Impacts of OCV and Air/Fuel Boundary
.........................106
2.12.2
Strategies
...............................................................................108
2.12.2.1
N2 Purge
.................................................................108
2.12.2.2
H2 Purge
.................................................................108
2.12.2.3
H2 Diffusion
..........................................................109
2.12.2.4
Filling Stack Enclosure with H2
.........................
Ill
2.13
Summary
............................................................................................112
3.
Hydrogen H2
................................................................................................115
3.1
Properties of H2
.................................................................................115
3.2
Generation of H2
................................................................................115
3.2.1
Reforming of Hydrocarbons and Alcohols
......................116
3.2.2
Cracking of Ammonia
.........................................................127
3.2.3
Electrolysis of Water
............................................................130
3.2.3.1
Efficiency
...............................................................130
3.2.3.2
Internal Pressurization
........................................134
3.2.3.3
Proton Onsite
РЕМ
Electrolyzer
........................136
3.2.4
Chemical Sources
.................................................................138
3.2.4.1
Metals
.....................................................................138
3.2.4.2
Complex Metal Hydrides
....................................141
3.3
Hydrogen Storage
.............................................................................143
3.3.1
Compressed Gas
..................................................................143
3.3.2
Metal Hydride
......................................................................143
3.4
Hydrogen Transportation and Refueling
......................................148
3.5
Summary
............................................................................................150
4.
Evaluation
.....................................................................................................153
4.1
Catalyst
...............................................................................................153
4.1.1
Composition
..........................................................................153
4.1.2
Size and Size Distribution
..................................................154
4.1.3
Crystallite Size
......................................................................155
Contents
vii
4.1.4
Surface
Area
..........................................................................155
4.1.5
Activity
..................................................................................157
4.1.6
Cyclic Voltammetry
.............................................................159
4.2
Membrane
..........................................................................................163
4.2.1
Proton Conductivity
............................................................163
4.2.2
Water Content
.......................................................................165
4.2.3
Durability
..............................................................................166
4.2.4
Dimensional Changes
.........................................................167
4.3
GDM
....................................................................................................168
4.3.1
Electronic Conductivity
......................................................168
4.3.2 Hydrophobie
ity
....................................................................169
4.3.3
Porosity
..................................................................................170
4.4
Plate
.....................................................................................................171
4.4.1
Conductivity
.........................................................................171
4.4.2
Density and Permeability
...................................................172
4.4.3
Corrosion Current
................................................................173
4.5
MEA
....................................................................................................175
4.5.1
Catalyst Loading
..................................................................175
4.5.2
Electrochemical Active Surface Area
................................175
4.5.3
H2 Crossover
.........................................................................175
4.6
Single Cell
..........................................................................................177
4.6.1
V-I Curve
...............................................................................177
4.6.2
Durability Assessment
........................................................178
4.6.3
Load Cycling
.........................................................................179
4.6.4
Temperature Cycling
...........................................................179
4.6.5
Poisoning Tolerance
.............................................................180
4.7
Stack
....................................................................................................182
4.7.1
Performance and Durability
..............................................182
4.7.2
Startup Rate and Subzero Temperature Challenge
........183
4.8
Balance of Plant
.................................................................................185
4.8.1
DC-DC Converter
................................................................185
4.8.2
Air Supply Device
................................................................186
4.8.3
Liquid Pump
.........................................................................187
4.8.4
Heat Exchanger
....................................................................188
4.8.5
Solenoid Valve
......................................................................190
4.8.6
Control Board
.......................................................................191
4.8.7
Flow Meter and Sensor
.......................................................191
4.8.8
Internal Power Supply
.........................................................192
4.9
System
.................................................................................................194
4.10
Summary
............................................................................................195
5.
Stationary Power
.........................................................................................197
5.1
Backup Power
....................................................................................197
5.1.1
Telecommunications Station
..............................................197
5.1.2
Fuel Cell System with Air-Cooled Stack
..........................200
viii Contents
5.1.2.1
System
Architecture
.............................................200
5.1.2.2
Fuel Cell System with
Ballard FCgen-
1020ACS Stack
.......................................................201
5.1.2.3
ReliOn Fuel Cell Systems
....................................211
5.1.3
Fuel Cell System with Liquid-Cooled Stack
.....................212
5.1.3.1
Features of the
5 kW
System
...............................213
5.1.3.2
Stack from Sunrise Power
...................................215
5.1.3.3
Breadboard System
..............................................218
5.1.3.4
FueL Cell System
...................................................222
5.2
Primary Power
...................................................................................226
5.2.1
Fuel Processing
.....................................................................226
5.2.1.1
Desulfurization
.....................................................227
5.2.1.2
Steam Reforming
..................................................228
5.2.1.3
Water-Gas Shift Reaction
...................................229
5.2.1.4
Preferential Oxidation
.........................................230
5.2.1.5
Steam Reforming
Methanol................................231
5.2.2
IdaTech/Ballard Systems
....................................................232
5.3
Summary
............................................................................................234
6.
Motive Power
...............................................................................................237
6.1
Fuel Cell Vehicles
..............................................................................237
6.2
Vehicle Power Requirements
...........................................................239
6.3
Driving Distance with
6
kg H2
........................................................244
6.4
Electrical Power Train
.......................................................................250
6.5
Fuel Cell System
................................................................................254
6.6
Examples
............................................................................................260
6.6.1
Tourist Cart
...........................................................................260
6.6.2
Car
..........................................................................................262
6.6.3
Forklift
...................................................................................266
6.6.3.1
Shanghai Shenli System
......................................268
6.6.3.2
Plug Power System
...............................................270
6.6.4
Data of Some Fuel Cell Vehicles
........................................270
6.7
Vehicle Test Procedures
....................................................................275
6.8
Summary
............................................................................................275
7.
Portable Power
.............................................................................................277
7.1
Volumetric Energy Density of Various Fuels
................................277
7.2
Direct
Methanol
Fuel Cells
..............................................................280
7.3
Conventional DMFC System Architecture
....................................283
7.4
DMFC System Using Neat
Methanol
by
МП
Micro Fuel Cells
... 285
7.4.1
How to Make It Work
..........................................................285
7.4.2
DMFC Charger
.....................................................................288
7.5
DMFC Systems Developed by SFC Energy
...................................291
7.6
Summary
............................................................................................295
Contents ix
8.
Perspectives
..................................................................................................297
8.1 Status and Targets.............................................................................297
8.1.1
DOE Funding
.......................................................................297
8.1.2
СНР
System
..........................................................................300
8.1.3
Cars and Buses
.....................................................................301
8.1.4
H2 Storage
..............................................................................303
8.1.5
Portable System
....................................................................304
8.2
Challenges
..........................................................................................306
8.3
Perspectives
........................................................................................307
Appendix A: Terminology
...............................................................................309
Appendix B: Brief Introduction to Fuel Cell Developers
..........................325
References
...........................................................................................................329
Index
.....................................................................................................................333
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| id | DE-604.BV041853157 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:06:56Z |
| institution | BVB |
| isbn | 9781466513709 |
| language | English |
| lccn | 013027624 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027297569 |
| oclc_num | 889712963 |
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| owner | DE-703 DE-29T |
| owner_facet | DE-703 DE-29T |
| physical | XXIX, 343 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | CRC Press |
| record_format | marc |
| series2 | Electrochemical energy storage and conversion |
| spelling | Qi, Zhigang Verfasser aut Proton exchange membrane fuel cells Zhigang Qi Boca Raton, FL [u.a.] CRC Press 2014 XXIX, 343 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Electrochemical energy storage and conversion Includes bibliographical references (p. 329-331) and index Polymer-Elektrolytmembran-Brennstoffzelle (DE-588)4450903-0 gnd rswk-swf Polymer-Elektrolytmembran-Brennstoffzelle (DE-588)4450903-0 s DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027297569&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Qi, Zhigang Proton exchange membrane fuel cells Polymer-Elektrolytmembran-Brennstoffzelle (DE-588)4450903-0 gnd |
| subject_GND | (DE-588)4450903-0 |
| title | Proton exchange membrane fuel cells |
| title_auth | Proton exchange membrane fuel cells |
| title_exact_search | Proton exchange membrane fuel cells |
| title_full | Proton exchange membrane fuel cells Zhigang Qi |
| title_fullStr | Proton exchange membrane fuel cells Zhigang Qi |
| title_full_unstemmed | Proton exchange membrane fuel cells Zhigang Qi |
| title_short | Proton exchange membrane fuel cells |
| title_sort | proton exchange membrane fuel cells |
| topic | Polymer-Elektrolytmembran-Brennstoffzelle (DE-588)4450903-0 gnd |
| topic_facet | Polymer-Elektrolytmembran-Brennstoffzelle |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027297569&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT qizhigang protonexchangemembranefuelcells |