Chemistry, manufacture and applications of natural rubber:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Amsterdam [u.a.]
Elsevier Woodhead
2014
|
| Series: | Woodhead publishing in materials
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | XXVI, 502 S. |
| ISBN: | 9780857096838 |
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| adam_text | Contents
Contributor contact details
xiii
Introduction
xvii
S. Kohjiya, Kyoto University, Japan and Y. Ikeda, Kyoto Institute
of Technology, Japan
Part I Properties and processing of natural rubber
1
1
Biosynthesis of natural rubber (NR) in different
rubber-producing species
3
K. Cornish, The Ohio State University, USA
1.1
Introduction
3
1.2
Rubber biosynthesis
6
1.3
Rubber particles and rubber biosynthesis
10
1.4
Kinetic analyses of rubber
transferase
12
1.5
Regulation of biosynthetic rate
13
1.6
Regulation of molecular weight
19
1.7
Identification and purification of rubber
transferase
23
1.8
Conclusions
24
1.9
Acknowledgments
25
1.10
References
25
2
Natural rubber (NR) biosynthesis: perspectives from
polymer chemistry
30
J.
E- Puskás
and K. Chiang, University of Akron, USA and
B. Barkakaty, Oak Ridge National Laboratory, USA, formerly of
University of Akron, USA
2.1
Introduction
30
2.2
Background on natural rubber (NR)
31
2.3
Synthetic polyisoprenes (PIPs)
36
2.4
Biosynthesis of NR
41
2.5
in vitro biosynthesis of NR
47
vi
Contents
2.6
NR
ín
health
care
51
2.7
Future trends
54
2.8
Acknowledgments
57
2.9
References and further reading
57
3
Chemical modification of natural rubber (NR) for
improved performance
68
P. Phinyocheep, Mahidol University, Thailand
3.1
Introduction: The role of chemical modification in
creating high-performance natural rubber (NR)
68
3.2
The main types of chemical modification of NR
70
3.3
Chemical modification by changing the structure or
weight of rubber molecules
71
3.4
Chemical modification of the carbon—carbon double bond
80
3.5
Chemical modification by grafting molecules of a
different polymer type
95
3.6
Conclusions: Key issues in improving the properties of
NR
104
3.7
Future trends
106
3.8
Sources of further information and advice
108
3.9
References
110
4
Understanding network control by vulcanization for
sulfur cross-linked natural rubber (NR)
119
Y. Ikeda, Kyoto Institute of Technology, Japan
4.1
Introduction: The importance of sulfur cross-linking of
rubber
119
4.2
Using small-angle neutron scattering to analyze the
network structure of sulfur cross-linked cis-1,4-
polyisoprene
122
4.3
Network control in sulfur cross-linked
си-
1,4-
polyisoprene
126
4.4
Effect of network structure on strain-induced
crystallization of sulfur cross-linked
cis-
1
,4-polyisoprene
127
4.5
Future trends: Key issues in improving the properties of
natural rubber (NR)
131
4.6
Acknowledgments
131
4.7
References
132
5
The effect of strain-induced crystallization (SIC) on
the physical properties of natural rubber (NR)
135
S.
Toki,
National Metal and Materials Technology Center, Thailand
5.1
Introduction
135
Contents
vii
5.2
Te m peratu
re-induced crystallization (TIC) and strain-
induced crystallization (SIC)
136
5.3
Stress relaxation and SIC
137
5.4
Stress-strain relation and SIC
144
5.5
Tear resistance and SIC
154
5.6
Green strength and SIC
158
5.7
Conclusions
162
5.8
Acknowledgment
163
5.9
References
163
6
Generating particulate silica fillers in situ to
improve the mechanical properties of natural
rubber (NR)
168
A. Tohsan and Y. Ikeda, Kyoto Institute of Technology, Japan
6.1
Introduction: Silica as a filler for rubber
168
6.2
Particulate silica generated in situ
170
6.3
Recent processes for adding filler to rubber
171
6.4
Applications of in situ silica
188
6.5
Conclusions: Key issues in improving the properties of
natural rubber (NR)
188
6.6
Future trends
188
6.7
Acknowledgments
189
6.8
References
189
7 Hydrophobie
and hydrophilic silica-filled cross-linked
natural rubber
(NR):
structure and properties
193
А. Като,
NISSAN ARC Ltd, Japan and Y.
Кокиво,
R. Tsushi
and
Y. Ikeda, Kyoto Institute of Technology, Japan
7.1
Introduction: Silica reinforcement of natural rubber
(NR)
193
7.2
Testing hydrophobic and hydrophilic silica fillers: sample
preparation
196
7.3
Methods for analyzing silica filler behavior in cross-
linked NR matrix
196
7.4
Understanding the behavior of hydrophobic and
hydrophilic silica fillers in cross-linked NR matrix
199
7.5
Comparing hydrophobic and hydrophilic silica-filled
cross-linked NR
208
7.6
Conclusions
211
7.7
Future trends
212
7.8
Acknowledgments
212
7.9
References
212
viii Contents
8
Computer
simulation
of network formation in natural
rubber (NR)
216
T. Nakao, The University of Tokyo, Japan, formerly of Sumitomo
Bakelite
Co. Ltd, Japan and S. Kohjiya, Kyoto University, Japan
8.1
Introduction
216
8.2
Simulation methods for cold mastication of natural rubber
(NR)
217
8.3
Simulation methods for vulcanization of NR
222
8.4
Summary
229
8.5
Future trends
229
8.6
Sources of further information and advice
231
8.7
Acknowledgement
232
8.8
References
232
8.9
Appendix: Basic concept of cascade theory
236
Part
H
Applications of natural rubber
247
9
Eco-friendly
bio-composites using natural rubber
(NR) matrices and natural fiber reinforcements
249
A. B. Nair and R. Joseph, Cochin University of Science and
Technology, India
9.1
Introduction
249
9.2
The importance of
eco-friendly
bio-composites from
natural rubber (NR)
254
9.3
Natural fiber reinforcement materials for NR bio-
composites
257
9.4
Factors influencing the effectiveness of fiber
reinforcement
264
9.5
Methods to improve the properties of NR bio-cornposites
265
9.6
Physical properties of NR bio-composites
268
9.7
Processing of NR bio-composites
272
9.8
Applications of NR-based bio-composites with NR
reinforcements
276
9.9
Future trends
278
9.10
Sources of further information and advice
280
9.11
References
282
10
Natural rubber (NR) composites using cellulosic
fiber reinforcements
284
R. C. R.
Nunes, Universidade
Federal do
Rio de Janeiro,
Brazil
10.1
Introduction: The importance of natural rubber
(NRVcellulose composites
284
Contents ix
10.2 NR/cellulose
composites
285
10.3 NR/natural
cellulose nanocomposites
288
10.4 NR/regenerated
cellulose
nanocomposites 290
10.5 Applications 297
10.6
Future
trends
298
10.7
References
298
11
Soft bio-composites from natural rubber (NR) and
marine products
303
S. Poompradub, Chulalongkorn University, Thailand
11.1
Introduction
303
11.2
Processes and materials for developing natural rubber
(NR) composites
306
11.3
Effects of marine product fillers on rubber composites
309
1
1.4
Conclusion
319
11.5
Future trends
320
1
1.6
Sources of further information and advice
321
11.7
References
322
12
Natural rubber (NR) for the tyre industry
325
Y. Hirata, H. Kondo and Y. Ozawa,
Bridgestone
Corporation, Japan
12.1
introduction
325
12.2
Tyre types, manufacture and requirements
326
12.3
Natural rubber (NR) properties required in tyre
manufacture
335
12.4
NR properties required in tyre products
337
12.5
Examples of NR use in demanding tyre applications
343
12.6
Quality standards for NR as a raw material
349
12.7
Future trends
350
12.8
References
352
13
Application of epoxidized natural rubber (NR) ¡n
pressure sensitive adhesives (PSAs)
353
A. S. Hashim and S. K. Ong, Universiti Kuala Lumpur, Malaysia
13.1
Introduction to pressure sensitive adhesives (PSAs)
353
13.2
Processing of natural rubber (NR) and NR-based PSAs
354
13.3
Assessing the performance of a PSA
354
13.4
The use of epoxidized NR as an adhesive
357
13.5
Effect of coating thickness
358
13.6
Effect of tackifier and filler
361
13.7
Effect of molecular weight
364
13.8
Effect of testing rate
367
13.9
Other factors affecting performance
368
χ
Contents
13.10
Future trends
369
13.11
Sources
of further information and advice
369
13.12
References
369
14
Use of natural rubber (NR) for vibration isolation and
earthquake protection of structures
371
Y. Fukahori, Queen Mary University of London, UK
14.1
Introduction
371
і
4.2
The concept of vibration isolation and earthquake
protection
372
14.3
Vibration isolation and earthquake protection systems
374
14.4
Characteristics of natural rubber (NR) for vibration
isolation and earthquake protection
375
14.5
Conclusion
380
14.6
References
381
Part Hi Environmental and safety issues
383
15
Improving the sustainable development of natural
rubber (NR)
385
S. Kohjiya, Kyoto University, Japan
15.1
Introduction
385
15.2
Supply and demand of natural rubber (NR) in the twenty-
first century
387
15.3
Biodiversity
389
15.4
Applications of state-of-the-art biotechnology
391
15.5
Biosafety
392
15.6
Conclusion and future trends
392
15.7
References
393
16
Recycling of natural and synthetic
isoprene
rubbers
395
A. I. Isayev, University of Akron, USA
16.1
Introduction
395
16.2
Approaches to the reuse and recycling of natural rubber
(NR)
398
16.3
Reuse of NR
400
16.4
Recycling of NR
405
16.5
Recycling of synthetic
isoprene
rubber
421
16.6
Future trends
427
16.7
Conclusions
428
16.8
Acknowledgements
429
16.9
References
429
Contents xi
17 Recycling
of sulfur cross-linked natural rubber
(NR)
using supercritical carbon dioxide
436
Y. Ikeda, Kyoto Institute of Technology, Japan
17.1
Introduction: Key problems in recycling sulfur cross-
linked natural rubber (NR)
436
17.2
Advantages of supercritical CO2 (scCO2) for the
devulcanization of sulfur cross-linked rubber
438
17.3
Devulcanization of sulfur cross-linked NR in scCO2
439
17.4
Devulcanization of carbon black-filled sulfur cross-linked
NR
440
17.5
Devulcanization of an NR-based truck
tire vulcanízate
442
17.6
The role of scCO2 in the devulcanization of sulfur cross-
linked rubber
443
17.7
Conclusion: Key issues in ensuring effective recycling of
sulfur cross-linked NR
448
17.8
Future trends
449
17.9
Acknowledgements
449
17.10
References
450
18
Recent research on natural rubber latex (NRL)
allergy
452
T. Palosuo, National Institute for Health and Welfare, Finland
18.1
Introduction: The problem of natural rubber latex (NRL)
allergy
452
18.2
Medical background to NRL allergy
453
18.3
Mechanisms of development and clinical presentation of
NRL allergy
457
18.4
Recent trends in the prevalence of NRL allergy
464
18.5
Key issues in reducing NRL allergy
466
18.6
Future trends
471
18.7
Conclusion
472
18.8
Sources of further information and advice
473
18.9
References
474
18.10
Appendix: Abbreviations
481
Index
483
WOODHEAD PUBLISHING IN MATERIALS
The growing demand for more sustainable materials for a variety of applications
has led to increased research on the properties of natural rubber. Chemistry,
Manufacture and Applications of Natural Rubber summarises this research and its
significance for the industrial applications of natural rubber.
Chapters in Part I explore the properties and processing of natural rubber
including the biosynthesis of natural rubber in different rubber-producing
species, chemical modification of natural rubber for improved performance, and
the effect of strain-induced crystallization on the physical properties of natural
rubber. Further chapters highlight hydrophobic and hydrophilic silica-filled cross-
linked natural rubber and computer simulation of network formation in natural
rubber. Part II focuses on applications of natural rubber including
eco-friendly
bio-
composites
usi ng
natural rubber matrices and reinforcements, soft bio-composites
from natural rubber and marine products, natural rubber for the tyre industry, the
application of epoxtdized natural rubber in pressure sensitive adhesives (PSAs),
and the use of natural rubber for vibration isolation and earthquake protection
of structures. Finally, chapters in Part III consider environmental and safety issues
associated with natural rubber including improving the sustainable development
of natural rubber, the recycling of natural and synthetic
isoprene
rubbers and of
sulfur cross-linked natural rubber, and recent research on natural rubber latex
allergy.
Chemistry, Manufacture and Applications of Natural Rubber is a comprehensive
resource for academics, chemists, chemical engineers, mechanical engineers and
other professionals in the rubber industry, as well as those industries, including
automotive, civil and medical engineering, using natural rubber products.
Shinzo Kohjiya is a Professor Emeritus, Kyoto University, Japan. Yuko Ikeda is
an Associate Professor at the Department of Chemistry and Materials Technology,
Kyoto Institute of Technology, Japan.
|
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| dewey-full | 678.62 |
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| dewey-ones | 678 - Elastomers and elastomer products |
| dewey-raw | 678.62 |
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| dewey-tens | 670 - Manufacturing |
| discipline | Physik Werkstoffwissenschaften / Fertigungstechnik |
| format | Book |
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| id | DE-604.BV041852115 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T01:06:55Z |
| institution | BVB |
| isbn | 9780857096838 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027296554 |
| oclc_num | 876426473 |
| open_access_boolean | |
| owner | DE-703 DE-29T DE-706 |
| owner_facet | DE-703 DE-29T DE-706 |
| physical | XXVI, 502 S. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Elsevier Woodhead |
| record_format | marc |
| series2 | Woodhead publishing in materials |
| spelling | Chemistry, manufacture and applications of natural rubber ed. by Shinzo Kohjiya ... Amsterdam [u.a.] Elsevier Woodhead 2014 XXVI, 502 S. txt rdacontent n rdamedia nc rdacarrier Woodhead publishing in materials Gummiherstellung (DE-588)4404207-3 gnd rswk-swf Chemische Eigenschaft (DE-588)4371174-1 gnd rswk-swf Gummi (DE-588)4022538-0 gnd rswk-swf Natürliches organisches Material (DE-588)4721793-5 gnd rswk-swf Gummiprodukt (DE-588)4158550-1 gnd rswk-swf Gummiverarbeitung (DE-588)4278968-0 gnd rswk-swf Kautschuk (DE-588)4030108-4 gnd rswk-swf Gummi (DE-588)4022538-0 s Natürliches organisches Material (DE-588)4721793-5 s Gummiherstellung (DE-588)4404207-3 s DE-604 Kautschuk (DE-588)4030108-4 s Gummiprodukt (DE-588)4158550-1 s Gummiverarbeitung (DE-588)4278968-0 s Chemische Eigenschaft (DE-588)4371174-1 s Kohjiya, Shinzo Sonstige (DE-588)1072395436 oth Erscheint auch als Online-Ausgabe 978-0-85709-691-3 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027296554&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027296554&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Chemistry, manufacture and applications of natural rubber Gummiherstellung (DE-588)4404207-3 gnd Chemische Eigenschaft (DE-588)4371174-1 gnd Gummi (DE-588)4022538-0 gnd Natürliches organisches Material (DE-588)4721793-5 gnd Gummiprodukt (DE-588)4158550-1 gnd Gummiverarbeitung (DE-588)4278968-0 gnd Kautschuk (DE-588)4030108-4 gnd |
| subject_GND | (DE-588)4404207-3 (DE-588)4371174-1 (DE-588)4022538-0 (DE-588)4721793-5 (DE-588)4158550-1 (DE-588)4278968-0 (DE-588)4030108-4 |
| title | Chemistry, manufacture and applications of natural rubber |
| title_auth | Chemistry, manufacture and applications of natural rubber |
| title_exact_search | Chemistry, manufacture and applications of natural rubber |
| title_full | Chemistry, manufacture and applications of natural rubber ed. by Shinzo Kohjiya ... |
| title_fullStr | Chemistry, manufacture and applications of natural rubber ed. by Shinzo Kohjiya ... |
| title_full_unstemmed | Chemistry, manufacture and applications of natural rubber ed. by Shinzo Kohjiya ... |
| title_short | Chemistry, manufacture and applications of natural rubber |
| title_sort | chemistry manufacture and applications of natural rubber |
| topic | Gummiherstellung (DE-588)4404207-3 gnd Chemische Eigenschaft (DE-588)4371174-1 gnd Gummi (DE-588)4022538-0 gnd Natürliches organisches Material (DE-588)4721793-5 gnd Gummiprodukt (DE-588)4158550-1 gnd Gummiverarbeitung (DE-588)4278968-0 gnd Kautschuk (DE-588)4030108-4 gnd |
| topic_facet | Gummiherstellung Chemische Eigenschaft Gummi Natürliches organisches Material Gummiprodukt Gummiverarbeitung Kautschuk |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027296554&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027296554&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT kohjiyashinzo chemistrymanufactureandapplicationsofnaturalrubber |