Trace metals in aquatic systems:
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| Main Author: | |
|---|---|
| Format: | Electronic eBook |
| Language: | English |
| Published: |
Chichester, West Sussex [u.a.]
Wiley-Blackwell
2013
|
| Subjects: | |
| Online Access: | FRO01 UBT01 Volltext |
| Item Description: | "The textbooks that currently exist do not deal with this particular subject in a comprehensive fashion, and therefore this book is being proposed to full this gap"-- |
| Physical Description: | 1 Online-Ressource |
| ISBN: | 1118274571 9781118274576 9781118274583 9781118274590 9781118274606 |
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| 505 | 0 | |a Cover; Title page; Copyright page; Contents; Preface; About the companion website; CHAPTER 1: Introduction; 1.1 A historical background to metal aquatic chemistry; 1.2 Historical problems with metal measurements in environmental media; 1.3 Recent advances in aquatic metal analysis; References; Problems; CHAPTER 2: An introduction to the cycling of metals in the biosphere; 2.1 The hydrologic cycle; 2.2 An introduction to the global cycling of trace metal(loid)s; 2.2.1 The sources and cycling of metal(loid)s in the biosphere; 2.2.2 Metal(loid) partitioning and solubility in natural waters | |
| 505 | 0 | |a 2.2.3 Human influence over metal(loid) fate and transport2.2.4 Trace metal(loid) inputs to the atmosphere; 2.2.5 Metal(loid)s in the terrestrial environment and freshwater ecosystems; 2.2.6 The transport of metal(loid)s to the ocean; 2.2.7 Trace metal(loid)s in ocean waters; 2.2.8 Trace metal(loid) inputs from hydrothermal vents; 2.3 Global cycles of some important trace metals; 2.3.1 The global cycles of cadmium, copper, and zinc; 2.3.2 The global cycle of mercury and lead; 2.4 Chapter summary; References; Problems | |
| 505 | 0 | |a CHAPTER 3: Chemical thermodynamics and metal(loid) complexation in natural waters3.1 Thermodynamic background for understanding trace metal(loid) complexation; 3.1.1 The relationship between free energy and the equilibrium constant; 3.1.2 Ionic strength effects; 3.1.3 Thermodynamic equilibrium, kinetics and steady state; 3.2 Bonding, electronic configuration, and complex formation; 3.2.1 Ligand Field Theory; 3.2.2 Thermodynamic effects of orbital splitting; 3.2.3 Inorganic chemistry and complexation of transition metals | |
| 505 | 0 | |a 3.2.4 Inorganic chemistry and complexation of non-transition metals and metalloids3.3 Complexation of metals in solution; 3.3.1 Inorganic complexation; 3.3.2 An approach to determining metal(loid) speciation in solution; 3.3.3 The chemistry and speciation of metal-binding ligands; 3.3.4 The complexation of the major ions in solution; 3.3.5 Metal complexation with low molecular weight organic ligands; 3.3.6 Complexation to large molecular weight organic matter; 3.4 Trace metal interactions with the solid phase; 3.4.1 Precipitation and dissolution; 3.4.2 Adsorption of metals to aqueous solids | |
| 505 | 0 | |a 3.4.3 Dissolved-particulate partition coefficients3.4.4 Adsorption isotherms; 3.4.5 A complexation-based model for adsorption; 3.5 Redox transformations and thermodynamic calculations; 3.5.1 Electrochemistry and the equilibrium constant; 3.5.2 The range in electrode potential and the stability of water; 3.5.3 Equilibrium calculations involving redox reactions; 3.5.4 Environmental considerations and controlling reactions; 3.6 Chapter summary; References; Problems; CHAPTER 4: Modeling approaches to estimating speciation and interactions in aqueous systems; 4.1 Introduction | |
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| 650 | 4 | |a Trace elements / Analysis | |
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| contents | Cover; Title page; Copyright page; Contents; Preface; About the companion website; CHAPTER 1: Introduction; 1.1 A historical background to metal aquatic chemistry; 1.2 Historical problems with metal measurements in environmental media; 1.3 Recent advances in aquatic metal analysis; References; Problems; CHAPTER 2: An introduction to the cycling of metals in the biosphere; 2.1 The hydrologic cycle; 2.2 An introduction to the global cycling of trace metal(loid)s; 2.2.1 The sources and cycling of metal(loid)s in the biosphere; 2.2.2 Metal(loid) partitioning and solubility in natural waters 2.2.3 Human influence over metal(loid) fate and transport2.2.4 Trace metal(loid) inputs to the atmosphere; 2.2.5 Metal(loid)s in the terrestrial environment and freshwater ecosystems; 2.2.6 The transport of metal(loid)s to the ocean; 2.2.7 Trace metal(loid)s in ocean waters; 2.2.8 Trace metal(loid) inputs from hydrothermal vents; 2.3 Global cycles of some important trace metals; 2.3.1 The global cycles of cadmium, copper, and zinc; 2.3.2 The global cycle of mercury and lead; 2.4 Chapter summary; References; Problems CHAPTER 3: Chemical thermodynamics and metal(loid) complexation in natural waters3.1 Thermodynamic background for understanding trace metal(loid) complexation; 3.1.1 The relationship between free energy and the equilibrium constant; 3.1.2 Ionic strength effects; 3.1.3 Thermodynamic equilibrium, kinetics and steady state; 3.2 Bonding, electronic configuration, and complex formation; 3.2.1 Ligand Field Theory; 3.2.2 Thermodynamic effects of orbital splitting; 3.2.3 Inorganic chemistry and complexation of transition metals 3.2.4 Inorganic chemistry and complexation of non-transition metals and metalloids3.3 Complexation of metals in solution; 3.3.1 Inorganic complexation; 3.3.2 An approach to determining metal(loid) speciation in solution; 3.3.3 The chemistry and speciation of metal-binding ligands; 3.3.4 The complexation of the major ions in solution; 3.3.5 Metal complexation with low molecular weight organic ligands; 3.3.6 Complexation to large molecular weight organic matter; 3.4 Trace metal interactions with the solid phase; 3.4.1 Precipitation and dissolution; 3.4.2 Adsorption of metals to aqueous solids 3.4.3 Dissolved-particulate partition coefficients3.4.4 Adsorption isotherms; 3.4.5 A complexation-based model for adsorption; 3.5 Redox transformations and thermodynamic calculations; 3.5.1 Electrochemistry and the equilibrium constant; 3.5.2 The range in electrode potential and the stability of water; 3.5.3 Equilibrium calculations involving redox reactions; 3.5.4 Environmental considerations and controlling reactions; 3.6 Chapter summary; References; Problems; CHAPTER 4: Modeling approaches to estimating speciation and interactions in aqueous systems; 4.1 Introduction |
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| indexdate | 2024-07-10T01:06:21Z |
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| isbn | 1118274571 9781118274576 9781118274583 9781118274590 9781118274606 |
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| spelling | Mason, Robert P. 1956- Verfasser (DE-588)1034562088 aut Trace metals in aquatic systems Robert P. Mason Chichester, West Sussex [u.a.] Wiley-Blackwell 2013 1 Online-Ressource txt rdacontent c rdamedia cr rdacarrier "The textbooks that currently exist do not deal with this particular subject in a comprehensive fashion, and therefore this book is being proposed to full this gap"-- Cover; Title page; Copyright page; Contents; Preface; About the companion website; CHAPTER 1: Introduction; 1.1 A historical background to metal aquatic chemistry; 1.2 Historical problems with metal measurements in environmental media; 1.3 Recent advances in aquatic metal analysis; References; Problems; CHAPTER 2: An introduction to the cycling of metals in the biosphere; 2.1 The hydrologic cycle; 2.2 An introduction to the global cycling of trace metal(loid)s; 2.2.1 The sources and cycling of metal(loid)s in the biosphere; 2.2.2 Metal(loid) partitioning and solubility in natural waters 2.2.3 Human influence over metal(loid) fate and transport2.2.4 Trace metal(loid) inputs to the atmosphere; 2.2.5 Metal(loid)s in the terrestrial environment and freshwater ecosystems; 2.2.6 The transport of metal(loid)s to the ocean; 2.2.7 Trace metal(loid)s in ocean waters; 2.2.8 Trace metal(loid) inputs from hydrothermal vents; 2.3 Global cycles of some important trace metals; 2.3.1 The global cycles of cadmium, copper, and zinc; 2.3.2 The global cycle of mercury and lead; 2.4 Chapter summary; References; Problems CHAPTER 3: Chemical thermodynamics and metal(loid) complexation in natural waters3.1 Thermodynamic background for understanding trace metal(loid) complexation; 3.1.1 The relationship between free energy and the equilibrium constant; 3.1.2 Ionic strength effects; 3.1.3 Thermodynamic equilibrium, kinetics and steady state; 3.2 Bonding, electronic configuration, and complex formation; 3.2.1 Ligand Field Theory; 3.2.2 Thermodynamic effects of orbital splitting; 3.2.3 Inorganic chemistry and complexation of transition metals 3.2.4 Inorganic chemistry and complexation of non-transition metals and metalloids3.3 Complexation of metals in solution; 3.3.1 Inorganic complexation; 3.3.2 An approach to determining metal(loid) speciation in solution; 3.3.3 The chemistry and speciation of metal-binding ligands; 3.3.4 The complexation of the major ions in solution; 3.3.5 Metal complexation with low molecular weight organic ligands; 3.3.6 Complexation to large molecular weight organic matter; 3.4 Trace metal interactions with the solid phase; 3.4.1 Precipitation and dissolution; 3.4.2 Adsorption of metals to aqueous solids 3.4.3 Dissolved-particulate partition coefficients3.4.4 Adsorption isotherms; 3.4.5 A complexation-based model for adsorption; 3.5 Redox transformations and thermodynamic calculations; 3.5.1 Electrochemistry and the equilibrium constant; 3.5.2 The range in electrode potential and the stability of water; 3.5.3 Equilibrium calculations involving redox reactions; 3.5.4 Environmental considerations and controlling reactions; 3.6 Chapter summary; References; Problems; CHAPTER 4: Modeling approaches to estimating speciation and interactions in aqueous systems; 4.1 Introduction SCIENCE / Chemistry / Organic bisacsh NATURE / Natural Resources bisacsh NATURE / Rocks & Minerals bisacsh Chemie Trace elements / Analysis Water / Analysis Water chemistry Electronic books Erscheint auch als Druck-Ausgabe, Hardcover 978-1-4051-6048-3 https://onlinelibrary.wiley.com/doi/book/10.1002/9781118274576 Verlag Volltext |
| spellingShingle | Mason, Robert P. 1956- Trace metals in aquatic systems Cover; Title page; Copyright page; Contents; Preface; About the companion website; CHAPTER 1: Introduction; 1.1 A historical background to metal aquatic chemistry; 1.2 Historical problems with metal measurements in environmental media; 1.3 Recent advances in aquatic metal analysis; References; Problems; CHAPTER 2: An introduction to the cycling of metals in the biosphere; 2.1 The hydrologic cycle; 2.2 An introduction to the global cycling of trace metal(loid)s; 2.2.1 The sources and cycling of metal(loid)s in the biosphere; 2.2.2 Metal(loid) partitioning and solubility in natural waters 2.2.3 Human influence over metal(loid) fate and transport2.2.4 Trace metal(loid) inputs to the atmosphere; 2.2.5 Metal(loid)s in the terrestrial environment and freshwater ecosystems; 2.2.6 The transport of metal(loid)s to the ocean; 2.2.7 Trace metal(loid)s in ocean waters; 2.2.8 Trace metal(loid) inputs from hydrothermal vents; 2.3 Global cycles of some important trace metals; 2.3.1 The global cycles of cadmium, copper, and zinc; 2.3.2 The global cycle of mercury and lead; 2.4 Chapter summary; References; Problems CHAPTER 3: Chemical thermodynamics and metal(loid) complexation in natural waters3.1 Thermodynamic background for understanding trace metal(loid) complexation; 3.1.1 The relationship between free energy and the equilibrium constant; 3.1.2 Ionic strength effects; 3.1.3 Thermodynamic equilibrium, kinetics and steady state; 3.2 Bonding, electronic configuration, and complex formation; 3.2.1 Ligand Field Theory; 3.2.2 Thermodynamic effects of orbital splitting; 3.2.3 Inorganic chemistry and complexation of transition metals 3.2.4 Inorganic chemistry and complexation of non-transition metals and metalloids3.3 Complexation of metals in solution; 3.3.1 Inorganic complexation; 3.3.2 An approach to determining metal(loid) speciation in solution; 3.3.3 The chemistry and speciation of metal-binding ligands; 3.3.4 The complexation of the major ions in solution; 3.3.5 Metal complexation with low molecular weight organic ligands; 3.3.6 Complexation to large molecular weight organic matter; 3.4 Trace metal interactions with the solid phase; 3.4.1 Precipitation and dissolution; 3.4.2 Adsorption of metals to aqueous solids 3.4.3 Dissolved-particulate partition coefficients3.4.4 Adsorption isotherms; 3.4.5 A complexation-based model for adsorption; 3.5 Redox transformations and thermodynamic calculations; 3.5.1 Electrochemistry and the equilibrium constant; 3.5.2 The range in electrode potential and the stability of water; 3.5.3 Equilibrium calculations involving redox reactions; 3.5.4 Environmental considerations and controlling reactions; 3.6 Chapter summary; References; Problems; CHAPTER 4: Modeling approaches to estimating speciation and interactions in aqueous systems; 4.1 Introduction SCIENCE / Chemistry / Organic bisacsh NATURE / Natural Resources bisacsh NATURE / Rocks & Minerals bisacsh Chemie Trace elements / Analysis Water / Analysis Water chemistry |
| title | Trace metals in aquatic systems |
| title_auth | Trace metals in aquatic systems |
| title_exact_search | Trace metals in aquatic systems |
| title_full | Trace metals in aquatic systems Robert P. Mason |
| title_fullStr | Trace metals in aquatic systems Robert P. Mason |
| title_full_unstemmed | Trace metals in aquatic systems Robert P. Mason |
| title_short | Trace metals in aquatic systems |
| title_sort | trace metals in aquatic systems |
| topic | SCIENCE / Chemistry / Organic bisacsh NATURE / Natural Resources bisacsh NATURE / Rocks & Minerals bisacsh Chemie Trace elements / Analysis Water / Analysis Water chemistry |
| topic_facet | SCIENCE / Chemistry / Organic NATURE / Natural Resources NATURE / Rocks & Minerals Chemie Trace elements / Analysis Water / Analysis Water chemistry |
| url | https://onlinelibrary.wiley.com/doi/book/10.1002/9781118274576 |
| work_keys_str_mv | AT masonrobertp tracemetalsinaquaticsystems |