The chemistry of bio-based polymers:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Beverly, Ma. [u.a.]
Scrivener [u.a.]
2014
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | XIV, 338 S. Ill., graph. Darst. |
| ISBN: | 9781118837252 |
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MARC
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| 020 | |a 9781118837252 |9 978-1-118-83725-2 | ||
| 024 | 3 | |a 9781118837252 | |
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| 100 | 1 | |a Fink, Johannes Karl |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a The chemistry of bio-based polymers |c Johannes Karl Fink |
| 264 | 1 | |a Beverly, Ma. [u.a.] |b Scrivener [u.a.] |c 2014 | |
| 300 | |a XIV, 338 S. |b Ill., graph. Darst. | ||
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-027263952 | ||
Record in the Search Index
| _version_ | 1804152148248756224 |
|---|---|
| adam_text | Contents
Preface
Xlii
1 An
Overview of Methods and Standards
1
1.1
History of Biodegradable Plastics
1
1.2
Green Chemistry
2
1.2.1
Genetic Engineering
4
1.3
Commercial Situation
5
1.4
Environmental Situation
7
1.4.1
Problems with Biobased Composites
9
1.4.2 Biodegradation 10
1.5
Properties of Biodegradable Polymers
12
1.6
Special Methods of Synthesis
14
1.6.1
Conventional Methods
14
1.6.2
Click Chemistry
15
1.6.3
Enzymatic Polymerization
16
1.6.4
Chemoenzymatic Polymerization
17
1.6.5
Vine-twining Polymerization
19
1.6.6
Bacterial Synthesis
20
1.7
Biodegradability Standards
20
1.7.1
Guidelines for the Development of Standards
21
1.7.2
Specifications for Compostable Plastics
21
1.7.3
Ultimate Anaerobic Biodegradability
21
1.7.4
Aerobic Biodegradability
24
1.7.5
Biodegradability of Plastics in Sea water
26
1.8
Test of the Biological Origin
29
References
35
vi
Contents
Part I Bio-based Polymers Degradation and Chemistry
43
2
Vinyl Based Polymers
45
2.1
Polyolefins
45
2.1.1
Degradability
46
2.1.2
Degradation Mechanism
46
2.1.3
Pro-degradants
47
2.2
Poly(styrene) Elastomers
48
2.3
Poly(vinyl alcohol)
48
2.3.1
Plasticized Compositions
49
2.3.2
Hydrogels
50
2.4
Poly(vinyl butyral)
51
2.4.1
Blends with Poly(3-hydroxybutyrate)
52
2.4.2
Blends with Polydactic acid)
53
2.4.3
Paper coatings
53
2.4.4
Fibers
54
2.4.5
Membranes
55
2.4.6
Solar Cells
56
2.4.7
Adhesive for Safety Glass
57
References
60
3
Acid and Lactone Polymers
63
3.1
Polydactic acid)
63
3.1.1
Production Processes for Polydactic acid)
63
3.1.2
Surface Modification of Fibers
69
3.1.3
Influence of Fabrication Methods and
Kenaf Fiber Length
69
3.1.4
Kenaf fibers
f
or Reinforcement of PP
70
3.1.5
Reinforced Composites
71
3.1.6
Laminated Composites from Kenaf Fiber
71
3.1.7
Copolyesters
72
3.1.8
Transparent Crystalline Polydactic acid)
73
ЗЛ.9
Laminated
Biocomposites
73
3.2
Polyíglycolic acid)s
74
3.2.1
Glycolic acid
74
3.2.2
Polymers, Copolymers, and Blends
76
3.2.3
Condensation Polymer of Glycerol
76
Contents
vii
3.3
Butyrolactone-based Vinyl Monomers
77
3.3.1
TulipalinA
77
3.3.2
a-Methylene-y-valerolactone
78
3.4
Poly(caprolactone)
81
References
83
Ester and Amide Polymers
87
4.1
Poly(ester)s
87
4.1.1
Methyl-lO-undecenoate
87
4.1.2
Poly
(butylène
adipa te)
Copolyesters
87
4.1.3
Poly(hydroxyalkanoate)s
88
4.1.4
Poly(hydroxybutyrate)
89
4Л.5
PolyChydroxyvalerate)
91
4.1.6
Polyfô-hydroxyhexanoic
acid)
93
4.1.7 Polyiß-hydroxyoctanoate) 94
4.1.8
Polyíy-glutamic
acid)
95
4.1.9
Poly
(buty
lene succinate)
95
4.1.10
Dianhydrohexitols based Polymers
98
4.1.11
Aliphatic-Aromatic Copolyesters
102
4.1.12
Succinate Based Polyesters
108
4.1.13
Sebacate Based Polyesters
108
4.1.14
Unsatura
ted Polyesters
112
4.1.15
Sulfonated Polyesters
113
4.2
Plant oil-based
Biopolymers 117
4.2.1
Plant Oils with Acrylic
Moitiés
118
4.2.2
Plant Oils with Phosphorus
Moitiés
120
4.2.3
Vanillin Based Monomers
121
4.2.4
Vegetable oil
Thermosets
123
4.3
Poly(amide)s
124
4.3
Л
Soy Based Bio-plastic and Chopped
Industrial Hemp
124
4.3.2
Soy bean based Composites
124
References
131
Carbohydrate Related Polymers
137
5.1
Starch
137
5ЛЛ
Starch Modification
138
5
Л
.2
Starch Granules
140
viii
Contents
5.1.3
Baked Foams
140
5.1.4
High Starch Polymer
140
5.1.5
Destructurization of Natural Starch
142
5.1.6
Melt Processable Starch
143
5.1.7
Wet-spinning Processes for Starch
145
5
Л
.8
Pre-gelled Starch Suspensions
145
5.1.9
Processing of Natural Starch
146
5.1.10
Granular Starch as Additive to
Conventional Polymers
146
5.2
Cellulose
149
5.2.1
Liquid Crystalline Derivatives
150
5.2.2
Cellulose Fibers
151
5.2.3
Modified Cellulose Fibers
154
5.3
Cellulose ethers
158
5.4
Cellulose esters
158
5.5
Cellulose ether esters
158
5.6
Lignin
160
5.7
Biodegradable Nanocomposites
162
5.7.1
Oxidation of Spruce and Pulps
162
5.7.2
Modified Cellulose Nanofibers
164
5.7.3
Biobased Epoxy Nanocomposites
164
5.8 Chitin
164
References
167
6
Other Polymer Types
171
6.1
Terpenes
171
6.1.1
Grafted
Terpene
171
6.1.2
Thiol-Ene Additions
172
6.1.3
Piñenes
172
6.2
Poly(urethane)s
176
6.2.1
Poiy(ester urethane)s
177
6.3
Cationic lipopolymers
178
6.4
Plastics from Bacteria
179
6.4.1
Biodegradability of
Poly(hydroxyalkanoate)
180
6.5
Biobased Epoxy Resins
180
6.5.1
Poloxamers
181
6.6
Phosphate Containing Polymers
181
6.7
Polyketais
187
8
Contents
ix
6.8
Bio-rubber
188
6.9
Collagen
189
6.10
Pyridinium Modified Polymers
189
6.11
Commercial Biodegradable Polymers
190
References
192
rt II Applications
195
Packaging and Food Applications
197
7.1
Packaging
197
7.1
Л
Packaging Materials
197
7.1.2
Lightweight Compostable Packaging
198
7.1.3
Laminate Coatings
198
7.1.4
PLA
Resins
199
7.1.5
Starch Compositions
201
7.1.6
Heat-sealable Paperboard
203
7.1.7
Packages with Corrosion Inhibitor
204
7.1.8
Multi-wall Package
206
7.1.9
Cushioning Nuggets
206
7.1.10
Fluid Containers
207
7.2
Fibers and Nets
210
7.2.1
Multicomponent Fiber
210
7.2.2
Biodegradable netting
211
7.3
Foams
213
7.3.1
Foamed Articles
213
7.3.2
Blends
214
7.3.3
Starch-polyester Graft Copolymer
214
7.3.4
Foamed Gelling Hydrocolloids
215
7.4
Biodegradable Hot melt Adhesive Compositions
217
7.5
Food Applications
218
7.5.1
Chewing Gum
218
References
219
Medical Applications
223
8.1
Drug Delivery
223
8.1.1
Acacia
227
8.1.2
Carrageenan
228
8.1.3
Cellulose
230
χ
Contents
8.1.4
Chitosan
231
8.1.5
GellanGum
231
8.1.6
Guar Gum
231
8.1.7
Hyaluronic Acid Derivatives
232
8.1.8
Khaya Gum
233
8.1.9
Locust Bean Gum
233
8.1.10
Pectin
234
8.1.11
Xanthan Gum
234
8.1.12
Electrospinning
234
8.1.13
Drug Release from Electrospun Fibers
235
8.2
Tissue Engineering
238
8.2.1
Scaffolds for Tissue Engineering
239
8.3
Tissue Markers
240
8.4
Hydrogels
242
8.5
Microporous Materials
243
8.6
Implants
246
8.6.1
Inflammatory Problems with Implants
246
8.6.2
Eye Implants
247
8.6.3
Thermosetting Implants
248
8.6.4
Neurotoxin Implants
252
8.6.5
Water Soluble Glass Fibers
252
8.7
Shape Memory Polymers
252
8.7.1
Shape Memory Polyesters
254
8.8
Stents
255
8.8.1
Surface Erosion
256
8.8.2
Tubular Main Body
257
8.8.3
Multilayer Stents
258
8.9
Thermogelling Materials
258
8.10
Wound Dressings
259
8.11
Bioceramics
259
8.12
Conjugates
261
References
262
Personal Care and Sanitary Goods
269
9.1
Breathable Biodegradable Hot Melt Composition
269
9.2
Sanitary Goods
269
9.3
Superabsorbent
Materials
272
References
273
Contents
xi
10
Miscellaneous Applications
275
10.1
Flooring Materials
275
10.2
Abrasives and Polishing Compositions
279
10.2.1
Cleansers
279
10.2.2
Polishing Pads
280
10.3
Lubricants
282
10.4
Renewable Cards
282
10.5
Biodegradable Irrigation Pipe
283
10.6
Thermosensitive Material
284
10.7
Biodegradable scale inhibitors
286
10.7.1
Phosphorus-Containing Polymer
286
10.8
Nanocomposites
287
10.9
Molded Articles from Fruit Residues
287
10.10
Fluorescent Biodegradable Particles
287
10.11
Test Cylinder Mold for Testing Concrete
290
10Л2
Flexographic Inks
290
10.13
Audio Systems
292
10.14
Automotive Uses
293
10.15
Green Hot Melt Adhesives
294
10.16
Mechanistic Studies
295
10.16.1
Olefin
Isomerization
295
References
297
U
Biofuels
299
11.1
Xenobiotics
299
11.2 Biopolymers
300
11.2.1
Polytf-lactide)
300
11.3
Bioethanol
302
11,3.1
Pretreatment
Methods
303
11.3.2
Cellulases and Hemicellulases
305
11.3.3
Production from Starch
307
11.3.4
Production from Lignocellulose
308
11.3.5
Production from Lichenan
309
11.4
Biobutanol and Biobutanediol
310
11.5
Biodiesel
313
11.5.1
Production from Microalgae Beats
314
11.5.2
Improvement of Diesel Fuel Properties
by
Terpenes
314
References
317
xii
Contents
Index
321
Tradenames
321
Acronyms
326
Chemicals
328
General Index
336
An exhaustive
and
tfmeły
overview of renewable polymers
from a respected chemist and successful author
The recent explosion of interdisciplinary research has fragmented the knowledge
base surrounding renewable polymers. The Chemistry of Bio-based Polymers
brings together, in one volume, the research and work of Professor Johannes
Rnk, focusing on biopolymers that can be synthesized from renewable polymers.
After introducing general aspects of the field, the book s subsequent chafers
examine the chemistry of biodegradable polymeric types sorted by their chemical
compounds, including the synthesis of low molecular compounds. Various
categories of biopolymers are detailed including vinyl-based polymers, acid and
tortone
polymers, ester and amide polymers, carbohydrate-related polymers
and others. Procedures for the preparation of biopolymers and biodegradable
nanocomposites are arranged by chemical methods and in vitro biological
methods, with discussion of the issue of plastics from bacteria. 1
The factors influencing the degradation and
biodégradation
of polymers used in
food packaging, exposed to various environments, are detailed at length. The book
covers the medical applications of bio-based polymers, concentrating on controlled
drug delivery, temporary
prostheses,
and scaffolds for tissue engineering.
Professo
ñnk
also addresses renewable resources for fabricating biofuels and argues for
biorefineries, as biomass feedstocks am more efficiently handled locally.
The Chemistry of Bio-based Polymers
wíl
be read by chemists, polymer and
materials scientists, chemical, bio-based, and
biomedical
engineers, agricultural
and environmental faculty and all those who work in the bioeconomy area.
This book
wil
be critical for engineers in a number of industries including food
packaging, medical devices, personal care, fuels, auto, and construction.
Johannes Karl Rnk is Professor of Macromotecuiar Chemistry at
Monianunrversitát
Leoben,
Austria. His industry and academic career spans
more 1han
30
years in the fields of polymers, and
г^
research interests include
characterization, flame retardancy, triemxxlynarrocs and the degradation of
polymers,
pyrołyste,
and
adhesivas,
ftoisssor Rr* has published several books
on physk^ criernistiy
агкЈ
p^^
Sensors and Actoato (Wiley-Scrivener
2012)
Cover Design: Russet Richardson
ftont
Govor
BectoQfOund: Dfi&B/nstiin
Inset images: Courtesy of Johannes Karl
Њк
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| id | DE-604.BV041818788 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:06:06Z |
| institution | BVB |
| isbn | 9781118837252 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027263952 |
| oclc_num | 876132414 |
| open_access_boolean | |
| owner | DE-29T DE-703 DE-83 |
| owner_facet | DE-29T DE-703 DE-83 |
| physical | XIV, 338 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Scrivener [u.a.] |
| record_format | marc |
| spelling | Fink, Johannes Karl Verfasser aut The chemistry of bio-based polymers Johannes Karl Fink Beverly, Ma. [u.a.] Scrivener [u.a.] 2014 XIV, 338 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd rswk-swf Biologisch abbaubarer Kunststoff (DE-588)4634464-0 s DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027263952&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027263952&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Fink, Johannes Karl The chemistry of bio-based polymers Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd |
| subject_GND | (DE-588)4634464-0 |
| title | The chemistry of bio-based polymers |
| title_auth | The chemistry of bio-based polymers |
| title_exact_search | The chemistry of bio-based polymers |
| title_full | The chemistry of bio-based polymers Johannes Karl Fink |
| title_fullStr | The chemistry of bio-based polymers Johannes Karl Fink |
| title_full_unstemmed | The chemistry of bio-based polymers Johannes Karl Fink |
| title_short | The chemistry of bio-based polymers |
| title_sort | the chemistry of bio based polymers |
| topic | Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd |
| topic_facet | Biologisch abbaubarer Kunststoff |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027263952&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027263952&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT finkjohanneskarl thechemistryofbiobasedpolymers |