Electronic properties of interfaces in molecular organic photovoltaic cells:
Saved in:
| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
Berlin
2014
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturverzeichnis Blätter 114 - 132 |
| Physical Description: | 134 Blätter Illustrationen, Diagramme |
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MARC
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| 245 | 1 | 0 | |a Electronic properties of interfaces in molecular organic photovoltaic cells |c von Dipl.-Phys. Andreas Wilke |
| 264 | 1 | |a Berlin |c 2014 | |
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Record in the Search Index
| _version_ | 1804151966759124992 |
|---|---|
| adam_text | CONTENTS
1 INTRODUCTION
6
2 FUNDAMENTALS
12
2.1 PHOTOELECTRON SPECTROSCOPY 12
2.1.1 FUNDAMENTAL PRINCIPLES 12
2.1.2 EVALUATION OF PHOTOEMISSION SPECTRA 15
2.2 ELECTRONIC STRUCTURE OF CONJUGATED ORGANIC MOLECULES 19
2.2.1 THE ISOLATED CONJUGATED ORGANIC MOLECULE 19
2.2.2 MOLECULAR ORGANIC THIN FILMS 23
2.3 ENERGY LEVEL ALIGNMENT MECHANISMS AT INTERFACES 26
2.3.1 ORGANIC/ELECTRODE INTERFACES 26
2.3.2 ORGANIC/ORGANIC INTERFACES 29
2.4 STRUCTURAL PROPERTIES OF SOLID MOLECULAR FILMS 33
2.4.1 VACUUM SUBLIMED MOLECULAR FILMS 33
2.4.2 ORIENTATION OF THE MOLECULAR LAYER 35
2.5 QUASI-FERMI LEVEL DISTRIBUTIONS OF AN ILLUMINATED SEMICONDUCTOR 37
2.5.1 FERMI ENERGY
AND ELECTROCHEMICAL POTENTIAL 38
2.5.2 QUASI FERMI LEVEL SPLITTING
AND CHARGE CURRENT 40
2.5.3 IV-CHARACTERISTICS OF A PN-JUNCTION SOLAR CELL 41
2.6 ELECTROSTATIC MODEL FOR ORGANIC PHOTOVOLTAIC CELLS 43
2.6.1 ANALYTICAL EXPRESSION FOR THE OPEN CIRCUIT VOLTAGE (V
OC
) 43
2.6.2 ELECTRICAL RESISTANCE NEAR V
OR
46
2.6.3 V RELATED ENERGY LOSS 47
2.7 EQUIVALENT CIRCUIT MODEL FOR ORGANIC PHOTOVOLTAIC CELLS 49
3 MATERIALS AND EXPERIMENTAL SETUPS
51
3.1 MATERIALS 51
3.1.1 INDIUM TIN OXIDE 51
3.1.2 HOLE TRANSPORT LAYERS 51
3.1.3 ORGANIC SEMICONDUCTORS 52
3.1.4 TOP CONTACTS 53
3.2 EXPERIMENTAL SETUPS 54
4 RESULTS AND DISCUSSION
56
4.1 ORGANIC/CONDUCTING POLYMER INTERFACES 56
4.1.1 FERMI LEVEL PINNING 56
4.1.2 NEUTRAL VS. P-DOPED DIINDENOPERYLENE CONTACT 60
4.1.3 POLARIZATION ALIGNMENT 63
4.1.4 ENERGY LEVEL DIAGRAMS 65
4.2 ELECTRONIC STRUCTURE OF D/A HETEROJUNCTIONS 68
4.2.1 COPPER PHTALOCYANINE/FULLERENE HETEROJUNCTIONS 68
4.2.2 COPPER PHTALOCYANINE/HEXADECAFLUOROPHTHALOCYANINE
HETEROJUNCTIONS 73
HTTP://D-NB.INFO/1049349415
4.2.3 LAYERED DIINDENOPERYLENE/FULLERENE HETEROJUNCTIONS 80
4.2.4 CORRELATION BETWEEN D/A INTERFACE ENERGETICS AND V
OC
86
4.3 ELECTRONIC STRUCTURE OF TOP CONTACT INTERFACES 92
4.3.1 BATHOCUPROINE/C
60
HETEROJUNCTION 92
4.3.2 SAMARIUM/BATHOCUPROINE CONTACT 94
4.3.3 ENERGY LEVEL DIAGRAM OF THE
DIINDENOPERYLENE/C
60
ORGANIC SOLAR CELL 96
4.4 IV-CHARACTERISTICS OF DIINDENOPERYLENE/C
60
SOLAR CELLS 98
4.4.1 NEUTRAL VS. P-DOPED BOTTOM CONTACT 98
4.5 RECOMBINATION PROCESSES INSIDE OPVCS 101
4.5.1 INTENSITY DEPENDENT LOSSES OF V
OR
101
4.5.2 TEMPERATURE DEPENDENT LOSSES OF V 103
5 SUMMARY AND CONCLUSION
106
6 PUBLICATION LIST
112
BIBLIOGRAPHY
114
SELBSTSTANDIGKEITSERKLARUNG
133
ACKNOWLEDGEMENTS
134
|
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| author | Wilke, Andreas 1982- |
| author_GND | (DE-588)1047717697 |
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| dewey-full | 537.6226 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 537 - Electricity and electronics |
| dewey-raw | 537.6226 |
| dewey-search | 537.6226 |
| dewey-sort | 3537.6226 |
| dewey-tens | 530 - Physics |
| discipline | Chemie / Pharmazie Physik Elektrotechnik / Elektronik / Nachrichtentechnik Energietechnik |
| format | Thesis Book |
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| indexdate | 2024-07-10T01:03:13Z |
| institution | BVB |
| language | English |
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| physical | 134 Blätter Illustrationen, Diagramme |
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| spelling | Wilke, Andreas 1982- Verfasser (DE-588)1047717697 aut Electronic properties of interfaces in molecular organic photovoltaic cells von Dipl.-Phys. Andreas Wilke Berlin 2014 134 Blätter Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Literaturverzeichnis Blätter 114 - 132 Dissertation Humboldt-Universiät zu Berlin 2014 (DE-588)4113937-9 Hochschulschrift gnd-content Reproduziert als Wilke, Andreas Electronic properties of interfaces in molecular organic photovoltaic cells Berlin : MIK-Center GmbH, 2014 2 Mikrofiches (DE-604)BV041792935 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027140200&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Wilke, Andreas 1982- Electronic properties of interfaces in molecular organic photovoltaic cells |
| subject_GND | (DE-588)4113937-9 |
| title | Electronic properties of interfaces in molecular organic photovoltaic cells |
| title_auth | Electronic properties of interfaces in molecular organic photovoltaic cells |
| title_exact_search | Electronic properties of interfaces in molecular organic photovoltaic cells |
| title_full | Electronic properties of interfaces in molecular organic photovoltaic cells von Dipl.-Phys. Andreas Wilke |
| title_fullStr | Electronic properties of interfaces in molecular organic photovoltaic cells von Dipl.-Phys. Andreas Wilke |
| title_full_unstemmed | Electronic properties of interfaces in molecular organic photovoltaic cells von Dipl.-Phys. Andreas Wilke |
| title_short | Electronic properties of interfaces in molecular organic photovoltaic cells |
| title_sort | electronic properties of interfaces in molecular organic photovoltaic cells |
| topic_facet | Hochschulschrift |
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