Supported ionic liquids: fundamentals and applications
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Weinheim
Wiley-VCH
2014
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| ISBN: | 3527324291 9783527324293 9783527654789 |
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MARC
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| 245 | 1 | 0 | |a Supported ionic liquids |b fundamentals and applications |c ed. by Rasmus Fehrmann ... |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2014 | |
| 300 | |a XXI, 473 S. |b Ill., graph. Darst. | ||
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CONTENTS ,
PREFACE XV
LIST OF CONTRIBUTORS XVII
1
INTRODUCTION 1
RASMUS FEHRMANN, MARCO HAUMANN, AND ANDERS RIISAGER
1.1
A CENTURY OF SUPPORTED LIQUIDS 1
1.2
SUPPORTED IONIC LIQUIDS 2
1.3 APPLICATIONS IN CATALYSIS 5
1.4 APPLICATIONS IN SEPARATION 5
1.5 COATING OF HETEROGENEOUS CATALYSTS 6
1.6 MONOLAYERS OF IL ON SURFACES 7
1.7 CONCLUSION 7
REFERENCES 8
PART 1 CONCEPT AND BUILDING BLOCKS 11
2 INTRODUCING IONIC LIQUIDS 13
TOM WELTON
2.1 INTRODUCTION 13
2.2 PREPARATION 13
2.3 LIQUID RANGE 14
2.4 STRUCTURES 16
2.4.1 THE LIQUID/SOLID INTERFACE 17
2.4.2 THE LIQUID/GAS INTERFACE 19
2.5
PHYSICAL PROPERTIES 20
2.5.1 THE LIQUID/SOLID INTERFACE 21
2.5.2 THE LIQUID/GAS INTERFACE 21
2.5.3 POLARITY 22
2.5.4 CHROMATOGRAPHIC MEASUREMENTS AND THE ABRAHAM MODEL OF
POLARITY 24
2.5.5 INFINITE DILUTION ACTIVITY COEFFICIENTS 24
2.6
EFFECTS OF IONIC LIQUIDS ON'CHEMICAL REACTIONS 26
2.7
IONIC LIQUIDS AS PROCESS SOLVENTS IN INDUSTRY 29
2.8 SUMMARY 30
REFERENCES 31
HTTP://D-NB.INFO/1037407482
VI | CONTENTS
3 POROUS INORGANIC MATERIALS AS POTENTIAL SUPPORTS FOR IONIC LIQUIDS 37
WILHELM SCHWIEGER, THANGARAJ SELVAM, MICHAEL KLUMPP, AND
MARTIN HARTMANN
3.1 INTRODUCTION 37
3.2 POROUS MATERIALS - AN OVERVIEW 39
3.2.1 HISTORY 39
3.2.2 PORE SIZE 40
3.2.3 STRUCTURAL ASPECTS 41
3.2.4 CHEMISTRY 43
3.2.5 SYNTHESIS 43 ,
3.3 SILICA-BASED MATERIALS - AMORPHOUS 48
3.3.1 SILICA GELS 48
3.3.2 PRECIPITATED SILICAS 49
3.3.3 POROUS GLASS 49
3.4 LAYERED MATERIALS 51
3.5 MICROPOROUS MATERIALS 52
3.5.1 ZEOLITES 52
3.5.2 ALPOS/SAPOS 54
3.5.3 HIERARCHICAL POROSITY IN ZEOLITE CRYSTALS 55
3.6 ORDERED MESOPOROUS MATERIALS 56
3.6.1 SILICA-BASED CLASSICAL COMPOUNDS 58
3.6.2 PMOS 60
3.6.3 MESOPOROUS CARBONS 61
3.6.4 OTHER MESOPOROUS OXIDES 61
3.6.5 ANODIC OXIDIZED MATERIALS 62
3.7 STRUCTURED SUPPORTS AND MONOLITHIC MATERIALS 63
3.7.1 MONOLITHS WITH HIERARCHICAL POROSITY 64
3.7.2 HIERARCHICALLY STRUCTURED REACTORS 65
3.8 CONCLUSIONS 66
REFERENCES 66
4 SYNTHETIC METHODOLOGIES FOR SUPPORTED IONIC LIQUID MATERIALS 75
REINOUT MEIJBOOM, MARCO HAUMANN, THOMAS E. MIILLER, AND
NORMEN SZESNI
4.1 INTRODUCTION 75
4.2 SUPPORT MATERIALS 76
4.3 PREPARATION METHODS FOR SUPPORTED IONIC LIQUIDS 77
4.3.1 INCIPIENT WETNESS IMPREGNATION 77
4.3.2 FREEZE-DRYING 79
4.3.3 SPRAY COATING 80
4.3.4 CHEMICALLY BOUND IONIC LIQUIDS 82
4.3.5 IL*SILICA
HYBRID MATERIALS 89
4.4 SUMMARY 91
REFERENCES 91
CONTENTS | VII
PART II SYNTHESIS AND PROPERTIES 95
5 PORE VOLUME AND SURFACE AREA OF SUPPORTED IONIC LIQUIDS SYSTEMS 97
FLORIAN HEYM, CHRISTOPH KERN, JOHANNES THIESSEN,
AND ANDREAS JESS
5.1 EXAMPLE I: [EMIM][NTF
2
] ON POROUS SILICA 98
5.2 EXAMPLE II: SCILL CATALYST (COMMERCIAL NI CATALYST) COATED WITH
[BMIM][0CS0
4
] 99
ACKNOWLEDGMENTS 103
SYMBOLS 104
ABBREVIATIONS 104
REFERENCES 104
6 TRANSPORT PHENOMENA, EVAPORATION, AND THERMAL STABILITY OF SUPPORTED
IONIC LIQUIDS 105
FLORIAN HEYM, CHRISTOPH KERN, JOHANNES THIESSEN,
AND ANDREAS JESS
6.1 INTRODUCTION 105
6.2 DIFFUSION OF GASES AND LIQUIDS IN ILS AND DIFFUSIVITY OF ILS IN
GASES 106
6.2.1 DIFFUSIVITY OF GASES AND LIQUIDS IN ILS 106
6.2.2 DIFFUSION COEFFICIENT OF EVAPORATED ILS IN GASES 108
6.3 THERMAL STABILITY AND VAPOR PRESSURE OF PURE ILS 109
6.3.1 DRAWBACKS AND OPPORTUNITIES REGARDING STABILITY AND VAPOR PRESSURE
M EASUREMENTS OF I LS 109
6.3.2 EXPERIMENTAL METHODS TO DETERMINE THE STABILITY AND VAPOR PRESSURE
OFILS 110
6.3.3 DATA EVALUATION AND MODELING METHODOLOGY 110
6.3.3.1 EVALUATION OF VAPOR PRESSURE AND DECOMPOSITION OF ILS BY AMBIENT
PRESSURE TG AT CONSTANT HEATING RATE 110
6.3.3.2 EVALUATION OF VAPOR PRESSURE OF ILS BY HIGH VACUUM TG 114
6.3.4 VAPOR PRESSURE DATA AND KINETIC PARAMETERS OF DECOMPOSITION OF
PURE ILS 116
6.3.4.1 KINETIC DATA OF THERMAL DECOMPOSITION OF PURE ILS 116
6.3.4.2 VAPOR PRESSURE OF PURE ILS 116
6.3.5 GUIDELINES TO DETERMINE THE VOLATILITY AND STABILITY OF ILS 118
6.3.6 CRITERIA FOR THE MAXIMUM OPERATION TEMPERATURE OF ILS 118
6.3.6.1 MAXIMUM OPERATION TEMPERATURE OF ILS WITH REGARD TO THERMAL
DECOMPOSITION 118
6.3.6.2 MAXIMUM OPERATION TEMPERATURE OF ILS WITH REGARD TO
EVAPORATION 120
6.4 VAPOR PRESSURE AND THERMAL DECOMPOSITION OF SUPPORTED ILS 120
6.4.1 THERMAL DECOMPOSITION OF SUPPORTED ILS 121
6.4.2 MASS LOSS OF SUPPORTED ILS BY EVAPORATION 123
6.4.2.1 EVAPORATION OF ILS COATED ON SILICA-(SILP-SYSTEM) 123
6.4.2.2 EVAPORATION OF ILS COATED ON A NI-CATALYST (SCILL-SYSTEM) 132
6.4.2.3 EVALUATION OF INTERNAL SURFACE AREA BY THE EVAPORATION RATE OF
SUPPORTED ILS 132
VIIII
CONTENTS
6.4.3 CRITERIA FOR THE MAXIMUM OPERATION TEMPERATURE OF SUPPORTED
ILS 134
6.4.3.1 MAXIMUM OPERATION TEMPERATURE OF SUPPORTED ILS WITH REGARD TO
THERMAL STABILITY 134
6.4.3.2 MAXIMUM OPERATION TEMPERATURE OF SUPPORTED ILS WITH REGARD TO
EVAPORATION 135
6.5 OUTLOOK 137
ACKNOWLEDGMENTS 138
SYMBOLS 138
ABBREVIATIONS 140
REFERENCES 140 '
7 IONIC LIQUIDS AT THE GAS-LIQUID AND SOLID-LIQUID INTERFACE -
CHARACTERIZATION AND PROPERTIES 145
ZLATA GRENOBLE AND STEVEN BALDELLI
7.1 INTRODUCTION 145
7.2 CHARACTERIZATION OF IONIC LIQUID SURFACES BY SPECTROSCOPIC
TECHNIQUES 146
7.2.1 TYPES OF INTERFACIAL SYSTEMS INVOLVING IONIC LIQUIDS 146
7.2.2 OVERVIEW OF SURFACE ANALYTICAL TECHNIQUES FOR CHARACTERIZATION OF
IONIC LIQUIDS 146
7.2.3 STRUCTURAL AND ORIENTATIONAL ANALYSIS OF IONIC LIQUIDS AT THE
GAS-LIQUID INTERFACE 147
7.2.3.1 PRINCIPLES OF SUM-FREQUENCY VIBRATIONAL SPECTROSCOPY 147
7.2.4 CATION-SPECIFIC IONIC LIQUID ORIENTATIONAL ANALYSIS 148
7.2.5 ANION-SPECIFIC IONIC LIQUID ORIENTATIONAL ANALYSIS 154
7.2.6 IONIC LIQUID INTERFACIAL ANALYSIS BY OTHER SURFACE-SPECIFIC
TECHNIQUES 157
7.2.7 IONIC LIQUID EFFECTS ON SURFACE TENSION 162
7.2.8 IONIC LIQUID EFFECTS ON SURFACE CHARGE DENSITY 163
7.3 ORIENTATION AND PROPERTIES OF IONIC LIQUIDS AT THE SOLID-LIQUID
INTERFACE 165
7.3.1 SURFACE ORIENTATIONAL ANALYSIS OF IONIC LIQUIDS ON DRY SILICA 165
7.3.2 CATION ORIENTATIONAL ANALYSIS 166
7.3.3 ALKYL CHAIN LENGTH EFFECTS ON ORIENTATION 167
7.3.4 COMPETING ANIONS AND CO-ADSORPTION 168
7.3.5 COMPUTATIONAL SIMULATIONS OF IONIC LIQUID ON SILICA 168
7.3.6 IONIC LIQUIDS ON TITANIA (TI0
2
) 170
7 A COMMENTS 172
REFERENCES 173
8 SPECTROSCOPY ON SUPPORTED IONIC LIQUIDS 177 .
PETER S. SCHULZ
8.1 NMR-SPECTROSCOPY 178
8.1.1 SPECTROSCOPY OF SUPPORT AND IL 178
CONTENTS IIX
8.1.2 SPECTROSCOPY OF THE CATALYST 183
8.2 IR SPECTROSCOPY 186
REFERENCES 189
9 A PRIORI SELECTION OF THE TYPE OF IONIC LIQUID 191
WOLFGANG ARLT AND ALEXANDER BUCHELE
9.1 INTRODUCTION AND OBJECTIVE 191
9.2 METHODS 191
9.2.1 EXPERIMENTAL DETERMINATION OF GAS SOLUBILITIES 192
9.2.1.1 MAGNETIC SUSPENSION BALANCE 192
9.2.1.2 ISOCHORIC SOLUBILITY CELL 194
9.2.1.3 INVERSE GAS CHROMATOGRAPHY 295
9.2.2 PREDICTION OF GAS SOLUBILITIES WITH COSMO-RS 196
9.2.3 REACTION EQUILIBRIUM AND REACTION KINETICS 197
9.3 USAGE OF COSMO-RS TO PREDICT SOLUBILITIES IN IL 198
9.4 RESULTS OF REACTION MODELING 201
9.5 PERSPECTIVES OF THE A PRIORI SELECTION OF I LS 202
REFERENCES 205
PART III CATALYTIC APPLICATIONS 209
10 SUPPORTED IONIC LIQUIDS AS PART OF A BUILDING-BLOCK SYSTEM FOR
TAILORED
CATALYSTS 211
THOMAS E. MIILLER
10.1 INTRODUCTION 211
10.2 IMMOBILIZED CATALYSTS 212
10.3 SUPPORTED IONIC LIQUIDS 214
10.4 THE BUILDING BLOCKS 215
10.4.1 IONIC LIQUID 215
10.4.2 SUPPORT 216
10.4.3 CATALYTIC FUNCTION 218
10.4.3.1 TYPE A1 - TASK SPECIFIC IL 219
10.4.3.2 TYPE A2 - IMMOBILIZED HOMOGENEOUS CATALYSTS AND METAL
NANOPARTICLES 219
10.4.3.3 TYPE B - HETEROGENEOUS CATALYSTS COATED WITH IL 221
10.4.3.4 TYPE C - CHEMICALLY BOUND MONOLAYERS OF IL 221
10.4.4 ADDITIVES AND PROMOTERS 222
10.4.5 PREPARATION AND CHARACTERIZATION OF CATALYSTS INVOLVING SUPPORTED
ILS 222
10.5 CATALYSIS IN SUPPORTED THIN FILMS OF IL 222
10.6 SUPPORTED FILMS OF IL IN CATALYSIS 223
10.6.1 HYDROGENATION REACTIONS 224
10.6.2 HYDROAMINATION 225
10.7 ADVANTAGES AND DRAWBACKS OF THE CONCEPT 228
10.8 CONCLUSIONS 229
X I
CONTENTS
ACKNOWLEDGMENTS 229
REFERENCES 229
11 COUPLING REACTIONS WITH SUPPORTED IONIC LIQUID CATALYSTS 233
ZHENSHAN HOU AND BUXING HAN
11.1 INTRODUCTION 233
11.2 A SHORT HISTORY OF SUPPORTED IONIC LIQUIDS 234
11.3 PROPERTIES OF SIL 234
11.4 APPLICATION OF SIL IN COUPLING REACTIONS 235
11.4.1 C-C COUPLING REACTIONS 235
11.4.1.1 STILLE CROSS COUPLING REACTIONS 235
11.4.1.2 FRIEDEL-CRAFTS ALKYLATION 235
11.4.1.3 OLEFIN HYDROFORMYLATION REACTION 236
11.4.1.4 METHANOL CARBONYLATION 237
11.4.1.5 SUZUKI COUPLING REACTIONS 237
11.4.1.6 HECK COUPLING REACTIONS 239
11.4.1.7 DIELS-ALDER CYDOADDITION 241
11.4.1.8 MUKAIYAMA REACTION 242
11.4.1.9 BIGLINELLI REACTION 242
11.4.1.10 OLEFIN METATHESIS REACTION 243
11.4.2 C-N COUPLING REACTION 243
11.4.2.1 HYDROAMINATION 243
11.4.2.2 N-ARYLATION OF N-CONTAINING HETEROCYCLES 244
11.4.2.3 HUISGEN [3+2] CYDOADDITION 244
11.4.3 MISCELLANEOUS COUPLING REACTION 244
11.5 CONDUSION 246
REFERENCES 246
12 SELECTIVE HYDROGENATION FOR FINE CHEMICAL SYNTHESIS 251
PASI VIRTANEN, EERO SALMINEN, PAIVI MAKI-ARVELA, AND JYRI-PEKKA MIKKOLA
12.1 INTRODUCTION 251
12.2 SELECTIVE HYDROGENATION OF A,P-UNSATURATED ALDEHYDES 251
12.3 ASYMMETRIC HYDROGENATIONS OVER CHIRAL METAL COMPLEXES
IMMOBILIZED IN SILCAS 257
12.4 CONCLUSIONS 261
REFERENCES 261
13 HYDROGENATION WITH NANOPARTIDES USING SUPPORTED IONIC LIQUIDS 263
JACKSON D. SCHOLTEN AND JAIRTON DUPONT
13.1 INTRODUCTION 263
13.2 MNPS DISPERSED IN ILS: GREEN CATALYSTS FOR MULTIPHASE
REACTIONS 264
13.3 MNPS IMMOBILIZED ON SUPPORTED IONIC LIQUIDS: ALTERNATIVE MATERIALS
FOR CATALYTIC REACTIONS 267
13.4 CONDUSIONS 275
REFERENCES 275
CONTENTS | XI
14 SOLID CATALYSTS WITH IONIC LIQUID LAYER (SCILL) 279
WOLJGANG KORTH AND ANDREAS JESS
14.1 INTRODUCTION 279
14.2 CLASSIFICATION OF APPLICATIONS OF IONIC LIQUIDS IN HETEROGENEOUS
CATALYSIS 280
14.3 PREPARATION AND CHARACTERIZATION OF THE PHYSICAL PROPERTIES OF THE
SCILL SYSTEMS 283
14.3.1 PREPARATION OF SCILL CATALYSTS 283
14.3.2 NERNST PARTITION COEFFICIENTS 284
14.3.3 PORE VOLUME AND SURFACE AREA OF THE SCILL CATALYST WITH
[BMIM][0CS0
4
] AS IL 287
14.4 KINETIC STUDIES WITH SCILL CATALYSTS 287
14.4.1 EXPERIMENTAL 287
14.4.2 HYDROGENATION OF 1,5-CYCLOOCTADIENE (COD) 288
14.4.2.1 REACTION STEPS OF 1,5-COD HYDROGENATION ON THE INVESTIGATED NI
CATALYST 288
14.4.2.2 INFLUENCE OF ILCOATING OF THE NI CATALYST ON THE SELECTIVITY OF
COD
HYDROGENATION 288
14.4.2.3 INFLUENCE OF IL COATING OF THE CATALYST ON THE RATE OF COD
HYDROGENATION 293
14.4.2.4 INFLUENCE OF PORE DIFFUSION ON THE EFFECTIVE RATE OF COD
HYDROGENATION 293
14.4.2.5 INFLUENCE OF PORE DIFFUSION ON THE SELECTIVITY OF COD
HYDROGENATION 295
14.4.2.6 STABILITY OF THE IL LAYER AND DEACTIVATION OF IL-COATED
CATALYST 297
14.4.3 HYDROGENATION OF OCTINE, CINNAMALDEHYDE, AND NAPHTHALENE WITH
SCILL CATALYSTS 297
14.4.4 HYDROGENATION OF CITRAL WITH SCILL CATALYSTS 298
14.5 CONCLUSIONS AND OUTLOOK 300
ACKNOWLEDGMENTS 300
SYMBOLS USED 300
GREEK SYMBOLS 301
ABBREVIATIONS AND SUBSCRIPTS 301
REFERENCES 302
15 SUPPORTED IONIC LIQUID
PHASE (SILP) MATERIALS IN HYDROFORMYLATION
CATALYSIS 307
ANDREAS SCHONWEIZ AND ROBERT
FRANKE
15.1 SILP MATERIALS IN LIQUID-PHASE HYDROFORMYLATION
REACTIONS 307
15.2 GAS-PHASE SILP HYDROFORMYLATION CATALYSIS 311
15.3 SILP COMBINED WITH SCC0
2
- EXTENDING THE SUBSTRATE
RANGE 339
15.4 CONTINUOUS SILP GAS-PHASE METHANOL CARBONYLATION 322
XII
| CONTENTS
15.5 CONCLUSION AND FUTURE POTENTIAL 323
REFERENCES 324
16 ULTRALOW TEMPERATURE WATER-CAS SHIFT REACTION ENABLED BY SUPPORTED
IONIC LIQUID PHASE CATALYSTS 327
SEBASTIAN WERNER AND MARCO HAUMANN
16.1 INTRODUCTION TO WATER-GAS SHIFT REACTION 327
16.1.1 HETEROGENEOUS WGS CATALYSTS 327
16.1.2 HOMOGENEOUS WGS CATALYSTS 329
16.2 CHALLENGES 332-
16.3 SILP CATALYST DEVELOPMENT 332
1
16.4 BUILDING-BLOCK OPTIMIZATION 333
16.4.1 CATALYST PRECURSOR 334
16.4.2 SUPPORT MATERIAL 335
16.4.3 1L VARIATION 337
16.4.4 CATALYST LOADING 338
16.4.5 IL LOADING 339
16.4.6 COMBINATION OF OPTIMIZED PARAMETERS 340
16.5 APPLICATION-SPECIFIC TESTING 341
16.5.1 RESTART BEHAVIOR 341
16.5.2 INDUSTRIAL SUPPORT MATERIALS 343
16.5.3 ELEVATED PRESSURE 345
16.5.4 REFORMATE SYNTHESIS GAS TESTS 346
16.6 CONCLUSION 348
REFERENCES 348
17 BIOCATALYTIC PROCESSES BASED ON SUPPORTED IONIC LIQUIDS 351
EDUARDO GARCFA-VERDUGO, PEDRO LOZANO, AND
SANTIAGO V. LUIS
17.1 INTRODUCTION AND GENERAL CONCEPTS 351
17.1.1 ENZYMES AND IONIC LIQUIDS 351
17.1.2 SUPPORTED ILS FOR BIOCATALYTIC PROCESSES 353
17.1.3 REACTOR CONFIGURATIONS WITH SUPPORTED ILS FOR BIOCATALYTIC
PROCESSES 355
17.2 BIOCATALYSTS BASED ON SUPPORTED IONIC LIQUID PHASES
(SILPS) 356
17.3 BIOCATALYSTS BASED ON COVALENTLY SUPPORTED IONIC LIQUID-LIKE PHASES
(SILLPS) 360
17.4 CONCLUSIONS/FUTURE TRENDS AND PERSPECTIVES 365
ACKNOWLEDGMENTS 365
REFERENCES 365
18 SUPPORTED IONIC LIQUID
PHASE CATALYSTS WITH SUPERCRITICAL FLUID
FLOW 369
RUBTN DUQUE AND DAVID J. COLE-HAMILTON
18.1 INTRODUCTION 369
18.2 SILP CATALYSIS 369
CONTENTS I XIII
18.2.1 LIQUID-PHASE REACTIONS 369
18.2.2 GAS-PHASE REACTIONS 370
18.2.3 SUPERCRITICAL FLUIDS 371
18.2.4 SCF IL BIPHASIC SYSTEMS 372
18.2.5 SILP CATALYSIS WITH SUPERCRITICAL FLOW 375
REFERENCES 381
PART IV SPECIAL APPLICATIONS 385
19 PHARMACEUTICAL^ ACTIVE SUPPORTED IONIC LIQUIDS 387
O. ANDREEA COJOCARU, AMAL SIRIWARDANA, GABRIELA GURAU, AND
ROBIN D. ROGERS
19.1 ACTIVE PHARMACEUTICAL INGREDIENTS IN IONIC LIQUID FORM 387
19.2 SOLID-SUPPORTED PHARMACEUTICALS 389
19.3 SILICA MATERIALS FOR DRUG DELIVERY 389
19.4 FACTORS THAT INFLUENCE THE LOADING AND RELEASE RATE OF DRUGS 391
19.4.1 ADSORPTIVE PROPERTIES (PORE SIZE, SURFACE AREA, PORE VOLUME) OF
MESOPOROUS MATERIALS 391
19.4.1.1 PORE SIZE 391
19.4.1.2 SURFACE AREA 392
19.4.1.3 PORE VOLUME 392
19.4.2 SURFACE FUNCTIONALIZATION OF MESOPOROUS MATERIALS 392
19.4.3 DRUG LOADING PROCEDURES 394
19.4.3.1 COVALENT ATTACHMENT 394
19.4.3.2 PHYSICAL TRAPPING 394
19.4.3.3 ADSORPTION 395
19.5 SILPS APPROACH FOR DRUG DELIVERY 395
19.5.1 ILS CONFINED ON SILICA 395
19.5.2 API-ILS CONFINED ON SILICA 396
19.5.2.1 SYNTHESIS AND CHARACTERIZATION OF SILP MATERIALS 396
19.5.2.2 RELEASE STUDIES OF THE API-ILS FROM THE SILP MATERIALS 399
19.6 CONCLUSIONS 402
REFERENCES 402
20 SUPPORTED PROTIC IONIC LIQUIDS IN POLYMER MEMBRANES FOR ELECTROLYTES
OF NONHUMIDIFIED FUEL CELLS 407
TOMOHIRO YASUDA AND MASAYOSHI WATANABE
20.1 INTRODUCTION 407
20.2 PROTIC ILS AS ELECTROLYTES FOR FUEL CELLS 409
20.2.1 PROTIC ILS 409
20.2.2 THERMAL STABILITY OF PROTIC IL 410
20.2.3 PILS PREFERABLE FOR FUEL CELL APPLICATIONS 411
20.3 MEMBRANE FABRICATION INCLUDING PIL AND FUEL CELL OPERATION 411
20.3.1 MEMBRANE PREPARATION 411
20.3.2 FUEL CELL OPERATION USING SUPPORTED PILS IN MEMBRANES 414
XIV CONTENTS
20.4 PROTON CONDUCTING MECHANISM DURING FUEL CELL OPERATION 415
20.5 CONCLUSION 417
ACKNOWLEDGMENTS 418
REFERENCES 418
21 CAS SEPARATION USING SUPPORTED IONIC LIQUIDS 419
MARCO HAUMANN
21.1 SILP MATERIALS 419
21.1.1 SILP-FACILITATED GC 423
21.2 SUPPORTED IONIC EIQUID MEMBRANES (SILMS) 428
21.2.1 GAS SEPARATION 429
21.2.2 GAS SEPARATION AND REACTION 437
21.3 CONCLUSION 440
REFERENCES 441
22 IONIC LIQUIDS ON SURFACES - A PLETHORA OF APPLICATIONS 445
THOMAS J. S. SCHUBERT
22.1 INTRODUCTION 445
22.2 THE INFLUENCE OF ILS ON SOLID-STATE SURFACES 445
22.3 LAYERS OF ILS ON SOLID-STATE SURFACES 446
22.4 SELECTED APPLICATIONS 446
22.5 SENSORS 447
22.6 ELECTROCHEMICAL DOUBLE LAYER CAPACITORS (SUPERCAPACITORS) 449
22.7 DYE SENSITIZED SOLAR CELLS 451
22.8 LUBRICANTS 452
22.9 SYNTHESIS AND DISPERSIONS OF NANOPARTIDES 453
REFERENCES 454
PART V OUTLOOK 457
23 OUTLOOK - THE TECHNICAL PROSPECT OF SUPPORTED IONIC LIQUID
MATERIALS 459
PETER WASSERSCHEID
23.1 COMPETITIVE ADVANTAGE 460
23.2 OBSERVABILITY 462
23.3 TRIALABILITY 462
23.4 COMPATIBILITY 463
23.5 COMPLEXITY 463
23.6 PERCEIVED RISK 464
REFERENCES 465
INDEX 467 |
| any_adam_object | 1 |
| author2 | Fehrmann, Rasmus |
| author2_role | edt |
| author2_variant | r f rf |
| author_GND | (DE-588)1046918974 |
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| building | Verbundindex |
| bvnumber | BV041595042 |
| classification_rvk | VE 6350 |
| ctrlnum | (OCoLC)869891321 (DE-599)DNB1037407482 |
| dewey-full | 541.372 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.372 |
| dewey-search | 541.372 |
| dewey-sort | 3541.372 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV041595042 |
| illustrated | Illustrated |
| indexdate | 2024-08-03T01:13:30Z |
| institution | BVB |
| isbn | 3527324291 9783527324293 9783527654789 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027040027 |
| oclc_num | 869891321 |
| open_access_boolean | |
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| owner_facet | DE-703 DE-11 DE-29T DE-355 DE-BY-UBR DE-19 DE-BY-UBM |
| physical | XXI, 473 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Supported ionic liquids fundamentals and applications ed. by Rasmus Fehrmann ... Weinheim Wiley-VCH 2014 XXI, 473 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Catalysis Ionische Flüssigkeit (DE-588)7548899-1 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Ionische Flüssigkeit (DE-588)7548899-1 s DE-604 Fehrmann, Rasmus (DE-588)1046918974 edt Erscheint auch als Online-Ausgabe, EPUB 978-3-527-65480-2 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-65479-6 Erscheint auch als Online-Ausgabe, PDF 978-3-527-65481-9 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4387106&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027040027&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Supported ionic liquids fundamentals and applications Catalysis Ionische Flüssigkeit (DE-588)7548899-1 gnd |
| subject_GND | (DE-588)7548899-1 (DE-588)4143413-4 |
| title | Supported ionic liquids fundamentals and applications |
| title_auth | Supported ionic liquids fundamentals and applications |
| title_exact_search | Supported ionic liquids fundamentals and applications |
| title_full | Supported ionic liquids fundamentals and applications ed. by Rasmus Fehrmann ... |
| title_fullStr | Supported ionic liquids fundamentals and applications ed. by Rasmus Fehrmann ... |
| title_full_unstemmed | Supported ionic liquids fundamentals and applications ed. by Rasmus Fehrmann ... |
| title_short | Supported ionic liquids |
| title_sort | supported ionic liquids fundamentals and applications |
| title_sub | fundamentals and applications |
| topic | Catalysis Ionische Flüssigkeit (DE-588)7548899-1 gnd |
| topic_facet | Catalysis Ionische Flüssigkeit Aufsatzsammlung |
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