Aggregation induced emission: [2] Applications
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| Format: | Book |
| Language: | English |
| Published: |
Chichester
Wiley
2013
|
| Edition: | 1. publ. |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | XIV, 277 S. Ill., graph. Darst. |
| ISBN: | 9781118701768 |
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|---|---|
| adam_text | Contents
List of Contributors
xi
Preface
xiii
1
AIE or
AIEE Materials for Electroluminescence Applications
1
Ciucio-
Wen Lin and Chin-Ti Chen
Introduction
1
1
.2
EL Background, EL Efficiency, Color Chromaticity, and Fabrication Issues of OLEDs
2
1.3
AIE
or AIEE Silole Derivatives for OLEDs
7
1
.4
AIE
or AIEE Maleimide and Pyrrole Derivatives for OLEDs
10
1
.5
AIE
or AIEE Cyano-Substituted StiJbenoid and Distyrylbenzene Derivatives for OLEDs
14
1.6
AIE
or AIEE Triarylamine Derivatives for OLEDs
17
1
.7
AIE
or AIEE Triphenylethene and Tetraphenylethene Derivatives for OLEDs
17
1.8
White OLEDs Containing
AIE
or AIEE Materials
31
1
.9
Perspectives
36
References
37
2
Crystallization-Induced Phosphorescence for Purely Organic Phosphors at Room
Temperature and Liquid Crystals with Aggregation-Induced Emission Characteristics
43
Wang Zhang Yuan, Yongming Zhang and Ben Zhong Tang
2.1
Crystallization-Induced Phosphorescence for Purely Organic Phosphors at Room
Temperature
43
2.1.1
Introduction
43
2.1.2
Molecular luminogens with crystallization-induced phosphorescence at room
temperature
44
2.2
Liquid Crystals with Aggregation-Induced Emission Characteristics
52
2.2.1
Luminescent liquid crystals
52
2.2.2
Aggregation-induced emission strategy towards high-efficiency luminescent
liquid crystals
53
2.3
Conclusions and Perspectives
57
References
58
3
Mechanochromic Aggregation-Induced Emission Materials
61
Zhenguo Chi and
Латі
Хи
3.1
Introduction
61
3.2
Mechanochromic Non-AIE Compounds
62
3.3
Mechanochromic
AIE
Compounds
64
vi
Contents
3.4
Conclusion
^-
References
·
4
Chiral Recognition and Enantiomeric Excess Determination Based on
Aggregation-Induced Emission
N7
Yan-Song Zlwiiii
4.1
Introduction to Chiral Recognition
^7
4.2
Chiral Recognition and Enantiomeric Excess Determination of Chiral
Animes
X8
4.3
Chiral Recognition and Enantiomeric Excess Determination ol Chiral Acids
Л
4.3.1
Enantiomeric excess determination ol chiral acids using
chira)
AIE
amines
1Л
4.3.2
Enantiomeric excess determination ol
chira!
acids using a chiral
receptor in the presence ol an
AIE
compound
УХ
4.4
Mechanism of Chiral Recognition Based on
AIE
I (H
4.4.1
Mechanism of chiral recognition by a chiral
AIE
monoamine
102
4.4.2
Mechanism ol chiral recognition by a chiral
ΛΙΕ
diamine
102
4.5
Prospects for Chiral Recognition Based on
AIE
104
References
105
5
AIE
Materials Towards Efficient Circularly Polarized Luminescence,
Organic Easing, and Superampiitied Detection of Explosives
107
Jianzliao Liu, Jacky W. Y. Lain and lien Zhang
ľany,
5.1
Introduction
107
5.2
AIE
Materials with Ki
licioni
Circularly Polarized Luminescence and
Large Dissymmetry Factor
107
5.2.1
Aggregation-induced circulardichroism
IOS
5.2.2
AIE.
fluorescence decay dynamics and theoretical understanding I
10
5.2.3
Aggregation-induced circularly polarized luminescence I
13
5.2.4
Supramoleeular assembly and structural modeling 1
15
5.3
AIE
Materials for Organic Lasing I I
8
5.3.1
Fabrication of nano-structures
118
5.3.2
Lasing performances
119
5.4
AIE
Materials for Superamplified Detection of Explosives
12
1
5.4.1
Hyperbranched polymer-based sensor
122
5.4.2
Mesoporous material-based sensor
127
5.5
Conclusion
127
References 1
28
6
Aggregation-Induced Emission and Applications of Aryl-Substituted Pyrrole
Derivatives
131
Bin
Tong
and Yuping
Doux
6.1
Introduction 1
3
1
6.2
Luminescence Properties of
Triphenylpyrrole
Derivatives in the Aggregated State
132
6.3
Applications
136
6.4
Aggregation-Induced Emission of Pentaphenylpyrrole
147
6.5
AIEE Mechanism of Pentaphenylpyrrole
150
6.6
Conclusion
152
References
152
Contents
vii
7 Biogenic
Amine
Sensing with Aggregation-Induced Emission-Active Tetraphenylethenes
157
Takanobu Sanji
and
Manato
Tanaka
7.1
Introduction
157
7.1.1
Biogenic amines
157
7.1.2
Sensing methods for biogenic amines
157
7.2
Fluorimetrie
Sensing of Biogenic Amines with AIE-Active TPEs
158
7.2.1
Design for
fluorimetrie
sensing of biogenic amines
158
7.2.2
Sensing studies and statistical analysis
158
7.2.3
Determination of
histamine
concentration
162
7.2.4
Fluorimetrie
sensing of melamine with AIE-active TPEs
163
7.3
Summary and Outlook
163
References
164
8
New Chemo-ZBiosensors with Silole and Tetraphenylethene Molecules Based
on the Aggregation and Deaggregation Mechanism
165
Ming Wang, Guanxin Zhang and Deqing Zhang
8.1
Introduction
165
8.2
Cation and
Anion
Sensors
166
8.3
Fluorimetrie
Biosensors for Biomacromolecules
169
8.4
Fluorimetrie
Assays for Enzymes
173
8.5
Fluorimetrie
Detection of Physiologically Important Small Molecules
180
8.6
Miscellaneous Sensors
183
8.7
Conclusion and Outlook
185
References 1
85
9
Carbohydrate-Functionalized AIE-Active Molecules as Luminescent Probes for
Biosensing
189
Qi Chen and Bao-Hang Han
9.1
Introduction
189
9.2
Carbohydrate-Bearing AIE-Active Molecules
190
9.2.1
Carbohydrate-bearing siloles
191
9.2.2
Carbohydrate-bearing phosphole oxides
192
9.2.3
Carbohydrate-bearing tetraphenylethenes
193
9.3
Luminescent Probes for Lectins
195
9.4
Luminescent Probes for Enzymes
199
9.5
Luminescent Probes for Viruses and Toxins
203
9.6
Conclusion
205
Acknowledgments
205
References
205
10
Aggregation-Induced Emission Dyes for In Vivo Functional Bioimaging
209
Jun
Qian, Dan Wang and Sailing He
10.1
Introduction
209
1
0.2
AIE
Dyes for Macro In Vivo Functional Bioimaging
210
10.2.1
AIE
dye-encapsulated phospholipid-PEG nanomicelles
210
10.2.2
AIE
dye-encapsulated nanomicelles for SLN mapping of mice
210
10.2.3
AIE
dye-encapsulated nanomicelles for tumor targeting of mice
216
viii Contents
10.2.4
Other types
oí
AIB-nanoparticles
l or
in vivo functional bioimaging
22
1
10.3
Multiphoton-Inducecl Fluorescence from
AIE
Dyes and Applications in
In Vivo Functional Microscopic Imaging
223
10.3.1
Two- and three-photon-inducod fluorescence of
ΑΙ Β
dyes
223
10.3.2
AIE
dye-encapsulated nanomicelles for iwo-pholon blood vessel imaging
of live mice
—
10.3.3
AIE
dye-encapsulated nanomicelles lor two-photon brain imaging
of live mice
-■
10.4
Summary and Perspectives
232
Acknowledgments
234
References
234
11
Specific Light-Up
Bioprobes
with Aggregation-Induced Emission Characteristics
for Protein Sensing 23M
J
ing Liang, Huibin Shi, Ben Zhang Tang and Bin Liu
11.1
Introduction
239
1
1.2
In Vitro Detection of
Integrin
ανβ
ţ
Using
и
TPS-Based Probe 240
11.2.1
Detection mechanisms
241
11.2.2
Synthesis and characterization of the TPS^cRGI) probe
24
1
11.2.3
Detection of integrin in solutions
243
1
1.2.4
In vitro sensing of
integrili in
cancer cells
244
11.3
Real-Time Monitoring of Cell Apoptosis and Drug Screening with a TPF-Based
hohe 245
1
1.3.1
Design principles
245
1
1.3.2
Synthesis and characterization oi Ac-DEVHK-TPE probe
246
11.3.3
Detection ofcaspase and kinetic study ofcaspase activities in solutions
247
1 1.3.4
Imaging of cell apoptosis and screening of apoplosis-indueing agents 24K
11.4
In Vivo Monitoring of Cell Apoptosis and Drug Screening with PyTPF-Bascd Probe
251
1
1.4.1
Working principles
251
1
1.4.2
Synthesis and characterization of DHVD-PyTPH probe
252
1
1
.4.3
Monitoring ofcaspase activities in solutions
253
11.4.4
In vitro and in vivo imaging of cell apoptosis
253
11.5
Conclusion
255
Acknowledgments
255
References
256
12
Applications of Aggregation-Induced Emission Materials in Biotechnology
259
Yuning Hong, Jacky W.Y. Lam ami Ben Zlwng Tang
12.1
Introduction
259
12.2
AIE
Materials for Nucleic Acid Studies
260
12.2.1
Quantitation and gel visualization of
DNA
and
RNA
260
12.2.2
Specific probing of G-quadruplex
DNA
formation
262
12.3
AIE
Materials for Protein Studies
263
12.3.1
Quantitation and PAGE staining of proteins
263
12.3.2
Fluorescence immunoassay by
AIE
materials
266
12.3.3
Monitoring of the unfolding/refolding process of human serum albumin
266
12.3.4
Monitoring and inhibition of amyloid fibrillation of insulin
267
Contents
¡χ
12.4
АІБ
Materials
for Live Cell Imaging 269
12.4.1
AIE bioprobes
for long-term cell tracking
269
12.4.2
AIE
nanoparticles for cell staining 2()9
12.5
Conclusion 271
979
References
Ł
L
inde,
275
AGGREGATION-INDUŒD
EMISSION
APPLICATIONS
EDITORS
ANJUN QIN
Department
of Polymer
Science and Engineering,
Zhejiang University, China
BEN ZHONG
TANG
Department
of Chemistry, The
Hong Kong
University of
Science
and Technology, China
Aggregation-Induced Emission
(AIE) ¡s a
novel photophysical phenomenon which offers a new platform
for researchers to look into the light-emitting processes from luminogen aggregates, from which useful
information on structure-property relationships may be collected and mechanistic insights may be
gained. The discovery of the
AIE
effect opens a new avenue for the development of new luminogen
materials in the aggregate or solid state. By enabling light emission in the practically useful solid state,
AIE
has the potential to significantly expand the technological applications of luminescent materials.
Aggregation-Induced Emission: Applications is the first book to explore the high-tech applications
of
AIE luminogens,
including technological utilizations of
AIE
materials in the areas of
electroluminescence, imechanochromism, chiral recognition, ionic sensing,
biomolecule
detection, and
cell imaging. Potential applications in room temperature phosphorescence, liquid crystals, circularly
polarized luminescence, and organic lasing are also introduced in this volume.
Topics covered include:
•
AIE
materials for electroluminescence applications
•
Liquid crystals with
AIE
characteristics
•
Mechanochromic
AIE
materials
•
Chiral recognition and enantiomeric differentiation based on
AIE
•
AIE
and applications of aryl-substituted pyrrole derivatives
New chemoVbiosensors with AlE-active molecules
•
AIE
luminogens for in vivo functional bioimaging
•
Applications of
AIE
materials in biotechnology
This book is essential reading for scientists and engineers who are designing optoelectronic materials
and
biomedical
sensors, and will also be of interest to academic researchers in materials science,
physical and synthetic organic chemistry as well as physicists and biological chemists.
Also available
as an e-book
ISBN
978-1-118-70176-8
9 781118 701768
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| spelling | Aggregation induced emission [2] Applications ed. by Anjun Qin ... 1. publ. Chichester Wiley 2013 XIV, 277 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Qin, Anjun edt (DE-604)BV041459875 2 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026906728&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026906728&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Aggregation induced emission |
| title | Aggregation induced emission |
| title_auth | Aggregation induced emission |
| title_exact_search | Aggregation induced emission |
| title_full | Aggregation induced emission [2] Applications ed. by Anjun Qin ... |
| title_fullStr | Aggregation induced emission [2] Applications ed. by Anjun Qin ... |
| title_full_unstemmed | Aggregation induced emission [2] Applications ed. by Anjun Qin ... |
| title_short | Aggregation induced emission |
| title_sort | aggregation induced emission applications |
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