Investigation of an active air sampling strategy for biocides, PCBs and PAHs at low air change rates:
Saved in:
| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
Berlin
BAM
2013
|
| Series: | BAM-Dissertationsreihe
104 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIV, 122 S. Ill., graph. Darst. |
| ISBN: | 9783981574838 |
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MARC
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Record in the Search Index
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| adam_text | TABLE OF CONTENTS
ZUSAMMENFASSUNG IX
ABSTRACT X
TABLE OF CONTENTS XI
1 INTRODUCTION 1
2 THEORETICAL PART 3
2.1 COMPOUND INFORMATION 3
2.2 WOOD PRESERVATIVES 9
2.2.1 APPLICATION OF WOOD PRESERVATIVES 9
2.2.1.1 WOOD PRESERVATIVES IN HOUSE CONSTRUCTION 10
2.2.1.2 ORGANIC POLLUTANTS IN THE MUSEUM ENVIRONMENT 10
2.3 LITERATURE STUDIES: AIR SAMPLING ADSORBENTS, STRATEGIES AND
MEASUREMENTS FOR
BIOCIDES, PCBS AND PAHS 11
2.4 AIR SAMPLJNG STRATEGIES: ACTIVE SAMPLING AND DIFFUSIVE SAMPLING 13
2.4.1 ACTIVE SAMPLING 13
2.4.2 DIFFUSIVE SAMPLING 13
2.5 EMISSION TEST CHAMBERS 14
2.5.1 MICRO-CHAMBER (M-CTE) 16
2.5.2 23 I AND 24 I EMISSION TEST CHAMBERS 16
2.5.3 SHOWCASES 19
2.5.4 COMPARISON OF THE CHAMBER TYPES 21
2.6 MEASUREMENT: MULTIPLE REACTION MONITORING 22
* 3 MATERIALS AND METHODS 23
3.1 INSTRUMENTATION 23
3.2 QUANTIFICATION AND IDENTIFICATION 23
4 METHOD DEVELOPMENT 24
4.1 GC-MS-MS METHOD 24
4.1.1 MULTIPLE REACTION MONITORING MEASUREMENTS 25
4.1.2 STATISTICAL PARAMETERS OF THE GC-MS-MS METHOD 27
4.1.2.1 LIMIT OF DETECTION AND LIMIT OF QUANTIFICATION 27
4.1.2.2 REPRODUCIBILITY 28
4.1.2.3 LINEARITY OF THE CALIBRATION 29
4.2 ADSORBENT SELECTION 30
4.2.1 DETERMINATION OF THE ELUTION VOLUME 32
4.2.2 ELUTION TEST 32
HTTP://D-NB.INFO/1036287548
4.3 EMISSION TEST CHAMBER MEASUREMENTS 33
4.3.1 AIR SAMPLING VOLUME 35
4.3.2 MICRO-CHAMBER 35
4.3.2.1 AIR SAMPLING AND BREAKTHROUGH EXPERIMENTS 35
4.3.2.2 COMPARISON OF THE ISTDS 37
4.3.3 EMISSION TEST CHAMBER EXPERIMENTS WITH SOAKED WOOD SAMPLES 38
4.3.3.1 SOAKED WOOD IN THE P-CTE 39
4.3.3.2 SOAKED WOOD IN SHOWCASES 41
4.3.3.3 SOAKED WOOD IN 23 I AND 24 I EMISSION TEST CHAMBERS 46
4.4 METHOD VALIDATION 51
4.4.1 METHOD RECOVERY . 51
4.4.1.1 RECOVERY OF THE ADSORBENT ELUTION/EXTRACTION 51
4.4.1.2 RECOVERY OF THE AIR SAMPLING METHOD 52
4.4.2 UNCERTAINTY IN MEASUREMENT 53
4.4.2.1 QUANTIFYING UNCERTAINTY U(XI) 56
4.4.3 ERROR AND UNCERTAINTY 60
4.4.3.1 MAXIMUM ERROR 61
5 APPLICATION OF THE DEVELOPED METHOD 64
5.1 INVESTIGATION OF REAL SAMPLES AND INDOOR AIR 64
5.1.1 INVESTIGATION OF REAL WOOD SAMPLES IN THE P-CTE 64
5.1.2 INVESTIGATION OF WOOD SAMPLES AND INDOOR AIR QUALITY OF A
WOOD-BASED WORLD
HERITAGE SITE CHURCH 65
5.1.3 AIR SAMPLING IN A MUSEUM REPOSITORY 65
5.2 EVALUATION OF THE REAL SAMPLES AND INDOOR AIR INVESTIGATIONS 65
5.2.1 RESULTS OF THE INVESTIGATION OF REAL WOOD SAMPLES IN THE P-CTE 66
5.2.2 RESULTS OF THE REAL WOOD SAMPLES FROM A WORLD HERITAGE SIDE CHURCH
AND AIR
SAMPLING IN THIS CHURCH 67
5.2.3 RESULTS OF THE AIR SAMPLING IN A MUSEUM REPOSITORY 68
5.2.4 COMPARISON SDVB-POLYMER - TENAX TA 69
6 DISCUSSION 70
6.1 STATISTICAL PARAMETERS OF THE DEVELOPED GC-MS-MS METHOD 70
6.2 ELUTION AND EXTRACTION EXPERIMENTS 70
6.3 P-CTE AIR SAMPLING EXPERIMENTS WITH TARGET COMPOUND SOLUTIONS 71
6.4 SOAKED WOOD SAMPLES IN EMISSION TEST CHAMBERS 72
6.5 METHOD VALIDATION: UNCERTAINTY IN MEASUREMENT AND MAXIMUM ERROR 76
7 CONCLUSION AND OUTLOOK . 77
7.1 CONCLUSION 77
7.2 OUTLOOK 78
8 LITERATURE 80
9 APPENDIX 86
9.1 CHEMICALS AND ADSORBENTS 86
9.2 EXPERIMENTAL PART. 87
9.2.1 CALIBRATION SOLUTIONS 87
9.2.1.1 PREPARATION OF CALIBRATION SOLUTIONS 87
9.2.1.2 CALIBRATION SOLUTIONS FOR THE LOD AND LOQ 87
9.2.2 ADSORBENT 87
9.2.2.1 SELECTION OF AN ADSORBENT 87
9.2.2.2 DETERMINATION OF THE ELUTION VOLUME 88
9.2.3 AIR SAMPLING 88
9.2.3.1 EQUIPMENT 88
9.2.3.2 GENERAL PROCEDURES 89
9.2.3.3 MICRO-CHAMBER 89
9.2.3.4 AIR SAMPLING AND BREAKTHROUGH EXPERIMENTS 89
9.2.3.5 COMPARISON OF THE ISTDS 90
9.2.4 AIR SAMPLING EXPERIMENTS WITH SOAKED WOOD 90
9.2.4.1 SOAKED WOOD IN THE (J-CTE 90
9.2.4.2 SOAKED WOOD IN SHOWCASES 91
9.2.4.3 SOAKED WOOD IN 23 I AND 24 I EMISSION TEST CHAMBERS 95
9.2.5 INVESTIGATIONS OF REAL SAMPLES AND INDOOR AIR 96
9.2.5.1 |J-CTE INVESTIGATIONS OF REAL WOOD SAMPLES 96
9.2.5.2 (J-CTE INVESTIGATIONS OF REAL WOOD SAMPLES FROM A WORLD HERITAGE
SITE
CHURCH AND AIR SAMPLING IN THIS CHURCH 97
9.2.5.3 AIR SAMPLING IN A MUSEUM REPOSITORY 98
9.3 TABLES 99
9.3.1 ISTD MIXTURES, ISTDS, TARGET COMPOUND SOLUTIONS AND CALIBRATION
SOLUTIONS 99
9.3.2 LIMITS OF QUANTIFICATION 102
9.3.3 LINEARITY OF THE CALIBRATION 103
9.3.4 ELUTION VOLUME 108
9.3.5 RESULTS OF SOAKED WOOD SAMPLES IN EMISSION TEST CHAMBERS 110
9.4 ABBREVIATIONS 116
9.5 LIST OF FIGURES
9.6 LIST OF TABLES
|
| any_adam_object | 1 |
| author | Mull, Birte |
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| author_facet | Mull, Birte |
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| dewey-full | 628.530287 |
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| dewey-ones | 628 - Sanitary engineering |
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| dewey-search | 628.530287 |
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| dewey-tens | 620 - Engineering and allied operations |
| discipline | Bauingenieurwesen |
| format | Thesis Book |
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| physical | XIV, 122 S. Ill., graph. Darst. |
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| spelling | Mull, Birte Verfasser (DE-588)1044997850 aut Investigation of an active air sampling strategy for biocides, PCBs and PAHs at low air change rates Birte Mull Berlin BAM 2013 XIV, 122 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier BAM-Dissertationsreihe 104 Zugl.: Berlin Techn. Univ., Diss., 2013 (DE-588)4113937-9 Hochschulschrift gnd-content BAM-Dissertationsreihe 104 (DE-604)BV019539588 104 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026906402&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Mull, Birte Investigation of an active air sampling strategy for biocides, PCBs and PAHs at low air change rates BAM-Dissertationsreihe |
| subject_GND | (DE-588)4113937-9 |
| title | Investigation of an active air sampling strategy for biocides, PCBs and PAHs at low air change rates |
| title_auth | Investigation of an active air sampling strategy for biocides, PCBs and PAHs at low air change rates |
| title_exact_search | Investigation of an active air sampling strategy for biocides, PCBs and PAHs at low air change rates |
| title_full | Investigation of an active air sampling strategy for biocides, PCBs and PAHs at low air change rates Birte Mull |
| title_fullStr | Investigation of an active air sampling strategy for biocides, PCBs and PAHs at low air change rates Birte Mull |
| title_full_unstemmed | Investigation of an active air sampling strategy for biocides, PCBs and PAHs at low air change rates Birte Mull |
| title_short | Investigation of an active air sampling strategy for biocides, PCBs and PAHs at low air change rates |
| title_sort | investigation of an active air sampling strategy for biocides pcbs and pahs at low air change rates |
| topic_facet | Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026906402&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV019539588 |
| work_keys_str_mv | AT mullbirte investigationofanactiveairsamplingstrategyforbiocidespcbsandpahsatlowairchangerates |