The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: a Non-Innocent Twist
Saved in:
| Main Author: | |
|---|---|
| Format: | Thesis Electronic eBook |
| Language: | English |
| Published: |
Cham [u.a.]
Springer International Publishing Switzerland
2013
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| Series: | Springer Theses
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| Subjects: | |
| Online Access: | UBT01 Volltext Inhaltsverzeichnis Abstract |
| Physical Description: | 1 Online-Ressource |
| ISBN: | 9783319016740 |
| DOI: | 10.1007/978-3-319-01674-0 |
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Record in the Search Index
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| adam_text | THE SIAMESE-TWIN PORPHYRIN AND ITS COPPER AND NICKEL COMPLEXES: A
NON-INNOCENT TWIST
/ BLUSCH, LINA K.
: 2013
TABLE OF CONTENTS / INHALTSVERZEICHNIS
GENERAL INTRODUCTION
OBJECTIVE
ROUTE TO THE SIAMESE-TWIN PORPHYRIN
SIAMESE-TWIN PORPHYRIN LH4
NICKEL AND COPPER COMPLEXES
REDOX PROPERTIES
SUMMARY AND OUTLOOK
EXPERIMENTAL SECTION
APENDIX: CRYSTALLOGRAPHIC DETAILS
DETAILS ON DFT CALCULATIONS
DIESES SCHRIFTSTUECK WURDE MASCHINELL ERZEUGT.
THE SIAMESE-TWIN PORPHYRIN AND ITS COPPER AND NICKEL COMPLEXES: A
NON-INNOCENT TWIST
/ BLUSCH, LINA K.
: 2013
ABSTRACT / INHALTSTEXT
THIS THESIS DESCRIBES THE FIRST ANDLONG-SOUGHTSUCCESSFUL SYNTHESIS
OF A NEW PYRAZOLE-EXPANDED PORPHYRIN, A HIGHER ANALOG OF PORPHYRIN. THIS
SIAMESE-TWIN PORPHYRIN PROVIDES TWO CONJOINED PORPHYRIN-LIKE
COORDINATION SPHERES, THUS BEING ABLE TO ACCOMMODATE TWO METAL IONS
WITHIN THE SAME LIGAND. IN HER THESIS, LINA BLUSCHNOT ONLYEXPLAINS
THE CHALLENGINGSYNTHESIS AND CHARACTERIZATION OF THE LIGAND SYSTEM,
BUT ALSO ITS APPLICATION TO THE SYNTHESIS OF HOMO- AND HETERO-BIMETALLIC
NI AND CUCOMPLEXES.SHE OBSERVES INTERESTING METAL-METAL-INTERACTIONS
IN THE COMPLEXES, THAT LEAD TO A NON-INNOCENT MULTISTEP REDOX CHEMISTRY.
THE LIGAND SYSTEM AND ITS COMPLEXES SHOW AN INTRIGUING TWISTED GEOMETRY,
GIVING RISE TO HELICAL CHIRALITY AND OTHER FASCINATING PROPERTIES. THIS
STUDY EXPLORES THE FIRST STEPSAND OPENS UPA NEW CHEMISTRY OF
EXPANDED PORPHYRINS WITH THE POTENTIAL TO BIOMIMETIC APPLICATIONS
DIESES SCHRIFTSTUECK WURDE MASCHINELL ERZEUGT.
|
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| spelling | Blusch, Lina K. Verfasser aut The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes a Non-Innocent Twist Lina K. Blusch Cham [u.a.] Springer International Publishing Switzerland 2013 1 Online-Ressource txt rdacontent c rdamedia cr rdacarrier Springer Theses Zugl.: Göttingen, Univ., Diss., 2013 Chemie Chemistry Chemistry, inorganic Bioorganic chemistry Chemistry, Organic (DE-588)4113937-9 Hochschulschrift gnd-content Erscheint auch als Druckausgabe 978-3-319-01673-3 https://doi.org/10.1007/978-3-319-01674-0 Verlag Volltext Springer Fremddatenuebernahme application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026888597&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Springer Fremddatenuebernahme application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026888597&sequence=000003&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Abstract |
| spellingShingle | Blusch, Lina K. The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes a Non-Innocent Twist Chemie Chemistry Chemistry, inorganic Bioorganic chemistry Chemistry, Organic |
| subject_GND | (DE-588)4113937-9 |
| title | The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes a Non-Innocent Twist |
| title_auth | The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes a Non-Innocent Twist |
| title_exact_search | The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes a Non-Innocent Twist |
| title_full | The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes a Non-Innocent Twist Lina K. Blusch |
| title_fullStr | The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes a Non-Innocent Twist Lina K. Blusch |
| title_full_unstemmed | The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes a Non-Innocent Twist Lina K. Blusch |
| title_short | The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes |
| title_sort | the siamese twin porphyrin and its copper and nickel complexes a non innocent twist |
| title_sub | a Non-Innocent Twist |
| topic | Chemie Chemistry Chemistry, inorganic Bioorganic chemistry Chemistry, Organic |
| topic_facet | Chemie Chemistry Chemistry, inorganic Bioorganic chemistry Chemistry, Organic Hochschulschrift |
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