Chemistry of main group heteroborates: = Chemie der Hauptgruppenheteroborate
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2011
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | VI, 230 S. Ill., graph. Darst. |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV041374987 | ||
| 003 | DE-604 | ||
| 005 | 20180919 | ||
| 007 | t | ||
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| 035 | |a (OCoLC)865727685 | ||
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| 041 | 0 | |a eng | |
| 049 | |a DE-188 |a DE-29T | ||
| 082 | 0 | |a 546.6712 |2 22//ger | |
| 100 | 1 | |a Fleischhauer, Sebastian |d 1982- |e Verfasser |0 (DE-588)1041734417 |4 aut | |
| 245 | 1 | 0 | |a Chemistry of main group heteroborates |b = Chemie der Hauptgruppenheteroborate |c vorgelegt von Sebastian Fleischhauer |
| 246 | 1 | 1 | |a Chemie der Hauptgruppenheteroborate |
| 264 | 1 | |c 2011 | |
| 300 | |a VI, 230 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Tübingen, Univ., Diss., 2011 | ||
| 650 | 0 | 7 | |a Borverbindungen |0 (DE-588)4007812-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Hauptgruppenelementverbindungen |0 (DE-588)4403467-2 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Borate |0 (DE-588)4146304-3 |2 gnd |9 rswk-swf |
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Datensatz im Suchindex
| _version_ | 1804151467415699456 |
|---|---|
| adam_text | CONTENTS
CONTENTS
1. INTRODUCTION 1
1.1 BORON HYDRIDE 1
1.2 TRANSITION METAL HETEROBORATES AND CARBORATES 3
1.3 GROUP 14 HETEROBORATES 4
1.4 GROUP 13 HETEROBORATES AND HETEROCARBORATES 5
1.5 FUNCTIONALIZATION OF BORANES AND BORATES 6
1.6 TIN CHEMISTRY 7
1.7 MOTIVATION 9
2. RESULTS 10
2.0 DFT CALCULATIONS OF MONO-HETEROBORATES 10
2.1 COMPLEXES OF STANNA- AND GERMA-CFOSO-DODECABORATE 13
2.1.1 GENERAL PROPERTIES 13
2.1.2 REACTION WITH [MOI-CL)CLCP*]
A
(M = RU, RH, IR) 20
2.1.3 REACTION WITH [IRCL
2
CP*(PME
3
)] 25
2.1.4 REACTION WITH [IR(/J-CL)(PPY)J
A
27
2.1.5 REACTION WITH [IR(//-C1)(C0E)
2
]
2
30
2.1.6 REACTION WITH [RU(/J-CL)CL(FJ
6
-C
6
H
6
)]
2
33
2.1.7 REACTION WITH [MNCP(CO)
2
*THF] 35
2.1.8 REACTION WITH [VCP(CO)
3
*THF] 38
2.1.9 REACTION WITH [CR(?
6
-C
6
H
6
)(CO)
3
] AND [MOCP(CO)
3
]
2
43
2.2 REACTIONS OF STANNA- AND GERMA-C/OSO-DODECABORATE WITH
HOMOLEPTIC CARBONYLS 46
2.2.2 REACTION WITH GROUP 6 CARBONYLS 46
2.2.3 REACTION WITH GROUP 8 CARBONYLS 49
2.2.4 REACTION WITH GROUP 9 CARBONYLS 57
I
HTTP://D-NB.INFO/1043767436
CONTENTS
2.3 REACTION OF STANNA-C/OSO-DODECABORATE WITH HALOCARBONYLS 60
2.3.1 REACTION WITH IRIDIUM AND RHODIUM HALOCARBONYLS 60
2.3.2 SYNTHESES OF COBALT STANNA-C/OSO-DODECABORATE COMPLEXES 74
2.3.3 REACTION WITH [RUFRI-CIYCOY 77
2.3.4 REACTION WITH [MNBR(CO)
S
] 79
2.4 OXIDATION CHEMISTRY OF STANNA-C/OSO-DODECABORATE 83
2.4.1 GENERAL PROPERTIES 83
2.4.2 SYNTHESIS OF [SNB
11
H
M
-SNB
11
H
11
]* 84
2.5 GROUP 13 HETEROBORATES 87
2.5.1 SYNTHESIS OF [BU
4
N]
4
[EB
11
H
1I
]
J
( E = GA, IN) 87
2.5.2 SYNTHESIS OF [B^N^CE^HNJTGACLJ-GAB, H
LO
OH] 93
2.5.3 OPTIMIZED SYNTHESIS OF [BU
4
N]
I
[B
LL
HJ 96
2.6 FUNCTIONALIZATION OF STANNA-C/OSO-DODECABORATE 97
2.6.1 GENERAL PROPERTIES 97
2.6.2 SYNTHESIS OF C/OSO-[SNB
N
H
10
OH]
2
- 98
2.6.3 HYDRIDE ABSTRACTION FROM [SNB^HJ
2
101
2.7 COORDINATION OF [S-SNB^HJ 107
2.7.1 GENERAL PROPERTIES 107
2.7.2 REACTION WITH [IR(^/-CL)CLCP*]
A
AND [IRCL
2
CP*PME
3
] 107
3. SUMMARY 111
4. EXPERIMENTAL SECTION 117
4.1 GENERAL ASPECTS AND STARTING MATERIALS 117
4.2 NMR SPECTROSCOPY 118
4.3 QUANTUM-CHEMICAL CALCULATIONS 119
4.4 SYNTHESES 120
II
CONTENTS
A APPENDIX 138
A.1 CRYSTALLOGRAPHIC DEFINITIONS 138
A.2 EXPERIMENTAL DETAILS OF THE X-RAY DIFFRACTION ANALYSIS AND DETAILS
OF THE
STRUCTURE REFINEMENT 139
A-3 CRYSTAL STRUCTURE REFINEMENT TABLES 146
A.3.01 [ME
3
HN]
2
[SNB
11
HJ 146
A.3.02 [ETJHN^TLRCP TSNB^H^ACN] 147
A.
3
.03[ET
4
N]
3
[IRCLCP*(SNB
II
H
11
)
;L
] 148
A.
3
.04[ME
4
N]
3
[RHCLCP*(SNB
11
H
11
)J 149
A.3.05[BU
3
HN]
4
[RUCP*H(SNB,
L
H
11
)
3
] 150
A.3.06 [ET
3
HN] [IRCLCP*(SNB
11
H
LL
)PME
3
] 151
A.3.07 [BU
J
MEN]
3
[IR(SNB
LL
H
IL
)
I
(7
A
-PPY)J 152
A.3.08 [BU
3
HN]
6
[IRH(SNB
11
H
11
)
4
(COE)] 153
A.3.09 [ET
4
N]
3
[RUCL(SNB
11
H
LL
)
2
(^
6
-C
6
H
6
)] 154
A.3.IO[PH
4
PYMNCP(SNB
U
H*)(CO)J 155
A.3.11 [PH
4
P]JMNCP(GEB
11
HJ(CO)
2
] 156
A.3.12 [PPH
4
]
I
[VCP(SNB
II
H
LI
)(CO)
3
] 157
A.3.13 [PPH
4
]
I
[VCP(SNB
II
H
LI
)(CO)
3
] 158
A.3.14 [BU
3
HN]
A
[CR(SNB
LL
H
LL
)
I
(^ -C
6
H
6
)(CO)
A
] 159
A.3.15 [BU
3
MEN][MOCP(SNB
N
H
N
)(CO)
3
] 160
A.3.16 [ET
4
N]
4
[MO-CIS-(GEB
LI
H
11
)
!1
(CO)
4
] 162
A.3.I7[PH
4
P]
2
[CR(SNB
11
H
11
)(CO)
5
] 161
A.3.18 [BU
3
HN],[FE(SNB
IL
H
II
)(CO)
4
] 163
A.3.19 [ET
3
MEN]
4
[FE(SNB
11
H
II
)
J
(CO)
3
] 164
A.3.20 [ME
4
N]
4
[RU
3
(SNB
11
H
II
)
2
(CO)J 165
A.
3
.2L[ET
4
N]
6
[RU
3
(SNB
LL
H
LL
)
3
(CO),] 166
A.3.22 [ME
4
N]
4
[OS
3
(SNB
II
H
U
)
2
(CO)
10
] 167
A.
3
.23[ET
3
HN]
4
[IR
4
(SNB
II
H
LI
)
2
(CO)J 168
A.3.24 [ET
3
MEN]
S
[RHO/-SNB
LL
H
LL
KSNB
11
H
11
)(CO)
I
]
2
169
A.3.25 [ET
4
N]
W
NAJRH(SNB
LL
H
II
)
3
(CO)
2
]
S
170
III
CONTENTS
A.
3
.26[ET
4
N]
5
[RH(GEB
LL
H
LL
)
3
(CO)
2
] 171
A.3.27 [ET
4
N]
J
[IR(SNB
11
H
11
)
3
(CO)J 172
A.
3
.28[ME
4
N]
S
[CO(SNB
LL
H
II
)
3
(COY 173
A
.3.29
[ME
4
N][RH(SNB
11
H
LL
)(CO)(PME
3
)
3
]
174
A.3.30 [ET
3
MEN]
4
[RUCL
J
(SNB
II
H
II
)
2
(CO)
J
] 175
A.331 [ET
4
N]
6
[MN(SNB
11
H
11
)
4
/RANS-(CO)
1
] 176
A-3-32 [ET
3
HN]
3
[SNB
LL
H
L0
-SNB
11
H
LL
] 177
A-3-33 [BU
4
N]
4
[INB
11
H
11
]
1
178
A.3.34 [BU
4
N]
2
[ET
3
HN][GACL
3
-GAB
11
H
L0
.0H
05
] 179
A-3-35 SNB
LL
H
9
(E,E-NME=CHME)
S
180
A.3.36 SNB
II
H
9
(Z,Z-NME=CHME)
2
181
A.3.37 SNB
LI
H
9
(E,E-NME=CHET)
A
182
A.3.38 [ET
4
N]
4
[IRCP*(S-SNB
U
H
LL
)
3
] 183
A-3-39[ET
4
N]
I
[IRCP*(S-SNB
LL
H
II
)
2
PME
3
] 184
A-4 POSTER PRESENTATIONS 185
A.5 PUBLICATIONS 185
A.6 DFT ANALYSIS CONDITIONS 186
A.6.1 [SNB,^,,]
2
186
A.6.2 [TB
II
H
II
]
2
(T = C, SI, GE) GAS PHASE 186
A.6.3 [TB^HJ
2-
(T = C, SI, GE) SOLUTION 187
A.6.4 [NB
N
H
N
] 187
A.6.5 [PB^HJ- 188
A.6.6 [ASB^J- 188
A.6.
7
TGAB
LL
H
LL
]3-
189
A.6.8 [ALB^H.J
3
189
A.6.9 [INB^H,,]
3-
190
A.6.10 [SNB
N
H
LO
OH]=- 190
A.6.11 [GAB^H^GACY
3
* 191
A.6.12 [SNB
11
H
10
-SNB
IL
H
11
]
3
191
A.6.13 [INB.JH,,],
4-
192
IV
CONTENTS
A.6.14 [RH
I
(SNB
II
H*)
4
(CO)
4
]
&
192
A
.6.15
[CO(SNB
11
H
IL
)
3
(CO
)
2
R
193
A.6.16 [RH(SNB
LL
H
11
)
3
(CO)
A
F 193
A
.6.17
[IR(SNB
11
H
LL
)
3
(CO)
J
]
5
194
A.6.18 [RH(SNB
LI
H*)(CO)(PME
3
Y- 194
A.6.19 [VCPCSNB
11
H
11
XCO)
3
?- 195
A
.6.20
[MNCP(SNB
11
H
LL
)(CO)
I
] -
195
A.6.21
[IKPPY^CSNB^H,,),]
3
- 196
A
.6.22
[FE(SNB
11
H
11
)
I
(CO)
3
]
4
196
A
.6.23
[SNCB
I0
H
U
]-, [SNC^H,,]
197
A
.6.24
[CR(SNB
N
H *),(I?
6
-C
6
H
S
)(CO)
1
]*
197
A
.7
ABBREVIATIONS AND UNITS
198
A.
7.1
ABBREVIATIONS
198
A.
7.2
UNITS
200
A
.8
LIST OF COMPOUNDS
201
REFERENCES
212
V
|
| any_adam_object | 1 |
| author | Fleischhauer, Sebastian 1982- |
| author_GND | (DE-588)1041734417 |
| author_facet | Fleischhauer, Sebastian 1982- |
| author_role | aut |
| author_sort | Fleischhauer, Sebastian 1982- |
| author_variant | s f sf |
| building | Verbundindex |
| bvnumber | BV041374987 |
| ctrlnum | (OCoLC)865727685 (DE-599)BSZ393453103 |
| dewey-full | 546.6712 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546.6712 |
| dewey-search | 546.6712 |
| dewey-sort | 3546.6712 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| genre_facet | Hochschulschrift |
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| illustrated | Illustrated |
| indexdate | 2024-07-10T00:55:17Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-026823076 |
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| open_access_boolean | |
| owner | DE-188 DE-29T |
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| physical | VI, 230 S. Ill., graph. Darst. |
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| spelling | Fleischhauer, Sebastian 1982- Verfasser (DE-588)1041734417 aut Chemistry of main group heteroborates = Chemie der Hauptgruppenheteroborate vorgelegt von Sebastian Fleischhauer Chemie der Hauptgruppenheteroborate 2011 VI, 230 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Tübingen, Univ., Diss., 2011 Borverbindungen (DE-588)4007812-7 gnd rswk-swf Hauptgruppenelementverbindungen (DE-588)4403467-2 gnd rswk-swf Borate (DE-588)4146304-3 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Borverbindungen (DE-588)4007812-7 s Hauptgruppenelementverbindungen (DE-588)4403467-2 s DE-604 Borate (DE-588)4146304-3 s DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026823076&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Fleischhauer, Sebastian 1982- Chemistry of main group heteroborates = Chemie der Hauptgruppenheteroborate Borverbindungen (DE-588)4007812-7 gnd Hauptgruppenelementverbindungen (DE-588)4403467-2 gnd Borate (DE-588)4146304-3 gnd |
| subject_GND | (DE-588)4007812-7 (DE-588)4403467-2 (DE-588)4146304-3 (DE-588)4113937-9 |
| title | Chemistry of main group heteroborates = Chemie der Hauptgruppenheteroborate |
| title_alt | Chemie der Hauptgruppenheteroborate |
| title_auth | Chemistry of main group heteroborates = Chemie der Hauptgruppenheteroborate |
| title_exact_search | Chemistry of main group heteroborates = Chemie der Hauptgruppenheteroborate |
| title_full | Chemistry of main group heteroborates = Chemie der Hauptgruppenheteroborate vorgelegt von Sebastian Fleischhauer |
| title_fullStr | Chemistry of main group heteroborates = Chemie der Hauptgruppenheteroborate vorgelegt von Sebastian Fleischhauer |
| title_full_unstemmed | Chemistry of main group heteroborates = Chemie der Hauptgruppenheteroborate vorgelegt von Sebastian Fleischhauer |
| title_short | Chemistry of main group heteroborates |
| title_sort | chemistry of main group heteroborates chemie der hauptgruppenheteroborate |
| title_sub | = Chemie der Hauptgruppenheteroborate |
| topic | Borverbindungen (DE-588)4007812-7 gnd Hauptgruppenelementverbindungen (DE-588)4403467-2 gnd Borate (DE-588)4146304-3 gnd |
| topic_facet | Borverbindungen Hauptgruppenelementverbindungen Borate Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026823076&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT fleischhauersebastian chemistryofmaingroupheteroborateschemiederhauptgruppenheteroborate AT fleischhauersebastian chemiederhauptgruppenheteroborate |