Olefin-Assisted Iron and Cobalt Catalyzed Cross-Coupling Reactions for the Synthesis of Highly Functionalized Styrene Derivatives:
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| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
München
Verl. Dr. Hut
2013
|
| Edition: | 1. Aufl. |
| Series: | Organische Chemie
|
| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | 215 S. graph. Darst. 210 mm x 148 mm, 327 g |
| ISBN: | 9783843910170 3843910170 |
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MARC
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Record in the Search Index
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|---|---|
| adam_text |
Table
of
Contents
.ниішннни«|нніниніншмнмІжи.«пІи>яіі«и«нн«иіт»нІи»нн«Інпшиін«н9
1.1
Iron and Cobalt Catalysis on Laboratory Scale
.9
12
Mechanistic
Background
.14
U
Iron and Cobalt Catalysis in Industrial Processes
.17
1.4
Olefin
Effects in Transition Metal Catalyzed Cross-Coupling Reactions
.19
\5 References
.21
2
Chlorostyrenes in Iron-Catalyzed Biaryl Coupling Reactions.
.25
2.1
Results and Discussion
.26
2.1.1
Introduction
.26
2.1.2
Discovery of a Iron-Catalyzed Cross-Coupling
.26
2.1.3
Biaryl Products
.31
2.1.4
Conclusion
.33
2.1.5
Domino Cross-Coupling-Hydrogenation Reactions
.34
2.1.6
References
.36
2.2
Experimental Section
.39
22.1
General
.39
222
Preparation of Starting Materials
.40
22.3
Biaryl Products
.45
22.4
Selected Spectra
.64
3
Highly
Cbemoselectìye
Cobalt-Catalyzed Biaryl Coupling Reactions
--------------------67
3.1
Results and Discussion
.68
3.1.1
Introduction
.68
3.12
Discovery of a Cobalt-Catalyzed Cross-Coupling
.69
3.13
Substrate Scope and Chemoselectivity
.70
3.1.4
Mechanistic Studies
.75
3.1.5
Comparison of
CoíIID.CoCD.Coí-I)
pre-catalysts
./.80
3.1.6
Conclusion
.86
3.1.7
References
.87
32
Experimental Section
.91
32.1
General
.91
322
Preparation of Starting Materials
.94
32.4
Preparation of
[KídmeKCoíC^ob}]
.107
32.5
Biaryl Products
.117
32.6
Selected Spectra
.137
4
Olefin-
Assisted Iron-Catalyzed Alkyiation of Aryl Chlorides
._
~.~.~.~.
_. 139
4.1
Results and Discussion
.140
4.1.1
Introduction
.140
4.12
Optimization and Scope
.141
4.13
Mechanistic Studies
.148
4.1.4
Summary and Outlook
.152
4.15
References
.153
42
Experimental Section
.157
42.1
General
.157
422
Preparation of Starting Materials
.158
42.4
Selected Spectra
.200
5
List of Abbreviations
. 203
6
Summary
.·.205
7 Zusammenfassung---------------.—.—.—.209
8
Curriculum
Vitae
_.213
9
Acknowledgements
.215 |
| any_adam_object | 1 |
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| author_facet | Gülak, Samet |
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| bvnumber | BV041373036 |
| ctrlnum | (OCoLC)862837286 (DE-599)DNB1035477572 |
| dewey-full | 540 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 540 - Chemistry and allied sciences |
| dewey-raw | 540 |
| dewey-search | 540 |
| dewey-sort | 3540 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | 1. Aufl. |
| format | Thesis Book |
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| indexdate | 2024-08-03T01:01:10Z |
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| isbn | 9783843910170 3843910170 |
| language | English |
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| physical | 215 S. graph. Darst. 210 mm x 148 mm, 327 g |
| publishDate | 2013 |
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| publisher | Verl. Dr. Hut |
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| series2 | Organische Chemie |
| spelling | Gülak, Samet Verfasser aut Olefin-Assisted Iron and Cobalt Catalyzed Cross-Coupling Reactions for the Synthesis of Highly Functionalized Styrene Derivatives Samet Gülak 1. Aufl. München Verl. Dr. Hut 2013 215 S. graph. Darst. 210 mm x 148 mm, 327 g txt rdacontent n rdamedia nc rdacarrier Organische Chemie Zugl.: Regensburg, Univ., Diss., 2013 Katalyse (DE-588)4029921-1 gnd rswk-swf Styrolderivate (DE-588)4327171-6 gnd rswk-swf Chemische Synthese (DE-588)4133806-6 gnd rswk-swf Kupplungsreaktion (DE-588)4166199-0 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Styrolderivate (DE-588)4327171-6 s Chemische Synthese (DE-588)4133806-6 s Kupplungsreaktion (DE-588)4166199-0 s Katalyse (DE-588)4029921-1 s DE-604 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4355326&prov=M&dok_var=1&dok_ext=htm Inhaltstext Digitalisierung UB Regensburg - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026821160&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gülak, Samet Olefin-Assisted Iron and Cobalt Catalyzed Cross-Coupling Reactions for the Synthesis of Highly Functionalized Styrene Derivatives Katalyse (DE-588)4029921-1 gnd Styrolderivate (DE-588)4327171-6 gnd Chemische Synthese (DE-588)4133806-6 gnd Kupplungsreaktion (DE-588)4166199-0 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4327171-6 (DE-588)4133806-6 (DE-588)4166199-0 (DE-588)4113937-9 |
| title | Olefin-Assisted Iron and Cobalt Catalyzed Cross-Coupling Reactions for the Synthesis of Highly Functionalized Styrene Derivatives |
| title_auth | Olefin-Assisted Iron and Cobalt Catalyzed Cross-Coupling Reactions for the Synthesis of Highly Functionalized Styrene Derivatives |
| title_exact_search | Olefin-Assisted Iron and Cobalt Catalyzed Cross-Coupling Reactions for the Synthesis of Highly Functionalized Styrene Derivatives |
| title_full | Olefin-Assisted Iron and Cobalt Catalyzed Cross-Coupling Reactions for the Synthesis of Highly Functionalized Styrene Derivatives Samet Gülak |
| title_fullStr | Olefin-Assisted Iron and Cobalt Catalyzed Cross-Coupling Reactions for the Synthesis of Highly Functionalized Styrene Derivatives Samet Gülak |
| title_full_unstemmed | Olefin-Assisted Iron and Cobalt Catalyzed Cross-Coupling Reactions for the Synthesis of Highly Functionalized Styrene Derivatives Samet Gülak |
| title_short | Olefin-Assisted Iron and Cobalt Catalyzed Cross-Coupling Reactions for the Synthesis of Highly Functionalized Styrene Derivatives |
| title_sort | olefin assisted iron and cobalt catalyzed cross coupling reactions for the synthesis of highly functionalized styrene derivatives |
| topic | Katalyse (DE-588)4029921-1 gnd Styrolderivate (DE-588)4327171-6 gnd Chemische Synthese (DE-588)4133806-6 gnd Kupplungsreaktion (DE-588)4166199-0 gnd |
| topic_facet | Katalyse Styrolderivate Chemische Synthese Kupplungsreaktion Hochschulschrift |
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| work_keys_str_mv | AT gulaksamet olefinassistedironandcobaltcatalyzedcrosscouplingreactionsforthesynthesisofhighlyfunctionalizedstyrenederivatives |