Thermodynamics of geothermal fluids:
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| Other Authors: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Chantilly, Va.
Mineralogical Soc. of America
2013
|
| Series: | Reviews in mineralogy and geochemistry
76 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturangaben |
| Physical Description: | X, 350 S. Ill., graph. Darst., Kt. |
| ISBN: | 9780939950911 |
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| 245 | 1 | 0 | |a Thermodynamics of geothermal fluids |c ed. Andri Stefánsson ... |
| 264 | 1 | |a Chantilly, Va. |b Mineralogical Soc. of America |c 2013 | |
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1
Thermodynamics of
Geothermal Fluids
76
Reviews in Mineralogy and Geochemistry
76
TABLE OF CONTENTS
Thermodynamics of Geothermal Fluids
Andri
Stefansson,
Thomas Driesner,
Pascale Bénézeth
INTRODUCTION TO THE VOLUME
.1
REFERENCES
.4
Ĺ
The Molecular-Scale Fundament of
Geothermal Fluid Thermodynamics
Thomas Driesner
INTRODUCTION
.5
BASIC RELATIONS BETWEEN THE MOLECULAR SCALE AND THE
MACROSCOPIC THERMODYNAMIC PROPERTIES OFGEOFLUIDS
.8
Simplified descriptions of molecular interactions
.9
Basic concepts of statistical thermodynamics
.10
Fluctuations and thermodynamic properties
.12
Understanding fluid thermodynamics from pair correlation functions
.13
Molecular simulation
.15
GENERAL MOLECULAR-SCALE FEATURES OF AQUEOUS GEOFLUIDS
.16
Hydration
of ions
.17
Ion pairing and clustering
.18
Speciation
.19
EFFECTS OF TEMPERATURE, PRESSURE/DENSITY, AND
CONCENTRATION ON THE
HYDRATION
OF IONS IN SOLUTION
.20
Temperature, pressure and concentration effects on the of hydration
shell structure
.22
FLUID THERMODYNAMICS ON THE MACROSCOPIC AND MOLECULAR
SCALES IN THE CRITICAL AND SUPERCRITICAL REGIONS
.24
An explanation of the divergence of derivative thermodynamic properties
near the critical point
.24
The molecular-scale picture behind near-critical divergence
.25
Thermodynamics ofGeothermal Fluids
-
Table of Contents
POSSIBLE FUTURE ROUTES TOWARDS IMPROVED
THERMODYNAMIC MODELS FOR GEOTHERMAL FLUIDS FROM
AMBIENT TO SUPERCRITICAL CONDITIONS
.28
REFERENCES
.30
ó
Thermodynamics of Aqueous Species at
High Temperatures and Pressures:
Equations of State and Transport Theory
David
Dolejš
INTRODUCTION
.35
CONCENTRATION SCALES AND CONVERSION RELATIONSHIPS
.36
CONVENTIONS FOR THERMODYNAMIC PROPERTIES
.39
BASIC THERMODYNAMIC MODELS FOR AQUEOUS EQUILIBRIA
.42
Approximations to the Gibbs energy function
.42
Predictions using the solvent density
.43
Predictions using the electrostatic theory
.45
EQUATIONS OF STATE FOR AQUEOUS SPECIES
.46
Thermodynamics of hydration
.46
Macroscopic thermodynamic models
.53
Electrostatic models
.54
Density models
.59
APPLICATIONS OF AQUEOUS THERMODYNAMICS
TO FLUID-ROCK INTERACTIONS
.64
Transport theory and estimation of fluid fluxes
.65
CONCLUDING REMARKS AND PERSPECTIVES
.70
ACKNOWLEDGMENTS
.72
REFERENCES
. . .72
4
Mineral Solubility and Aqueous Speciation
Hydrothermal
Conditions to
300 °С -
The Carbonate System as an Example
Pascale Bénézeth, Andri
Stefansson,
Quentin Gautier, Jacques
Schott
INTRODUCTION
.
81
COMMON
TECHNIQUES
FOR EXPERIMENTS
AT
.
HYDROTHERMAL CONDITIONS
.
85
Batch reactors
. .
or
Electrode
systems and high temperature
pH
measurements and titrations
.89
In situ vibrational and electronic spectroscopy
96
SPECIATION AND THERMODYNAMIC STABILITIES IN
.
CARBON-CONTAINING AQUEOUS SOLUTIONS
.97
vi
Thermodynamics of
Geothermal
Fluids
-
Table of Contents
Aqueous speciation of CCVbearing solutions
.97
Molecular structure of various aqueous carbon species
.102
CARBONATE SOLUBILITY AND MINERALIZATION
.105
Calcite
.106
Magnesium-carbonates
.109
Dolomite
.120
Siderite
.121
CONCLUSION
.124
ACKNOWLEDGMENTS
.124
REFERENCES
.124
Э
Thermodynamic Modeling of Fluid-Rock Interaction
at Mid-Crustal to Upper-Mantle Conditions
Craig E. Manning
INTRODUCTION
.135
CHEMICAL POTENTIALS OF AQUEOUS SPECIES IN
НЮН-РГ
FLUIDS
.136
Standard state chemical potentials of aqueous species
.136
Activity models for aqueous species
.139
COMPARISON OF EXPERIMENTAL AND CALCULATED
MINERAL SOLUBILITY
.142
APPLICATIONS
.146
Activity-activity diagrams
.146
Homogeneous equilibria
.148
The
pH
dependence of mineral solubility
.150
Buffering of
pH
by rock-forming minerals
.152
Salinity and saline brines
.154
"Excess" solubility and identification of additional solutes
.156
Concluding remarks
.159
ACKNOWLEDGMENTS
.160
REFERENCES
.160
Õ
Speciation and Transport of Metals and
Metalloids in Geological Vapors
Gleb
S.
Pokrovski, Anastassia Y.
Borisova,
Andrey
Y.
Bychkov
INTRODUCTION
.165
SPECIATION, THERMODYNAMICS, AND PARTITIONING
OF METALS AND METALLOIDS IN GEOLOGICAL VAPORS
.167
Volcanic vapors
.167
Hydrothermal-magmatic vapors
.171
Vapor-brine-supercritical fluid-silicate melt partitioning in experimental
and natural systems
.186
vii
Thermodynamics ofGeothermal Fluids
-
Table of Contents
ROLE OF THE VAPOR-LIKE FLUIDS IN METAL AND METALLOID
TRANSPORT IN NATURAL SYSTEMS AND THE FORMATION OF
ORE DEPOSITS
.192
Low-temperature boiling geothermal systems
.192
Magmatic
-hydrothermal
systems
.197
MAJOR CONCLUSIONS
.204
REMAINING GAPS AND NEAR-FUTURE CHALLENGES
.205
Analytical challenges
.205
Experimental challenges
.206
Modeling challenges
.207
ACKNOWLEDGMENTS
.208
REFERENCES
.208
/
Solution Calorimetry Under
Hydrothermal
Conditions
Peter Trentaine, Hugues ArcL·
INTRODUCTION
.219
THERMODYNAMIC RELATIONS
.220
Equations for the temperature and pressure dependence of Gibbs energies
and equilibrium constants
.220
Solvation effects
.221
The temperature dependence of standard partial molar properties
.224
"EQUATIONS OF STATE" FOR STANDARD PARTIAL MOLAR PROPERTIES
.225
The "density" model
.225
The Helgeson-Kirkham-Flowers-Tanger model
.226
THERMODYNAMICS OF SOLUTION CALORIMETRY
.228
Standard partial molar heat capacities and volumes
.228
Standard partial molar enthalpies and heats of mixing
.229
Excess properties
. 230
DENSIMETRY
.
ľľ^'ľľľľZZZZZľľ"Z'ľZľZZľ233
Vibrating-tube densimeters
. 233
HEAT-CAPACITY CALORIMETRY
.
.ΖΣΖΖΣΣΣΣΣΣΣΖ
.235
Pioneering studies
. 235
The Picker flow microcalorimeter
.236
Twin-cell differential scanning nanocalorimeters and Calvet calorimeters
.240
Integral heat of solution measurements
. . 243
HEAT OF MIXING CALORIMETRY
.245
Pioneering instruments
.245
Power-compensated isothermal flow heat of mixing calorimeters
.247
Flow heat of mixing cells in Calvet calorimeters
.249
Steam-gas mixtures
.252
Calibration of isothermal heat-of-mixing calorimeters
253
DISCUSSION
.255
Current state-of-the-art for
hydrothermal
solution calorimetry
.255
Data compilations
. 255
Some current areas for investigation
.255
viii
Thermodynamics of
Geołhermal
Fluids
-
Table of Contents
CONCLUDING REMARKS
.257
ACKNOWLEDGMENTS
.257
REFERENCES
.257
Ö
Structure and Thermodynamics of
Subduction
Zone Fluids from
Spectroscopie
Studies
Carmen Sanchez-Valle
INTRODUCTION
.265
CHEMISTRY AND STRUCTURE OF
SUBDUCTION
ZONE FLUIDS
.266
Chemistry of
subduction
zone fluids
.266
Polymerization of silicate components in high-pressure fluids
.267
CONTROLS ON TRACE ELEMENT SPECIATION IN
SUBDUCTION
ZONE FLUIDS
.272
STUDIES ON TRACE ELEMENT SPECIATION IN
SUBDUCTION
ZONE
FLUIDS BY X-RAY ABSORPTION SPECTROSCOPY
.273
X-ray absorption spectroscopy
(XAS)
.274
XAS
measurements in high-pressure fluids
.274
SPECIATION OF TRACE ELEMENTS IN
SUBDUCTION
ZONE FLUIDS
.277
Speciation of High Field Strength Elements (HFSE)
.277
Speciation of Rare Earth Elements (REE)
.281
MOBILIZATION AND FRACTIONATION OF TRACE ELEMENTS IN
SUBDUCTION
ZONES
.284
High Field Strength Elements (HFSE)
.284
Mobilization of REE and LREE/HREE fractionation
.285
PRESSURE-VOLUME-TEMPERATURE-COMPOSITION (PVTx) RELATIONS
AND THERMODYNAMIC PROPERTIES OF AQUEOUS FLUIDS
.285
Equations of state (EoS) for aqueous fluids
.285
Experimental studies of PVTx properties in aqueous systems
.286
EQUATIONS OF STATE OF FLUIDS FROM SOUND VELOCITY
MEASUREMENTS BY BRILLOUIN SPECTROSCOPY
.287
Principles of Brillouin scattering spectroscopy
.288
Brillouin spectroscopy of fluids underpressure
.290
Determination of density from measured sound velocities
.291
PHYSICO-CHEMISTRY OF AQUEOUS FLUIDS AT ELEVATED
PRESSURES
(> 0.5
GPa)
.292
Volumetric properties of high-pressure aqueous fluids
(> 0.5
GPa)
.292
Solute-solvent interactions in salt solutions under pressure
.295
Fugacity
and activity of water in high-pressure salt solutions
.297
CONCLUDING REMARKS AND OUTLOOK
.301
ACKNOWLEDGMENTS
.302
REFERENCES
.302
ix
Thermodynamics of Geothermal Fluids
-
Table of Contents
9
Thermodynamics of Organic Transformations
in
Hydrothermal
Fluids
Everett
L
Shock, Peter
Canovas,
Zitning Yang,
Grayson Boy
er,
Kristin Johnson, Kirtland Robinson,
Kristopher Fecteau, Todd Windman, Alysia Cox
MESSAGES FROM NATURE
.311
ORGANIC INVENTORY OF
HYDROTHERMAL
FLUIDS
.311
HYDROTHERMAL
ORGANIC TRANSFORMATION PROCESSES
.315
THERMODYNAMIC EXPLANATIONS
.320
Hydrocarbon dissolution
.320
Hydration/dehydration
.323
Oxidation/reduction
.324
Relative stabilities
.328
EXPERIMENTAL TESTS
.332
Hydration/dehydration reactions
.332
Oxidation/reduction reactions
.335
Relative stabilities and irreversible reactions
.337
FUTURE DIRECTIONS FOR
HYDROTHERMAL
ORGANIC
TRANSFORMATIONS
.341
REFERENCES
.342 |
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| id | DE-604.BV041286079 |
| illustrated | Illustrated |
| indexdate | 2024-07-20T06:25:36Z |
| institution | BVB |
| isbn | 9780939950911 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-026735158 |
| oclc_num | 858599730 |
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| owner | DE-703 DE-B16 DE-12 DE-29 |
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| physical | X, 350 S. Ill., graph. Darst., Kt. |
| publishDate | 2013 |
| publishDateSearch | 2013 |
| publishDateSort | 2013 |
| publisher | Mineralogical Soc. of America |
| record_format | marc |
| series | Reviews in mineralogy and geochemistry |
| series2 | Reviews in mineralogy and geochemistry |
| spelling | Thermodynamics of geothermal fluids ed. Andri Stefánsson ... Chantilly, Va. Mineralogical Soc. of America 2013 X, 350 S. Ill., graph. Darst., Kt. txt rdacontent n rdamedia nc rdacarrier Reviews in mineralogy and geochemistry 76 Literaturangaben Thermodynamik (DE-588)4059827-5 gnd rswk-swf Hydrogeologie (DE-588)4026307-1 gnd rswk-swf Hydrogeochemie (DE-588)4225478-4 gnd rswk-swf Geothermik (DE-588)4020285-9 gnd rswk-swf Hydrogeologie (DE-588)4026307-1 s Hydrogeochemie (DE-588)4225478-4 s Geothermik (DE-588)4020285-9 s Thermodynamik (DE-588)4059827-5 s DE-604 Stefánsson, Andri edt Reviews in mineralogy and geochemistry 76 (DE-604)BV013377203 76 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026735158&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Thermodynamics of geothermal fluids Reviews in mineralogy and geochemistry Thermodynamik (DE-588)4059827-5 gnd Hydrogeologie (DE-588)4026307-1 gnd Hydrogeochemie (DE-588)4225478-4 gnd Geothermik (DE-588)4020285-9 gnd |
| subject_GND | (DE-588)4059827-5 (DE-588)4026307-1 (DE-588)4225478-4 (DE-588)4020285-9 |
| title | Thermodynamics of geothermal fluids |
| title_auth | Thermodynamics of geothermal fluids |
| title_exact_search | Thermodynamics of geothermal fluids |
| title_full | Thermodynamics of geothermal fluids ed. Andri Stefánsson ... |
| title_fullStr | Thermodynamics of geothermal fluids ed. Andri Stefánsson ... |
| title_full_unstemmed | Thermodynamics of geothermal fluids ed. Andri Stefánsson ... |
| title_short | Thermodynamics of geothermal fluids |
| title_sort | thermodynamics of geothermal fluids |
| topic | Thermodynamik (DE-588)4059827-5 gnd Hydrogeologie (DE-588)4026307-1 gnd Hydrogeochemie (DE-588)4225478-4 gnd Geothermik (DE-588)4020285-9 gnd |
| topic_facet | Thermodynamik Hydrogeologie Hydrogeochemie Geothermik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026735158&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV013377203 |
| work_keys_str_mv | AT stefanssonandri thermodynamicsofgeothermalfluids |