Crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics:
Saved in:
| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
Jülich
Forschungszentrum Jülich
2012
|
| Series: | Schriften des Forschungszentrums Jülich
Reihe Schlüsseltechnologien ; 44 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Zsfassung in dt. und engl. Sprache |
| Physical Description: | III, 190 S. Ill., graph. Darst. |
| ISBN: | 9783893368020 |
Staff View
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Record in the Search Index
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| adam_text | IMAGE 1
C O N T E N T S
1 M U L T I F E R R O I C C O M P O U N D S 1
1.1 INTRODUCTION 2
1.2 MAGNETOELECTRIC MULTIFERROICS 3
1.2.1 T H E ORIGIN OF MULTIFERROICITY 4
1.2.2 DIFFERENT ROUTES T O MULTIFERROICITY 6
1.3 AIMS OF RESEARCH 11
2 T H E O R E T I C A L B A C K G R O U N D A N D E X P E R I M E N T A
L
M E T H O D S 13
2.1 SYNTHESIS OF POLYCRYSTALLINE POWDERS A N D GROWTH OF SINGLE CRYSTALS
. . . . 14
2.1.1 SOLID S T A T E REACTION ROUTE 14
2.1.2 CRYSTAL GROWTH BY OPTICAL FLOATING ZONE TECHNIQUE 15
2.2 POWDER X-RAY DIFFRACTION 17
2.2.1 THEORETICAL BACKGROUND 17
2.2.2 EXPERIMENTAL TECHNIQUE 22
2.3 NEUTRON SCATTERING 24
2.3.1 THEORETICAL BACKGROUND 24
2.3.2 SCATTERING FORMULAE 25
2.3.3 EXPERIMENTAL TECHNIQUES 35
3 S T R U C T U R A L , M A G N E T I C A N D T H E R M A L P R O P E R
T I E S O F
H O C R 0 3 4 1
3.1 INTRODUCTION 42
3.2 EXPERIMENTAL 44
3.3 RESULTS 44
3.3.1 CRYSTAL STRUCTURE 44
3.3.2 MAGNETIZATION 48
3.3.3 SPECIFIC H E A T 49
3.4 DISCUSSION 58
3.5 CONCLUSIONS 60
I
HTTP://D-NB.INFO/1025093828
IMAGE 2
C O N T E N T S
4 M A G N E T I C O R D E R I N G A N D M A G N E T O E L A S T I C E F
F E C T I N
H O C R 0 3 6 3
4.1 INTRODUCTION 64
4.2 EXPERIMENTAL 65
4.3 RESULTS A N D DISCUSSION 66
4.3.1 MAGNETIC ORDERING 66
4.3.2 MAGNETOELASTIC EFFECT 79
4.4 CONCLUSIONS 82
5 C R Y S T A L F I E L D S A N D M A G N E T I C E X C I T A T I O N S
I N H O C R 0 3 8 5
5.1 INTRODUCTION 86
5.2 CRYSTAL FIELD CALCULATION 86
5.2.1 CRYSTAL FIELD THEORY VERSUS LIGAND FIELD THEORY 86
5.2.2 POINT-CHARGE MODEL 87
5.3 EXPERIMENTAL 91
5.4 RESULTS A N D DISCUSSION 91
5.4.1 CRYSTAL FIELD LEVELS 91
5.4.2 SPIN FLUCTUATIONS 97
5.5 CONCLUSIONS 99
6 U N C O N V E N T I O N A L M A G N E T I C O R D E R I N G I N H E X
A G O N A L
D Y M N 0 3 1 0 1
6.1 INTRODUCTION 102
6.2 EXPERIMENTAL RESULTS A N D DISCUSSION 103
6.2.1 SYNTHESIS A N D GROWTH OF SINGLE CRYSTALS 103
6.2.2 STRUCTURAL PROPERTIES 104
6.2.3 MAGNETIC PROPERTIES 107
6.2.4 T H E R M A L PROPERTIES 110
6.2.5 NEUTRON SCATTERING MEASUREMENTS 114
6.2.6 SINGLE CRYSTAL N E U T R O N SCATTERING MEASUREMENTS 120
6.3 CONCLUSIONS . . * 123
7 I N C O M M E N S U R A T E M A G N E T I C O R D E R I N G I N
MNO.9MO.1WO4
( M = C O , C U ) 1 2 7
7.1 INTRODUCTION 128
7.2 EXPERIMENTAL 129
7.2.1 SYNTHESIS 129
7.2.2 CRYSTAL S T R U C T U R E 130
7.2.3 MAGNETIC A N D T H E R M A L PROPERTIES 130
I I
IMAGE 3
CONTENTS
7.3 MAGNETIC ORDERING 133
7.3.1 EXPERIMENTAL 133
7.3.2 MAGNETIC S T R U C T U R E REFINEMENT 134
7.4 S U M M A R Y AND CONCLUSIONS 139
8 S U M M A R Y A N D O U T L O O K 1 4 1
8.1 ORTHORHOMBIC H O C R 0 3 142
8.2 HEXAGONAL D Y M N 0 3 144
8.3 WOLFRAMITE MNO.9COO.1WO4 A N D MNO.9CUO.1WO4 145
APPENDICES
A LIST O F ACRONYMS 1 4 9
B T H E R I E T V E L D M E T H O D 1 5 1
C CRYSTAL A N D M A G N E T I C STRUCTURE D E T E R M I N A T I O N O F
H O C R O S 1 5 7
C . L REPRESENTATION ANALYSIS OF H O C R 0 3 WITH B A S L R E P S 157
C.2 MAGNETIC STRUCTURE REFINEMENT OF HOCROS USING F U L L P R O F 159
D REFINED STRUCTURE PARAMETERS O F H O C R O S 163
E REFINED STRUCTURE PARAMETERS O F /IDYMNOA 165
F F U L L P R O F CONTROL (INPUT) FILES USED FOR T H E R I E T V E L D
REFINEMENT O F T H E
MAGNETIC STRUCTURES O F M N I _ X M 3 ; W 0 4 169
BIBLIOGRAPHY 175
ACKNOWLEDGEMENTS
I I I
|
| any_adam_object | 1 |
| author | Chogondahalli Muniraju, Naveen Kumar |
| author_GND | (DE-588)102677392X |
| author_facet | Chogondahalli Muniraju, Naveen Kumar |
| author_role | aut |
| author_sort | Chogondahalli Muniraju, Naveen Kumar |
| author_variant | m n k c mnk mnkc |
| building | Verbundindex |
| bvnumber | BV041092843 |
| ctrlnum | (OCoLC)854728506 (DE-599)DNB1025093828 |
| format | Thesis Book |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV041092843 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:39:25Z |
| institution | BVB |
| isbn | 9783893368020 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-026069403 |
| oclc_num | 854728506 |
| open_access_boolean | |
| owner | DE-12 |
| owner_facet | DE-12 |
| physical | III, 190 S. Ill., graph. Darst. |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | Forschungszentrum Jülich |
| record_format | marc |
| series | Schriften des Forschungszentrums Jülich |
| series2 | Schriften des Forschungszentrums Jülich : Reihe Schlüsseltechnologien |
| spelling | Chogondahalli Muniraju, Naveen Kumar Verfasser (DE-588)102677392X aut Crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics Naveen Kumar Chogondahalli Muniraju Jülich Forschungszentrum Jülich 2012 III, 190 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Schriften des Forschungszentrums Jülich : Reihe Schlüsseltechnologien 44 Zsfassung in dt. und engl. Sprache Zugl.: Aachen, Techn. Hochsch., Diss., 2012 Thermodynamische Eigenschaft (DE-588)4126056-9 gnd rswk-swf Chromate (DE-588)4318015-2 gnd rswk-swf Manganate (DE-588)4168785-1 gnd rswk-swf Kristallstrukturanalyse (DE-588)4137204-9 gnd rswk-swf Perowskitstruktur (DE-588)4275319-3 gnd rswk-swf Multiferroikum (DE-588)7845875-4 gnd rswk-swf Wolframate (DE-588)4190201-4 gnd rswk-swf Neutronenstreuung (DE-588)4041980-0 gnd rswk-swf Magnetische Eigenschaft (DE-588)4129002-1 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Multiferroikum (DE-588)7845875-4 s Manganate (DE-588)4168785-1 s Chromate (DE-588)4318015-2 s Perowskitstruktur (DE-588)4275319-3 s Kristallstrukturanalyse (DE-588)4137204-9 s Magnetische Eigenschaft (DE-588)4129002-1 s Thermodynamische Eigenschaft (DE-588)4126056-9 s Neutronenstreuung (DE-588)4041980-0 s DE-604 Wolframate (DE-588)4190201-4 s Schriften des Forschungszentrums Jülich Reihe Schlüsseltechnologien ; 44 (DE-604)BV023237997 44 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026069403&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Chogondahalli Muniraju, Naveen Kumar Crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics Schriften des Forschungszentrums Jülich Thermodynamische Eigenschaft (DE-588)4126056-9 gnd Chromate (DE-588)4318015-2 gnd Manganate (DE-588)4168785-1 gnd Kristallstrukturanalyse (DE-588)4137204-9 gnd Perowskitstruktur (DE-588)4275319-3 gnd Multiferroikum (DE-588)7845875-4 gnd Wolframate (DE-588)4190201-4 gnd Neutronenstreuung (DE-588)4041980-0 gnd Magnetische Eigenschaft (DE-588)4129002-1 gnd |
| subject_GND | (DE-588)4126056-9 (DE-588)4318015-2 (DE-588)4168785-1 (DE-588)4137204-9 (DE-588)4275319-3 (DE-588)7845875-4 (DE-588)4190201-4 (DE-588)4041980-0 (DE-588)4129002-1 (DE-588)4113937-9 |
| title | Crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics |
| title_auth | Crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics |
| title_exact_search | Crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics |
| title_full | Crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics Naveen Kumar Chogondahalli Muniraju |
| title_fullStr | Crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics Naveen Kumar Chogondahalli Muniraju |
| title_full_unstemmed | Crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics Naveen Kumar Chogondahalli Muniraju |
| title_short | Crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics |
| title_sort | crystal and spin structure and their relation to physical properties in some geometrical and spin spiral multiferroics |
| topic | Thermodynamische Eigenschaft (DE-588)4126056-9 gnd Chromate (DE-588)4318015-2 gnd Manganate (DE-588)4168785-1 gnd Kristallstrukturanalyse (DE-588)4137204-9 gnd Perowskitstruktur (DE-588)4275319-3 gnd Multiferroikum (DE-588)7845875-4 gnd Wolframate (DE-588)4190201-4 gnd Neutronenstreuung (DE-588)4041980-0 gnd Magnetische Eigenschaft (DE-588)4129002-1 gnd |
| topic_facet | Thermodynamische Eigenschaft Chromate Manganate Kristallstrukturanalyse Perowskitstruktur Multiferroikum Wolframate Neutronenstreuung Magnetische Eigenschaft Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026069403&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV023237997 |
| work_keys_str_mv | AT chogondahallimunirajunaveenkumar crystalandspinstructureandtheirrelationtophysicalpropertiesinsomegeometricalandspinspiralmultiferroics |