Handbook of laser induced breakdown spectroscopy:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Chichester
Wiley
2013
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | Includes bibliographical references and index. - Formerly CIP |
| Beschreibung: | XVII, 407 S. Ill., graph. Darst. |
| ISBN: | 9781119971122 |
Internformat
MARC
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| 100 | 1 | |a Cremers, David A. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Handbook of laser induced breakdown spectroscopy |c David A. Cremers ; Leon J. Radziemski |
| 246 | 1 | 3 | |a Handbook of laser-induced breakdown spectroscopy |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Chichester |b Wiley |c 2013 | |
| 300 | |a XVII, 407 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index. - Formerly CIP | ||
| 650 | 0 | 7 | |a Laserinduzierte Breakdown-Spektroskopie |0 (DE-588)4745837-9 |2 gnd |9 rswk-swf |
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| 700 | 1 | |a Radziemski, Leon J. |e Verfasser |4 aut | |
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Datensatz im Suchindex
| _version_ | 1804150317544112128 |
|---|---|
| adam_text | Contents
Preface
x¡
Acronyms, Constants, and Symbols xv
1
Introduction
1
1.1
Atomic Optical Emission Spectrochemistry
(OES)
1
1.1.1
Conventional
OES
1
1.1.2
Laser
OES
1
1.2
Laser-índuced
Breakdown Spectroscopy (LIBS)
2
1.3
LIBS History
1960-1980 7
1.4
LIBS History
1981-1990 9
1 -5
LIBS History
1991 -2000 11
1.6
LIBS History
2001-2012 14
References
18
2
Basics of the LIBS Plasma
29
2. !
LIBS Plasma Fundamentals
29
2.1.1
Spectral Lines and Line Profiles
32
2.1.2
Determining Electron Densities from Spectral Line Widths
34
2.1.3
Plasma Opacity
37
2.1.4
Temperature and Thermodynamic Equilibrium
38
2.2
Laser-Induced Breakdown
46
2.2.1
Breakdown in Gases
46
2.2.2
Post-Breakdown Phenomena in Gases
48
2.2.3
Breakdown in and on Solids, Aerosols, and Liquids
48
2.2.4
Post-Breakdown Phenomena on Solid Surfaces
50
2.3
Laser Ablation from Surfaces and Aerosols
53
2.4
Nanosecond and Femtosecond Double- or Multiple-Pulse LIBS
58
2.5
Summary
63
2.6
Problems
63
References
64
3
LIBS Apparatus Fundamentals
69
3.1
Basic LIBS Apparatus
69
3.2
Lasers
70
3.2.1
Laser Fundamentals
70
3.2.2
Types of Lasers
72
3.2.3
Properties of Laser Light Important for LIBS
76
viii Contents
3.2.4 Generation
of Additional Wavelengths
78
3.2.5
Double-Pulse Operation
78
3.3
Optical Systems
80
3.3.1
Focusing and Light Collection
80
3.3.2
Lenses
82
3.3.3
Fiber Optic Cables
82
3.4
Methods of Spectral Resolution
86
3.4.1
Introduction
86
3.4.2
Spectral Resolution Devices
88
102
109
109
110
114
115
117
118
123
123
123
129
131
131
138
140
144
144
146
References
148
References for Detection Limits
150
Qualitative LIBS Analysis
151
5.1
Introduction
151
5 .2
Identifying Elements
151
5.3
Material Identification
156
5.4
Process Monitoring
159
5.4.1
Introduction
159
5.4.2
Experimental
162
5.4.3
Results
163
5.4.4
Conclusions
169
5.5
Material Sorting/Distinguishing
169
5.5.1
Surface Condition
169
5.5.2
Type of Analysis
171
5.5.3
Sorting Materials of Close Composition
173
5.5.4
Other Examples of Material Identification
174
3.5
Detectors
3.6
Detection System Calibrations
3.6.1
Wavelength Calibration
3.6.2
Spectral Response Calibration
3.7
Timing Considerations
3.8
Methods of LIBS Deployment
3.9
Problems
References
LIBS Analytical Figures of Merit and Calibration
4.1
Introduction
4.2
Basics of a LIBS Measurement
4.3
Precision
4.4
Calibration
4.4.1
Calibration Curves
4.4.2
Calibration Standards
4.4.3
Calibration-Free LIBS
4.5
Detection Limit
4.6
Accuracy
4.7
Problems
Contents ix
5.6 Site
Screening Using LIBS
177
5.7 Semiquantitative
Analysis
178
5.8
Problems
180
References
182
6
Quantitative LIBS Analysis
185
6.1
Introduction
185
6.2
Effects of Sampling Geometry
185
6.3
Other Sampling Considerations
189
6.4
Incomplete Vaporization and Ablation Stoichiometry
193
6.5
Use of Internal Standardization
194
6.6
Chemical Matrix Effects
196
6.7
Example of LIBS Measurement: Impurities in Lithium-Containing
Solutions
198
6.7.1
Objective
198
6.7.2
Experimental
198
6.7.3
Results
201
6.7.4
Discussion of Results
205
6.8
Example of LIBS Measurement: Detection of Materials on Swipes
206
6.8.1
Objective
206
6.8.2
Experimental
206
6.8.3
Results
209
6.9
Reported Figures of Merit for LIBS Measurements and Comparison
with Standard Methods
211
6.10
Enhancing Quantitative Analysis via Sophisticated Signal Processing
219
6.11
Conclusions
220
References
221
7
Chemometric Analysis in LIBS
223
7.1
Introduction
223
7.2
Chemometric Terms
227
7.3
Chemometric Analysis/Model Development
232
7.3.1
Data Collection
232
7.3.2
Data Preprocessing: Selection of Variables
234
7.3.3
Train the Model (Calibration)
236
7.3.4
Selecting the Criteria for Classification
238
7.3.5
Test the Model (Validation)
239
7.3.6
Refine the Model Parameters
239
7.3.7
Using the Model
240
7.3.8
Improve the Training Data
241
7.4
Summary
241
References
241
S
Remote LIBS Measurements
257
8.1
Introduction
257
8.2
Conventional Open-Path LIBS
259
χ
Contents
8.2.1
Apparatus
259
8.2.2
Focusing the Laser Pulse
260
8.2.3
Collecting the Plasma Light
264
8.2.4
Results Using Conventional Open-Path LIBS
265
8.3
Standoff LIBS Using Femtosecond Pulses
270
8.3.1
Conventional Remote LIBS Using Femtosecond Laser Pulses
270
8.3.2
Remote Analysis by Filamentation Produced by Femtosecond
Pulses
271
8.4
Fiber Optic LIBS
276
8.4.1
Fiber Optics for Light Collection
276
8.4.2
Fibers for Laser Pulse Delivery
277
8.4.3
Applications of Fiber Optics
280
References
284
9
Selected LIBS Applications
289
9.1
Introduction
289
9.2
LIBS and the CBRNE Threats
289
9.2.1
Background
289
9.2.2
Nuclear Material and Isotope Detection
291
9.2.3
Detection of Explosives
294
9.2.4
Chemical and Biological Agent Detection
295
9.3
LIBS Analysis of Liquids and Solids in Liquids
297
9.4
Transportable LIBS Instrument for Stand-off Analysis
303
9.4.1
Instrument Design
303
9.4.2
Instrument Capabilities
307
9.4.3
Consideration of Detection Scenarios
312
9.5
LIBS for Space Applications
313
9.5.1
Background
313
9.5.2
Laboratory Studies of LIBS for Space Missions
313
9.5.3
ChemCam LIBS Instrument on MSL Rover
322
References
325
A Safety Considerations in LIBS
333
В
Major LIBS References
337
С
Detection Limits from the Literature
341
D
Examples of LIBS Spectra
377
E
Solutions to Problems
387
Index
397
Second Edition
Handbook of
LASER-INDUCED
BREAKDOWN
SPECTROSCOPY
David
Α.
Cremers, Applied Research Associates Ine,
Albuquerque,
NM,
USA
Leon J. Radziemski,
Tucson,
AZ,
USA
This fully updated new edition of the Handbook of Laser-Induced Breakdown Spectroscopy presents:
•
Comprehensive coverage of the basic principles of LIBS methodology
•
A discussion of the many advantages of the method, along with limitations, providing a balanced overview
of its capabilities
•
The different types of components that can be used for LIBS apparatuses
•
The methods of sampling in different media
•
An overview of real-world applications of the method.
The authors have induded in this second edition:
•
New chapters on:
•
the rapidly growing area of chemometric-based analysis of UBS spectra for the identification
of complex materials
*
some of the latest UBS applications including design and capabilities of an open path stand-off
instrument
•
End-of-chapter Problems to challenge the reader s understanding
•
Updated data tables related to analysis using UBS
•
A new Appendix showing annotated UBS spectra
|
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| discipline | Chemie / Pharmazie Physik |
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| id | DE-604.BV040993695 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:37:00Z |
| institution | BVB |
| isbn | 9781119971122 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025971440 |
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| physical | XVII, 407 S. Ill., graph. Darst. |
| publishDate | 2013 |
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| spelling | Cremers, David A. Verfasser aut Handbook of laser induced breakdown spectroscopy David A. Cremers ; Leon J. Radziemski Handbook of laser-induced breakdown spectroscopy 2. ed. Chichester Wiley 2013 XVII, 407 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index. - Formerly CIP Laserinduzierte Breakdown-Spektroskopie (DE-588)4745837-9 gnd rswk-swf Laserinduzierte Breakdown-Spektroskopie (DE-588)4745837-9 s DE-604 Radziemski, Leon J. Verfasser aut Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025971440&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025971440&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Cremers, David A. Radziemski, Leon J. Handbook of laser induced breakdown spectroscopy Laserinduzierte Breakdown-Spektroskopie (DE-588)4745837-9 gnd |
| subject_GND | (DE-588)4745837-9 |
| title | Handbook of laser induced breakdown spectroscopy |
| title_alt | Handbook of laser-induced breakdown spectroscopy |
| title_auth | Handbook of laser induced breakdown spectroscopy |
| title_exact_search | Handbook of laser induced breakdown spectroscopy |
| title_full | Handbook of laser induced breakdown spectroscopy David A. Cremers ; Leon J. Radziemski |
| title_fullStr | Handbook of laser induced breakdown spectroscopy David A. Cremers ; Leon J. Radziemski |
| title_full_unstemmed | Handbook of laser induced breakdown spectroscopy David A. Cremers ; Leon J. Radziemski |
| title_short | Handbook of laser induced breakdown spectroscopy |
| title_sort | handbook of laser induced breakdown spectroscopy |
| topic | Laserinduzierte Breakdown-Spektroskopie (DE-588)4745837-9 gnd |
| topic_facet | Laserinduzierte Breakdown-Spektroskopie |
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