Polymer-graphene nanocomposites:
Saved in:
| Other Authors: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Cambridge
RSC-Publ.
2012
|
| Series: | RSC nanoscience and nanotechnology
26 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | XI, 267 S. Ill., graph. Darst. |
| ISBN: | 9781849735674 |
Staff View
MARC
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Record in the Search Index
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| adam_text | Contents
Chapter
1 Graphene
Functìonalization:
Λ
Review 1
Mo Song and Dongyu
Cai
1.1
Introduction
1
1.2
Fabrication of Graphene
3
1.2.1
Mechanical Cleavage
3
1.2.2
Reduction of Graphene Oxide
5
1.2.3
Chemical Vapour Deposition
12
1.2.4
Synthesis of Graphene Nanoribbons (GNRs)
14
1.2.5
Other Methods
17
1.3
Functìonalization
of Graphene
19
1.3.1
Functionalization of Graphene with Organic
Species
19
1.3.2
Functionalization of Graphene with
Macromolecules
24
1.3.3
Functionalization of Graphene with Inorganic
Nanoparticles (INPs)
30
1.4
Functionalized Graphene-Polymer Nanocomposites
(FPNs)
35
1.4.1
Fabrication
36
1.4.2
Mechanical Properties
36
1.4.3
Electrical Properties
38
1.4.4
Thermal Properties
39
1.5
Conclusions and Perspective
42
References
44
RSC Nanoscience
&
Nanotechnology No.
26
Polymer-Graphene Nanocomposites
Edited by
Vikas
Mittaí
г
The Royal Society of Chemistry
2012
Published by the Royal Society of Chemistry, www.rsc.org
vii
viii Contents
Chapter
2
Gelation of Graphene Oxide
52
Gaoquan Shi
2.1
Introduction
52
2.2
GO-Based Gels
53
2.2.1
Acid-Induced Gelation
53
2.2.2
Cross-linker-Induced Gelation
55
2.3
Reduced GO-Based Gels
60
2.3.1 Hydrothermal
or Solvothermal Reduction
60
2.3.2
Chemical Reduction
62
2.3.3
Electrochemical Reduction
62
2.4
Conclusion
63
Acknowledgements
63
References
63
Chapter
3
Electrically Conductive Polymer-Graphene Composites
Prepared Using Latex Technology
66
Nadia
Grossiord, Marie-Claire Hermant and Evgeniy
Tkaly
a
3.1
Introduction
66
3.2
Fundamentals of Latex Technology
67
3.2.1
In Situ Polymerization and Heterocoagulation
Strategies
70
3.3
Graphene-Polymer Composites via Latex Technology
72
3.4
Graphene-Polymer Composite Production: An
Overview
75
3.5
Industrial Relevance
76
3.6
Conclusion
81
References
82
Chapter
4
Polymer-Graphene Nanocomposites by Living Polymerization
(RAFT) in
Miniemulsion
86
Hussein M. Etmimi and Ron D. Sanderson
4.1
Introduction
86
4.2
Synthesis of PGNs Based on Functionalized Graphene
87
4.3
Miniemulsion
Polymerization
89
4.3.1
Miniemulsion Versus Emulsion Polymerization
90
4.3.2
Typical Miniemulsion Formulations
91
4.3.3
Preparation of
Miniemulsions
92
4.3.4
Initiators Used in
Miniemulsions
93
4.3.5
Miniemulsion Polymerization for the Synthesis
of PGNs
94
Contents ix
4.4
Conventional Free Radical Polymerization Versus
Controlled/Living Radical Polymerization
95
4.5
Fundamentals of CLRP
96
4.6
Common CLRP Techniques
97
4.6.1
NMP
97
4.6.2
ATRP
98
4.6.3
RAFT-Mediated Polymerization
99
4.7
RAFT-Mediated Emulsion Polymerization Versus
Miniemulsion
Polymerization
100
4.8
Synthesis of PGNs Using the RAFT Process in
Miniemulsion
101
4.9
Characterization of PGNs Synthesized by the RAFT
Method
103
4.9.1
FT-IR and Solubility Analysis
103
4.9.2
ТЕМ
Analysis
105
4.9.3
XRD Analysis
106
4.9.4
SEC Analysis
107
4.9.5
Mechanical Properties
108
4.9.6
Thermal Stability
110
4.10
Conclusions 111
References
112
Chapter
5
In Situ Polymerization in the Presence of Graphene
117
Yuan
Ни
and Chenlu
Bao
117
118
121
124
125
126
130
131
132
References
132
Chapter
6
Microstructure and Properties of Compatibilized
Polyethylene-Graphene Oxide Nanocomposites
141
A. U. Chaudhry,
Vikas
Mittal
and
N.
B. Matsko
6.1
Introduction
141
6.2
Experimental
144
6.2.1
Materials
144
5.1
Introduction
5.2
Polyaniline
(PANI)
5.3
Polypyrrole (PPy)
5.4
Epoxy
5.5
Poly(methyl methacrylate) (PMMA)
5.6
Polystyrene (PS)
5.7
Polyurethane
(PU)
5.8
Other Polymers
5.9
Summary
Contents
6.2.2
Preparation of Graphite Oxide and Graphene
Oxide
144
6.2.3
Nanocomposite Generation
145
6.2.4
Material Characterization
145
6.3
Results and Discussion
146
6.4
Conclusions
159
Acknowledgements
159
References
159
Chapter
7 pH-Sensitive
Graphene-Polymer Nanocomposites
162
Jingquan Liu and Thomas P. Davis
7.1
Introduction
162
7.2
Preparation of Graphene-Polymer Nanocomposites
164
7.2.1
Covalent Bonding
164
7.2.2
Non-Covalent Interactions
165
7.3
Applications of
pH-Sensitive
Graphene Polymer
Nanocomposites
167
7.3.1
Sensors and Detection Devices
167
7.3.2
Catalysis and Cells
170
7.3.3
Supercapacitors
171
7.3.4
Drug Delivery
172
7.3.5
Others
173
7.4
Conclusions and Perspectives
174
Acknowledgement
174
References
174
Chapter
8
Disperatole
Graphene Oxide-Polymer Nanocomposites
179
Gang Liu, Koon-Gee Neoh and En-Tang
Kong
8.1
Introduction
179
8.2
Covalently Functionalized Graphene Oxide-Polymer
Nanocomposites
180
8.3
The Grafting from Approach
182
8.4
The Grafting to Approach
189
8.5
Non-Covalent Functionalization of Graphene Oxide
Nanosheets
196
8.6
Summary and Future Challenges
203
References
204
Contents xi
Chapter
9 Graphene-Conducting
Polymer Nanocomposites Prepared by
Interfacial
Polymerization
211
Sergio H. Domingues,
Rodrigo
V.
Salvatierra
and
Aldo
J. G.
Zarbin
9.1
Introduction
211
9.2
Conducting Polymers
212
9.2.1
Polyaniline
(PANI)
213
9.3
Graphene-Polyaniline
Nanocomposites
214
9.4
Graphene-Polyaniline Nanocomposites Through
Interfacial
Polymerization
215
9.5
Conclusion and Final Remarks
223
References
224
Chapter
10
Crystallization Properties of Isotactic Polypropylene—
Graphene Nanocomposites
227
Jia-Zhuang Xu, Zhong-Ming Li and Benjamin S. Hsiao
10.1
Introduction
227
10.2
Intrachain
Confo
rmational Ordering of iPP-
Graphene Nanocomposites
229
10.3
Crystallization Kinetics of iPP-Graphene
Nanocomposites Under Shear Flow
235
10.3.1
Crystallization Under Quiescent Conditions
235
10.3.2
Crystallization Under Shear Flow
236
10.3.3
Combined Effect of GNSs and Shear Flow on
Crystallization of iPP
245
10.4
Summary
249
Acknowledgement
249
References
249
Subject Index
252
Graphene
is an emerging material for generating polymer
nanocomposites. Its heat conducting properties are greater than any
other material, yet so dense not even helium can pass through its
honeycomb lattice. The inclusion of small amounts of graphene to
polymer matrices has the possibility of significantly improving their
electrical, barrier and mechanical properties.
Since the Nobel prize for Physics was awarded in
2010
for the isolation
of graphene there has been an explosion in graphene research and
the discovery of new applications. This book discusses the current
state-of-the-art in graphene nanocomposites with expertise drawn
from across the globe. Insights into the functionalisation of graphene
are presented, in the context of various polymer systems, along with
appropriate methodologies to be adopted. Grasping this view from
several active researchers in the field gives the editor the opportunity
to look where future trends are heading.
This is an important handbook for anyone wishing to get a
comprehensive view of graphene nanocomposites and bring
established methodologies into their laboratory. Post-graduate
students and established researchers alike will benefit from this book.
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| id | DE-604.BV040979189 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:36:41Z |
| institution | BVB |
| isbn | 9781849735674 |
| language | English |
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| physical | XI, 267 S. Ill., graph. Darst. |
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| spelling | Polymer-graphene nanocomposites ed. by Vikas Mittal Polymer graphene nanocomposites Cambridge RSC-Publ. 2012 XI, 267 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier RSC nanoscience & nanotechnology 26 Nanokomposit (DE-588)4768127-5 gnd rswk-swf Graphen (DE-588)7591667-8 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Graphen (DE-588)7591667-8 s Polymere (DE-588)4046699-1 s Nanokomposit (DE-588)4768127-5 s DE-604 Mittal, Vikas (DE-588)140061096 edt RSC nanoscience and nanotechnology 26 (DE-604)BV035798085 26 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025957222&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025957222&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Polymer-graphene nanocomposites RSC nanoscience and nanotechnology Nanokomposit (DE-588)4768127-5 gnd Graphen (DE-588)7591667-8 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4768127-5 (DE-588)7591667-8 (DE-588)4046699-1 |
| title | Polymer-graphene nanocomposites |
| title_alt | Polymer graphene nanocomposites |
| title_auth | Polymer-graphene nanocomposites |
| title_exact_search | Polymer-graphene nanocomposites |
| title_full | Polymer-graphene nanocomposites ed. by Vikas Mittal |
| title_fullStr | Polymer-graphene nanocomposites ed. by Vikas Mittal |
| title_full_unstemmed | Polymer-graphene nanocomposites ed. by Vikas Mittal |
| title_short | Polymer-graphene nanocomposites |
| title_sort | polymer graphene nanocomposites |
| topic | Nanokomposit (DE-588)4768127-5 gnd Graphen (DE-588)7591667-8 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Nanokomposit Graphen Polymere |
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