Catalysis in ionic liquids: from catalyst synthesis to application
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| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Cambridge
Royal Soc. of Chemistry
2014
|
| Series: | RSC catalysis series
15 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIII, 620 S. Ill., graph. Darst. |
| ISBN: | 9781849736039 |
Staff View
MARC
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| 245 | 1 | 0 | |a Catalysis in ionic liquids |b from catalyst synthesis to application |c ed. by Chris Hardacre ... |
| 264 | 1 | |a Cambridge |b Royal Soc. of Chemistry |c 2014 | |
| 300 | |a XIII, 620 S. |b Ill., graph. Darst. | ||
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Record in the Search Index
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|---|---|
| adam_text | Contents
fí
Chapter
1
Catalytic Conversion of Biomass in Ionic Liquids
1
Hui
Wang, Leah E. Block and Robin D. Rogers
1.1
Introduction
1
1.2
Catalytic Dissolution of Lignocellulosic Biomass
2
1.3
Catalytic Degradation of Biomass
3
1.3.1
Catalytic Degradation of Cellulose
3
1.3.2
Catalytic Degradation of
Lignin
8
1.3.3
Catalytic Degradation of Hemicellulose
11
1.3.4
Catalytic Degradation of Lignocellulosic
Biomass
12
1.4
Conclusions
15
References
16
Chapter
2
Biocatarysis in Ionic Liquids
20
Roger A Sheldon
2.1
Introduction
20
2.2
Scenarios and Definitions
21
2.3
The First Examples of Biocatalysis in Ionic Liquid
Media
22
2.4
The Drivers for
Biotransformations in
ILs
24
2.5
Properties of Ionic Liquids: How Green Are They?
24
2.6
Activation and Stabilization of Enzymes in ILs
28
2.7
Selectivity Enhancements in ILs
31
2.8
Downstream Processing and Product Separation
34
2.9
Biotransformations
of Highly Polar Substrates such
as Carbohydrates
35
RSC Catalysis Series No.
15
Catalysis in Ionic Liquids: From Catalyst Synthesis to Application
Edited by Chris Hardacre and Vasile Parvulescu
φ
The Royal Society of Chemistry
2014
Published by the Royal Society of Chemistry, www.rsc.org
• ·
VII
viu
Contents
2.10
Conclusions and Future Outlook
38
References
39
Chapter
3
Homogeneous Catalysis in Ionic Liquids
44
Simon Doherty
3.1
Concepts, Principles and Practise
44
3.1.1
General Introduction
44
3.1.2
Catalyst Solubility and Ligand Substitution/
Abstraction in Ionic Liquids
46
3.1.3
Synthesis, Purification and Stability
47
3.1.4
Coordination and Non-Innocent Behaviour
of Ionic Liquids
50
3.1.5
Strategies in Ionic Liquid Catalysis
53
3.1.6
Ionic Liquid Effects
62
3.1.7
Catalysis in Microstructured Reactors and
Supports
68
3.1.8
Nomenclature
69
3.2
Applications of Ionic Liquids in Homogeneous
Carbonylation, Hydroformylation and Transition
Metal-Catalysed Cross-Coupling Catalysis
70
3.2.1
Carbonylations Involving Electrophiles
70
3.2.2
Hydroformylation
79
3.2.3
Transition Metal-Catalysed Cross-Coupling
in Ionic Liquid
89
3.3
Applications of Ionic Liquids in Homogeneous
Oxidation and
Hydrogénation
Catalysis
110
3.3.1
Oxidations
110
3.3.2
Hydrogénation
135
3.4
Lewis and Bronsted Acid Catalysis
161
3.4.1
Lewis Acid Catalysis
161
3.4.2
Catalysis Involving Bronsted Acid Ionic
Liquids
185
3.5
Organocatalysis, Metathesis, Ring Opening
Polymerisation and Dimerisation/Oligomerisation
198
3.5.1
Organocatalysis
198
3.5.2
Metathesis
211
3.5.3
Ring Opening Polymerisation
220
3.5.4
Dimerisation and Oligomerisation
224
3.6
Biomass Transformations and Catalysis with
Transition Metal Nanoparticles
233
3.6.1
Biomass Transformations
233
3.6.2
Catalysis with Transition Metal
Nanoparticles
248
Concluding Remarks
278
References
280
Contents ix
Chapter
4
Catalysis in Ionic Liquid-Supercritical CO2 Systems
309
Mark]. Muldoon
4.1
Introduction
309
4.2
Physicochemical Properties of IL-scCOa Systems
313
4.2.1
Phase Behaviour
313
4.2.2
Solubility of Other Gases
317
4.2.3
Solvent-Solute Interactions
317
4.2.4
Properties that Influence Mass Transport
319
4.2.5
Partition Coefficients
320
4.3
Illustrative Examples of Catalysis in IL-SCCO2
systems
322
4.3.1
Hydroformylation
322
4.3.2
Hydrogénation
326
4.3.3
Hydroviny
lation
331
4.3.4
Oxidation Reactions
331
4.3.5
Enzymatic Catalysis
334
4.3.6
Miscellaneous
338
4.4
Conclusions and Perspective
340
References
341
Chapter
5
Heterogeneous Catalysis in Ionic Liquids
345
Peter Goodrich, Christopher Hardacre and
Vasile I. Parvulescu
5.1
5.2
5.3
5.4
Introduction
345
Hydrogénation
Reactions
346
5.2.1
Solubility of Hydrogen in ILs and scCO2
Systems
347
5.2.2
Heterogeneous
Hydrogénation
Reactions
347
Dehydrogenation
362
Oxidation
362
5.4.1
Oxidation of Hydrocarbons
363
5.4.2
Oxidation of Alcohols
364
5.4.3
Selective Oxidation
366
5.4.4
Stereoselective Oxidation
367
5.4.5
Heterocyclic Compounds
367
5.4.6
Sulfoxidation
367
5.4.7
Epoxidation
369
5.5
Heterogeneous Carbon-Carbon Bond Formation
Employing Ionic Liquids
371
5.5.1
Supported Heck and Similar Carbon-Carbon
Bond Forming Reactions
371
5.5.2
Heterogeneous Friedel-Crafts Reactions in
Ionic Liquids
374
x
Contents
5.5.3 Asymmetrie
C-C
Bond Forming Reactions
375
5.5.4
Cyclopropanations
377
5.6
Conversion of CO2 into Valuable Compounds
378
5.6.1
Synthesis of Cyclic Carbonates
378
5.6.2
Hydrogénation
of CO2 to Formic Acid
381
5.7
Ionic Liquids in Valorization of Biomass
381
Conclusions
383
References
383
Chapter
6
Modification of Supports and Heterogeneous Catalysts by
Ionic Liquids: SILP and SCILL Systems
391
Peter
Claus
and Frederick Schwab
6.1
Introduction
391
6.2
Applications of SILP Systems
393
6.3
Applications of SCILL Systems
399
6.4
Applications of Other
IL
Systems
403
6.5
Understanding the Role of
IL
404
6.6
Conclusions
406
References
407
Chapter
7
SILP and SCILL Catalysis
410
Marco
Haumann
and Peter
Wasserscheid
7.1
Introduction
410
7.2
Support Texture Influence Exemplified for SILP
Hydroformylation Catalysis
415
7.3
Surface Acidity Exemplified for SILP
Hydroformylation Catalysis
416
7.4
Influence of Surface Reactivity in SILP Catalysis
418
7.5
Surface Wettability Exemplified for SILP
Hydroformylation Catalysis
423
7.6
Ionic Liquid Loading in SILP and SCILL Catalysis
425
7.7
Larger Scale Synthesis of SILP and SCILL Materials
427
References
429
Chapter
8
Etectrocatarysis in Ionic Liquids
433
Leigh Aldous, Asim Khan, Md. Mokarrom Hossain and
Chuan Zhao
8.1
Introduction
433
8.1.1
What is Electrocatalysis
434
8.1.2
Ionic Liquids and their Properties
438
8.1.3
Why might Ionic Liquids influence
Electrocatalysts
441
Contents xi
8.2
Examples of Electrocatalysis in Ionic Liquids
442
8.2.1
Hydrogen Evolution and Oxidation in Ionic
Liquids
443
8.2.2
Water Electrolysis in Association with
Ionic Liquids
448
8.2.3
Oxygen Reduction Reaction in
Ionic Liquids
452
8.2.4
Carbon Dioxide Reduction in
Ionic Liquids
456
8.2.5 Methanol,
Formic Acid and Carbon
Monoxide Oxidation in Ionic Liquids
458
8.2.6
Alkyl
and Aryl Halides
459
8.2.7
Application of Ionic Liquids in the Synthesis
of Electrocatalysts
460
8.2.8
Electrocatalysis in Electroanalytical Studies
Employing Ionic Liquids
462
8.3
Conclusions
465
References
466
Chapter
9
Photochemistry in Ionic Liquids
474
Hermenegildo
Garcia and Sergio Navalon
9.1
Definition
474
9.2
Polarity in ILs
474
9.3
Apoiar
Domains in ILs
476
9.4
Viscosity in ILs
477
9.5
Photochemical Stability of ILs
478
9.6
Primary Photochemical Events Upon Direct
Excitation of Imidazolium ILs
481
9.7
Photoluminescence
in ILs
483
9.8
Photo-Friedel-Crafts Acylation in ILs
485
9.9
Photochromism in ILs
486
9.10
Reversible Photoresponsive Films based
on ILs
489
9.11
Use of ILs as Solvents in Photochirogenesis
490
9.12
Photochemical Synthesis Using Singlet
Oxygen in ILs
495
9.13
Pollutant Degradation in ILs
497
9.14
Photochemical Generation of Noble and Transition
Metal Nanoparticles in ILs
498
9.15
Photochemistry of Gold Nanoparticles in ILs
501
9.16
Solar Fuels Using ILs
503
9.17
Conclusions and Future Prospects
503
References
504
Contents
Chapter
10 lonothermal
Synthesis
508
F.
H.
Aidoudi
and R. E. Morris
10.1
Introduction
508
10.2
Ionic Liquids—A Special Class of Molten Salts
509
10.2.1
Definition of Ionic Liquids
509
10.2.2
Modern Ionic Liquids versus Traditional
Molten Salts
509
10.2.3
Properties of Ionic Liquids
509
10.2.4
Deep Eutectic Solvents
510
10.3
Synthetic Methods for the Preparation of
Materials
511
10.3.1
Solid State Reactions
511
10.3.2
Synthesis in Solution
512
10.4 lonothermal
Synthesis of Zeolites
512
10.4.1
lonothermal Synthesis of
Aluminophosphates and Related
Structures
514
10.4.2
lonothermal Synthesis of Silicon and
Transition Metal-based Zeolites
514
10.5
lonothermal Synthesis of Metal-Organic
Frameworks
516
10.6
Extending lonothermal Synthesis for the
Preparation of Other Types of Materials
518
10.6.1
lonothermal Synthesis of Hybrid Metal
Fluorides
518
10.6.2
lonothermal Synthesis of Other Solids
520
10.7
lonothermal Synthesis and Microwaves
521
10.8
The Role of ILs in lonothermal Synthesis
of Materials
523
10.8.1
IL
Plays an Effective Role
523
10.8.2
ILs as Solvent Only
529
10.9
Effect of Water and Other Mineralisers
529
10.10
Conclusions and Perspectives
530
References
531
Chapter
11
Metal Nanoparticle Synthesis in Ionic Liquids
537
Christoph
Janiak
11.1
Introduction
537
11.2
Ionic Liquids (ILs)
539
11.3
Metal Nanoparticles and Ionic Liquids
541
11.4
Synthesis of Metal Nanoparticles in Ionic Liquids
544
11.4.1
Chemical Reduction
544
11.4.2
Photochemical Reduction
553
Contents
xiii
11.4.3
Sonochemical (Ultrasound) Reduction
554
11.4.4
Electrochemical) Reduction
554
11.4.5
Gas-Phase Synthesis
555
11.4.6
Metal Nanoparticles from Zero-Valent Metal
Precursors
558
11.5
Conclusions
569
Acknowledgements
569
References
569
Subject Index
578
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| isbn | 9781849736039 |
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| spelling | Catalysis in ionic liquids from catalyst synthesis to application ed. by Chris Hardacre ... Cambridge Royal Soc. of Chemistry 2014 XIII, 620 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier RSC catalysis series 15 Katalyse (DE-588)4029921-1 gnd rswk-swf Ionische Flüssigkeit (DE-588)7548899-1 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Ionische Flüssigkeit (DE-588)7548899-1 s Katalyse (DE-588)4029921-1 s DE-604 Hardacre, Chris Sonstige oth RSC catalysis series 15 (DE-604)BV035969664 15 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025957103&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Catalysis in ionic liquids from catalyst synthesis to application RSC catalysis series Katalyse (DE-588)4029921-1 gnd Ionische Flüssigkeit (DE-588)7548899-1 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)7548899-1 (DE-588)4143413-4 |
| title | Catalysis in ionic liquids from catalyst synthesis to application |
| title_auth | Catalysis in ionic liquids from catalyst synthesis to application |
| title_exact_search | Catalysis in ionic liquids from catalyst synthesis to application |
| title_full | Catalysis in ionic liquids from catalyst synthesis to application ed. by Chris Hardacre ... |
| title_fullStr | Catalysis in ionic liquids from catalyst synthesis to application ed. by Chris Hardacre ... |
| title_full_unstemmed | Catalysis in ionic liquids from catalyst synthesis to application ed. by Chris Hardacre ... |
| title_short | Catalysis in ionic liquids |
| title_sort | catalysis in ionic liquids from catalyst synthesis to application |
| title_sub | from catalyst synthesis to application |
| topic | Katalyse (DE-588)4029921-1 gnd Ionische Flüssigkeit (DE-588)7548899-1 gnd |
| topic_facet | Katalyse Ionische Flüssigkeit Aufsatzsammlung |
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