Photocatalysis and water purification: from fundamentals to recent applications
Gespeichert in:
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| Format: | Buch |
| Sprache: | English |
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Weinheim
Wiley-VCH
2013
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| Schriftenreihe: | Materials for Sustainable Energy and Development
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| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XXXI, 406 S. Ill., graph. Darst. |
| ISBN: | 9783527331871 |
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| 245 | 1 | 0 | |a Photocatalysis and water purification |b from fundamentals to recent applications |c ed. by Pierre Pichat |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2013 | |
| 300 | |a XXXI, 406 S. |b Ill., graph. Darst. | ||
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IMAGE 1
V I I
CONTENTS
SERIES EDITOR PREFACE XVII PREFACE X I X
ABOUT T H E SERIES EDITOR XXIII ABOUT T H E VOLUME EDITOR XXV LIST O F
CONTRIBUTORS XXVII
PART I FUNDAMENTALS: ACTIVE SPECIES, MECHANISMS, REACTION PATHWAYS 1
1 IDENTIFICATION AND ROLES O F T H E ACTIVE SPECIES GENERATED ON VARIOUS
PHOTOCATALYSTS 3 7 YOSHIO NOSAKA AND ATSUKO Y. NOSAKA
1.1 KEY SPECIES I N PHOTOCATALYTIC REACTIONS 3
1.2 TRAPPED ELECTRON A N D HOLE 6
1.3 SUPEROXIDE RADICAL A N D HYDROGEN PEROXIDE (OJ~ A N D H2O2) 7 1.4
HYDROXYL RADICAL (OH*) 9
1.5 SINGLET MOLECULAR OXYGEN ('02) 12
1.6 REACTION MECHANISMS FOR BARE I 1 O 2 15
1.7 REACTION MECHANISMS O F VISIBLE-LIGHT-RESPONSIVE PHOTOCATALYSTS 17
1.8 CONCLUSION 20
REFERENCES 21
2 PHOTOCATALYTIC REACTION PATHWAYS - EFFECTS O F MOLECULAR STRUCTURE,
CATALYST, AND WAVELENGTH 2 5 WILLIAM S. JENKS 2.1 INTRODUCTION 2 5
2.2 METHODS FOR PATHWAY DETERMINATION 2 7
2.3 PROTOTYPICAL OXIDATIVE REACTIVITY I N PHOTOCATALYTIC DEGRADATIONS 2
9 2.3.1 OXIDATION O F ARENES A N D THE IMPORTANCE O F ADSORPTION 3 0
2.3.1.1 HYDROXYLATION A N D THE SOURCE O F OXYGEN 3 0 2.3.1.2
RING-OPENING REACTIONS 32
HTTP://D-NB.INFO/1026137322
IMAGE 2
V I I I CONTENTS
2.3.1.3 INDICATORS O F SET VERSUS HYDROXYL CHEMISTRY I N AROMATIC
SYSTEMS 3 2
2.3.2 CARBOXYLIC ACIDS 3 5
2.3.3 ALCOHOL FRAGMENTATION A N D OXIDATION 36
2.3.4 OXIDATION O F ALKYL SUBSTITUENTS 37
2.3.5 APPARENT HYDROLYSIS REACTIONS 38
2.3.6 SULFUR-BEARING COMPOUNDS 39
2.4 PROTOTYPICAL REDUCTIVE REACTIVITY I N PHOTOCATALYTIC DEGRADATIONS 39
2.5 T H E USE O F ORGANIC MOLECULES AS TEST PROBES FOR NEXT-GENERATION
PHOTOCATALYSTS 41 2.6 MODIFIED CATALYSTS: WAVELENGTH-DEPENDENT CHEMISTRY
O F ORGANIC
PROBES 42
2.7 CONCLUSIONS 44
REFERENCES 45
3 PHOTOCATALYTIC MECHANISMS AND REACTION PATHWAYS DRAWN FROM KINETIC AND
PROBE MOLECULES 53 CLAUDIO MINERO, VALTER MAURINO, AND DAVIDE VIONE 3.1
THE PHOTOCATALYIC RATE 53
3.1.1 OTHER KINETIC MODELS 5 5
3.1.2 SUBSTRATE-MEDIATED RECOMBINATION 5 7
3.2 SURFACE SPECIATION 60
3.2.1 DIFFERENT COMMERCIAL CATALYSTS 60
3.2.2 SURFACE MANIPULATION 61
3.2.3 CRYSTAL FACES 62
3.2.4 SURFACE TRAPS FOR HOLES 64
3.3 MULTISITE KINETIC MODEL 65
3.4 CONCLUSION 68
REFERENCES 68
PART II IMPROVING T H E PHOTOCATALYTIC EFFICACY 73
4 DESIGN AND DEVELOPMENT O F ACTIVE TITANIA AND RELATED
PHOTOCATALYSTS 75 BUNSHO OHTANI
4.1 INTRODUCTION - A THERMODYNAMIC ASPECT O F PHOTOCATALYSIS 75
4.2 PHOTOCATALYTIC ACTIVITY: REEXAMINATION 77
4.3 DESIGN O F ACTIVE PHOTOCATALYSTS 78
4.4 A CONVENTIONAL KINETICS I N PHOTOCATALYSIS: FIRST-ORDER KINETICS 79
4.5 A CONVENTIONAL KINETICS I N PHOTOCATALYSIS: LANGMUIR-HINSHELWOOD
MECHANISM 80 4.6 TOPICS A N D PROBLEMS RELATED TO PARTICLE SIZE O F
PHOTOCATALYSTS 82
4.7 RECOMBINATION O F A PHOTOEXCITED ELECTRON A N D A POSITIVE HOLE 8 5
4.8 EVALUATION O F CRYSTALLINITY AS A PROPERTY AFFECTING PHOTOCATALYTIC
ACTIVITY 86
IMAGE 3
CONTENTS | I X
4.9 ELECTRON TRAPS AS A POSSIBLE CANDIDATE O F A RECOMBINATION CENTER 87
4.10 DONOR LEVELS - A MEANING O F N-TYPE SEMICONDUCTOR 89
4.11 DEPENDENCE O F PHOTOCATALYTIC ACTIVITIES O N PHYSICAL A N D
STRUCTURAL PROPERTIES 90
4.11.1 CORRELATION BETWEEN PHYSICAL PROPERTIES A N D PHOTOCATALYTIC
ACTIVITIES 90 4.11.2 STATISTICAL ANALYSIS O F CORRELATION BETWEEN
PHYSICAL PROPERTIES A N D PHOTOCATALYTIC ACTIVITIES - A TRIAL 92 4.11.3
C O M M O N FEATURES O F TITANIA PARTICLES WITH HIGHER PHOTOCATALYTIC
ACTIVITY 94
4.11.4 HIGHLY ACTIVE MESOSCOPIC ANATASE PARTICLES O F POLYHEDRAL SHAPE
95 4.12 SYNERGETIC EFFECT 96
4.13 DOPING 97
4.14 CONCLUSIVE REMARKS 98
ACKNOWLEDGMENTS 99 REFERENCES 99
5 MODIFIED PHOTOCATALYSTS 103
NURIT SHAHAM-WALDMANN AND YARON PAZ 5.1 WHY MODIFYING? 103
5.2 FORMS O F MODIFICATION 104
5.3 MODIFIED PHYSICOCHEMICAL PROPERTIES 106
5.3.1 CRYSTALLINITY A N D PHASE STABILITY 106
5.3.2 SURFACE MORPHOLOGY, SURFACE AREA, A N D ADSORPTION 107 5.3.3
ADSORPTION O F OXYGEN 111
5.3.4 CONCENTRATION O F SURFACE O H 111
5.3.5 SPECIFICITY 112
5.3.5.1 TI02 SURFACE OVERCOATING 115 5.3.5.2 COMPOSITES COMPRISED O F
TI02 A N D METALLIC NANOISLANDS 116 5.3.5.3 DOPING WITH METAL IONS A N D
OXIDES 116 5.3.5.4 UTILIZING THE "ADSORB A N D SHUTTLE" MECHANISM TO
OBTAIN
SPECIFICITY 117
5.3.5.5 MESOPOROUS MATERIALS 119 5.3.5.6 MOLECULAR IMPRINTING 120
5.3.6 PRODUCTS' CONTROL 122
5.3.6.1 SURFACE MODIFICATION BY MOLECULAR IMPRINTING 123 5.3.6.2
COMPOSITES COMPRISED O F T I 0 2 A N D METALLIC NANOISLANDS 124 5.3.6.3
DOPING WITH METAL IONS 124
5.3.6.4 NONMETALLIC COMPOSITE 125 5.3.6.5 TI02 MORPHOLOGY A N D
CRYSTALLINE PHASE 125 5.3.7 REDUCING DEACTIVATION 125
5.3.8 RECOMBINATION RATES A N D CHARGE SEPARATION 126 5.3.8.1 STRUCTURE
MODIFICATION 127 5.3.8.2 COMPOSITES-METAL ISLANDS 127 5.3.8.3 COMPOSITES
COMPRISING CARBONACEOUS MATERIALS 128
IMAGE 4
X I CONTENTS
5.3.8.4 COMPOSITES COMPOSED O F TIC 2 A N D NONOXIDE SEMICONDUCTORS 128
5.3.8.5 COMPOSITES COMPOSED O F T I 0 2 A N D OTHER OXIDES 129 5.3.8.6
DOPING WITH METALS 131
5.3.8.7 DOPING WITH NONMETALS 132
5.3.9 VISIBLE L I G H T ACTIVITY 132
5.3.10 CHARGING-DISCHARGING 132
5.3.11 MASS TRANSFER 133
5.3.12 FACILITATING PHOTOCATALYSIS I N DEAERATED SUSPENSIONS 134 SUMMARY
134 REFERENCES 134
6 IMMOBILIZATION O F A SEMICONDUCTOR PHOTOCATALYST ON SOLID SUPPORTS:
METHODS, MATERIALS, AND APPLICATIONS 145 DIDIER ROBERT, VALINE KELLER,
AND NICOLAS KELLER 6.1 INTRODUCTION 145
6.2 IMMOBILIZATION TECHNIQUES 147
6.3 SUPPORTS 152
6.3.1 PACKED-BED PHOTOCATALYTIC MATERIALS 153 6.3.2 MONOLITHIC
PHOTOCATALYTIC MATERIALS 155 6.3.3 OPTICAL FIBERS 164
6.4 LABORATORY A N D INDUSTRIAL APPLICATIONS O F SUPPORTED
PHOTOCATALYSTS 168 6.5 CONCLUSION 171
REFERENCES 172
7 WASTEWATER TREATMENT USING HIGHLY FUNCTIONAL IMMOBILIZED T I 0 2
THIN-FILM PHOTOCATALYSTS 179
MASAYA MATSUOKA, TAKASHI TOYAO, Y U HORIUCHI, MASATO TAKEUCHI, AND
MASAKAZU ANPO 7.1 INTRODUCTION 179
7.2 APPLICATION O F A CASCADE FALLING-FILM PHOTOREACTOR (CFFP) FOR T H E
REMEDIATION O F POLLUTED WATER A N D AIR U N D E R SOLAR LIGHT
IRRADIATION 180 7.3 APPLICATION O F TI02 THIN-FILM-COATED FIBERS FOR THE
REMEDIATION OF
POLLUTED WATER 184
7.4 APPLICATION O F TI02 T H I N FILM FOR PHOTOFUEL CELLS (PFC) 186
7.5 PREPARATION O F VISIBLE-LIGHT-RESPONSIVE T I 0 2 T H I N FILMS A N D
THEIR APPLICATION TO THE REMEDIATION O F POLLUTED WATER 187 7.5.1
VISIBLE-LIGHT-RESPONSIVE TI02 THIN FILMS PREPARED BY CATION OR ANION
DOPING 188
7.5.2 VISIBLE-LIGHT-RESPONSIVE TI02 THIN FILMS PREPARED BY THE MAGNETRON
SPUTTERING DEPOSITION METHOD 190 7.6 CONCLUSIONS 195
REFERENCES 195
IMAGE 5
CONTENTS I X I
8 SENSITIZATION O F TITANIA SEMICONDUCTOR: A PROMISING STRATEGY TO
UTILIZE
VISIBLE LIGHT 199 ZHAOHUI WANG, CHUNCHENG CHEN, WANHONG MA, AND JINCAI
ZHAO 8.1 INTRODUCTION 199
8.2 PRINCIPLE O F PHOTOSENSITIZATION 200
8.3 DYE SENSITIZATION 201
8.3.1 FUNDAMENTALS O F DYE SENSITIZATION 202
8.3.1.1 GEOMETRY A N D ELECTRONIC STRUCTURE O F INTERFACE 202 8.3.1.2
EXCITED-STATE REDOX PROPERTIES O F DYES 203 8.3.1.3 ELECTRON TRANSFER
FROM DYES TO T1O2 205 8.3.2 APPLICATION O F DYE SENSITIZATION 208
8.3.2.1 NONREGENERATIVE DYE SENSITIZATION 208 8.3.2.2 REGENERATIVE DYE
SENSITIZATION 211 8.4 POLYMER SENSITIZATION 213
8.4.1 CARBON NITRIDE POLYMER 213
8.4.2 CONDUCTING POLYMERS 214
8.5 SURFACE-COMPLEX-MEDIATED SENSITIZATION 214 8.5.1 ORGANIC LIGAND 215
8.5.2 INORGANIC LIGAND 217
8.6 SOLID SEMICONDUCTOR/METAL SENSITIZATION 218
8.6.1 SMALL-BAND-GAP SEMICONDUCTOR 219 8.6.1.1 BASIC CONCEPTS 219
8.6.1.2 CATEGORY IN TERMS O F CHARGE TRANSFER PROCESS 219 8.6.2
PLASMONIC METAL 222
8.6.2.1 BASIC CONCEPTS 222
8.6.2.2 PROPOSED MECHANISMS 224
8.6.2.3 CRITICAL PARAMETERS 225
8.7 OTHER STRATEGIES TO MAKE TITANIA VISIBLE LIGHT ACTIVE 226
8.7.1 BAND GAP ENGINEERING 226
8.7.1.1 METAL DOPING 226
8.7.1.2 NONMETAL DOPING 227
8.7.1.3 CODOPING 227
8.7.2 STRUCTURE/SURFACE ENGINEERING 228
8.8 CONCLUSIONS 230
ACKNOWLEDGMENT 231 REFERENCES 231
9 PHOTOELECTROCATALYSIS FOR WATER PURIFICATION 241
ROSSANO AMADELLI AND LUCA SAMIOLO 9.1 INTRODUCTION 241
9.2 PHOTOEFFECTS AT SEMICONDUCTOR INTERFACES 242
9.3 WATER DEPOLLUTION AT PHOTOELECTRODES 245
9.3.1 MORPHOLOGY A N D MICROSTRUCTURE 245
9.3.2 EFFECT O F APPLIED POTENTIAL 247
9.3.3 EFFECT O F P H 247
IMAGE 6
X I I | CONTENTS
9.3.4 EFFECT O F OXYGEN 248
9.3.5 ELECTROLYTE COMPOSITION 249
9.4 PHOTOELECTRODE MATERIALS 249
9.4.1 TITANIUM DIOXIDE 249
9.4.1.1 CATION DOPING 250
9.4.1.2 NONMETAL DOPING 250
9.4.2 OTHER SEMICONDUCTOR PHOTOELECTRODES 251 9.4.2.1 ZINC OXIDE A N D
IRON OXIDE 251
9.4.2.2 TUNGSTEN TRIOXIDE 251
9.4.2.3 BISMUTH VANADATE 251
9.4.3 COUPLED SEMICONDUCTORS 251
9.4.3.1 N - N HETEROJUNCTIONS 253
9.4.3.2 P - N HETEROJUNCTIONS 254
9.5 ELECTRODES PREPARATION A N D REACTORS 255
9.6 CONCLUSIONS 256
REFERENCES 257
PART III EFFECTS O F PHOTOCATALYSIS ON NATURAL ORGANIC MATTER AND
BACTERIA 271
10 PHOTOCATALYSIS O F NATURAL ORGANIC MATTER IN WATER: CHARACTERIZATION
AND TREATMENT INTEGRATION 273 SANLY LIU, MAY LIM AND ROSE AMAL 10.1
INTRODUCTION 273
10.2 MONITORING TECHNIQUES 274
10.2.1 TOTAL ORGANIC CARBON 275
10.2.2 UV-VIS SPECTROSCOPY 275
10.2.3 FLUORESCENCE SPECTROSCOPY 277 10.2.4 MOLECULAR SIZE FRACTIONATION
278
10.2.5 RESIN FRACTIONATION 280
10.2.6 INFRARED SPECTROSCOPY 280
10.3 BY-PRODUCTS FROM THE PHOTOCATALYTIC OXIDATION O F NOM A N D ITS
RESULTANT DISINFECTION BY-PRODUCTS (DBPS) 281 10.4 HYBRID PHOTOCATALYSIS
TECHNOLOGIES FOR THE TREATMENT O F NOM 284 10.5 CONCLUSIONS 287
REFERENCES 289
11 WATERBORNE ESCHERICHIA COLI INACTIVATION BY T I 0 2 PHOTOASSISTED
PROCESSES: A BRIEF OVERVIEW 295 JULIDN ANDRIS RENGIFO-HERRERA, ANGELA
GIOVANA RINCON, AND CESAR PULGARIN 11.1 INTRODUCTION 295
11.2 PHYSICOCHEMICAL ASPECTS AFFECTING THE PHOTOCATALYTIC E. COLI
INACTIVATION 296 11.2.1 EFFECT O F BULK PHYSICOCHEMICAL PARAMETERS 296
IMAGE 7
CONTENTS X I I I
11.2.1.1 EFFECT O F TIC 2 CONCENTRATION A N D LIGHT INTENSITY 296
11.2.1.2 SIMULTANEOUS PRESENCE O F ANIONS A N D ORGANIC MATTER 297
11.2.1.3 P H INFLUENCE 298
11.2.1.4 OXYGEN CONCENTRATION 298 11.2.2 PHYSICOCHEMICAL CHARACTERISTICS
O F TI02 299 11.3 USING O F N-DOPED T 1 O 2 I N PHOTOCATALYTIC
INACTIVATION O F WATERBORNE MICROORGANISMS 299
11.4 BIOLOGICAL ASPECTS 302
11.4.1 INITIAL BACTERIAL CONCENTRATION 302 11.4.2 PHYSIOLOGICAL STATE O
F BACTERIA 302 11.5 PROPOSED MECHANISMS SUGGESTED FOR BACTERIA ABATEMENT
BY HETEROGENEOUS TI02 PHOTOCATALYSIS 303
11.5.1 EFFECT O F UV-A LIGHT ALONE A N D I 1 O 2 I N THE DARK 303
11.5.2 CELL INACTIVATION BY IRRADIATED TI02 NANOPARTICLES 304 11.6
CONCLUSION 304
REFERENCES 305
PART IV MODELING. REACTORS. PILOT PLANTS 311
12 PHOTOCATALYTIC TREATMENT O F WATER: IRRADIANCE INFLUENCES 313 DAVID
OLLIS 12.1 INTRODUCTION 313
12.1.1 CHAPTER TOPICS 313
12.1.2 PHOTON UTILIZATION EFFICIENCY 313 12.2 REACTION ORDER I N
IRRADIANCE: INFLUENCE O F ELECTRON-HOLE RECOMBINATION A N D THE H I G H
IRRADIANCE PENALTY 314 12.3 LANGMUIR-HINSHELWOOD (LH) KINETIC FORM:
EQUILIBRATED
ADSORPTION 315
12.4 PSEUDO-STEADY-STATE ANALYSIS: NONEQUILIBRATED ADSORPTION 317 12.5
MASS TRANSFER A N D DIFFUSION INFLUENCES AT STEADY CONDITIONS 321 12.6
CONTROLLED PERIODIC ILLUMINATION: ATTEMPT TO BEAT
RECOMBINATION 323
12.7 SOLAR-DRIVEN PHOTOCATALYSIS: NEARLY CONSTANT N U V IRRADIANCE 324
12.8 MECHANISM O F HYDROXYL RADICAL ATTACK: SAME IRRADIANCE DEPENDENCE
326 12.9 SIMULTANEOUS HOMOGENEOUS A N D HETEROGENEOUS
PHOTOCHEMISTRY 327
12.10 DYE-PHOTOSENSITIZED AUTO-OXIDATION 328 12.11 INTERPLAY BETWEEN
FLUID RESIDENCE TIMES A N D IRRADIANCE PROFILES 329 12.11.1 BATCH
REACTORS 329
12.11.2 FLOW REACTORS 329
12.12 Q U A N T U M YIELD, PHOTONIC EFFICIENCY, A N D ELECTRICAL ENERGY
PER ORDER 331
IMAGE 8
X I V I CONTENTS
12.13 CONCLUSIONS 332
REFERENCES 332
13 A METHODOLOGY FOR MODELING SLURRY PHOTOCATALYTIC REACTORS FOR
DEGRADATION O F AN ORGANIC POLLUTANT IN WATER 335 ORLANDO M. ALFANO,
ALBERTO E. CASSANO, RODOLFO J. BRANDI, AND MANIA L. SATUF 13.1
INTRODUCTION A N D SCOPE 335
13.2 EVALUATION O F THE OPTICAL PROPERTIES O F AQUEOUS T I 0 2 S U S P E
N S I O N S 337
13.2.1 SPECTROPHOTOMETRIC MEASUREMENTS O F TI02 SUSPENSIONS 338 13.2.2
RADIATION FIELD IN THE SPECTROPHOTOMETER SAMPLE CELL 339 13.2.3
PARAMETER ESTIMATION 341
13.3 RADIATION MODEL 342
13.3.1 EXPERIMENTAL SET U P A N D PROCEDURE 343
13.3.2 RADIATION FIELD INSIDE THE PHOTOREACTOR 344 13.4 Q U A N T U M
EFFICIENCIES O F 4-CHLOROPHENOL PHOTOCATALYTIC DEGRADATION 346 13.4.1
CALCULATION O F THE Q U A N T U M EFFICIENCY 346 13.4.2 EXPERIMENTAL
RESULTS 347
13.5 KINETIC MODELING O F THE POLLUTANT PHOTOCATALYTIC DEGRADATION 348
13.5.1 MASS BALANCES 348
13.5.2 KINETIC MODEL 349
13.5.3 KINETIC PARAMETERS ESTIMATION 350
13.6 BENCH-SCALE SLURRY PHOTOCATALYTIC REACTOR FOR DEGRADATION OF
4-CHLOROPHENOL 352 13.6.1 EXPERIMENTS 352
13.6.2 REACTOR MODEL 352
13.6.2.1 RADIATION MODEL 352
13.6.2.2 REACTION RATES 354
13.6.2.3 MASS BALANCES I N THE TANK A N D REACTOR 354 13.6.3 RESULTS 355
13.7 CONCLUSIONS 356
ACKNOWLEDGMENTS 357 REFERENCES 3 5 7
14 DESIGN AND OPTIMIZATION O F PHOTOCATALYTIC WATER PURIFICATION
REACTORS 362 TSUYOSHI OCHIAI AND AKIRA FUJISHIMA 14.1 INTRODUCTION 361
14.1.1 MARKET TRANSITION O F INDUSTRIES RELATED TO PHOTOCATALYSIS 361
14.1.2 HISTORICAL OVERVIEW 361
14.2 CATALYST IMMOBILIZATION STRATEGY 363
14.2.1 AQUEOUS SUSPENSION 363
14.2.2 IMMOBILIZATION O F TI02 PARTICLES ONTO SOLID SUPPORTS 365
IMAGE 9
CONTENTS | X V
14.3 SYNERGISTIC EFFECTS O F PHOTOCATALYSIS A N D OTHER METHODS 366
14.3.1 DEPOSITION O F METALLIC NANOPARTICLES ONTO TIC 2 SURFACE FOR
DISINFECTION 366 14.3.2 COMBINATION WITH ADVANCED OXIDATION PROCESSES
(AOPS) 3 6 7 14.4 EFFECTIVE DESIGN O F PHOTOCATALYTIC REACTOR SYSTEM 369
14.4.1 TWO MAIN STRATEGIES FOR THE EFFECTIVE REACTORS 369
14.4.2 DESIGN OFTOTAL SYSTEM 371
14.5 FUTURE DIRECTIONS A N D CONCLUDING REMARKS 372
ACKNOWLEDGMENTS 373 REFERENCES 373
15 SOLAR PHOTOCATALYTIC PILOT PLANTS: COMMERCIALLY AVAILABLE REACTORS
377 SIXTO MALATO, PILAR FERNDNDEZ-IBDNEZ, MANEIL IGNACIO MALDONADO,
ISABEL OILER, AND MARIA INMACULADA POLO-LOPEZ 15.1 INTRODUCTION 3 7 7
15.2 COMPOUND PARABOLIC CONCENTRATORS 379
15.3 TECHNICAL ISSUES: REFLECTIVE SURFACE A N D PHOTOREACTOR 382 15.4
SUSPENDED OR SUPPORTED PHOTOCATALYST 386
15.5 SOLAR PHOTOCATALYTIC TREATMENT PLANTS 388
15.6 SPECIFIC ISSUES RELATED WITH SOLAR PHOTOCATALYTIC DISINFECTION 390
15.7 CONCLUSIONS 394
ACKNOWLEDGMENTS 395 REFERENCES 395
INDEX 399 |
| any_adam_object | 1 |
| author2 | Pichat, Pierre |
| author2_role | edt |
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| author_facet | Pichat, Pierre |
| building | Verbundindex |
| bvnumber | BV040936302 |
| classification_rvk | AR 22362 UM 4500 VE 7040 VE 8300 VN 9360 |
| classification_tum | UMW 360f CHE 189f |
| ctrlnum | (OCoLC)840903349 (DE-599)DNB1026137322 |
| dewey-full | 628.166 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 628 - Sanitary engineering |
| dewey-raw | 628.166 |
| dewey-search | 628.166 |
| dewey-sort | 3628.166 |
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| discipline | Chemie / Pharmazie Allgemeines Physik Chemie Bauingenieurwesen Umwelt |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV040936302 |
| illustrated | Illustrated |
| indexdate | 2024-08-21T00:40:49Z |
| institution | BVB |
| isbn | 9783527331871 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025915156 |
| oclc_num | 840903349 |
| open_access_boolean | |
| owner | DE-384 DE-11 DE-91G DE-BY-TUM DE-29T DE-92 |
| owner_facet | DE-384 DE-11 DE-91G DE-BY-TUM DE-29T DE-92 |
| physical | XXXI, 406 S. Ill., graph. Darst. |
| publishDate | 2013 |
| publishDateSearch | 2013 |
| publishDateSort | 2013 |
| publisher | Wiley-VCH |
| record_format | marc |
| series2 | Materials for Sustainable Energy and Development |
| spelling | Photocatalysis and water purification from fundamentals to recent applications ed. by Pierre Pichat Weinheim Wiley-VCH 2013 XXXI, 406 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Materials for Sustainable Energy and Development Fotokatalyse (DE-588)4193873-2 gnd rswk-swf Wasseraufbereitung (DE-588)4064698-1 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Fotokatalyse (DE-588)4193873-2 s Wasseraufbereitung (DE-588)4064698-1 s DE-604 Pichat, Pierre edt X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4126139&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025915156&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Photocatalysis and water purification from fundamentals to recent applications Fotokatalyse (DE-588)4193873-2 gnd Wasseraufbereitung (DE-588)4064698-1 gnd |
| subject_GND | (DE-588)4193873-2 (DE-588)4064698-1 (DE-588)4143413-4 |
| title | Photocatalysis and water purification from fundamentals to recent applications |
| title_auth | Photocatalysis and water purification from fundamentals to recent applications |
| title_exact_search | Photocatalysis and water purification from fundamentals to recent applications |
| title_full | Photocatalysis and water purification from fundamentals to recent applications ed. by Pierre Pichat |
| title_fullStr | Photocatalysis and water purification from fundamentals to recent applications ed. by Pierre Pichat |
| title_full_unstemmed | Photocatalysis and water purification from fundamentals to recent applications ed. by Pierre Pichat |
| title_short | Photocatalysis and water purification |
| title_sort | photocatalysis and water purification from fundamentals to recent applications |
| title_sub | from fundamentals to recent applications |
| topic | Fotokatalyse (DE-588)4193873-2 gnd Wasseraufbereitung (DE-588)4064698-1 gnd |
| topic_facet | Fotokatalyse Wasseraufbereitung Aufsatzsammlung |
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