Activation and transformation of n-alkanes and n-alkene in zeolites:
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| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
2012
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| Subjects: | |
| Online Access: | Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121203-1113168-1-4 Inhaltsverzeichnis |
| Physical Description: | VII, 111 Bl. graph. Darst. |
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| 245 | 1 | 0 | |a Activation and transformation of n-alkanes and n-alkene in zeolites |c Lin Lin |
| 264 | 1 | |c 2012 | |
| 300 | |a VII, 111 Bl. |b graph. Darst. | ||
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| 337 | |b n |2 rdamedia | ||
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| 650 | 0 | 7 | |a Zeolith |0 (DE-588)4067660-2 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Alkane |0 (DE-588)4191827-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Alkene |0 (DE-588)4001207-4 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
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| 689 | 0 | 2 | |a Alkene |0 (DE-588)4001207-4 |D s |
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Record in the Search Index
| _version_ | 1804150209799782400 |
|---|---|
| adam_text | IMAGE 1
TABLE O F CONTENTS
TABLE OF CONTENTS
ACKNOWLEDGMENTS I
ABSTRACT ILL
TABLE OF CONTENTS IV
CHAPTER 1
1. INTRODUCTION 2
1.1 GENERAL INTRODUCTION 2
1.2 ADSORPTION OF ALIPHATIC HYDROCARBON IN ZEOLITES 4
1.3 MECHANISM OF ALKANE AND ALKENE CRACKING 7
1.3.1 PROTOLYTIC CRACKING OF ALKANE 7
1.3.2 CRACKING OF ALKENES . 9
1.3.3 ALKANE DEHYDROGENATION 12
1.4 CATALYTIC ACTIVITY OF PROTOLYTIC CRACKING 13
1.4.1 CONCENTRATING THE REACTANTS 14
1.4.2 ROLE OF PORE STRUCTURE 15
1.4.3 ROLE OF ACID PROPERTIES 17
1.5 SCOPE OF THE THESIS 18
1.6 REFERENCES 21
CHAPTER 2
2. INFLUENCE OF TRANSITION ENTHALPY AND ENTROPY ON THE PROTOLYTIC
CRACKING OF ALKANE 2 2
IV
HTTP://D-NB.INFO/1034627112
IMAGE 2
TABLE O F CONTENTS
2.1 INTRODUCTION 26
2.2 METHODS 29
2.2.1 CATALYST TREATMENT 29
2.2.2 KINETIC MEASUREMENT OF MONOMOLECULAR ALKANE ACTIVATION 30
2.2.3 KINETIC MODELS IN THERMODYNAMICALLY NONIDEAL SYSTEM OF ZEOLITE 31
2.3 RESULTS AND DISCUSSION 34
2.3.1 MONOMOLECULAR ACTIVATION ON H-ZSM-5 SAMPLES IN THE INDIVIDUAL
REACTION PATHWAYS 34
2.3.2 EFFECTS OF SI TO AL RATIO IN SAMPLES ON KINETICS OF MONOMOLECULAR
C3-C6
PARAFFINS CRACKING 46
2.4 CONCLUSIONS 48
2.5 APPENDIX 49
2.6 REFERENCES 50
CHAPTER 3
3. TRANSITION STATE CONSIDERATION IN PROTOLYTIC CRACKING ON STEAMED
H-ZSM-5 53
3.1 INTRODUCTION 55
3.2 METHODS 56
3.2.1 CATALYSTS PREPARATION BY STEAMING TREATMENT 56
3.2.2 POWDER X-RAY DIFFRACTION (XRD) 57
3.2.3 INFRARED SPECTROSCOPY OF ADSORBED PYRIDINE 57
3.2.4 27 AI MASNMR 58
3.2.5 KINETIC MEASUREMENT OF N-PENTANE ACTIVATION 58
V
IMAGE 3
TABLE O F CONTENTS
3.3 RESULTS 59
3.3.1 CATALYSTS CHARACTERIZATION 59
3.3.2 KINETIC MEASUREMENT 64
3.4 DICUSSION 65
3.5 CONCLUSIONS 72
3.6 REFERENCES 74
CHAPTER 4
4. MECHANISTIC CONSEQUENCE OF REACTION INTERMEDIATES IN ACID-
CATALYSIS BY ZEOLITES: KINETIC STUDIES OF 1-PENTENE CRACKING 78
4.1 INTRODUCTION 80
4.2 EXPERIMENTAL 81
4.2.1 CATALYSTS PREPARATION AND CHARACTERIZATION 81
4.2.2 1-PENTENE CONVERSION ON H-ZSM-5 82
4.3 RESULTS 83
4.3.1 REACTION PATHWAYS IN ACTIVATION OF 1-PENTENE 83
4.3.2 KINETIC STUDIES OF MONOMOLECULAR AND OLIGOMERIZATION-CRACKING 88
4.3.3 CATALYST DECAY 90
4.4 DISCUSSION 92
4.4.1 MECHANISTIC IMPLICATIONS FOR KINETICS IN MONOMOLECULAR CRACKING 92
4.4.2 TEMPERATURE DEPENDENCE OF THE REACTION RATE IN
OLIGOMERIZATION-CRACKING... 99
4.4.3 CATALYSTS DEACTIVATION BEHAVIOR 100
4.5 CONCLUSIONS 101
4.6 APPENDIX DERIVATION OF RATE EXPRESSION FOR OLIGOMERIZATION-CRACKING
102
VI
IMAGE 4
TABLE O F CONTENTS
4.7 REFERENCES 103
CHAPTERS
5. SUMMARY AND CONCLUSIONS 106
CURRICULUM VITAE 110
LIST OF PUBLICATIONS I L L
VII
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| spelling | Lin, Lin Verfasser aut Activation and transformation of n-alkanes and n-alkene in zeolites Lin Lin 2012 VII, 111 Bl. graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 2012 Zeolith (DE-588)4067660-2 gnd rswk-swf Alkane (DE-588)4191827-7 gnd rswk-swf Alkene (DE-588)4001207-4 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Zeolith (DE-588)4067660-2 s Alkane (DE-588)4191827-7 s Alkene (DE-588)4001207-4 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:91-diss-20121203-1113168-1-4 http://mediatum.ub.tum.de/node?id=1113168 Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121203-1113168-1-4 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025895768&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Lin, Lin Activation and transformation of n-alkanes and n-alkene in zeolites Zeolith (DE-588)4067660-2 gnd Alkane (DE-588)4191827-7 gnd Alkene (DE-588)4001207-4 gnd |
| subject_GND | (DE-588)4067660-2 (DE-588)4191827-7 (DE-588)4001207-4 (DE-588)4113937-9 |
| title | Activation and transformation of n-alkanes and n-alkene in zeolites |
| title_auth | Activation and transformation of n-alkanes and n-alkene in zeolites |
| title_exact_search | Activation and transformation of n-alkanes and n-alkene in zeolites |
| title_full | Activation and transformation of n-alkanes and n-alkene in zeolites Lin Lin |
| title_fullStr | Activation and transformation of n-alkanes and n-alkene in zeolites Lin Lin |
| title_full_unstemmed | Activation and transformation of n-alkanes and n-alkene in zeolites Lin Lin |
| title_short | Activation and transformation of n-alkanes and n-alkene in zeolites |
| title_sort | activation and transformation of n alkanes and n alkene in zeolites |
| topic | Zeolith (DE-588)4067660-2 gnd Alkane (DE-588)4191827-7 gnd Alkene (DE-588)4001207-4 gnd |
| topic_facet | Zeolith Alkane Alkene Hochschulschrift |
| url | http://mediatum.ub.tum.de/node?id=1113168 https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20121203-1113168-1-4 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025895768&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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