Understanding advanced physical inorganic chemistry: the learner's approach
Written for students taking either the University of Cambridge A-level examinations or the International Baccalaureate examinations, this textbook covers essential topics under both stipulated chemistry syllabi. It is written in such a way as to guide the reader through the understanding and applica...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New Jersey [u.a.]
World Scientific
2011
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Zusammenfassung: | Written for students taking either the University of Cambridge A-level examinations or the International Baccalaureate examinations, this textbook covers essential topics under both stipulated chemistry syllabi. It is written in such a way as to guide the reader through the understanding and applications of essential chemical concepts by introducing a discourse feature-the asking and answering of questions-that stimulates coherent thinking and hence, elucidates ideas. Based on the Socratic Method, questions are implanted throughout the book to help facilitate the reader's development in forming logical conclusions of concepts. The book helps students to master fundamental chemical concepts in a simple way. --Back Cover |
| Beschreibung: | Hier auch später erschienene, unveränderte Nachdrucke. - Includes index |
| Beschreibung: | XV, 472 S. graph. Darst. 23 cm |
| ISBN: | 9789814317269 |
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| 520 | |a Written for students taking either the University of Cambridge A-level examinations or the International Baccalaureate examinations, this textbook covers essential topics under both stipulated chemistry syllabi. It is written in such a way as to guide the reader through the understanding and applications of essential chemical concepts by introducing a discourse feature-the asking and answering of questions-that stimulates coherent thinking and hence, elucidates ideas. Based on the Socratic Method, questions are implanted throughout the book to help facilitate the reader's development in forming logical conclusions of concepts. The book helps students to master fundamental chemical concepts in a simple way. --Back Cover | ||
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Datensatz im Suchindex
| _version_ | 1804150191031320576 |
|---|---|
| adam_text | Titel: Understanding advanced physical inorganic chemistry
Autor: Dericks-Tan, Jeanne S. E
Jahr: 2011
Contents
Preface v
Acknowledgements vii
1. Atomic Structure and the Periodic Table 1
1.1 The Subatomic Particles of Matter.............. 1
1.1.1 Behaviour in an electric field/magnetic field .... 1
1.1.2 Isotopes........................ 3
1.1.3 Relative masses of an element............ 4
1.2 Orbitals and Quantum Numbers............... 6
1.2.1 The nature of electron................ 6
1.2.2 Shapes of orbitals................... 10
1.3 Electronic Configurations................... 12
1.3.1 Rules used in working out electronic
configuration..................... 12
1.3.2 Electronic configuration of transition elements . . . 15
1.3.3 Anomalous electronic configurations........ 16
1.4 Ionisation Energies....................... 16
1.4.1 Factors influencing the magnitude of ionisation
energies........................ 17
1.5 Periodic Table: Trend in Ionisation Energy......... 22
1.6 Periodic Table: Trend in Atomic Radii............ 24
2. Chemical Bonding 29
2.1 Metallic Bonding........................ 29
2.1.1 Physical properties of metals ............ 30
2.2 Ionic Bonding (or Electrovalent Bonding).......... 31
2.2.1 Guidelines for drawing dot-and-cross diagrams ... 34
2.2.2 Physical properties of ionic Compounds....... 35
x Understanding Advanced Physical Inorganic Chemistry
2.3 Covalent Bonding....................... 39
2.3.1 Covalent bond formation............... 40
2.3.2 Dative covalent bond (coordinate bond)...... 42
2.3.3 Factors affecting strength of covalent bond..... 44
2.3.4 Shapes of molecules ? The VSEPR model..... 46
2.3.5 Using the Hybridisation Model to understand
shape.......................... 52
2.3.6 Delocalised bonding/resonance........... 56
2.4 Intermediate Bond Types................... 58
2.4.1 Covalent character in ionic bonds.......... 58
2.4.2 Ionic character in covalent bonds.......... 60
2.5 Physical Properties of Covalent Compounds......... 62
2.5.1 Properties of giant covalent Compounds ...... 62
2.5.2 Properties of simple covalent Compounds...... 64
2.6 Intermolecular Forces of Attraction ............. 64
2.6.1 Instantaneous dipole-induced dipole (id-id)
interactions...................... 65
2.6.2 Permanent dipole-permanent dipole (pd-pd)
interactions...................... 67
2.6.3 Hydrogen bonding.................. 70
2.7 Summary of Chemical Bonding: Putting it all
Together............................ 74
3. Ideal Gas and Gas Laws 81
3.1 Gas Laws............................ 82
3.1.1 Boyle s law ...................... 82
3.1.2 Charles law...................... 83
3.1.3 Gay-Lussac s law................... 84
3.1.4 Avogadro s law.................... 84
3.1.5 The ideal gas law................... 88
3.1.6 Further manipulations of the ideal gas
equation........................ 90
3.1.7 Dalton s Law of Partial Pressure.......... 91
3.1.8 Types of mathematical problems involving the gas
laws.......................... 95
3.2 Kinetic Theory of Gases.................... 96
3.2.1 Graphical plots representing ideal behaviour .... 97
3.2.2 Deviation from ideal gas behaviour......... 100
3.2.3 Nature of gas..................... 103
Contents xi
4. Chemical Thermodynamics 109
4.1 Energy Changes in Chemical Reactions........... 110
4.1.1 Standard enthalpy changes.............. 113
4.1.2 Calculating enthalpy changes from experimental
data.......................... 117
4.1.3 Calculation of enthalpy changes using
Hess Law....................... 122
4.1.4 Constructing energy cycles.............. 123
4.1.5 Born-Haber cycle and Hess law........... 127
4.1.6 Constructing Born-Haber cycles .......... 129
4.1.7 Energetics involving aqueous ionic Compounds ... 133
4.2 Entropy............................. 135
4.2.1 What is entropy?................... 137
4.2.2 Factors affecting entropy of a chemical System . . . 138
4.2.3 Predicting the spontaneity of a reaction...... 141
4.2.4 Relationship between AG^, A#e, ASe
and temperature................... 142
5. Reaction Kinetics 147
5.1 Qualitative Analysis of Reaction Rates ........... 147
5.1.1 Factors affecting reaction rates........... 150
5.2 Quantitative Analysis of Reaction Rates........... 155
5.2.1 Rate of reaction.................... 155
5.2.2 The rate equation (Rate law)............ 159
5.2.3 Experimental methods used to determine order of
reaction........................ 164
5.3 Rate Equation and Reaction Mechanism........... 182
5.4 Transition State Theory.................... 184
5.5 Catalysis............................ 187
5.5.1 Homogeneous catalysis................ 187
5.5.2 Heterogeneous catalysis ............... 188
5.5.3 Autocatalysis..................... 190
5.5.4 Enzymes (biological catalysts)............ 191
6. Chemical Equilibria 197
6.1 Reversible Reactions...................... 197
6.2 Equilibrium Systems...................... 199
6.3 Equilibrium Constants Kc and Kp.............. 200
xii Understanding Advanced Physical Inorganic Chemistry
6.3.1 Writing Kc or Kp for heterogeneous equilibria . . . 204
6.3.2 Calculations involving Kc..............205
6.3.3 Calculations involving Kp..............208
6.4 Le Chatelier s Principle....................211
6.4.1 Effect of concentration changes...........211
6.4.2 Effect of pressure changes..............214
6.4.3 Effect of temperature changes............220
6.4.4 Effect of temperature changes on the value of the
equilibrium constant.................222
6.4.5 Effect of catalyst...................223
6.5 The Haber Process.......................226
7. Ionic Equilibria 231
7.1 The Br0nsted-Lowry Theory of Acids and Bases......232
7.2 Conjugate Acid-Base Pairs..................234
7.3 The pH Scale..........................234
7.4 The Dissociation Constant of Water, Kw..........235
7.5 Strength of Acids .......................240
7.6 Acid Dissociation Constant Ka and pKa...........241
7.7 Strength of Bases .......................246
7.8 Base Dissociation Constant K^ and pifb ..........247
7.9 Complementary Strengths of a Conjugate
Acid-Base Pair.........................249
7.10 Hydration and Hydrolysis...................251
7.10.1 Classifying type of salt based on strengths of acid
and base that form it.................253
7.10.2 Hydrolysis of high charge density cations .....255
7.11 Buffer Solutions........................256
7.11.1 How does an acidic buffer work...........256
7.11.2 How does an alkaline buffer work..........258
7.11.3 The role of buffer in Controlling pH in blood .... 259
7.11.4 Calculating pH of buffer Solutions..........260
7.12 Acid-Base Indicators .....................263
7.13 Acid-Base Titrations .....................266
7.13.1 Titration curve of a strong acid-strong base
titration........................268
7.13.2 Titration curve of a weak acid-strong base
titration........................269
Contents xiii
7.13.3 Titration curve of a strong acid weak base
titration........................276
7.13.4 Titration curve of a weak acid-weak base
titration........................278
7.13.5 Titration curve of a polybasic acid-strong base
titration........................280
7.13.6 Titration curve of a carbonate?strong acid
titration (Double-Indicator Method)........281
7.13.7 Titration curve of a mixture of weak acids ?
strong base titration.................286
7.13.8 Back-titration ....................288
7.14 Solubility Product Ksp ....................290
7.14.1 Solubility and Ksp ..................291
7.14.2 Ionic product and Ksp................293
7.14.3 Common ion effect..................295
7.14.4 Solubility in qualitative analysis...........297
Redox Chemistry and Electrochemical Cells 303
8.1 Rules for Assignment of Oxidation States..........307
8.2 Balancing Redox Equations..................310
8.3 Redox Titrations........................313
8.3.1 Manganate(VII) titrations..............314
8.3.2 Dichromate(VI) titrations..............315
8.3.3 Iodine-thiosulfate titrations.............316
8.4 Redox Reactions and Electricity...............318
8.4.1 Electrode potential.................. 319
8.4.2 Experimental set-up of half-cells .......... 322
8.4.3 Information obtained from the Standard electrode
potential........................ 325
8.4.4 Describing cell components using conventional
notation........................ 328
8.4.5 Calculating Standard cell potential......... 330
8.4.6 Using £^.ellto predict feasibility of a reaction . . . 332
8.4.7 Effect of concentration changes on £^.ellvalue . . . 335
8.4.8 Effect of ligands on ^?value............ 337
8.5 Types of Electrochemical Cells................ 338
8.6 Electrolysis........................... 341
8.6.1 Faraday s laws of electrolysis ............ 342
xiv Understanding Advanced Physical Inorganic Chemistry
8.6.2 Selective discharge of ions............345
8.6.3 Industrial uses of electrolysis ..........347
9. The Periodic Table ? Chemical Periodicity 357
9.1 Atomic Structure and Period 3 Elements..........359
9.1.1 Trend in atomic radius..............359
9.1.2 Trend in ionic radius...............361
9.1.3 Trend in first ionisation energy (Ist I.E.) .... 362
9.1.4 Trend in electronegativity............363
9.2 Structure, Bonding and Period 3 Elements.........364
9.2.1 Variation in melting points and boiling
points.......................364
9.2.2 Variation in electrical conductivity.......365
9.3 Oxides and Chlorides of Period 3 Elements........366
9.3.1 Oxides of Period 3 elements...........369
9.3.2 Chlorides of Period 3 elements .........373
10. Chemistry of Groups 2 and 7 381
10.1 Atomic Structure and Group Trends............381
10.1.1 Trend in atomic radius..............381
10.1.2 Trend in ionic radius...............382
10.1.3 Trend in Ist LE..................382
10.1.4 Trend in electron affinity.............382
10.1.5 Trend in electronegativity............383
10.1.6 Trend in metallic character...........383
10.2 Physical Properties of Group 2 Elements..........384
10.3 Chemical Properties of Group 2 Elements.........384
10.3.1 Reaction with water...............386
10.3.2 Reaction with oxygen ..............387
10.4 Thermal Stability of Group 2 Compounds.........387
10.5 Some Uses of Group 2 Elements and Their
Compounds..........................391
10.6 Properties of Beryllium...................391
10.7 Solubility of Group 2 Compounds..............394
10.8 Physical Properties of Group 7 Elements..........397
10.8.1 Melting point, boiling point and volatility . . . 397
10.8.2 Colour.......................398
10.8.3 Solubility in water................399
10.8.4 Solubility in organic solvent...........399
Contents xv
10.8.5 Trend in bond energy ..............400
10.9 Chemical Properties of Group 7 Elements.........400
10.9.1 Displacement reaction of halogens .......402
10.9.2 Reaction with thiosulfate ............403
10.9.3 Reaction with alkali ...............406
10.9.4 Reaction with hydrogen.............408
10.10 Hydrogen Halides.......................409
10.10.1 Thermal stability of hydrogen halides......410
10.10.2 Acidity of hydrogen halides...........411
10.10.3 Reaction of halides with concentrated acid . . .411
10.10.4 Distinguishing tests for halide ions.......413
10.11 Industrial Uses and Environmental Impact of Group 7
Elements and Their Compounds..............415
10.11.1 Fluorine and its Compounds...........415
10.11.2 Chlorine and its Compounds...........415
10.11.3 Bromine and its Compounds...........415
11. Introduction to Transition Metals and Their Chemistry 421
11.1 Writing Electronic Configuration..............422
11.2 Physical Properties of Transition Metals..........425
11.2.1 Trend in atomic radius..............425
11.2.2 Trend in ionic radius...............426
11.2.3 Trend in first ionisation energy.........427
11.2.4 Trend in melting and boiling points.......428
11.2.5 Trend in electrical conductivity.........429
11.2.6 Trend in density .................429
11.3 Chemical Properties of Transition Metals.........430
11.3.1 Variable oxidation states............. 430
11.3.2 Catalytic properties ............... 434
11.3.3 Formation of complexes............. 437
11.3.4 The property of colour.............. 444
11.3.5 Ligand exchange reactions............ 451
11.3.6 Selected reactions of some transition metals
and their Compounds...............458
Index 465
|
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| spelling | Tan, Jeanne Verfasser aut Understanding advanced physical inorganic chemistry the learner's approach Jeanne Tan ; Kim Seng Chan New Jersey [u.a.] World Scientific 2011 XV, 472 S. graph. Darst. 23 cm txt rdacontent n rdamedia nc rdacarrier Hier auch später erschienene, unveränderte Nachdrucke. - Includes index Written for students taking either the University of Cambridge A-level examinations or the International Baccalaureate examinations, this textbook covers essential topics under both stipulated chemistry syllabi. It is written in such a way as to guide the reader through the understanding and applications of essential chemical concepts by introducing a discourse feature-the asking and answering of questions-that stimulates coherent thinking and hence, elucidates ideas. Based on the Socratic Method, questions are implanted throughout the book to help facilitate the reader's development in forming logical conclusions of concepts. The book helps students to master fundamental chemical concepts in a simple way. --Back Cover Physical inorganic chemistry Anorganische Chemie (DE-588)4002145-2 gnd rswk-swf Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Physikalische Chemie (DE-588)4045959-7 s Anorganische Chemie (DE-588)4002145-2 s DE-604 Chan, Kim Seng Verfasser aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025886064&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Tan, Jeanne Chan, Kim Seng Understanding advanced physical inorganic chemistry the learner's approach Physical inorganic chemistry Anorganische Chemie (DE-588)4002145-2 gnd Physikalische Chemie (DE-588)4045959-7 gnd |
| subject_GND | (DE-588)4002145-2 (DE-588)4045959-7 (DE-588)4123623-3 |
| title | Understanding advanced physical inorganic chemistry the learner's approach |
| title_auth | Understanding advanced physical inorganic chemistry the learner's approach |
| title_exact_search | Understanding advanced physical inorganic chemistry the learner's approach |
| title_full | Understanding advanced physical inorganic chemistry the learner's approach Jeanne Tan ; Kim Seng Chan |
| title_fullStr | Understanding advanced physical inorganic chemistry the learner's approach Jeanne Tan ; Kim Seng Chan |
| title_full_unstemmed | Understanding advanced physical inorganic chemistry the learner's approach Jeanne Tan ; Kim Seng Chan |
| title_short | Understanding advanced physical inorganic chemistry |
| title_sort | understanding advanced physical inorganic chemistry the learner s approach |
| title_sub | the learner's approach |
| topic | Physical inorganic chemistry Anorganische Chemie (DE-588)4002145-2 gnd Physikalische Chemie (DE-588)4045959-7 gnd |
| topic_facet | Physical inorganic chemistry Anorganische Chemie Physikalische Chemie Lehrbuch |
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