Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element:
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| Main Author: | |
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| Format: | Thesis Book |
| Language: | English |
| Published: |
2011
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| Subjects: | |
| Online Access: | Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20111214-1084664-1-1 Inhaltsverzeichnis |
| Physical Description: | XII, 244 S. graph. Darst. |
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| 100 | 1 | |a Siggelkow, Lisa |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element |c Lisa Siggelkow |
| 264 | 1 | |c 2011 | |
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Record in the Search Index
| _version_ | 1804150166559653888 |
|---|---|
| adam_text | IMAGE 1
CONTENTS
1 INTRODUCTION 1
1.1 MOTIVATION 1
1.2 CLASSES O F INTERMETALLIC AND POLAR INTERMETALLIC COMPOUNDS 2
1.2.1 HEUSLER AND HALF-HEUSLER PHASES 3
1.2.2 HUME-ROTHERY PHASES 4
1.2.3 LAVES PHASES 4
1.2.4 ZINTL PHASES 5
1.2.5 POLAR INTERMETALLIC COMPOUNDS 7
1.3 SCOPE AND OUTLINE O F THIS WORK 8
1.4 REFERENCES 10
2 EXPERIMENTAL SECTION 15
2.1 SYNTHESIS 15
2.1.1 ELEMENTS USED F O R SYNTHESIS 15
2.1.2 DISTILLATION O F THE ALKALINE EARTH METALS 15
2.1.3 SYNTHESIS 18
2.2 X-RAY DIFFRACTION STUDIES AND STRUCTURE REFINEMENT 24
2.2.1 POWDER X-RAY DIFFRACTION ANALYSIS 24
2.2.2 SINGLE CRYSTAL X-RAY DIFFRACTION ANALYSIS 25
2.3 SCANNING ELECTRON MICROSCOPY (SEM) AND 26
ENERGY DISPERSIVE X-RAY SPECTROSCOPY (EDX)
2.4 DIFFERENTIAL THERMAL ANALYSIS (DTA) 26
2.5 MAGNETIC MEASUREMENTS 26
2.6 COMPUTATIONAL METHODS 27
2.7 REFERENCES 29
HTTP://D-NB.INFO/1034283987
IMAGE 2
IV
CONTENTS
3 RESULTS AND DISCUSSION 31
3.1 OUTLINE 31
3.2 BINARY INTERMETALLIC PHASES IN THE SYSTEMS AE/TT (AE: SR, BA; TT:
GE, SN) 31
3.2.1 SRJGEF, BAJGES AND BAJSRI2 31
3.3 POLAR INTERMETALLIC PHASES IN THE SYSTEMS AE! NI/GE (AE: MG, CA, SR,
BA) 33
3.3. J BANI}GE AND CAJNIJGEI 34
3.3.2 BA 2NI5GE4 36
3.3.3 CANISGEJ, CAISNI68GE}J ANDCAJNI4GGE22 3 8
3.3.4 LAVES PHASES IN THE SYSTEM MG/NI/GE 40
3.3.5 NICKEL GERMANIDES O F ALKALINE EARTH METALS 42
- STRUCTURAL PECULIARITIES AND RELATIONSHIPS
3.4 POLAR INTERMETALLIC PHASES IN THE SYSTEMS CA/CO/SI AND BA/CO/GE 45
3.4.1 CACO2SI2 AND BACO2GE2 45
3.5 POLAR INTERMETALLIC PHASES IN THE SYSTEMS ^E/NI/SN (AE: MG, CA) 46
3.5.1 CA 2NISN2 46
3.5.2 MGO.39(2)NISNI,6I(2 )OND MG 2.6I(2)NUSN3,3G(2) 49
3.6 CONCLUSION 51
3.7 REFERENCES 53
4 PUBLICATIONS 55
4.1 LIST OF PUBLICATIONS 55
4.2 BINARY INTERMETALLIC PHASES IN THE SYSTEMS AE/TT (AE: SR, BA; TT:
GE, SN) 57
4.2.1 SR 7GE6, BAJGE6 AND BA3SN2 - THREE NEW BINARY COMPOUNDS
CONTAINING DUMBBELLS AND FOUR-MEMBERED CHAINS O F TETREL ATOMS
WITH CONSIDERABLE GE-GE RE-BONDING CHARACTER
4.3 POLAR INTERMETALLIC PHASES IN THE SYSTEMS ^E/NI/GE (AE: MG, CA, SR,
BA) 107
4.3.1 BANI2GE AND CA4NI4GE}- TWO LAYERED STRUCTURES WITH 2 M[NI2GEJ 107
AND 2 JNI4GE3] NETWORKS
4.3.2 SYNTHESIS, STRUCTURE AND CHEMICAL BONDING O F BA2NI;GE4 - AN 111
INTERMETALLIC COMPOUND WITH A NEW TWO-DIMENSIONAL 2 A3[NISGEJ
STRUCTURAL MOTIF
IMAGE 3
CONTENTS
V
4.3.3 COMPLEX LNTERMETALLIC COMPOUNDS: CANI;GE;, GAISNU&EN AND 113
CAYNIIGGEA - THREE MULTIFACETED NI-GE FRAMEWORK STRUCTURES
COMBINING THE STRUCTURAL MOTIFS OFNI^GE AND CANI2GE2
4.3.4 LAVES PHASES IN THE SYSTEM MG/NI/GE 117
4.3.5 NICKEL GERMANIDES O F A IKALINE EARTH METALS 143
- STRUCTURAL PECULIARITIES AND RELATIONSHIPS
4.4 POLAR LNTERMETALLIC PHASES IN THE SYSTEMS CA/CO/SI AND BA/CO/GE 203
4.4.1 SYNTHESIS, STRUCTURE AND CHEMICAL BONDING O F CACOISI2 AND 203
BACO2GE2 - TWO NEW COMPOUNDS WITH THCR2SI2 STRUCTURE TYPE
4.5 POLAR LNTERMETALLIC PHASES IN THE SYSTEMS J4E/NI/SN (AE: MG, CA) 209
4.5.1 CA2NISN 2 - A POLYMORPHIC LNTERMETALLIC PHASE: ATOMIC AND 209
ELECTRONIC STRUCTURE AS WELL AS A TOPOLOGICAL DESCRIPTION O F THE
PHASE TRANSITION BY A SIGMATROPIC-TYPE REARRANGEMENT OFNI AND
SN ATOMS
4.5.2 MGO.39(2)NISNI,6I(2) AND MG2_6I(2)NI4SNS.39(2) - TWO NEW
LNTERMETALLIC 211
PHASES IN THE SYSTEM MG/NI/SN
5 APPENDIX 237
ORGANISATION OF THIS WORK
THIS WORK IS COMPOSED AS A PAPER STYLE THESIS. THE CONTENT IS ORGANIZED
AS FOLLOWS:
* CHAPTER 1: INTRODUCTION TO THE TOPIC OF INTERMETALLICS AND POLAR
INTERMETALLIC
COMPOUNDS.
* CHAPTER 2: DETAILS ON THE EMPLOYED EXPERIMENTAL AND COMPUTATIONAL
METHODS.
* CHAPTER 3: SUMMARY OF ALL RESULTS OF THIS THESIS.
* CHAPTER 4: PUBLICATIONS. THESE FORM THE MAIN BODY OF THIS THESIS. IF
ALREADY
PUBLISHED, THE CORRESPONDING BIBLIOGRAPHIC CITATION AND, IF NECESSARY,
AN ADDITIONAL
APPENDIX IS GIVEN. THE MANUSCRIPTS IN PREPARATION FOR SUBMISSION ARE
EMBEDDED
AND FOLLOWED BY THE CORRESPONDING SUPPORTING INFORMATION.
* CHAPTER 5: GENERAL APPENDIX.
|
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| spelling | Siggelkow, Lisa Verfasser aut Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element Lisa Siggelkow 2011 XII, 244 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 2011 Intermetallische Verbindungen (DE-588)4162028-8 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Intermetallische Verbindungen (DE-588)4162028-8 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:91-diss-20111214-1084664-1-1 http://mediatum.ub.tum.de/node?id=1084664 Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20111214-1084664-1-1 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025862487&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Siggelkow, Lisa Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element Intermetallische Verbindungen (DE-588)4162028-8 gnd |
| subject_GND | (DE-588)4162028-8 (DE-588)4113937-9 |
| title | Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element |
| title_auth | Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element |
| title_exact_search | Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element |
| title_full | Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element Lisa Siggelkow |
| title_fullStr | Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element Lisa Siggelkow |
| title_full_unstemmed | Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element Lisa Siggelkow |
| title_short | Synthesis, characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal - transition metal - tetrel element |
| title_sort | synthesis characterization and computational studies of binary and ternary intermetallic compounds in the systems alkaline earth metal transition metal tetrel element |
| topic | Intermetallische Verbindungen (DE-588)4162028-8 gnd |
| topic_facet | Intermetallische Verbindungen Hochschulschrift |
| url | http://mediatum.ub.tum.de/node?id=1084664 https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20111214-1084664-1-1 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025862487&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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