Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries: investigations of limiting factors of electrolytes
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| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
2012
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | VI, 209 S. graph. Darst. |
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| 100 | 1 | |a Schmitz, Raphael Wilhelm |d 1983- |e Verfasser |0 (DE-588)1027091202 |4 aut | |
| 245 | 1 | 0 | |a Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries |b investigations of limiting factors of electrolytes |c vorgelegt von Raphael Wilhelm Schmitz |
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Record in the Search Index
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| adam_text | TABLE OF CONTENTS
ACKNOWLEDGEMENT ILL
ABSTRACT V
TABLE OF CONTENTS 1
1 GREENER FUTURE 5
2 THE BATTERY 7
2.1 PRIMARY BATTERY 7
2.2 SECONDARY BATTERY 8
2.2.1 LITHIUM-ION BATTERY 8
3 COMPONENTS OF LITHIUM-ION ACCUMULATORS 10
3.1 ANODE MATERIALS 10
3.2 ELECTROLYTE SOLUTIONS - AND THEIR PHYSICAL PROPERTIES 14
3.3 SOLVENTS 16
3.4 LITHIUM SALTS 18
3.4.1 THE MATTER OF THERMAL AGING 20
3.5 SOLID ELECTROLYTE INTERPHASE (SEI) 25
3.6 CATHODE MATERIALS 26
3.7 INTERFACE BETWEEN ELECTROLYTE AND ELECTRODE
1251
28
4 MEASUREMENT TECHNIQUES 31
4.1 CONDUCTIVITY 31
4.2 CONDUCTIVITY VERSUS MOBILITY 32
4.3 PERFORMANCE IN A LITHIUM-ION BATTERY CELL TEST 35
4.3.1 CONSTANT CURRENT CHARGE / DISCHARGE 35
4.3.2 POTENTIOSTATIC CYCLING - CYCLIC VOLTAMMETRY AND ESW
11281
38
4.4 SPECTROSCOPIC METHODS 40
4.4.1 INFRARED SPECTROSCOPY 40
1 I
HTTP://D-NB.INFO/1033850330
4.4.2 FOURIER TRANSFORMATION INFRARED (FTIR) SPECTROSCOPY 42
4.5 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY 44
4.6 X-RAY PHOTOELECTRON SPECTROSCOPY (XPS)
[139]
46
5 EXPERIMENTAL 48
5.1 MEASUREMENT INSTRUMENTS 48
5.2 CYCLIC VOLTAMMETRY AND ESW 48
5.3 CONSTANT CURRENT CYCLING AND CYCLIC VOLTAMMETRY 49
5.3.1 CELL SETUP 49
5.3.2 TESTING PROCEDURE OF CONSTANT CURRENT/POTENTIOSTATIC CYCLING 50
5.3.3 TESTING PROCEDURE OF CYCLIC VOLTAMMETRY 51
5.3.4 ELECTROCHEMICAL STABILITY WINDOW 51
5.4 CONDUCTIVITY 52
5.5 IN SITU FTIR 52
5.6 IN SITU RAMAN SPECTROSCOPY 54
5.7 GAS CHROMATOGRAPHY COMBINED WITH MASS SPECTROMETRY (GC-MS) 55
5.8 XPS MEASUREMENTS 55
5.9 CHEMICALS 55
5.10 ELECTROLYTE AND ELECTRODE PREPARATION 57
5.11 THERMAL AGING BY NMR 58
6 RESULTS & DISCUSSION 60
6.1 AGING INVESTIGATIONS TOWARDS MORE THERMALLY STABLE ELECTROLYTES 60
6.1.1 THERMAL AGING OF 1M LIPF
6
IN EC:DEC (3:7) -RESULTS AND DISCUSSION 61
6.1.2 INVESTIGATIONS OF BORON SALT BASED ELECTROLYTES - RESULTS AND
DISCUSSION 65
6.1.3 DFOB SYNTHESIS BY USING THE EQUILIBRIUM 73
6.1.4 SUMMARY - AGING INVESTIGATIONS TOWARDS MORE THERMALLY STABLE
ELECTROLYTES 74
6.2 NEW LITHIUM SALTS FOR
BATTERY ELECTROLYTES 76
6.3 LITHIUM-L,L,2
;
2
;
-TETRAFLUORO-2-METHOXY-ETHANESUFONATE (LITFMES - LIB-7) 77
6.3.1 CONDUCTIVITY MEASUREMENTS & ELECTROCHEMICAL STABILITY WINDOWS 79
_
6.3.2 CONSTANT CURRENT CYCLING 82
6.3.3 XPS SURFACE ANALYSIS OF CYCLED CELLS 113
6.3.4 SUMMARY - NEW SALTS FOR
LITHIUM-ION BATTERIES: LIB-7 123
6.4 LITHIUM-L
;
2
;
2,2-TETRAFLUORO-L-(TRIFLUOROMETHOXY)-ETHANESULFONATE (LITFES - LIB-8)
127
6.4.1 CONDUCTIVITY & ELECTROCHEMICAL STABILITY WINDOW 128
6.4.2 CONSTANT CURRENT CYCLING 130
6.4.3 SUMMARY - NEW SALTS FOR
LITHIUM-ION BATTERIES: LIB-8 153
6.5 INVESTIGATION OF THE OXIDATIVE POLYMERIZATION MECHANISM OF VC 156
6.5.1 THEORY OF VC AND PC DECOMPOSITION 156
6.5.2 SUMMARY - OXIDATION OF VINYLENE CARBONATE 178
7 SUMMARY 181
8 APPENDIX 190
9 LITERATURE 201
10 CURRICULUM VITAE 207
3 I
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| id | DE-604.BV040671661 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:28:46Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025498214 |
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| physical | VI, 209 S. graph. Darst. |
| publishDate | 2012 |
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| spelling | Schmitz, Raphael Wilhelm 1983- Verfasser (DE-588)1027091202 aut Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries investigations of limiting factors of electrolytes vorgelegt von Raphael Wilhelm Schmitz 2012 VI, 209 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Münster, Univ., Diss., 2012 Elektrolyt (DE-588)4151826-3 gnd rswk-swf Elektrode (DE-588)4014247-4 gnd rswk-swf Lithiumbatterie (DE-588)4167901-5 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Lithiumbatterie (DE-588)4167901-5 s Elektrode (DE-588)4014247-4 s Elektrolyt (DE-588)4151826-3 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025498214&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Schmitz, Raphael Wilhelm 1983- Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries investigations of limiting factors of electrolytes Elektrolyt (DE-588)4151826-3 gnd Elektrode (DE-588)4014247-4 gnd Lithiumbatterie (DE-588)4167901-5 gnd |
| subject_GND | (DE-588)4151826-3 (DE-588)4014247-4 (DE-588)4167901-5 (DE-588)4113937-9 |
| title | Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries investigations of limiting factors of electrolytes |
| title_auth | Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries investigations of limiting factors of electrolytes |
| title_exact_search | Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries investigations of limiting factors of electrolytes |
| title_full | Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries investigations of limiting factors of electrolytes vorgelegt von Raphael Wilhelm Schmitz |
| title_fullStr | Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries investigations of limiting factors of electrolytes vorgelegt von Raphael Wilhelm Schmitz |
| title_full_unstemmed | Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries investigations of limiting factors of electrolytes vorgelegt von Raphael Wilhelm Schmitz |
| title_short | Investigations of processes at the electrode/electrolyte interface in Lithium-ion batteries |
| title_sort | investigations of processes at the electrode electrolyte interface in lithium ion batteries investigations of limiting factors of electrolytes |
| title_sub | investigations of limiting factors of electrolytes |
| topic | Elektrolyt (DE-588)4151826-3 gnd Elektrode (DE-588)4014247-4 gnd Lithiumbatterie (DE-588)4167901-5 gnd |
| topic_facet | Elektrolyt Elektrode Lithiumbatterie Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025498214&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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